scholarly journals Galvano-Fenton Engineering Solution with Spontaneous Catalyst’s Generation from Waste: Experimental Efficiency, Parametric Analysis and Modeling Interpretation Applied to a Clean Technology for Dyes Degradation in Water

Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5640
Author(s):  
Hamza Ferkous ◽  
Kaouther Kerboua ◽  
Oualid Hamdaoui ◽  
Naoufel Haddour ◽  
Abdulaziz Alghyamah
Keyword(s):  
Correlation Coefficients ◽  
Operating Conditions ◽  
Experimental Results ◽  
Elementary Reactions ◽  
Chain Reactions ◽  
Degradation Rates ◽  
Constant Rate ◽  
Initiation Stage ◽  
Kinetics Of ◽  
Selection Of

In this paper, the degradation of the diazo dye naphthol blue black (NBB) using the Galvano-Fenton process is studied experimentally and numerically. The simulations are carried out based on the anodic, cathodic, and 34 elementary reactions evolving in the electrolyte, in addition to the oxidative attack of NBB by HO• at a constant rate of 3.35×107 mol−1·m3·s−1 during the initiation stage of the chain reactions. The selection of the operating conditions including the pH of the electrolyte, the stirring speed, and the electrodes disposition is performed by assessing the kinetics of NBB degradation; these parameters are set to 3, 350 rpm and a parallel disposition with a 3 cm inter-electrode distance, respectively. The kinetics of Fe(III) in the electrolyte were monitored using the principles of Fricke dosimetry and simulated numerically. The model showed more than a 96% correlation with the experimental results in both the blank test and the presence of the dye. The effects of H2O2 and NBB concentrations on the degradation of the dye were examined jointly with the evolution of the simulated H2O2, Fe2+, and HO• concentrations in the electrolyte. The model demonstrated a good correlation with the experimental results in terms of the initial degradation rates, with correlation coefficients exceeding 98%.

scholarly journals A Mathematical Model for Dehydration by Successive Pressure Drops: Simulation of Discarded Potatoes Dehydration

2021 ◽  
Vol 8 (2) ◽  
pp. 26-39
Author(s):  
Sebastian Gutierrez-Pacheco ◽  
Joahnn H Palacios ◽  
Alfonso Parra-Coronado ◽  
Stéphane Godbout
Keyword(s):  
Pressure Drop ◽  
Drying Kinetics ◽  
Operating Conditions ◽  
Thin Layers ◽  
Drying Rate ◽  
Pressure Drops ◽  
Mathematical Simulations ◽  
Kinetics Of ◽  
By Products ◽  
Selection Of

Dehydration by Successive Pressure Drops (SPD) is a process with high potential for treating heat-sensitive materials; this includes agro-industry by-products. However, the response of drying kinetics to operating conditions of SPD is not fully understood. The present manuscript refers to mathematical simulations to describe drying kinetics of discarded potatoes using SPD. While there are numerous theoretical, semi-theorical and empirical mathematical models, the selection of the appropriate model is a rigorous process. In this paper, the Thompson thin-layer semi-theoretical model was chosen since the assumptions for this model (e.g., product is arranged in thin layers) are fulfilled for the SPD. As a result of mathematical simulation, it was possible to describe the drying kinetics in terms of the major parameters of SPD namely pressurizing level (Pa) and the Frequency of Pressure Drop (FPD). The dehydration by SPD allows the removal of water from the material, mainly at the pressure drop. If this stage occurs more frequently, the drying rate increases. The model developed describes at less 91% of the variability of the experimental data. It is recommended to use high FPD and Pa equals to 0.50 MPa.

A Theoretical Consideration of the Kinetics of Multiple Substrate Utilization in Anaerobic Digestion

1993 ◽  
Vol 28 (7) ◽  
pp. 77-80 ◽  
Author(s):  
M. Kuroda ◽  
Y. Sakakibara ◽  
Wang Jin ◽  
Yu Erjie ◽  
Wang Baozhen ◽  
...  
Keyword(s):  
Anaerobic Digestion ◽  
Analytical Model ◽  
Theoretical Consideration ◽  
Substrate Utilization ◽  
Experimental Results ◽  
Organic Substances ◽  
Degradation Rates ◽  
Variation Curve ◽  
Multiple Substrate ◽  
Kinetics Of

Degradation of a mixture of various organic substances was regarded as a multiple substrate phenomenon; an analytical model for evaluation of degradation rates of each component was developed and the calculation procedure was shown based on the analytical model. Each component of the mixture is degraded sequentially in order of degradation rates, and the degradation rates of each component can be evaluated by analysing a time-TOC concentration variation curve obtained experimentally. Calculated values were compared with experimental results.

