scholarly journals Preliminary Study on New Alternative Binders through Re-Refined Engine Oil Bottoms (REOBs) and Industrial By-Product Additives

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7269
Author(s):  
Michele Porto ◽  
Paolino Caputo ◽  
Valeria Loise ◽  
Abraham A. Abe ◽  
Giulia Tarsi ◽  
...  

Recent studies have worked towards addressing environmental issues such as global warming and greenhouse gas emissions due to the increasing awareness of the depletion of natural resources. The asphalt industry is seeking to implement measures to reduce its carbon footprint and to promote sustainable operations. The reuse of several wastes and by-products is an example of a more eco-friendly activity that fulfils the circular economy principle. Among all possible solutions, the road pavement sector encourages, on one hand, the use of recycled materials as a partial replacement of the virgin lithic skeleton; on the other hand, it promotes the use of recycled materials to substituting for a portion of the petroleum bituminous binder. This study aims to use Re-refined Engine Oil Bottoms (REOBs) as a main substitute and additives from various industrial by-products as a full replacement for virgin bitumen, producing high-performing alternative binders. The REOBs have been improved by utilizing additives in an attempt to improve their specific properties and thus to bridge the gap between REOBs and traditional bituminous binders. An even larger amount of virgin and non-renewable resources can be saved using these new potential alternative binders together with the RAP aggregates. Thus, the reduction in the use of virgin materials is applied at the binder and the asphalt mixture levels. Rheological, spectroscopic, thermogravimetric, and mechanical analysis were used to characterize the properties, composition, and characteristics of the REOBs, REOB-modified binders, and asphalt mixes. Thanks to the rheological investigations of possible alternative binders, 18 blends were selected, since they behaved like an SBS-modified bitumen, and then they were used for producing the corresponding asphalt mixtures. The preliminary mechanical analysis of the asphalt mixtures shows that six mixes have promising responses in terms of stiffness, tensile resistance, and water susceptibility. Nevertheless, the high variability of recycled materials and by-products has to be taken into consideration during the definition of alternative binders and recycled asphalt mixtures. In fact, this study highlights the crucial effects of the chemical composition of the constituents and their compatibility on the behaviour of the final product. This preliminary study represents a first attempt to define alternative binders, which can be used in combination with recycled aggregates for producing more sustainable road materials. However, further analysis is necessary in order to assess the durability and the ageing tendency of the materials.

2017 ◽  
Vol 19 (6) ◽  
pp. 1489-1498 ◽  
Author(s):  
Pedro Lastra-González ◽  
Miguel A. Calzada-Pérez ◽  
Daniel Castro-Fresno ◽  
Irune Indacoechea-Vega

2020 ◽  
Vol 10 (4) ◽  
pp. 1204 ◽  
Author(s):  
Giulia Tarsi ◽  
Paolino Caputo ◽  
Michele Porto ◽  
Cesare Sangiorgi

Thanks to greater attention to the environment and the depletion of non-renewable resources, the sustainability and the circular economy have become crucial topics. The current trend of pavement engineering is to reduce the use of standard bitumen by replacing it with more sustainable materials such as industrial residues and by-products. In this regard, the present study aims to characterize innovative extended bitumen using recycled materials. Due to promising preliminary results as bitumen modifiers, the powdered rubber from end-of-life tires and the re-refined engine oil bottom (REOB) have been investigated as feasible components of bitumen extenders. Nevertheless, several variables strongly affect the performance of the resulting binder, which cannot be neglected. Hence, this research focuses on the rubber–REOB interaction in order to evaluate their optimum ratio, which may maximize the use and advantages of both recycled materials as suitable partial replacements for bitumen. Various rubber–REOB ratios were considered and investigated by means of low and high frequency nuclear magnetic resonance (NMR) spectrometers and scanning electron microscope (SEM).


