scholarly journals Nanocellulose Xerogel as Template for Transparent, Thick, Flame-Retardant Polymer Nanocomposites

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3032
Author(s):  
Wataru Sakuma ◽  
Shuji Fujisawa ◽  
Lars A. Berglund ◽  
Tsuguyuki Saito
Keyword(s):  
Polymer Composites ◽  
Flexural Modulus ◽  
Cellulose Nanofibers ◽  
High Strength ◽  
High Porosity ◽  
Load Bearing ◽  
Surface Areas ◽  
Reinforced Composite ◽  
Reinforcing Fillers ◽  
The Matrix

Cellulose nanofibers (CNFs) have excellent properties, such as high strength, high specific surface areas (SSA), and low coefficients of thermal expansion (CTE), making them a promising candidate for bio-based reinforcing fillers of polymers. A challenge in the field of CNF-reinforced composite research is to produce strong and transparent CNF/polymer composites that are sufficiently thick for use as load-bearing structural materials. In this study, we successfully prepared millimeter-thick, transparent CNF/polymer composites using CNF xerogels, with high porosity (~70%) and high SSA (~350 m2 g−1), as a template for monomer impregnation. A methacrylate was used as the monomer and was cured by UV irradiation after impregnation into the CNF xerogels. The CNF xerogels effectively reinforced the methacrylate polymer matrix, resulting in an improvement in the flexural modulus (up to 546%) and a reduction in the CTE value (up to 78%) while maintaining the optical transparency of the matrix polymer. Interestingly, the composites exhibited flame retardancy at high CNF loading. These unique features highlight the applicability of CNF xerogels as a reinforcing template for producing multifunctional and load-bearing polymer composites.

Study on Mechanical Property of Aluminium 6061 with E Glass Fiber Reinforced Composite

2018 ◽  
Vol 877 ◽  
pp. 50-53 ◽  
Author(s):  
Vinayashree ◽  
R. Shobha
Keyword(s):  
Mechanical Properties ◽  
Glass Fiber ◽  
High Strength ◽  
Matrix Alloy ◽  
Stir Casting ◽  
Reinforced Composite ◽  
Reinforcement Content ◽  
Glass Fiber Reinforced ◽  
The Matrix ◽  
Glass Fibre Reinforced

Aluminium composites are in predominant use due to their lower weight and high strength among the MMC’s. Aluminium 6061 is selected as matrix and E-glass fiber is selected as reinforcement. Fabrication of composite is done by stir casting method. Each fabrication carries the E-glass reinforcement content varied from 2% to 10%. The present article attempts to evaluate the mechanical properties of E-glass fibre reinforced composite and study the effect of reinforcement on the matrix alloy through mechanical properties. When compared to ascast mechanical properties the UTS has increased from 74.28 N/sq mm to 146.8 N/sq mm for a composite at 6% E-glass. The hardness of as-cast has also increased from 22 RHB to 43 RHB at 6% E-glass and the wear of composite has exhibited a decreasing tend with increase in reinforcement content along the sliding distance. The results are analyzed in certain depth in the current paper. The mechanical properties of composites have improved with the increase in the weigh percentage of glass fiber in the aluminium matrix.

scholarly journals Anisotropic Cellulose Nanofibers/Polyvinyl Alcohol/Graphene Aerogels Fabricated by Directional Freeze-drying as Effective Oil Adsorbents

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 712 ◽  
Author(s):  
Lijie Zhou ◽  
Shengcheng Zhai ◽  
Yiming Chen ◽  
Zhaoyang Xu
Keyword(s):  
Polyvinyl Alcohol ◽  
Freeze Drying ◽  
High Efficiency ◽  
Cellulose Nanofibers ◽  
High Strength ◽  
Dip Coating ◽  
High Porosity ◽  
Water Contact ◽  
Water Separation ◽  
Composite Aerogel

Under the current situation of frequent oil spills, the development of green and recyclable high-efficiency oil-absorbing aerogel materials has attracted wide attention from researchers. In this study, we report a high-strength, three-dimensional hydrophobic cellulose nanofiber (CNF)/polyvinyl alcohol (PVA)/graphene oxide (GO) composite aerogel with an anisotropic porous structure, which was fabricated by directional freeze-drying technology using anisotropically grown ice crystals as a template, followed by hydrophobic treatment with a simple dip coating process. The prepared composite aerogel presented anisotropic multi-level pore microstructures, low density (17.95 mg/cm3) and high porosity (98.8%), good hydrophobicity (water contact angle of 142°) and great adsorption capacity (oil absorption reaching 96 times its own weight). More importantly, the oriented aerogel had high strength, whose compressive stress at 80% strain reached 0.22 MPa and could bear more than 22,123 times its own weight without deformation. Therefore, the CNF/PVA/GO composite aerogel prepared by a simple and easy-to-operate directional freeze-drying method is a promising absorbent for oil-water separation.

