scholarly journals Electrochemical Characterization of Mancozeb Degradation for Wastewater Treatment Using a Sensor Based on Poly (3,4-ethylenedioxythiophene) (PEDOT) Modified with Carbon Nanotubes and Gold Nanoparticles

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1449 ◽  
Author(s):  
Roy Zamora-Sequeira ◽  
Fernando Alvarado-Hidalgo ◽  
Diana Robles-Chaves ◽  
Giovanni Sáenz-Arce ◽  
Esteban Avendano-Soto ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Gold Nanoparticles ◽  
Wastewater Treatment ◽  
High Performance ◽  
Large Scale ◽  
Wastewater Treatment Plants ◽  
High Resolution Mass Spectrometry ◽  
Low Cost ◽  
Ethylene Thiourea ◽  
Electrochemical Electrode

Mancozeb is a worldwide fungicide used on a large scale in agriculture. The active component and its main metabolite, ethylene thiourea, has been related to health issues. Robust, fast, and reliable methodologies to quantify its presence in water are of great importance for environmental and health reasons. The electrochemical evaluation of mancozeb using a low-cost electrochemical electrode modified with poly (3,4-ethylene dioxythiophene), multi-walled carbon nanotubes, and gold nanoparticles is a novel strategy to provide an in-situ response for water pollution from agriculture. Additionally, the thermal-, electrochemical-, and photo-degradation of mancozeb and the production of ethylene thiourea under controlled conditions were evaluated in this research. The mancozeb solutions were characterized by electrochemical oxidation and ultraviolet-visible spectrophotometry, and the ethylene thiourea concentration was measured using ultra-high-performance liquid chromatography high-resolution mass spectrometry. The degradation study of mancozeb may provide routes for treatment in wastewater treatment plants. Therefore, a low-cost electrochemical electrode was fabricated to detect mancozeb in water with a robust electrochemical response in the linear range as well as a quick response at a reduced volume. Hence, our novel modified electrode provides a potential technique to be used in environmental monitoring for pesticide detection.

Determination of pharmaceutical residues and assessment of their removal efficiency at the Daugavgriva municipal wastewater treatment plant in Riga, Latvia

2016 ◽  
Vol 75 (2) ◽  
pp. 387-396 ◽  
Author(s):  
I. Reinholds ◽  
O. Muter ◽  
I. Pugajeva ◽  
J. Rusko ◽  
I. Perkons ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
High Performance ◽  
Emerging Contaminants ◽  
Municipal Wastewater ◽  
Wastewater Treatment Plants ◽  
High Resolution Mass Spectrometry ◽  
Treatment Plant ◽  
Pharmaceutical Products ◽  
Municipal Wastewater Treatment ◽  
Toxicological Studies

Pharmaceutical products (PPs) belong to emerging contaminants that may accumulate along with other chemical pollutants in wastewaters (WWs) entering industrial and/or urban wastewater treatment plants (WWTPs). In the present study, the technique of ultra-high-performance liquid chromatography coupled to Orbitrap high-resolution mass spectrometry (Orbitrap-HRMS) was applied for the analysis of 24 multi-class PPs in WW samples collected at different technological stages of Daugavgriva WWTP located in Riga, Latvia. Caffeine and acetaminophen levels in the range of 7,570–11,403 ng/L and 810–1,883 ng/L, respectively, were the predominant compounds among 19 PPs determined in the WW. The results indicate that aerobic digestion in biological ponds was insufficiently effective to degrade most of the PPs (reduction efficiency <0–50.0%) with the exception of four PPs that showed degradation efficiency varying from 55.0 to 99.9%. Tests of short-term chemical and enzymatic hydrolysis for PP degradation in WW samples were performed, and the results reflected the complexity of different degradation mechanisms and physicochemical transformations of PPs. The toxicological studies of WW impact on Daphnia magna indicated gradual reduction of the total toxicity through the treatment stages at the WWTP.

scholarly journals Donnan Membrane Process for the Selective Recovery and Removal of Target Metal Ions—A Mini Review