Author(s):  
Ki Hoon Moon ◽  
Augusto Cannone Falchetto ◽  
Di Wang ◽  
Yun Su Kim

Using reclaimed asphalt material for rehabilitation and construction of new asphalt pavements is currently a common practice not only in view of the economic benefits associated with this process but also because of the reduced exploitation of natural resources. For this reason, road authorities have implemented recommendations and guidelines to regulate the use of reclaimed asphalt pavement (RAP) and other recycled materials such as industrial by-products. Nevertheless, the combined use of different recycled materials is not commonly addressed. In this paper, the effect of adding RAP and taconite (a mining by-product) on fatigue and low temperature properties of asphalt mixture was investigated with two different testing geometries: indirect tensile (IDT) and semi-circular bending (SCB). Fatigue behavior, creep stiffness, relaxation modulus, low temperature fracture energy, and fracture toughness were also evaluated, computed, and then compared. A more brittle behavior was observed for mixture prepared with RAP material, however, the mechanical performance was not significantly different for mixtures containing 20% RAP alone and in combination with 50% taconite compared with conventional asphalt mixtures designed with virgin material. This was not the case when RAP content was increased up to 50%, showing a substantially poorer response both in terms of fatigue and low temperature characteristics and suggesting the RAP had a dominant effect. The present exploratory research seems to support the idea of combining RAP and different industry by-products, such as taconite, as long as the RAP content is kept below a specific threshold.


2021 ◽  
Vol 13 (4) ◽  
pp. 2146
Author(s):  
Anik Gupta ◽  
Carlos J. Slebi-Acevedo ◽  
Esther Lizasoain-Arteaga ◽  
Jorge Rodriguez-Hernandez ◽  
Daniel Castro-Fresno

Porous asphalt (PA) mixtures are more environmentally friendly but have lower durability than dense-graded mixtures. Additives can be incorporated into PA mixtures to enhance their mechanical strength; however, they may compromise the hydraulic characteristics, increase the total cost of pavement, and negatively affect the environment. In this paper, PA mixtures were produced with 5 different types of additives including 4 fibers and 1 filler. Their performances were compared with the reference mixtures containing virgin bitumen and polymer-modified bitumen. The performance of all mixes was assessed using: mechanical, hydraulic, economic, and environmental indicators. Then, the Delphi method was applied to compute the relative weights for the parameters in multi-criteria decision-making methods. Evaluation based on distance from average solution (EDAS), technique for order of the preference by similarity to ideal solution (TOPSIS), and weighted aggregated sum product assessment (WASPAS) were employed to rank the additives. According to the results obtained, aramid pulp displayed comparable and, for some parameters such as abrasion resistance, even better performance than polymer-modified bitumen, whereas cellulose fiber demonstrated the best performance regarding sustainability, due to economic and environmental benefits.


2021 ◽  
Vol 13 (5) ◽  
pp. 2756
Author(s):  
Federica Vitale ◽  
Maurizio Nicolella

Because the production of aggregates for mortar and concrete is no longer sustainable, many attempts have been made to replace natural aggregates (NA) with recycled aggregates (RA) sourced from factories, recycling centers, and human activities such as construction and demolition works (C&D). This article reviews papers concerning mortars with fine RA from C&D debris, and from the by-products of the manufacturing and recycling processes of building materials. A four-step methodology based on searching, screening, clustering, and summarizing was proposed. The clustering variables were the type of aggregate, mix design parameters, tested properties, patents, and availability on the market. The number and the type of the clustering variables of each paper were analysed and compared. The results showed that the mortars were mainly characterized through their physical and mechanical properties, whereas few durability and thermal analyses were carried out. Moreover, few fine RA were sourced from the production waste of construction materials. Finally, there were no patents or products available on the market. The outcomes presented in this paper underlined the research trends that are useful to improve the knowledge on the suitability of fine RA from building-related processes in mortars.


