scholarly journals Carbonation and Chloride Ions’ Penetration of Alkali-Activated Materials: A Review

Molecules ◽  
2020 ◽  
Vol 25 (21) ◽  
pp. 5074
Author(s):  
Xuanhan Zhang ◽  
Kaidi Long ◽  
Wei Liu ◽  
Lixiao Li ◽  
Wu-Jian Long
Keyword(s):  
Carbon Footprint ◽  
Reaction Mechanisms ◽  
Ordinary Portland Cement ◽  
Chloride Ions ◽  
Reaction Products ◽  
Chemical Reaction Mechanisms ◽  
Corrosion Mechanisms ◽  
Mitigation Methods ◽  
Alkali Activated ◽  
Lower Carbon

Alkali-activated materials (AAMs) are widely recognized as potential alternatives to ordinary Portland cement (OPC) due to their lower carbon footprint. However, like OPC, AAMs can also generate some durable problems when exposed to aggressive environments and the mechanisms and possible improvements are still not fully clear in existing investigations. Furthermore, the corrosion mechanisms of AAMs are different from OPC due to the discrepant reaction products and pore structures. Thus, this study’s aim is to review the chemical reaction mechanisms, factors, and mitigation methods when AAMs are attacked by carbonation and chloride ions, along with a summative discussion regarding instructive insights to durable problems of AAMs.

A Paramedic Treatment for Modeling Explicitly Solvated Chemical Reaction Mechanisms

2018 ◽  
Author(s):  
Yasemin Basdogan ◽  
John Keith
Keyword(s):  
Reaction Mechanism ◽  
Chemical Reaction ◽  
Reaction Mechanisms ◽  
Reaction Pathway ◽  
Optimization Procedure ◽  
Cost Effective ◽  
Chemical Reaction Mechanisms ◽  
Solvent Molecules ◽  
Dynamics Simulations ◽  
Mbh Reaction

<div> <div> <div> <p>We report a static quantum chemistry modeling treatment to study how solvent molecules affect chemical reaction mechanisms without dynamics simulations. This modeling scheme uses a global optimization procedure to identify low energy intermediate states with different numbers of explicit solvent molecules and then the growing string method to locate sequential transition states along a reaction pathway. Testing this approach on the acid-catalyzed Morita-Baylis-Hillman (MBH) reaction in methanol, we found a reaction mechanism that is consistent with both recent experiments and computationally intensive dynamics simulations with explicit solvation. In doing so, we explain unphysical pitfalls that obfuscate computational modeling that uses microsolvated reaction intermediates. This new paramedic approach can promisingly capture essential physical chemistry of the complicated and multistep MBH reaction mechanism, and the energy profiles found with this model appear reasonably insensitive to the level of theory used for energy calculations. Thus, it should be a useful and computationally cost-effective approach for modeling solvent mediated reaction mechanisms when dynamics simulations are not possible. </p> </div> </div> </div>

scholarly journals A Review of the Mechanical Properties and Durability of Ecological Concretes in a Cold Climate in Comparison to Standard Ordinary Portland Cement-Based Concrete

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen
Keyword(s):  
Carbon Dioxide ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Cold Climate ◽  
Supplementary Cementitious Materials ◽  
Short Exposure ◽  
Chemical Admixtures ◽  
Composite Cements ◽  
Alkali Activated

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.

scholarly journals Using telemedicine for a lower carbon footprint in healthcare: A twofold tale of healing

2021 ◽  
Vol 1 ◽  
pp. 100006
Author(s):  
Christos Tsagkaris ◽  
Anastasiia V. Hoian ◽  
Shoaib Ahmad ◽  
Mohammad Yasir Essar ◽  
Loyle Wesley Campbell ◽  
...  
Keyword(s):  
Carbon Footprint ◽  
Lower Carbon

Utilizing alkali-activated materials as ordinary Portland cement replacement to study the bond performance of fiber-reinforced polymer bars in seawater sea-sand concrete

2022 ◽  
pp. 136943322110651
Author(s):  
Ruiming Cao ◽  
Bai Zhang ◽  
Luming Wang ◽  
Jianming Ding ◽  
Xianhua Chen
Keyword(s):  
Tensile Strength ◽  
Bond Strength ◽  
Ordinary Portland Cement ◽  
Concrete Strength ◽  
Fiber Reinforced Polymer ◽  
Bond Performance ◽  
Reinforced Polymer ◽  
Sea Sand ◽  
Frp Bars ◽  
Alkali Activated

Alkali-activated materials (AAMs) are considered an eco-friendly alternative to ordinary Portland cement (OPC) for mitigating greenhouse-gas emissions and enabling efficient waste recycling. In this paper, an innovative seawater sea-sand concrete (SWSSC), that is, seawater sea-sand alkali-activated concrete (SWSSAAC), was developed using AAMs instead of OPC to explore the application of marine resources and to improve the durability of conventional SWSSC structures. Then, three types of fiber-reinforced polymer (FRP) bars, that is, basalt-FRP, glass-FRP, and carbon-FRP bars, were selected to investigate their bond behavior with SWSSAAC at different alkaline dosages (3%, 4%, and 6% Na2O contents). The experimental results manifested that the utilization of the alkali-activated binders can increase the splitting tensile strength ( ft) of the concrete due to the denser microstructures of AAMs than OPC pastes. This improved characteristic was helpful in enhancing the bond performance of FRP bars, especially the slope of bond-slip curves in the ascending section (i.e., bond stiffness). Approximately three times enhancement in terms of the initial bond rigidity was achieved with SWSSAAC compared to SWSSC at the same concrete strength. Furthermore, compared with the BFRP and GFRP bars, the specimens reinforced with the CFRP bars experienced higher bond strength and bond rigidity due to their relatively high tensile strength and elastic modulus. Additionally, significant improvements in initial bond stiffness and bond strength were also observed as the alkaline contents (i.e., concrete strength) of the SWSSAAC were aggrandized, demonstrating the integration of the FRP bars and SWSSAAC is achievable, which contributes to an innovative channel for the development of SWSSC pavements or structures.

scholarly journals Leaching, carbonation and chloride ingress in reinforced alkali-activated fly ash mortars

2018 ◽  
Vol 199 ◽  
pp. 02025 ◽  
Author(s):  
Gregor J. G. Gluth ◽  
Petr Hlaváček ◽  
Steffi Reinemann ◽  
Gino Ebell ◽  
Jürgen Mietz
Keyword(s):  
Fly Ash ◽  
Visual Inspection ◽  
Electrochemical Behaviour ◽  
Transport Coefficients ◽  
Chloride Penetration ◽  
Chloride Ingress ◽  
Reaction Products ◽  
Steel Bars ◽  
Alkali Activated Binders ◽  
Alkali Activated

Alkali-activated fly ash mortars were studied with regard to durability-relevant transport coefficients and the electrochemical behaviour of embedded carbon steel bars on exposure of the mortars to leaching, carbonation and chloride penetration environments. The transport coefficients differed considerably between different formulations, being lowest for a mortar with BFS addition, but still acceptable for one of the purely fly ash-based mortars. Leaching over a period of ~300 days in de-ionized water did not lead to observable corrosion of the embedded steel, as shown by the electrochemical data and visual inspection of the steel. Exposure to 100 % CO2 atmosphere caused steel depassivation within approx. two weeks; in addition, indications of a deterioration of the mortar were observed. The results are discussed in the context of the different reaction products expected in highand low-Ca alkali-activated binders, and the alterations caused by leaching and carbonation.

Sign in / Sign up

Export Citation Format

Share Document