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 358
Author(s):  
Dennis Asante-Sackey ◽  
Sudesh Rathilal ◽  
Emmanuel Kweinor Tetteh ◽  
Elorm Obotey Ezugbe ◽  
Lingham V. Pillay
Keyword(s):  
Wastewater Treatment ◽  
Metal Ions ◽  
Large Scale ◽  
Wastewater Treatment Plants ◽  
Low Cost ◽  
Potential Gradient ◽  
External Energy ◽  
Membrane Technologies ◽  
Exchange Membrane ◽  
Pressure Driven

Membrane-based water purification technologies contribute significantly to water settings, where it is imperative to use low-cost energy sources to make the process economically and technically competitive for large-scale applications. Donnan membrane processes (DMPs) are driven by a potential gradient across an ion exchange membrane and have an advantage over fouling in conventional pressure driven membrane technologies, which are gaining attention. DMP is a removal, recovery and recycling technology that is commonly used for separation, purification and the concentrating of metals in different water and waste streams. In this study, the principle and application of DMP for sustainable wastewater treatment and prospects of chemical remediation are reviewed and discussed. In addition, the separation of dissolved metal ions in wastewater settings without the use of pressure driven gradients or external energy supply membrane technologies is highlighted. Furthermore, DMP distinctive configurations and operational factors are explored and the prospects of integrating them into the wastewater treatment plants are recommended.

Bottlenecks in the Implementation of On-Site Wastewater Treatment Plants on a Large Scale in The Netherlands

1990 ◽  
Vol 22 (3-4) ◽  
pp. 291-298
Author(s):  
Frits A. Fastenau ◽  
Jaap H. J. M. van der Graaf ◽  
Gerard Martijnse
Keyword(s):  
Wastewater Treatment ◽  
The Netherlands ◽  
Large Scale ◽  
Wastewater Treatment Plants ◽  
Housing Stock ◽  
Research Work ◽  
Field Research ◽  
Domestic Wastewater ◽  
Research Programme ◽  
Definition Of

More than 95 % of the total housing stock in the Netherlands is connected to central sewerage systems and in most cases the wastewater is treated biologically. As connection to central sewerage systems has reached its economic limits, interest in on-site treatment of the domestic wastewater of the remaining premises is increasing. A large scale research programme into on-site wastewater treatment up to population equivalents of 200 persons has therefore been initiated by the Dutch Ministry of Housing, Physical Planning and Environment. Intensive field-research work did establish that the technological features of most on-site biological treatment systems were satisfactory. A large scale implementation of these systems is however obstructed in different extents by problems of an organisational, financial and/or juridical nature and management difficulties. At present research is carried out to identify these bottlenecks and to analyse possible solutions. Some preliminary results are given which involve the following ‘bottlenecks':-legislation: absence of co-ordination and absence of a definition of ‘surface water';-absence of subsidies;-ownership: divisions in task-setting of Municipalities and Waterboards; divisions involved with cost-sharing;-inspection; operational control and maintenance; organisation of management;-discharge permits;-pollution levy;-sludge disposal. Final decisions and practical elaboration of policies towards on-site treatment will have to be formulated in a broad discussion with all the authorities and interest groups involved.

Application of nanomaterials in microbial-cell biosensor constructions

2015 ◽  
Vol 69 (1) ◽  
Author(s):  
Jana Šefčovičová ◽  
Jan Tkac
Keyword(s):  
Carbon Nanotubes ◽  
Gold Nanoparticles ◽  
Rapid Detection ◽  
Food Industry ◽  
Low Cost ◽  
Microbial Cell ◽  
Direct Connection ◽  
Qualitative Detection ◽  
Analytical Tools ◽  
Cell Biosensor

AbstractMicrobial cell biosensors, where cells are in direct connection with a transducer enabling quantitative and qualitative detection of an analyte, are very promising analytical tools applied mainly for assays in the environmental field, food industry or biomedicine. Microbial cell biosensors are an excellent alternative to conventional analytical methods due to their specificity, rapid detection and low cost of analysis. Nowadays, nanomaterials are often used in the construction of biosensors to improve their sensitivity and stability. In this review, the combination of microbial and other individual cells with different nanomaterials (carbon nanotubes, graphene, gold nanoparticles, etc.) for the construction of biosensors is described and their applications are provided as well.

scholarly journals Functionalized Carbon Nanotubes (CNTs) for Water and Wastewater Treatment: Preparation to Application