IMPROVEMENT OF SPRING DURUM WHEAT SELECTION METHODOLOGIES UNDER CLIMATE CHANGE CONDITIONS

1970 ◽  
pp. 33-36
Author(s):  
А. I. Grabovets ◽  
V. P. Kadushkina ◽  
S. А. Kovalenko
Keyword(s):  
Grain Yield ◽  
Durum Wheat ◽  
Correlation Coefficient ◽  
Harvest Index ◽  
Unit Area ◽  
Correlation Coefficients ◽  
Chemical Mutagenesis ◽  
Main Method ◽  
The Relationship ◽  
Selection Of

With the growing aridity of the climate on the Don, it became necessary to improve the methodology for conducting the  breeding of spring durum wheat. The main method of obtaining the source material remains intraspecific step hybridization. Crossings were performed between genetically distant forms, differing in origin and required traits and properties. The use of chemical mutagenesis was a productive way to change the heredity of genotypes in terms of drought tolerance. When breeding for productivity, both in dry years of research and in favorable years, the most objective markers were identified — the size of the aerial mass, the mass of grain per plant, spike, and harvest index. The magnitude of the correlation coefficients between the yield per unit area and the elements of its structure is established. It was most closely associated with them in dry years, while in wet years it decreased. Power the correlation of the characteristics of the pair - the grain yield per square meter - the aboveground biomass averaged r = 0.73, and in dry years it was higher (0.91) than in favorable ones (0.61 - 0.70) , between the harvest and the harvest index - r = 0.81 (on average). In dry years, the correlation coefficient increased to 0.92. Research data confirms the greatest importance of the mass of grain from one ear and the plant in the formation of grain yield per unit area in both dry and wet years. In dry years, the correlation coefficient between yield and grain mass per plant was on average r = 0.80; in favorable years, r = 0.69. The relationship between yield and grain mass from the ear was greater — r = 0.84 and r = 0.82, respectively. Consequently, the breeding significance of the aboveground mass and the productivity of the ear, as a criterion for the selection of the crop, especially increases in the dry years. They were basic in the selection.

Elaboration and Characterization of the Properties of Refractory Cr Base Alloys

2010 ◽  
Vol 72 ◽  
pp. 46-52 ◽  
Author(s):  
Laurent Royer ◽  
Stéphane Mathieu ◽  
Christophe Liebaut ◽  
Pierre Steinmetz
Keyword(s):  
Mechanical Properties ◽  
Melting Point ◽  
Molten Glass ◽  
Energy Production ◽  
Creep Properties ◽  
Refractory Alloys ◽  
Industrial Use ◽  
Kinetics Of ◽  
Selection Of

For energy production and also for the glass industry, finding new refractory alloys which could permit to increase the process temperatures to 1200°C or more is a permanent challenge. Chromium base alloys can be good candidates, considering the melting point of Cr itself, and also its low corrosion rate in molten glass. Two families of alloys have been studied for this purpose, Cr-Mo-W and Cr-Ta-X alloys (X= Mo, Si..). A finer selection of compositions has been done, to optimize their chemical and mechanical properties. Kinetics of HT oxidation by air, of corrosion by molten glass and also creep properties of several alloys have been measured up to 1250°C. The results obtained with the best alloys (Cr-Ta base) give positive indications as regards the possibility of their industrial use.

Influence of the spray drying operating conditions on the estimated drying kinetics of emulsion single droplets and the properties of microencapsulated chia oil

2021 ◽  
Vol 383 ◽  
pp. 302-317
Author(s):  
M. Gabriela Bordón ◽  
Noelia P.X. Alasino ◽  
Vanina Martínez ◽  
Regina Gauna Peter ◽  
Ramiro Iturralde ◽  
...  
Keyword(s):  
Spray Drying ◽  
Drying Kinetics ◽  
Operating Conditions ◽  
Single Droplets ◽  
Kinetics Of ◽  
Chia Oil

scholarly journals Kinetics of Anti-SARS-CoV-2 Antibody Responses 3 Months Post Complete Vaccination with BNT162b2; A Prospective Study in 283 Health Workers

