scholarly journals Complementary Use of Magnetometric Measurements for Geochemical Investigation of Light REE Concentration in Anthropogenically Polluted Soils

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 457
Author(s):  
Piotr Fabijańczyk ◽  
Jarosław Zawadzki
Keyword(s):  
Soil Samples ◽  
Soil Conditions ◽  
Soil Cores ◽  
Light Rare Earth ◽  
Polluted Soils ◽  
Chemical Measurements ◽  
Geochemical Investigation ◽  
Light Rare Earth Elements ◽  
Soil Magnetic Susceptibility ◽  
Geophysical Measurements

The purpose of this study was to use fast geophysical measurements of soil magnetic susceptibility (κ) as supplementary data for chemical measurements of selected light rare earth elements (REEs) in soil. In order to ensure diversity in soil conditions, anthropogenic conditions and types of land use, seven areas were selected, all located in regions subjected to past or present industrial pollution. Magnetometric parameters were measured using a selected magnetic sensor that was specially designed for measurements of soil cores and were used to classify collected soil cores into six distinctive types. The analysis of REEs concentrations in soil was carried out taking into account the grouping of collected soil samples based on the type of study area (open, forested and mountain), and additionally on the measured magnetometric parameters of collected soil cores. A use of magnetometric measurements provided different, but complementary to chemical measurements information, which allowed to obtain deeper insight on REEs concentrations in soils in studied areas.

scholarly journals Behavior of Eucalyptus grandis and E. cloeziana seedlings grown in arsenic-contaminated soil

2010 ◽  
Vol 34 (3) ◽  
pp. 985-992 ◽  
Author(s):  
Roseli Freire Melo ◽  
Luiz Eduardo Dias ◽  
Jaime Wilson Vargas de Mello ◽  
Juraci Alves Oliveira
Keyword(s):  
Root System ◽  
Plant Height ◽  
Contaminated Soil ◽  
Dry Matter ◽  
Eucalyptus Grandis ◽  
Soil Samples ◽  
Mining Activities ◽  
Polluted Soils ◽  
Interveinal Chlorosis ◽  
Apical Bud

Arsenic has been considered the most poisonous inorganic soil pollutant to living creatures. For this reason, the interest in phytoremediation species has been increasing in the last years. Particularly for the State of Minas Gerais, where areas of former mining activities are prone to the occurrence of acid drainage, the demand is great for suitable species to be used in the revegetation and "cleaning" of As-polluted areas. This study was carried out to evaluate the potential of seedlings of Eucalyptus grandis (Hill) Maiden and E. cloeziana F. Muell, for phytoremediation of As-polluted soils. Soil samples were incubated for a period of 15 days with different As (Na2HAsO4) doses (0, 50, 100, 200, and 400 mg dm-3). After 30 days of exposure the basal leaves of E. cloeziana plants exhibited purple spots with interveinal chlorosis, followed by necrosis and death of the apical bud at the 400 mg dm-3 dose. Increasing As doses in the soil reduced root and shoot dry matter, plant height and diameter in both species, although the reduction was more pronounced in E. cloeziana plants. In both species, As concentrations were highest in the root system; the highest root concentration was found in E. cloeziana plants (305.7 mg kg-1) resulting from a dose of 400 mg dm-3. The highest As accumulation was observed in E. grandis plants, which was confirmed as a species with potential for As phytoextraction, tending to accumulate As in the root system and stem.

scholarly journals The use of N HNO3 to determine copper and zinc levels in heavy-metal polluted tropical soils

2021 ◽  
Vol 905 (1) ◽  
pp. 012001
Author(s):  
A K Salam ◽  
M Milanti ◽  
G Silva ◽  
F Rachman ◽  
I M T D Santa ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Tropical Soils ◽  
Correlation Study ◽  
Relative Strength ◽  
Soil Samples ◽  
Water Spinach ◽  
Polluted Soils ◽  
Chemical Extractants ◽  
Soil Zn ◽  
Zinc Levels

Abstract This study compared N HNO3 to other methods to determine plant available heavy metals in heavy-metal polluted soils. Soil samples were obtained from an experimental field treated with industrial waste after 22 years of the amendment and employed to conduct the comparative and correlation study. Soil samples were analyzed for Cu using various methods, planted in a glass house with several plants, and analyzed for soil and plant Cu and Zn. The relative strength of the chemical extractants followed the order of N HNO3 ≈ N HCl > Buffered DTPA ≈ Unbuffered DTPA > M CaCl2 ≈ N NH4OAc pH 7. A high correlation was observed for soil extracted Cu by M CaCl2 or N NH4OAc pH 7 or N HCl vs. Buffered DTPA and N HNO3 or N NH4OAc pH 7 vs. N HCl. High correlations of plant and soil Cu extracted by N HNO3 were shown by caisim, water spinach, land spinach, and corn, while plant and soil Zn were shown by caisim, water spinach, land spinach, and lettuce.

scholarly journals Draft Requirement of Two Animal - Drawn Institute for Agricultural Research (IAR) Weeders