2021 ◽  
Vol 13 (10) ◽  
pp. 5717
Author(s):  
Mian Muhammad-Ahson Aslam ◽  
Hsion-Wen Kuo ◽  
Walter Den ◽  
Muhammad Usman ◽  
Muhammad Sultan ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Wastewater Treatment ◽  
Water Resources ◽  
Large Scale ◽  
Industrial Applications ◽  
Biological Species ◽  
Special Focus ◽  
Water And Wastewater Treatment ◽  
Adsorption Sites ◽  
Water And Wastewater

As the world human population and industrialization keep growing, the water availability issue has forced scientists, engineers, and legislators of water supply industries to better manage water resources. Pollutant removals from wastewaters are crucial to ensure qualities of available water resources (including natural water bodies or reclaimed waters). Diverse techniques have been developed to deal with water quality concerns. Carbon based nanomaterials, especially carbon nanotubes (CNTs) with their high specific surface area and associated adsorption sites, have drawn a special focus in environmental applications, especially water and wastewater treatment. This critical review summarizes recent developments and adsorption behaviors of CNTs used to remove organics or heavy metal ions from contaminated waters via adsorption and inactivation of biological species associated with CNTs. Foci include CNTs synthesis, purification, and surface modifications or functionalization, followed by their characterization methods and the effect of water chemistry on adsorption capacities and removal mechanisms. Functionalized CNTs have been proven to be promising nanomaterials for the decontamination of waters due to their high adsorption capacity. However, most of the functional CNT applications are limited to lab-scale experiments only. Feasibility of their large-scale/industrial applications with cost-effective ways of synthesis and assessments of their toxicity with better simulating adsorption mechanisms still need to be studied.

scholarly journals Fate of selected pharmaceuticals and personal care products after secondary wastewater treatment processes in Taiwan

2010 ◽  
Vol 62 (10) ◽  
pp. 2450-2458 ◽  
Author(s):  
Angela Yu-Chen Lin ◽  
Cheng-Fan Lin ◽  
Yu-Ting Tsai ◽  
Hank Hui-Hsiang Lin ◽  
Jie Chen ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
High Performance ◽  
Wastewater Treatment Plants ◽  
Solid Phase ◽  
Personal Care Products ◽  
Personal Care ◽  
Matrix Interference ◽  
Treatment Processes ◽  
Liquid Chromatography Tandem Mass ◽  
Removal Efficiencies

Pharmaceuticals and personal care products (PPCPs) constitute a class of chemicals of emerging concern due to the potential risks they pose to organisms and the environment, even at low concentrations (ng/L). Recent studies have found that PPCPs are not efficiently removed in secondary wastewater treatment plants (WWTPs). This study has: (1) simultaneously investigated the occurrence of sixty-one PPCPs using solid phase extraction and high-performance liquid chromatography-tandem mass spectrometry, (2) evaluated removal efficiencies of target PPCPs in six WWTPs that discharge effluents into major Taiwanese rivers, and lastly (3) examined matrix interference during analysis of target PPCPs in water samples. The twenty target PPCPs were chosen for their high detection frequencies, high influent concentrations, and stability during wastewater treatment processes. Caffeine and acetaminophen were detected at the highest concentrations (as high as 24,467 and 33,400 ng/L) and were effectively removed (both >96%); other PPCPs were detected in the high ng/L range but were not effectively removed. Matrix interference (by ion suppression or enhancement) during the analysis resulted in underestimation of the removal efficiencies of erythromycin-H2O, cefazolin, clarithromycin, ibuprofen, diclofenac, clofibric acid and gemfibrozil.

scholarly journals Nanocone-Shaped Carbon Nanotubes Field-Emitter Array Fabricated by Laser Ablation

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3244
Author(s):  
Jiuzhou Zhao ◽  
Zhenjun Li ◽  
Matthew Thomas Cole ◽  
Aiwei Wang ◽  
Xiangdong Guo ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Laser Ablation ◽  
High Performance ◽  
Low Cost ◽  
Field Emitter ◽  
Beam Focusing ◽  
Field Emitter Arrays ◽  
Emitter Array ◽  
Field Emitter Array ◽  
Tip Radius

