scholarly journals Conducting Silicone-Based Polymers and Their Application

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2012
Author(s):  
Jadwiga Sołoducho ◽  
Dorota Zając ◽  
Kamila Spychalska ◽  
Sylwia Baluta ◽  
Joanna Cabaj
Keyword(s):  
Conducting Polymers ◽  
Heat Stability ◽  
Rechargeable Batteries ◽  
Environmental Stability ◽  
Degree Of Crystallinity ◽  
Effective Parameters ◽  
Electrically Conductive ◽  
The Past ◽  
Silicone Polymers ◽  
Low Temperature Flexibility

Over the past two decades, both fundamental and applied research in conducting polymers have grown rapidly. Conducting polymers (CPs) are unique due to their ease of synthesis, environmental stability, and simple doping/dedoping chemistry. Electrically conductive silicone polymers are the current state-of-the-art for, e.g., optoelectronic materials. The combination of inorganic elements and organic polymers leads to a highly electrically conductive composite with improved thermal stability. Silicone-based materials have a set of extremely interesting properties, i.e., very low surface energy, excellent gas and moisture permeability, good heat stability, low-temperature flexibility, and biocompatibility. The most effective parameters constructing the physical properties of CPs are conjugation length, degree of crystallinity, and intra- and inter-chain interactions. Conducting polymers, owing to their ease of synthesis, remarkable environmental stability, and high conductivity in the doped form, have remained thoroughly studied due to their varied applications in fields like biological activity, drug release systems, rechargeable batteries, and sensors. For this reason, this review provides an overview of organosilicon polymers that have been reported over the past two decades.

Conducting Polymers: Past, Present and Future…

1993 ◽  
Vol 328 ◽  
Author(s):  
Alan G. MacDiarmid ◽  
Arthur J. Epstein
Keyword(s):  
Conducting Polymers ◽  
Conducting Polymer ◽  
Electromagnetic Interference ◽  
Large Scale ◽  
Rechargeable Batteries ◽  
Organic Polymers ◽  
Electrically Conductive ◽  
Light Emitting ◽  
Gas Separation Membrane ◽  
Separation Membrane

ABSTRACTSince their discovery 16 years ago, the field of intrinsically conducing polymers — “synthetic Metals” — has developed at an unexpectedly rapid rate. The concept of “doping” is the unifying theme which distinguishes this class of organic polymers — “conducting polymers” — from all others. Doping results in dramatic electronic and magnetic changes with a concomitant increase in conductivity to, or approaching, the metallic regime. Doping phenomena and the chief types of dopable organic polymers are described with particular emphasis on polyaniline, which is now probably the most actively-studied conducting polymer. It has been commercialized on a relatively large scale and presently appears to be the leading conducting polymer for technology. It shows considerable promise for electromagnetic interference (EMI) shielding and as a gas separation Membrane, and is currently used in commercial rechargeable batteries. Polypyrrole is used commercially in capacitors and as an electrically conductive coating on conventional fabrics. Additional potential uses of conducting polymers such as light-emitting diodes, electrochromic windows, chemical sensors, etc. are also described briefly.

scholarly journals Conducting polymers: a comprehensive review on recent advances in synthesis, properties and applications

RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5659-5697 ◽  
Author(s):  
Namsheer K ◽  
Chandra Sekhar Rout
Keyword(s):  
Mechanical Properties ◽  
Electrical Property ◽  
Conducting Polymers ◽  
Inorganic Materials ◽  
Environmental Stability ◽  
Comprehensive Review ◽  
Recent Advances ◽  
Synthesis Properties

Conducting polymers are extensively studied due to their outstanding properties, including tunable electrical property, optical and high mechanical properties, easy synthesis and effortless fabrication and high environmental stability over conventional inorganic materials.

A Brief Review on Thermal Behaviour of PANI as Additive in Heat Transfer Fluid

2021 ◽  
Vol 02 (01) ◽  
Author(s):  
A.G.N. Sofiah ◽  
◽  
M. Samykano ◽  
S. Shahabuddin ◽  
K. Kadirgama ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Thermal Properties ◽  
Conducting Polymers ◽  
Volume Fraction ◽  
Corrosion Property ◽  
Environmental Stability ◽  
Heat Transfer Fluid ◽  
Thermal Engineering ◽  
Engineering System ◽  
Heat Transfer Fluids

Since a decade ago, investigation on nanofluids has grown significantly owing to its enhanced thermal properties compared to conventional heat transfer fluids. This engineered nanofluid has been widely used in the thermal engineering system to improve their energy consumption by improving the thermal efficiency of the system. The addition of nano-size particles as additives dispersed in the base fluids proved to significantly either improve or diminish the behaviour of the base fluids. The behaviour of the base fluid highly depends on the properties of the additives material, such as morphology, size, and volume fraction. Among the variety of nanoparticles studied, the conducting polymers have been subject of high interest due to its high environmental stability, good electrical conductivity, antimicrobial, anti-corrosion property and significantly cheap compared to other nanoparticles. As such, the main objective of the present review is to provide an overview of the work performed on thermal properties performance of conducting polymers based nanofluids.

