scholarly journals Water-Tree Resistability of UV-XLPE from Hydrophilicity of Auxiliary Crosslinkers

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4147
Author(s):  
Jun-Qi Chen ◽  
Xuan Wang ◽  
Wei-Feng Sun ◽  
Hong Zhao
Keyword(s):  
Molecular Simulation ◽  
Amorphous Phase ◽  
Viscoelastic Properties ◽  
Binary Systems ◽  
Interaction Parameters ◽  
Water Molecules ◽  
Stress Strain ◽  
Mixing Energy ◽  
Water Tree ◽  
Tree Resistance

The water-resistant characteristics of ultraviolet crosslinked polyethylene (UV-XLPE) are investigated specially for the dependence on the hydrophilicities of auxiliary crosslinkers, which is significant to develop high-voltage insulating cable materials. As auxiliary crosslinking agents of polyethylene, triallyl isocyanurate (TAIC), trimethylolpropane trimethacrylate (TMPTMA), and N,N′-m-phenylenedimaleimide (HAV2) are individually adopted to prepared XLPE materials with the UV-initiation crosslinking technique, for the study of water-tree resistance through the accelerating aging experiments with water blade electrode. The stress–strain characteristics and dynamic viscoelastic properties of UV-XLPE are tested by the electronic tension machine and dynamic thermomechanical analyzer. Monte Carlo molecular simulation is used to calculate the interaction parameters and mixing energy of crosslinker/water binary systems to analyze the compatibility between water and crosslinker molecules. Water-tree experiments verify that XLPE-TAIC represents the highest ability to inhibit the growth of water-trees, while XLPE-HAV2 shows the lowest resistance to water-trees. The stress–strain and viscoelastic properties show that the concentration of molecular chains connecting the adjacent lamellae in amorphous phase of XLPE-HAV2 is significantly higher than that of XLPE-TAIC and XLPE-TMPTMA. The molecular simulation results demonstrate that TAIC/water and TMPTMA/water binary systems possess a higher hydrophilicity than that of HAV2/water, as manifested by their lower interaction parameters and mixing free energies. The auxiliary crosslinkers can not only increase the molecular density of amorphous polyethylene between lamellae to inhibit water-tree growth, but also prevent water molecules at insulation defects from agglomerating into micro-water beads by increasing the hydrophilicity of auxiliary crosslinkers, which will evidently reduce the damage of micro-water beads on the amorphous phase in UV-XLPE. The better compatibility of TAIC and water molecules is the dominant reason accounting for the excellent water resistance of XLPE-TAIC.

scholarly journals Water-Tree Resistant Characteristics of Crosslinker-Modified-SiO2/XLPE Nanocomposites

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1398
Author(s):  
Yong-Qi Zhang ◽  
Xuan Wang ◽  
Ping-Lan Yu ◽  
Wei-Feng Sun
Keyword(s):  
Electric Fields ◽  
Tree Growth ◽  
Mechanical Analysis ◽  
Water Molecules ◽  
Crosslinking Degree ◽  
Water Tree ◽  
Tree Resistance ◽  
Alternating Electric Fields ◽  
Trimethylolpropane Triacrylate ◽  
Mechanical Performances

Trimethylolpropane triacrylate (TMPTA) as a photoactive crosslinker is grafted onto hydrophobic nanosilica surface through click chemical reactions of mercapto double bonds to prepare the functionalized nanoparticles (TMPTA-s-SiO2), which are used to develop TMPTA-s-SiO2/XLPE nanocomposites with improvements in mechanical strength and electrical resistance. The expedited aging experiments of water-tree growth are performed with a water-knife electrode and analyzed in consistence with the mechanical performances evaluated by means of dynamic thermo-mechanical analysis (DMA) and tensile stress–strain characteristics. Due to the dense cross-linking network of polyethylene molecular chains formed on the TMPTA-modified surfaces of SiO2 nanofillers, TMPTA-s-SiO2 nanofillers are chemically introduced into XLPE matrix to acquire higher crosslinking degree and connection strength in the amorphous regions between polyethylene lamellae, accounting for the higher water-tree resistance and ameliorated mechanical performances, compared with pure XLPE and neat-SiO2/XLPE nanocomposite. Hydrophilic TMPTA molecules grafted on the nano-SiO2 surface can inhibit the condensation of water molecules into water micro-beads at insulation defects, thus attenuating the damage of water micro-beads to polyethylene configurations under alternating electric fields and thus restricting water-tree growth in amorphous regions. The intensified interfaces between TMPTA-s-SiO2 nanofillers and XLPE matrix limit the segment motions of polyethylene molecular chains and resist the diffusion of water molecules in XLPE amorphous regions, which further contributes to the excellent water-tree resistance of TMPTA-s-SiO2/XLPE nanocomposites.