2021 ◽  
Vol 13 (6) ◽  
pp. 3315
Author(s):  
Mansour Fakhri ◽  
Danial Arzjani ◽  
Pooyan Ayar ◽  
Maede Mottaghi ◽  
Nima Arzjani

The use of waste materials has been increasingly conceived as a sustainable alternative to conventional materials in the road construction industry, as concerns have arisen from the uncontrolled exploitation of natural resources in recent years. Re-refined acidic sludge (RAS) obtained from a waste material—acidic sludge—is an alternative source for bitumen. This study’s primary purpose is to evaluate the resistance of warm mix asphalt (WMA) mixtures containing RAS and a polymeric additive against moisture damage and rutting. The modified bitumen studied in this research is a mixture of virgin bitumen 60/70, RAS (10, 20, and 30%), and amorphous poly alpha olefin (APAO) polymer. To this end, Marshall test, moisture susceptibility tests (i.e., tensile strength ratio (TSR), residual Marshall, and Texas boiling water), resilient modulus, and rutting assessment tests (i.e., dynamic creep, Marshall quotient, and Kim) were carried out. The results showed superior values for modified mixtures compared to the control mix considering the Marshall test. Moreover, the probability of a reduction in mixes’ moisture damage was proved by moisture sensitivity tests. The results showed that modified mixtures could improve asphalt mixtures’ permanent deformation resistance and its resilience modulus. Asphalt mixtures containing 20% RAS (substitute for bitumen) showed a better performance in all the experiments among the samples tested.


2016 ◽  
Vol 78 (7-2) ◽  
Author(s):  
Fauzan Mohd Jakarni ◽  
Muhammad Fudhail Rosli ◽  
Nur Izzi Md Yusoff ◽  
Md Maniruzzaman A Aziz ◽  
Ratnasamy Muniandy ◽  
...  

This paper presents a review of moisture damage performance tests on asphalt mixtures. The moisture damage remains to be a detriment to the durability of the Hot Mix Asphalt (HMA) pavement. Moisture damage can be defined in forms of adhesive failure between bitumen and aggregates and cohesive failure within bitumen. Aggregate mineralogy, bitumen characteristics and anti-stripping additive dominantly influence the performance of asphalt mixtures towards moisture damage alongside construction methods, climate and traffic loading. Various laboratory test methods have been developed to quantify the moisture damage performance of asphalt mixtures by resembles the action in the field, including qualitative test such as Boiling Water Test (ASTM D3625) and quantitative tests such as Modified Lottman Test (AASHTO T283). Both of these tests consist of two phases, which are conditioning and evaluation phase. This paper will review the effectiveness of the selected available tests based on various asphalt mixtures materials. Generally, this study indicates that asphalt mixtures consisted of limestone aggregates, modified bitumen and addition of anti-stripping additives will provide more resistant towards moisture damage. 


2018 ◽  
Vol 9 (4) ◽  
pp. 60 ◽  
Author(s):  
Giuseppe Cavallaro ◽  
Giuseppe Lazzara ◽  
Lorenzo Lisuzzo ◽  
Stefana Milioto ◽  
Filippo Parisi

We investigated the efficacy of several nanoclays (halloysite, sepiolite and laponite) as nanofillers for Mater-Bi, which is a commercial bioplastic extensively used within food packaging applications. The preparation of Mater-Bi/nanoclay nanocomposite films was easily achieved by means of the solvent casting method from dichloroethane. The prepared bio-nanocomposites were characterized by dynamic mechanical analysis (DMA) in order to explore the effect of the addition of the nanoclays on the mechanical behavior of the Mater-Bi-based films. Tensile tests found that filling Mater-Bi with halloysite induced the most significant improvement of the mechanical performances under traction force, while DMA measurements under the oscillatory regime showed that the polymer glass transition was not affected by the addition of the nanoclay. The tensile properties of the Mater-Bi/halloysite nanotube (HNT) films were competitive compared to those of traditional petroleum plastics in terms of the elastic modulus and stress at the breaking point. Both the mechanical response to the temperature and the tensile properties make the bio-nanocomposites appropriate for food packaging and smart coating purposes. Here, we report a preliminary study of the development of sustainable hybrid materials that could be employed in numerous industrial and technological applications within materials science and pharmaceutics.


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