scholarly journals Evaluation of Clay Hydration and Swelling Inhibition Using Quaternary Ammonium Dicationic Surfactant with Phenyl Linker

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4333 ◽  
Author(s):  
Mobeen Murtaza ◽  
Hafiz Mudaser Ahmad ◽  
Muhammad Shahzad Kamal ◽  
Syed Muhammad Shakil Hussain ◽  
Mohamed Mahmoud ◽  
...  
Keyword(s):  
Particle Size ◽  
Quaternary Ammonium ◽  
Gemini Surfactants ◽  
Drilling Fluid ◽  
Film Surface ◽  
Drilling Mud ◽  
Capillary Suction ◽  
Clay Swelling ◽  
Cationic Gemini Surfactants ◽  
Water Based

Water-based drilling fluids are extensively used for drilling oil and gas wells. However, water-based muds cause clay swelling, which severely affects the stability of wellbore. Due to two adsorption positions, it is expected that cationic gemini surfactants can reduce the clay swelling. In this work, quaternary ammonium dicationic gemini surfactants containing phenyl linkers and different counterions (Cl− and Br−) were synthesized, and the effect of variation in counterions on swelling and hydration properties of shales was studied. Numerous water-based drilling fluid formulations were prepared with different concentrations of surfactants to study the swelling inhibition capacity of surfactants. The performance of surfactant-containing drilling muds was evaluated by comparing them with base drilling mud, and sodium silicate drilling mud. Various experimental techniques were employed to study drilling mud characteristics such as rheology and filtration. The inhibition properties of drilling mud formulations were determined by linear swelling experiment, capillary suction time test, particle size distribution measurement, wettability measurements, and X-ray Diffraction (XRD). Experimental results showed that surfactant-based formulation containing bromide counterion exhibited superior rheological properties as compared to other investigated formulations. The filtration test showed that the gemini surfactant with chloride counterion had higher filtrate loss compared to all other formulations. The bentonite swelling was significantly reduced with increasing the concentration of dicationic surfactants as inhibitors, and maximum reduction in the linear swelling rate was observed by using a formulation containing surfactant with chloride counterion. The lowest capillary suction timer (CST) was obtained in the formulation containing surfactant with chloride counterion as less CST indicated the enhanced inhibition capacity. The particle size measurement showed that average bentonite particle size increased upon the addition of surfactants depicting the inhibition capacity. The increase in basal spacing obtained from XRD analysis showed the intercalation of gemini surfactants in interlayers of bentonite. The contact angle measurements were performed to study the wettability of the bentonite film surface, and the results showed that hydrophobicity increased by incorporating the surfactants to the drilling fluid.

Enhancement lubricity properties of water-based mud with nanoparticles

2020 ◽  
pp. 70-74
Author(s):  
V.V. Guliyev ◽  
◽  
◽  
Keyword(s):  
Yield Point ◽  
Coefficient Of Friction ◽  
Drilling Fluid ◽  
Research Work ◽  
Shear Thinning ◽  
Rheological Parameters ◽  
Drilling Process ◽  
Drilling Mud ◽  
Pseudoplastic Fluid ◽  
Water Based

Currently, a great number of drilling fluids with different additives are used all over the world. Such additives are applied to control the properties of the drilling mud. The main purpose for controlling is to achieve more effective and safe drilling process. This research work aims to develop Water-Based Mud (WBM) with a Coefficient of Friction (CoF) as low as Oil-Based Mud (OBM) and better rheological properties. As it is known, produced CoF by WBM is higher than OBM, which means high friction between wellbore or casing and drill string. It was the reason for studying the effect of nanosilica on drilling fluid properties such as lubricity, rheological parameters and filtrate loss volume of drilling mud. The procedures were carried out following API RP 13B and API 13I standards. Five concentrations of nanosilica were selected to be tested. According to the results obtained, it was defined that adding nanosilica into the mud decreases CoF of basic WBM by 26 % and justifies nanosilica as a good lubricating agent for drilling fluid. The decreasing trend in coefficient of friction and plastic viscosity for nanosilica was obtained until the concentration of 0.1 %. This reduction is due to the shear thinning or pseudoplastic fluid behavior. After 0.1 %, an increase at PV value trend indicates that it does not follow shear thinning behavior and after reaching a certain amount of dissolved solids in the mud, it acts like normal drilling fluid. The yield point of the mud containing nanoparticles was higher than the basic one. Moreover, a growth in the concentration leads to an increase in yield point value. The improvement of this fluid system cleaning capacity via hydraulics modification and wellhole stability by filter cake endurance increase by adding nanosilica is shown as well. The average well construction data of “Neft Dashlary” field was used for the simulation studies conducted for the investigation of hydraulics parameters of reviewed fluids for all series of experiments. The test results were accepted reliable in case of at least 3 times repeatability.