scholarly journals Dynamic Thermomechanical Analysis on Water Tree Resistance of Crosslinked Polyethylene

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 746 ◽  
Author(s):  
Kun Sun ◽  
Junqi Chen ◽  
Hong Zhao ◽  
Weifeng Sun ◽  
Yinsheng Chen ◽  
...  
Keyword(s):  
Amorphous Phase ◽  
Uv Irradiation ◽  
Tree Growth ◽  
Thermomechanical Analysis ◽  
Polymer Chains ◽  
Crosslinking Reaction ◽  
Crosslinking Degree ◽  
Water Tree ◽  
Tree Resistance ◽  
Β Relaxation

The water tree resistance of crosslinked polyethylene (XLPE) initiated by ultraviolet (UV) irradiation technique is investigated through a water blade electrode method, and the effects of the mechanism of UV irradiation crosslinking on inhibiting water tree growth are revealed with dynamic thermomechanical analysis (DMA). The accelerated water tree aging experiment shows that UV irradiation crosslinking inhibits the growth rate of water trees, and the water tree length and width is reduced with the increase of the crosslinking degree of XLPE. The DMA result demonstrates that the molecular activity of the amorphous phase in XLPE as represented by polyethylene β-relaxation is gradually intensified with the increase of the crosslinking reaction. Combined with the fatigue mechanism of water tree growth in semi-crystalline polymers, it is suggested that the UV irradiation crosslinking reaction can significantly improve the anti-water-tree performance of linear low-density polyethylene (LLDPE). The crosslinking bond in the amorphous phase of UV-photoinitiated crosslinking polyethylene can produce a large number of cross-connected polymer chains, by which the length of fiber is obviously increased, leading to an reduced force from the micro-water beads onto the crack tip and thus decreasing the rate of the material being destroyed by micro-water beads.

Viscosity of the binary systems 2-methyl-2-propanol with n-alkanes at T=(303.15, 308.15, 313.15, 318.15 and 323.15)K: Prediction and correlation – New UNIFAC–VISCO interaction parameters

2010 ◽  
Vol 299 (2) ◽  
pp. 191-197 ◽  
Author(s):  
Emila M. Živković ◽  
Mirjana Lj. Kijevčanin ◽  
Ivona R. Radović ◽  
Slobodan P. Šerbanović ◽  
Bojan D. Djordjević
Keyword(s):  
Binary Systems ◽  
Interaction Parameters

scholarly journals Polyethylene Nanocomposites for Power Cable Insulations

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 24 ◽  
Author(s):  
Ilona Pleşa ◽  
Petru Noţingher ◽  
Cristina Stancu ◽  
Frank Wiesbrock ◽  
Sandra Schlögl
Keyword(s):  
Electrical Performance ◽  
Power Cable ◽  
Power Cables ◽  
Structure Property ◽  
Thermoplastic Polymers ◽  
Water Tree ◽  
Tree Resistance ◽  
Structure Property Relationships ◽  
Aging Mechanisms ◽  
Comprehensive Study

This review represents a comprehensive study of nanocomposites for power cables insulations based on thermoplastic polymers such as polyethylene congeners like LDPE, HDPE and XLPE, which is complemented by original results. Particular focus lies on the structure-property relationships of nanocomposites and the materials’ design with the corresponding electrical properties. The critical factors, which contribute to the degradation or improvement of the electrical performance of such cable insulations, are discussed in detail; in particular, properties such as electrical conductivity, relative permittivity, dielectric losses, partial discharges, space charge, electrical and water tree resistance behavior and electric breakdown of such nanocomposites based on thermoplastic polymers are described and referred to the composites’ structures. This review is motivated by the fact that the development of polymer nanocomposites for power cables insulation is based on understanding more closely the aging mechanisms and the behavior of nanocomposites under operating stresses.