The nanocone-shaped carbon nanotubes field-emitter array (NCNA) is a near-ideal field-emitter array that combines the advantages of geometry and material. In contrast to previous methods of field-emitter array, laser ablation is a low-cost and clean method that does not require any photolithography or wet chemistry. However, nanocone shapes are hard to achieve through laser ablation due to the micrometer-scale focusing spot. Here, we develop an ultraviolet (UV) laser beam patterning technique that is capable of reliably realizing NCNA with a cone-tip radius of ≈300 nm, utilizing optimized beam focusing and unique carbon nanotube–light interaction properties. The patterned array provided smaller turn-on fields (reduced from 2.6 to 1.6 V/μm) in emitters and supported a higher (increased from 10 to 140 mA/cm2) and more stable emission than their unpatterned counterparts. The present technique may be widely applied in the fabrication of high-performance CNTs field-emitter arrays.

scholarly journals Process Design Kit and Design Automation for Flexible Hybrid Electronics

2019 ◽  
Vol 16 (3) ◽  
pp. 117-123
Author(s):  
Tsung-Ching Huang ◽  
Ting Lei ◽  
Leilai Shao ◽  
Sridhar Sivapurapu ◽  
Madhavan Swaminathan ◽  
...  
Keyword(s):  
Process Design ◽  
Design Automation ◽  
High Performance ◽  
Large Scale ◽  
Low Cost ◽  
Thin Film Transistor ◽  
Solution Process ◽  
Oxide Semiconductor ◽  
Wearable Electronics ◽  
Wide Range

Abstract High-performance low-cost flexible hybrid electronics (FHE) are desirable for applications such as internet of things and wearable electronics. Carbon nanotube (CNT) thin-film transistor (TFT) is a promising candidate for high-performance FHE because of its high carrier mobility, superior mechanical flexibility, and material compatibility with low-cost printing and solution processes. Flexible sensors and peripheral CNT-TFT circuits, such as decoders, drivers, and sense amplifiers, can be printed and hybrid-integrated with thinned (<50 μm) silicon chips on soft, thin, and flexible substrates for a wide range of applications, from flexible displays to wearable medical devices. Here, we report (1) a process design kit (PDK) to enable FHE design automation for large-scale FHE circuits and (2) solution process-proven intellectual property blocks for TFT circuits design, including Pseudo-Complementary Metal-Oxide-Semiconductor (Pseudo-CMOS) flexible digital logic and analog amplifiers. The FHE-PDK is fully compatible with popular silicon design tools for design and simulation of hybrid-integrated flexible circuits.

Large scale and low cost synthesis of multiwalled carbon nanotubes by mechanothermal absence catalysts

2010 ◽  
Vol 109 (1) ◽  
pp. 25-30 ◽  
Author(s):  
S A Manafi ◽  
M H Amin ◽  
M R Rahimipour ◽  
E Salahi ◽  
A Kazemzadeh
Keyword(s):  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Large Scale ◽  
Low Cost ◽  
Multiwalled Carbon

Recent progress in zinc-based redox flow batteries: a review

2021 ◽  
Author(s):  
Guixiang Wang ◽  
Haitao Zou ◽  
Xiaobo Zhu ◽  
Mei Ding ◽  
Chuankun Jia
Keyword(s):  
High Performance ◽  
Large Scale ◽  
Electrode Materials ◽  
Low Cost ◽  
Ion Selectivity ◽  
Commercial Application ◽  
Environmental Friendliness ◽  
Membrane Materials ◽  
Redox Flow Batteries ◽  
Flow Batteries

Abstract Zinc-based redox flow batteries (ZRFBs) have been considered as ones of the most promising large-scale energy storage technologies owing to their low cost, high safety, and environmental friendliness. However, their commercial application is still hindered by a few key problems. First, the hydrogen evolution and zinc dendrite formation cause poor cycling life, of which needs to ameliorated or overcome by finding suitable anolytes. Second, the stability and energy density of catholytes are unsatisfactory due to oxidation, corrosion, and low electrolyte concentration. Meanwhile, highly catalytic electrode materials remain to be explored and the ion selectivity and cost efficiency of membrane materials demands further improvement. In this review, we summarize different types of ZRFBs according to their electrolyte environments including ZRFBs using neutral, acidic, and alkaline electrolytes, then highlight the advances of key materials including electrode and membrane materials for ZRFBs, and finally discuss the challenges and perspectives for the future development of high-performance ZRFBs.

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