scholarly journals Comparative Analysis of the Effect of Barite and Hematite on the Rheology of Water-Based Drilling Mud

2021 ◽  
Vol 1 (2) ◽  
Author(s):  
Osei H
Keyword(s):  
Rheological Properties ◽  
Drilling Fluid ◽  
Attrition Rate ◽  
Drilling Mud ◽  
Cleaning Efficiency ◽  
Drilling Operation ◽  
Water Based ◽  
Petroleum Resources ◽  
Drilling Muds ◽  
The Impact

High demand for oil and gas has led to exploration of more petroleum resources even at remote areas. The petroleum resources are found in deeper subsurface formations and drilling into such formations requires a well-designed drilling mud with suitable rheological properties in order to avoid or reduce associated drilling problems. This is because rheological properties of drilling muds have considerable effect on the drilling operation and cleaning of the wellbore. Mud engineers therefore use mud additives to influence the properties and functions of the drilling fluid to obtain the desired drilling mud properties especially rheological properties. This study investigated and compared the impact of barite and hematite as weighting agents for water-based drilling muds and their influence on the rheology. Water-based muds of different concentrations of weighting agents (5%, 10%, 15% and 20% of the total weight of the drilling mud) were prepared and their rheological properties determined at an ambient temperature of 24ᵒC to check their impact on drilling operation. The results found hematite to produce higher mud density, plastic viscosity, gel strength and yield point when compared to barite at the same weighting concentrations. The higher performance of the hematite-based muds might be attributed to it having higher specific gravity, better particle distribution and lower particle attrition rate and more importantly being free from contaminants. The water-based muds with hematite will therefore be more promising drilling muds with higher drilling and hole cleaning efficiency than those having barite.

Heat Moisture Modified Rice Flours as Additive in Drilling Fluids

2021 ◽  
Vol 80 (1) ◽  
pp. 62-72
Author(s):  
Bunyami Shafie ◽  
Lee Huei Hong ◽  
Phene Neoh Pei Nee ◽  
Fatin Hana Naning ◽  
Tze Jin Wong ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Drilling Fluid ◽  
Low Cost ◽  
Health Concern ◽  
Drilling Fluids ◽  
Drilling Mud ◽  
Fluid Mixture ◽  
Gas Drilling ◽  
Water Based ◽  
Rice Flours

Drilling mud is a dense, viscous fluid mixture used in oil and gas drilling operations to bring rock cuttings to the earth's surface from the boreholes as well as to lubricate and cool the drill bit. Water-based mud is commonly used due to its relatively inexpensive and easy to dispose of. However, several components and additives in the muds become increasingly cautious and restricted. Starch was introduced as a safe and biodegradable additive into the water-based drilling fluid, in line with an environmental health concern. In this study, the suitability of four local rice flours and their heat moistures derivatives to be incorporated in the formulation of water-based drilling fluid was investigated. They were selected due to their natural amylose contents (waxy, low, intermediate, and high). They were also heat moisture treated to increase their amylose contents. Results showed that the addition of the rice flours into water-based mud significantly reduced the density, viscosity, and filtrate volume. However, the gel strength of the mud was increased. The rice flours, either native or heat moisture treated, could serve as additives to provide a variety of low cost and environmentally friendly drilling fluids to be incorporated and fitted into different drilling activity.