Cells ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 1942
Author(s):  
Evangelos Terpos ◽  
Ioannis P. Trougakos ◽  
Vangelis Karalis ◽  
Ioannis Ntanasis-Stathopoulos ◽  
Sentiljana Gumeni ◽  
...  
Keyword(s):  
Neutralizing Antibodies ◽  
Health Workers ◽  
Antibody Responses ◽  
Healthy Individuals ◽  
Younger Age ◽  
Constant Rate ◽  
Rate Of Decline ◽  
A Prospective Study ◽  
Kinetics Of ◽  
Over Time

The aim of this study was to investigate the kinetics of neutralizing antibodies (NAbs) and anti-SARS-CoV-2 anti-S-RBD IgGs up to three months after the second vaccination dose with the BNT162b2 mRNA vaccine. NAbs and anti-S-RBD levels were measured on days 1 (before the first vaccine shot), 8, 22 (before the second shot), 36, 50, and three months after the second vaccination (D111) (NCT04743388). 283 health workers were included in this study. NAbs showed a rapid increase from D8 to D36 at a constant rate of about 3% per day and reached a median (SD) of 97.2% (4.7) at D36. From D36 to D50, a slight decrease in NAbs values was detected and it became more prominent between D50 and D111 when the rate of decline was determined at −0.11 per day. The median (SD) NAbs value at D111 was 92.7% (11.8). A similar pattern was also observed for anti-S-RBD antibodies. Anti-S-RBDs showed a steeper increase during D22–D36 and a lower decline rate during D36–D111. Prior COVID-19 infection and younger age were associated with superior antibody responses over time. In conclusion, we found a persistent but declining anti-SARS-CoV-2 humoral immunity at 3 months following full vaccination with BNT162b2 in healthy individuals.

Numerical simulation and experimental performance research of cylindrical vane pump

2021 ◽  
pp. 095440622110200
Author(s):  
Yiqi Cheng ◽  
Xinhua Wang ◽  
Waheed Ur Rehman ◽  
Tao Sun ◽  
Hasan Shahzad ◽  
...  
Keyword(s):  
Numerical Analysis ◽  
Rotational Velocity ◽  
Geometric Theory ◽  
Mechanical Efficiency ◽  
Operating Conditions ◽  
Experimental Results ◽  
Field Analysis ◽  
Total Efficiency ◽  
Three Dimensional Model ◽  
Vane Pump

This study presents a novel cylindrical vane pump based on the traditional working principle. The efficiency of the cylindrical vane pump was verified by experimental validation and numerical analysis. Numerical analysis, such as kinematics analysis, was performed in Pro/Mechanism and unsteady flow-field analysis was performed using ANSYS FLUENT. The stator surface equations were derived using the geometric theory of the applied spatial triangulation function. A three-dimensional model of the cylindrical vane pump was established with the help of MATLAB and Pro/E. The kinematic analysis helped in developing kinematic equations for cylindrical vane pumps and proved the effectiveness of the structural design. The maximum inaccuracy error of the computational fluid dynamics (CFD) model was 5.7% compared with the experimental results, and the CFD results show that the structure of the pump was reasonable. An experimental test bench was developed, and the results were in excellent agreement with the numerical results of CFD. The experimental results show that the cylindrical vane pump satisfied the three-element design of a positive-displacement pump and the trend of changes in efficiency was the same for all types of efficiency under different operating conditions. Furthermore, the volumetric efficiency presented a nonlinear positive correlation with increased rotational velocity, the mechanical efficiency showed a nonlinear negative correlation, and the total efficiency first increased and then decreased. When the rotational velocity was 1.33[Formula: see text] and the discharge pressure was 0.68[Formula: see text], the total efficiency reached its maximum value.

Comparative kinetics of cytosine nucleosides. Influence of a 6-methyl substituent on degradation rates and pathways in aqueous buffers

1972 ◽  
Vol 15 (12) ◽  
pp. 1207-1214 ◽  
Author(s):  
Robert E. Notari ◽  
Donald T. Witiak ◽  
Joyce L. DeYoung ◽  
Ai Jeng Lin
Keyword(s):  
Methyl Substituent ◽  
Degradation Rates ◽  
Kinetics Of
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