Electron microscopy of rod/coil molecular composites

1983 ◽  
Vol 41 ◽  
pp. 32-33
Author(s):  
S. J. Krause ◽  
W. W. Adams
Keyword(s):  
Critical Factor ◽  
High Strength ◽  
Chain Polymer ◽  
New Class ◽  
Reinforced Composite ◽  
Transmission Electron ◽  
The Matrix ◽  
Molecular Composites ◽  
Flexible Coil ◽  
Rigid Rod

Molecular composites are a new class of structural polymers which are lightweight, high-strength, high-modulus, and environmentally resistant. A rigid-rod, extended chain, polymer is used to reinforce a matrix of flexible, coil-like polymer with the intent of achieving a composite on the molecular level which is analagous to a macroscopic chopped-fiber reinforced composite. The critical factor in making a molecular composite is that the rod-like reinforcing molecules be well dispersed and not phase separate from the matrix polymer to insure that the aspect ratio (ratio of length to width) of the reinforcing phase has a high value. This paper reports the first transmission electron microsopy (TEM) study of phase separation in molecular composites.

Impact Strength, Flexural Modulus and Wear Rate of PMMA Composites Reinforced by Eggshell Powders

2020 ◽  
Vol 38 (7A) ◽  
pp. 960-966
Author(s):  
Aseel M. Abdullah ◽  
Hussein Jaber ◽  
Hanaa A. Al-Kaisy
Keyword(s):  
Impact Strength ◽  
Wear Rate ◽  
Flexural Modulus ◽  
Matrix Material ◽  
Weight Fraction ◽  
Pure Pmma ◽  
Calcination Process ◽  
The Matrix ◽  
The Impact ◽  
Interface Bond

In the present study, the impact strength, flexural modulus, and wear rate of poly methyl methacrylate (PMMA) with eggshell powder (ESP) composites have been investigated. The PMMA used as a matrix material reinforced with ESP at two different states (including untreated eggshell powder (UTESP) and treated eggshell powder (TESP)). Both UTESP and TESP were mixed with PMMA at different weight fractions ranged from (1-5) wt.%. The results revealed that the mechanical properties of the PMMA/ESP composites were enhanced steadily with increasing eggshell contents. The samples with 5 wt.% of UTESP and TESP additions give the maximum values of impact strength, about twice the value of the pure PMMA sample. The calcination process of eggshells powders gives better properties of the PMMA samples compared with the UTESP at the same weight fraction due to improvements in the interface bond between the matrix and particles. The wear characteristics of the PMMA composites decrease by about 57% with increases the weight fraction of TESP up to 5 wt.%. The flexural modulus values are slightly enhanced by increasing of the ESP contents in the PMMA composites.

•Reinforcing fillers for polymer composites made from nonwoven organic materials

2018 ◽  
Vol 0 (10) ◽  
pp. 9-13
Author(s):  
A. N. Marycheva ◽  
◽  
T. A. Guzeva ◽  
P. M. Pye ◽  
L. Kh. Tun ◽  
...  
Keyword(s):  
Polymer Composites ◽  
Organic Materials ◽  
Reinforcing Fillers

STRENX 700

Alloy Digest ◽  
2017 ◽  
Vol 66 (2) ◽  
Keyword(s):  
Fracture Toughness ◽  
Yield Strength ◽  
Physical Properties ◽  
Structural Steel ◽  
Tensile Properties ◽  
High Strength ◽  
Load Bearing ◽  
Minimum Yield

Abstract Strenx 700 is a high-strength structural steel with a minimum yield strength of 650–700 MPa (94–102 ksi) depending on thickness. Strenx 700 meets the requirements of EN 10 025-6 for the S690 grade and thicknesses. Typical applications include demanding load-bearing structures. This datasheet provides information on composition, physical properties, and tensile properties as well as fracture toughness. It also includes information on surface qualities as well as forming, machining, and joining. Filing Code: SA-779. Producer or source: SSAB Swedish Steel Inc..

Load-Bearing Capacity of Direct Inlay-Retained Fibre-reinforced Composite Fixed Partial Dentures with Different Cross-Sectional Pontic Design

2017 ◽  
Vol 68 (1) ◽  
pp. 94-100
Author(s):  
Oana Tanculescu ◽  
Adrian Doloca ◽  
Raluca Maria Vieriu ◽  
Florentina Mocanu ◽  
Gabriela Ifteni ◽  
...  
Keyword(s):  
Bearing Capacity ◽  
Fracture Pattern ◽  
Load Bearing Capacity ◽  
Cross Sectional ◽  
Load Bearing ◽  
Reinforced Composite ◽  
Polyethylene Fibre

The load-bearing capacity and fracture pattern of direct inlay-retained FRC FDPs with two different cross-sectional designs of the ponticwere tested. The aim of the study was to evaluate a new fibre disposition. Two types of composites, Filtek Bulk Fill Posterior Restorative and Filtek Z250 (3M/ESPE, St. Paul, MN, USA), and one braided polyethylene fibre, Construct (Kerr, USA) were used. The results of the study suggested that the new tested disposition of the fibres prevented in some extend the delamination of the composite on buccal and facial sides of the pontic and increased the load-bearing capacity of the bridges.