Rheology and fluid loss of a polyacrylamide-based micro-gel particles in a water-based drilling fluid

2020 ◽  
Vol 10 (5) ◽  
pp. 657-662
Author(s):  
Gang Wang ◽  
Honghai Fan ◽  
Guancheng Jiang ◽  
Wanjun Li ◽  
Yu Ye ◽  
...  
Keyword(s):  
Particle Size ◽  
High Temperature ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Drilling Fluid ◽  
Crosslinking Agent ◽  
Fluid Loss ◽  
Temperature Property ◽  
Water Based ◽  
The Cross

In this paper, the cross-linked micro-gel polymer between acrylamide (AM) and N, N-Methylenebisacrylamide (MBA) was synthesized by dispersion polymerization. The initiator and crosslinking agent concentration were used to control the particle size of micro-gel polymer. The filtration property and mechanism of micro-gel were investigated comprehensively. The characteristics of micro-gel were checked by means of Fourier transform infrared spectroscopy, thermogravimetry, transmission electron microscopy, and particle size distribution, respectively. The results indicated that the cross-linked micro-gel polymer exhibited several outstanding merits, such as thermal stability (up to 200 °C), filtration control and rheological property. Microstructure analysis and particle size distribution examinations showed that the scale of micro-gel polymer was micro, which is in accord with design. Rheological tests demonstrated that the nonlinear structure of micro-gel polymer showed less impact on the apparent viscosity. The anti-high temperature property of micro-gel polymer was better than poly anioniccellulose (PAC) and asphalt widely applied in drilling fluid for anti-high temperature fluid-loss additive. As a result, the cross-linked micro-gel polymer had great potential to be applied in high temperature water-based mud.

Preparation of a Novel Viscosifier for Drilling Fluid by Sulfonation Technology Based on the Enriched Organic Compounds in TNT Red Water

2012 ◽  
Vol 151 ◽  
pp. 319-322 ◽  
Author(s):  
Fang Fang Wei ◽  
Yi He Zhang ◽  
Feng Zhu Lv
Keyword(s):  
Organic Compounds ◽  
Drilling Fluid ◽  
Experimental Results ◽  
Drilling Mud ◽  
Water Based

In this paper, sulfonates based on the enriched organic compounds in TNT red water have been prepared and their efficacy in water based drilling mud has been evaluated. The experimental results showed that the sulfonated products can be used as viscosifier for drilling fluid, which suggesting an attractive method for the possible commercial usage of waste red water.

Stabilization of Drilling Fluid Waste with Fly Ash

1986 ◽  
Vol 86 ◽  
Author(s):  
George M. Deeley ◽  
Larry W. Canter ◽  
Joakim G. Laguros
Keyword(s):  
Fly Ash ◽  
Caustic Soda ◽  
Drilling Fluid ◽  
Drilling Mud ◽  
Fly Ashes ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Water Based ◽  
Land Disposal ◽  
Drilling Muds

Water based drilling muds typically contain clays, barite, lime, caustic soda and other chemicals, such as polymers. Land disposal of these wastes raises the possibility of groundwater pollution which can be abated if the waste is stabilized either by chemical reaction or by solidification through some form of cementation. Many ASTM high-calcium (Class C) fly ashes are cementitious and thus may be useful in stabilization of drilling mud. The basic idea is to stabilize the clay-containing muds using the model of soil and roadbed stabilization with high-calcium fly ash [1]. Fly ash that is not utilized is considered to be a solid waste, so this application would would actually constitute codisposal of two wastes.

scholarly journals Preparation and Evaluation of Ammonium Adipate Solutions as Inhibitors of Shale Rock Swelling

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1013
Author(s):  
Sirong Xian ◽  
Shijun Chen ◽  
Yubo Lian ◽  
Weichao Du ◽  
Zhifei Song ◽  
...  
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Adipic Acid ◽  
Linear Expansion ◽  
Drilling Fluid ◽  
Inhibitory Effect ◽  
Distribution Analysis ◽  
Expansion Test ◽  
Water Based