A New Look at Measurements of Network Density

1986 ◽  
Vol 59 (1) ◽  
pp. 138-141 ◽  
Author(s):  
Robert A. Hayes
Keyword(s):  
Hysteresis Loop ◽  
Interaction Parameters ◽  
Network Density ◽  
Stress Strain ◽  
Solvent Interaction ◽  
Solvent Method ◽  
Strain Data ◽  
Good Agreement ◽  
Polymer Solvent ◽  
New Look

Abstract A two-solvent method for determining the polymer-solvent interaction parameters independently of stress-strain data is described. The values obtained are much lower than those reported previously. Network densities calculated from swelling data and these interaction parameters are in good agreement with those calculated from the return portion of a hysteresis loop at high elongations.

Viscoelastic Properties of PVB Interlayer for Laminated Glass Structures Used in Building Reconstructions

2019 ◽  
Vol 808 ◽  
pp. 115-122
Author(s):  
Miroslav Vokáč ◽  
Tomáš Hána ◽  
Klára V. Machalická ◽  
Martina Eliášová
Keyword(s):  
Viscoelastic Properties ◽  
Thermoplastic Polyurethane ◽  
Maxwell Model ◽  
Polyvinyl Butyral ◽  
Laminated Glass ◽  
Building Structures ◽  
Structural Element ◽  
Stress Strain ◽  
Existing Building ◽  
Material Parameters

Laminated glass is a structural element used extensively in a reconstruction of existing building structures because of its transparency and simplicity. When using laminated glass as a glass staircase, balustrades, transparent flooring, facades or other structural elements, it is advisable to consider the shear interaction of individual glass panes in the cross-section. A conservative approach where the glass panes shear interaction is not considered, is uneconomical. This interaction depends on the properties of polymeric interlayers used in lamination process. Various commercial products based on PVB (polyvinyl butyral), EVA (ethylene vinyl acetate), ionomer, or thermoplastic polyurethane (TPU) are used. Stiffness of polymers depends on temperature and duration of a load. Interlayers exhibit the viscoelastic properties and temperature dependency usually described by the generalized Maxwell model and WLF model (Williams-Landel-Ferry). Parameters of these models are the most effectively determined by Dynamic Mechanical Thermal Analysis (DMTA), where the material is cyclically loaded at different frequencies and temperatures. Material parameters were found by DMTA in shear for PVB type of interlayer Trosifol® BG R20. In addition, the experimental quasi-static loading tests in shear were performed at different loading rates and at various temperatures. These experimental stress-strain diagrams were compared to the theoretical stress-strain relations obtained from Maxwell model with material parameters based on DMTA testing. All tests were performed in Klokner Institute CTU in Prague.

Thermodynamics of binary systems using interaction parameters

1991 ◽  
Vol 22 (5) ◽  
pp. 593-605 ◽  
Author(s):  
J. P. Hajra ◽  
B. Mazumdar
Keyword(s):  
Binary Systems ◽  
Interaction Parameters

scholarly journals Modelling the Mechanical and Strain Recovery Behaviour of Partially Crystalline PLA

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1342 ◽  
Author(s):  
John Sweeney ◽  
Paul Spencer ◽  
Karthik Nair ◽  
Phil Coates
Keyword(s):  
Finite Element ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Stress Relaxation ◽  
Shape Memory ◽  
Yield Stress ◽  
Amorphous Phase ◽  
Strain Recovery ◽  
Stress Strain

This is a study of the modelling and prediction of strain recovery in a polylactide. Strain recovery near the glass transition temperature is the underlying mechanism for the shape memory in an amorphous polymer. The investigation is aimed at modelling such shape memory behaviour. A PLA-based copolymer is subjected to stress–strain, stress relaxation and strain recovery experiments at large strain at 60 °C just below its glass transition temperature. The material is 13% crystalline. Using published data on the mechanical properties of the crystals, finite element modelling was used to determine the effect of the crystal phase on the overall mechanical behaviour of the material, which was found to be significant. The finite element models were also used to relate the stress–strain results to the yield stress of the amorphous phase. This yield stress was found to possess strain rate dependence consistent with an Eyring process. Stress relaxation experiments were also interpreted in terms of the Eyring process, and a two-process Eyring-based model was defined that was capable of modelling strain recovery behaviour. This was essentially a model of the amorphous phase. It was shown to be capable of useful predictions of strain recovery.

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