The potential for geothermal lithium in Italy

2021 ◽  
Author(s):  
Pierfranco Lattanzi ◽  
Andrea Dini ◽  
Giovanni Ruggieri ◽  
Eugenio Trumpy
Keyword(s):  
Rechargeable Batteries ◽  
Thermal Waters ◽  
Past Century ◽  
Geothermal Resources ◽  
High Enthalpy ◽  
The Past ◽  
Geothermal Fluids ◽  
Deep Reservoir ◽  
Increasing Demand ◽  
Made In

<p>Italy has never been a lithium (Li) producer, and the potential for “hard rock” deposits is moderate at best. On the other hand, the increasing demand for Li-based rechargeable batteries fostered new interest in this metal, and prompted the quest for alternative resources. The extraction of Li from geothermal brines (“geothermal lithium”) is currently considered in several countries, including, in Europe, France, Germany, and UK (EGEC, 2020).</p><p>Italy has vast geothermal resources, and there is a potential for “geothermal lithium” as well. A preliminary survey of literature data pointed out several occurrences of fluids with Li contents up to hundreds of mg/L. Among high-enthalpy fluids, we point out those of Cesano, Mofete, and Latera. At Cesano, geothermal fluids contain about 350 mg/L lithium (Calamai et al., 1976). Early studies conducted in the past century (Pauwels et al., 1990) suggested the feasibility of lithium recovery from these fluids. Even higher contents (480 mg/L) occur in the deep reservoir at Mofete (Guglielminetti, 1986), whereas fluids in the shallow and intermediate reservoir in the same field contain 28 to 56 mg/L. Geothermal fluids at Latera have somewhat lower contents (max 13.5 mg/L; Gianelli and Scandiffio, 1989). Several low-enthalpy thermal waters in Emilia-Romagna, Sardinia, Sicily and Tuscany also show significant (> 1 mg/L) Li contents (max 96 mg/L at Salsomaggiore; Boschetti et al., 2011). There are no published Li data for high-enthalpy fluids at Larderello; however, evidence of Li-rich fluids was found in fluid inclusions in hydrothermal minerals (Cathelineau et al., 1994). Moreover, the shallow (ca. 3.5 km) granitoid body underlying the field contains a Li-rich (about 1,000 ppm) biotite (A. Dini, unpublished data); it has been estimated that such rock may contain as much as 500 g Li per cubic meter.</p><p> </p><p>References</p><p>Boschetti T., et al. - Aquat Geochem (2011) 17:71–108</p><p>Calamai A., et al. <strong>- </strong>Proc. U.N. Symp. Development Use Geotherm. Energy, S. Francisco, USA (1976), 305-313</p><p>Cathelineau M., et al. – Geochim. Cosmochim. Acta (1994) 58: 1083-1099</p><p>EGEC (European Geothermal Council). https://www.egec.org/time-to-invest-in-clean-geothermal-lithium-made-in-europe/. Accessed December 2, 2020.</p><p>Gianelli G., Scandiffio G. - Geothermics (1989) 18: 447-463</p><p>Guglielminetti M. - Geothermics (1986) 15: 781-790</p><p>Pauwels H., et al. - Proc. 12th New Zealand Geothermal Workshop (1990), 117-123</p>

Effect of Inorganic Doping on the Thermoelectric Behavior of Polyaniline Nanocomposites

2020 ◽  
Vol 835 ◽  
pp. 200-207
Author(s):  
Mariamu K. Ali ◽  
Ahmed Abd Moneim
Keyword(s):  
Electrical Conductivity ◽  
Conducting Polymers ◽  
Inorganic Nanoparticles ◽  
Inorganic Materials ◽  
Environmental Stability ◽  
Subsequent Reduction ◽  
Preparation Methods ◽  
Reduced Graphene

Polyaniline (PANI) has been considered for thermoelectric (T.E) applications due to its facile preparation methods, easy doping-dedoping processes and its environmental stability. Like other conducting polymers (CPs), it has low thermal conductivity (usually below 1 Wm-1K-1) which is favorable for T.E applications, however studies have shown that it still suffers from low power factors as a result of low electrical conductivity. For this reason, PANI has been compounded with other materials such as polymers, inorganic nanoparticles and carbon nanoparticles to enhance its electrical conductivity, power factors (PF) and ultimately zT value.This work is focused on the synthesis and characterization of n-type polyaniline nanocomposites doped with reduced graphene oxide (rGO). The rGO was prepared through oxidation of graphite and subsequent reduction and incorporated into polyaniline through in situ polymerization and the resulting nanocomposites were characterized. Addition of rGO resulted in enhancement of the electrical conductivity of polyaniline from 10-3 S/cm to 10-1 S/cm which is two orders of magnitude higher. This contributed to the enhanced PF, an indication that thermoelectric behavior of conducting polymers can be boosted through compounding with inorganic materials.