This study aimed to evaluate the inhibitory effect of a series of ammonium adipate solutions (AASs) by using the linear expansion test, thermogravimetric analysis (TGA), and particle size distribution analysis, and to examine the underlying inhibitory mechanism. A series of AASs was prepared from adipic acid and amines as small-molecule inhibitors of oil shale rock swelling. They were then evaluated by the bentonite linear expansion test. The best one, namely, AAS-8 (synthesized with adipic acid and tetraethylenepentamine in a ratio of acid group to amine group of 1:2), was evaluated in a water-based drilling fluid. The linear expansion test showed that the linear expansion rate of AAS-8 was the lowest (59.61%) when the concentration was 0.1%. The evaluation of the drilling fluid revealed that AAS-8 had a strong inhibitory effect on the swelling of hydrated bentonite particles in the water-based drilling fluid and was compatible with carboxymethyl cellulose (CMC) and modified starch. The inhibition mechanism of AAS-8 was investigated using TGA and particle size distribution analysis, which demonstrated that AAS-8 might enter the clay layer and bind the clay sheets together by electrostatic adsorption and hydrogen bonding.

scholarly journals An Adaptable Water-Based Mud System for Multiple Applications While Drilling

2019 ◽  
Vol 2 (2) ◽  
Keyword(s):  
Volcanic Ash ◽  
Salt Water ◽  
Drilling Fluid ◽  
Circulation System ◽  
Drilling Mud ◽  
Subsurface Geology ◽  
Water Based ◽  
Drilling Cost ◽  
Drilling Time ◽  
Fluid Characteristics

Due to significant variations of the subsurface geology from the surface to the top of reservoir and requirement of different fluid characteristics for drilling various hole there is a need to use various mud systems. These may include a simple spud mud for surface hole section, an inhibitive drilling fluid for reactive shale section, a salt water-based mud for salt diapirs and salt formations, and a highly lubricating mud for deviated hole sections with high dogleg severity.To optimize each of these separate and distinct scenarios, there is a need to change the mud system while drilling to overcome the technical challenges associated with these formations and wellbore profiles. The change over from one mud system to another is typically done between casing points while constructing the well to overcome specific drilling challenges associated with next whole section.There is significant time and effort required to clean the mud circulation system adequately before a mud change over in order to avoid any contamination of the new mud system.This is especially true when displacing a waterbased mud by an oil-based mud or an oil-based mud by a water-based mud.If this is not done properly, contamination of the new mud by the old mud could be a source of major problems due to partial or complete loss of functional ability of the new mud system. An adaptable drilling mud system that can easily be transformed from a spud mud system to an inhibitive, or a high lubricating or a salt water mud can provide the industry a versatile fluid system with multiple hole section applications.This removes much of the NPT associated with mud changeover, reduces the mud cost as compared to mixing a totally new mud system and eliminates concerns regarding mud contamination as well as any disposal or recycling cost for the replaced system. This paper describes a volcanic ash-based drilling mud that can be used as a spud mud to drill the surface hole, can easily be converted to an inhibitive mud system to drill reactive shale sections of a borehole, a salt water-based mud to drill the salt sections and also a high lubricating water-based drilling mud to reduce torque and drag problems in deviated and horizontal boreholes. The flexible and easily convertible nature of the base volcanic ash-based drilling mud has potential to reduce total drilling cost significantly as it eliminates a significant portion of non-productive drilling time associated with mud changeover, cleaning of mud circulation system, new mud preparation, incorporation of new mud in the circulation system and displacement of the old mud from the borehole by the new mud, etc.

Studies on the Relations between Dispersivity and Covering Property of White Water-Based Ink

2015 ◽  
Vol 731 ◽  
pp. 558-561
Author(s):  
Ying Gong ◽  
Xian Fu Wei ◽  
Chang Long Guo ◽  
Bei Qing Huang
Keyword(s):  
Particle Size ◽  
Fine Particle ◽  
Film Surface ◽  
Preparation Process ◽  
Test Paper ◽  
Covering Property ◽  
Sem Image ◽  
Water Based ◽  
Fine Particle Size ◽  
White Water

The white ink commonly serves as render ink in printing, and its covering property (CP), which is assumed to be influenced by the dispersion, plays a key role in color reproduction on the film surface. In order to research on the relations between dispersivity and CP, inks with different dispersion are prepared by changing the preparation process. The inks’ particle size and distribution are tested before it is coated onto the surface of covering property test paper. The morphologies of inks film are studied through SEM to examine the white ink’s dispersion and its influence on CP. The result shows that well dispersed inks have fine particle size and tend to uniformly distribute. There is hardly any agglomeration found on the well dispersed ink’s SEM image which is supposed to account for its high CP.

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