2020 ◽  
pp. 14-20
Author(s):  
Y. A. Unguwanrimi ◽  
A. M. Sada ◽  
G. N. Ugama ◽  
H. S. Garuba ◽  
A. Ugoani
Keyword(s):  
Soil Moisture ◽  
Moisture Content ◽  
Bulk Density ◽  
Soil Moisture Content ◽  
Agricultural Research ◽  
Soil Samples ◽  
Soil Conditions ◽  
Experimental Plot ◽  
Moisture Contents ◽  
Loam Soil

Draft requirements of two animal – drawn (IAR) weeders operating on loam soil were determined in the study. The implements include a straddle row weeder and an emcot attached rotary weeder evaluated under the same soil conditions, using a pair of white Fulani breed of oxen. The animal draft requirement was first estimated from the animal ergonomics measurements. Using area of 0.054 hectare as experimental plot for each implement the draft requirement of each implement was investigated after taking soil samples for soil moisture content and bulk density determinations. The implements tested showed variation in their average draft requirement. The straddle row weeder had the highest value of 338.15 N respectively while the emcot attached rotary weeder had the lowest value of 188.12 N with 47.03%, respectively. The average soil moisture contents and bulk density were 13.0% and 1.46%/cm3, respectively.

Depletion of light rare-earth elements in felsic magmas

Geology ◽  
1982 ◽  
Vol 10 (3) ◽  
pp. 129 ◽  
Author(s):  
Calvin F. Miller ◽  
David W. Mittlefehldt
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Light Rare Earth ◽  
Light Rare Earth Elements

Recycling and substitution of light rare earth elements, cerium, lanthanum, neodymium, and praseodymium from end-of-life applications - A review

2019 ◽  
Vol 236 ◽  
pp. 117573 ◽  
Author(s):  
Linda Omodara ◽  
Satu Pitkäaho ◽  
Esa-Matti Turpeinen ◽  
Paula Saavalainen ◽  
Kati Oravisjärvi ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
End Of Life ◽  
Light Rare Earth ◽  
Light Rare Earth Elements

Significance of the metasomatized lithospheric mantle in the formation of early basalts and Cu – platinum group element sulfide mineralization in the Coldwell Complex, Midcontinent Rift, Canada

2019 ◽  
Vol 56 (7) ◽  
pp. 693-714 ◽  
Author(s):  
David J. Good ◽  
Peter C. Lightfoot
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Trace Element ◽  
Lithospheric Mantle ◽  
Group Element ◽  
Light Rare Earth ◽  
Midcontinent Rift ◽  
Northern Margin ◽  
Lithospheric Mantle Source ◽  
Light Rare Earth Elements

A diverse suite of tholeiitic to alkaline basalt and gabbroic intrusions located in the Coldwell Complex on the northern margin of the Midcontinent Rift exhibit unusual trace element signatures that show enriched large ion lithophile elements and light rare earth elements with negative Nb and Zr anomalies. These features are not typical of magmas derived by partial melting within or above a rising mantle plume, as might be expected in an early Midcontinent Rift magmatic event. In this paper, we provide a detailed geochemical study of a 500 m thick sequence of metabasalt that represents the earliest stage of magmatism in the Coldwell Complex. We show that contamination or crystallization processes or subsequent metasomatism cannot explain the trace element variations. Instead, we propose partial melting in a metasomatized Subcontinental Lithospheric Mantle source to explain the decoupled behavior of large ion lithophile elements from light rare earth elements and heavy rare earth elements and rare earth elements from high field strength elements and the enriched Nd isotope signature of metabasalt. Similar features occur in unit 5b of the Mamainse Point Volcanic Group located at the northern margin of the Rift. An objective of this paper is to relate Two Duck Lake gabbro, host rock for low-sulfur, high precious metal sulfide mineralization at the Marathon deposit, to the metabasalt sequence. The excellent match of trace element abundances in Two Duck Lake gabbro to metabasalt unit 3 confirms an early Coldwell Complex age for metabasalt and a Subcontinental Lithospheric Mantle source for Cu – platinum group element mineralized gabbros.

scholarly journals Biosorption of lanthanum and samarium by chemically modified free Bacillus subtilis cells

2019 ◽  
Vol 9 (8) ◽  
Author(s):  
Ellen C. Giese ◽  
Caio S. Jordão
Keyword(s):  
Bacillus Subtilis ◽  
Waste Treatment ◽  
Physiological Activity ◽  
Lanthanide Ions ◽  
Aquatic Environments ◽  
Light Rare Earth ◽  
Chemically Modified ◽  
Langmuir Isotherm Model ◽  
Light Rare Earth Elements ◽  
Very High

Abstract Previous studies showed that Bacillus subtilis possessed high physiological activity in industrial waste treatment as a biosorbent for recovery metals, and in this study, the sorption capacity for both La3+ and Sm3+ was demonstrated. The effects of lanthanide concentration and contact time were tested to acid and alkali pre-treated cells. Very high levels of removal, reaching up to 99% were obtained for both lanthanide ions. Langmuir isotherm model was applied to describe the adsorption isotherm and indicated a better correlation with experimental data R2 = 0.84 for La3+ using sodium hydroxide pre-treated free cells and R2 = 0.73 for Sm3+ to acid pre-treated B. subtilis cells as biosorbents. Results of this study indicated that chemically modified B. subtilis cells are a very good candidate for the removal of light rare-earth elements from aquatic environments. The process is feasible, reliable, and eco-friendly.

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