Templating the 3D structure of conducting polymers with self-assembling peptides

2017 ◽  
Vol 5 (24) ◽  
pp. 4690-4696 ◽  
Author(s):  
T. J. Blatz ◽  
M. M. Fry ◽  
E. I. James ◽  
T. J. Albin ◽  
Z. Pollard ◽  
...  
Keyword(s):  
Conducting Polymers ◽  
3D Structure ◽  
Porous Structures ◽  
Electrically Conductive ◽  
Self Assembling

Polymerization of pre-assembled peptide–thiophene monomers produced electrically conductive gels with fibrous, porous structures.

Environmental stability of electrically conductive viologen-polyaniline systems

2002 ◽  
Vol 86 (8) ◽  
pp. 2099-2107 ◽  
Author(s):  
Baozong Zhao ◽  
K. G. Neoh ◽  
E. T. Kang
Keyword(s):  
Environmental Stability ◽  
Electrically Conductive

Polythiophene composites: a review of selected applications

2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Rajeshwar S. Bobade
Keyword(s):  
Conducting Polymers ◽  
Surface Film ◽  
Low Cost ◽  
Environmental Stability ◽  
Future Research ◽  
Inorganic Semiconductors ◽  
Polymer Properties ◽  
Wide Range ◽  
Mechanical Sensors ◽  
Low Cost Manufacturing

Abstract Conducting polymers (CPs) provide a class of processible, film forming semiconductors and metals. Electrical and optical properties of CPs, similar to those of metals and semiconductors, and the attractive properties associated with conventional polymers such as ease of synthesis and processing, has given these polymers a wide range of applications in the microelectronics industry, in biological field and also as humidity, chemical and mechanical sensors. The principal interest in the use of polymers lies in the scope for low cost manufacturing. Organic polymers offer several advantages over analogous inorganic semiconductors, the most important of which are the processability and the large surface film technology together with the possibility of tuning the polymer properties through a chemical design of the constituent units. In contrast, problems of environmental stability and the inability to process these into useful devices constitute the main drawbacks of organic materials. To set a material suitable for applications in various technological fields one has to improve the processability, mechanical strength and environmental stability of the polyheterocycles: one method adopted to do this is synthesizing the composites of conducting polymers within a matrix of insulating polymers. In this paper, the science of conducting polymers will be discussed. A review from literature on selected applications of organic devices based on conducting polythiophene and its composites will be discussed with a view to targeting the areas of future research in this topic.

Insights into g-C3N4 as chemi-resistive gas sensors towards VOCs and humidity- A review on state-of-the-art and recent advancements

2021 ◽  
Author(s):  
Parthasarathy Srinivasan ◽  
Soumadri Samanta ◽  
Akshay Krishnakumar ◽  
John Bosco Balaguru Rayappan ◽  
Kamalakannan Kailasam
Keyword(s):  
Carbon Nanotubes ◽  
Conducting Polymers ◽  
Metal Oxides ◽  
Gas Sensors ◽  
State Of The Art ◽  
2D Materials ◽  
The Past ◽  
Sensing Applications ◽  
Resistive Gas Sensors

Over the past decades, many materials like metal oxides, conducting polymers, carbon nanotubes, 2D materials, graphene, zeolites and porous organic frameworks (MOFs and COFs) have been explored for chemo-sensing applications...

scholarly journals Loop Length of Plain Single Weft Knitted Structure with Elastane

2013 ◽  
Vol 8 (2) ◽  
pp. 155892501300800 ◽  
Author(s):  
Alenka Pavko-Cuden ◽  
Ales Hladnik ◽  
Franci Sluga
Keyword(s):  
Geometrical Parameters ◽  
Loop Length ◽  
Loop Model ◽  
Porous Structures ◽  
Effective Parameters ◽  
Knitted Fabrics ◽  
Dimensional Changes ◽  
The Past ◽  
Knitted Structure ◽  
Linear Regressions

For decades, scientists have been trying to define relationships among yarn parameters, knitted fabric parameters, and knitting parameters with loop models. Recently, the geometrical loop models have returned to focus as they assist finding the effective parameters which cause dimensional changes during relaxation. Furthermore, they help designing knitted structures for technical applications and obtaining computer simulations of knitted structures. In the past, geometrical loop models considered more or less porous structures and the yarns used were mostly conventional, without elastane. The behavior and characteristics of compact knitted fabrics made from elasticized yarns have been investigated only recently. In general, mostly the structures with plated elastane threads have been analyzed. The aim of the research was to study the geometrical parameters (yarn thickness, loop width, loop height, fabric thickness, loop length) of plain single weft knitted structures made from various elasticized yarns, in comparison to equivalent structures made from conventional yarns. In the study, the most frequently applied loop models for the loop length calculations were evaluated with the emphasis on their adequacy for elasticized knitted structures. A new loop model for an elasticized weft knitted structure based on the multiple linear regressions was defined.

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