Promising hybrid fabrics based on carbon and aramid fibers as a reinforcing filler for polymer composites

2019 ◽  
pp. 86-95 ◽  
Author(s):  
G. F. Zhelezina ◽  
V. G. Bova ◽  
S. I. Voinov ◽  
A. Ch. Kan
Keyword(s):  
Composite Material ◽  
Polymer Composites ◽  
Carbon Fibers ◽  
Mechanical Characteristics ◽  
High Strength ◽  
High Modulus ◽  
Hybrid Composite Material ◽  
Hybrid Fabric ◽  
Reinforcing Filler ◽  
Physical And Mechanical Characteristics

The paper considers possibilities of using a hybrid fabric made of high-modulus carbon yarn brand ZhGV and high-strength aramid yarns brand Rusar-NT for polymer composites reinforcement. The results of studies of the physical and mechanical characteristics of hybrid composite material and values of the implementation of the strength and elasticity carbon fibers and aramid module for composite material are presented. 

scholarly journals Self-Reinforced Nylon 6 Composite for Smart Vibration Damping

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1235
Author(s):  
Bidita Salahuddin ◽  
Rahim Mutlu ◽  
Tajwar A. Baigh ◽  
Mohammed N. Alghamdi ◽  
Shazed Aziz
Keyword(s):  
Matrix Material ◽  
Nylon 6 ◽  
Vibration Damping ◽  
Vibration Energy ◽  
Damping Factor ◽  
Passive Vibration Control ◽  
Reinforced Composite ◽  
Coiled Structure ◽  
The Matrix ◽  
3D Printed

Passive vibration control using polymer composites has been extensively investigated by the engineering community. In this paper, a new kind of vibration dampening polymer composite was developed where oriented nylon 6 fibres were used as the reinforcement, and 3D printed unoriented nylon 6 was used as the matrix material. The shape of the reinforcing fibres was modified to a coiled structure which transformed the fibres into a smart thermoresponsive actuator. This novel self-reinforced composite was of high mechanical robustness and its efficacy was demonstrated as an active dampening system for oscillatory vibration of a heated vibrating system. The blocking force generated within the reinforcing coiled actuator was responsible for dissipating vibration energy and increase the magnitude of the damping factor compared to samples made of non-reinforced nylon 6. Further study shows that the appropriate annealing of coiled actuators provides an enhanced dampening capability to the composite structure. The extent of crystallinity of the reinforcing actuators is found to directly influence the vibration dampening capacity.

scholarly journals Efficient Improvement in Fracture Toughness of Laminated Composite by Interleaving Functionalized Nanofibers

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2509
Author(s):  
Seyed Mohammad Javad Razavi ◽  
Rasoul Esmaeely Neisiany ◽  
Moe Razavi ◽  
Afsaneh Fakhar ◽  
Vigneshwaran Shanmugam ◽  
...  
Keyword(s):  
Fracture Toughness ◽  
Fracture Behavior ◽  
Laminated Composite ◽  
Carbon Phase ◽  
Reinforced Composite ◽  
Reinforcing Agent ◽  
The Matrix ◽  
As Stress ◽  
Double Cantilever Beam Test ◽  
Pan Nanofiber

Functionalized polyacrylonitrile (PAN) nanofibers were used in the present investigation to enhance the fracture behavior of carbon epoxy composite in order to prevent delamination if any crack propagates in the resin rich area. The main intent of this investigation was to analyze the efficiency of PAN nanofiber as a reinforcing agent for the carbon fiber-based epoxy structural composite. The composites were fabricated with stacked unidirectional carbon fibers and the PAN powder was functionalized with glycidyl methacrylate (GMA) and then used as reinforcement. The fabricated composites’ fracture behavior was analyzed through a double cantilever beam test and the energy release rate of the composites was investigated. The neat PAN and functionalized PAN-reinforced samples had an 18% and a 50% increase in fracture energy, respectively, compared to the control composite. In addition, the samples reinforced with functionalized PAN nanofibers had 27% higher interlaminar strength compared to neat PAN-reinforced composite, implying more efficient stress transformation as well as stress distribution from the matrix phase (resin-rich area) to the reinforcement phase (carbon/phase) of the composites. The enhancement of fracture toughness provides an opportunity to alleviate the prevalent issues in laminated composites for structural operations and facilitate their adoption in industries for critical applications.

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