scholarly journals Understanding the Barrier and Mechanical Behavior of Different Nanofillers in Chitosan Films for Food Packaging

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 721 ◽  
Author(s):  
João Pires ◽  
Camila Damásio de Paula ◽  
Victor Gomes Lauriano Souza ◽  
Ana Luísa Fernando ◽  
Isabel Coelhoso
Keyword(s):  
Mechanical Properties ◽  
Mechanical Behavior ◽  
Food Packaging ◽  
Scientific Research ◽  
Barrier Properties ◽  
Plastic Pollution ◽  
Functional Attributes ◽  
Chitosan Films ◽  
Commercial Applications ◽  
Innovative Techniques

The continuous petroleum-based plastics manufacturing generates disposal issues, spreading the problem of plastic pollution and its rise in the environment. Recently, innovative techniques and scientific research promoted biopolymers as the primary alternative for traditional plastics, raising and expanding global bioplastic production. Due to its unmatched biological and functional attributes, chitosan (Ch) has been substantially explored and employed as a biopolymeric matrix. Nevertheless, the hydrophilicity and the weak mechanical properties associated with this biopolymer represent a significant intrinsic restriction to its implementation into some commercial applications, namely, in food packaging industries. Distinct methodologies have been utilized to upgrade the mechanical and barrier properties of Ch, such as using organic or inorganic nanofillers, crosslinkers, or blends with other polymers. This review intends to analyze the most recent works that combine the action of different nanoparticle types with Ch films to reinforce their mechanical and barrier properties.

scholarly journals Renewable cellulosic nanocomposites for food packaging to avoid fossil fuel plastic pollution: a review

2020 ◽  
Author(s):  
Umair Qasim ◽  
Ahmed I. Osman ◽  
Ala’a H. Al-Muhtaseb ◽  
Charlie Farrell ◽  
Mohammed Al-Abri ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Lignocellulosic Biomass ◽  
Food Packaging ◽  
Transmission Rate ◽  
Barrier Properties ◽  
Environmental Damage ◽  
Vapor Permeability ◽  
Plastic Pollution ◽  
Oxygen Transmission Rate ◽  
Cellulose Nanoparticles

Abstract The extensive use of petroleum-based synthetic and non-biodegradable materials for packaging applications has caused severe environmental damage. The rising demand for sustainable packaging materials has encouraged scientists to explore abundant unconventional materials. For instance, cellulose, extracted from lignocellulosic biomass, has gained attention owing to its ecological and biodegradable nature. This article reviews the extraction of cellulose nanoparticles from conventional and non-conventional lignocellulosic biomass, and the preparation of cellulosic nanocomposites for food packaging. Cellulosic nanocomposites exhibit exceptional mechanical, biodegradation, optical and barrier properties, which are attributed to the nanoscale structure and the high specific surface area, of 533 m2 g−1, of cellulose. The mechanical properties of composites improve with the content of cellulose nanoparticles, yet an excessive amount induces agglomeration and, in turn, poor mechanical properties. Addition of cellulose nanoparticles increases tensile properties by about 42%. Barrier properties of the composites are reinforced by cellulose nanoparticles; for instance, the water vapor permeability decreased by 28% in the presence of 5 wt% cellulose nanoparticles. Moreover, 1 wt% addition of filler decreased the oxygen transmission rate by 21%. We also discuss the eco-design process, designing principles and challenges.

scholarly journals Polyethylene Films Containing Plant Extracts in the Polymer Matrix as Antibacterial and Antiviral Materials

2021 ◽  
Vol 22 (24) ◽  
pp. 13438
Author(s):  
Magdalena Ordon ◽  
Magdalena Zdanowicz ◽  
Paweł Nawrotek ◽  
Xymena Stachurska ◽  
Małgorzata Mizielińska
Keyword(s):  
Mechanical Properties ◽  
Pseudomonas Syringae ◽  
Polymer Matrix ◽  
Food Packaging ◽  
Antibacterial Properties ◽  
Barrier Properties ◽  
Antiviral Effect ◽  
Extrusion Process ◽  
Mechanical And Thermal Properties ◽  
Bacterial Strains

Low density polyethylene (LDPE) films covered with active coatings containing mixtures of rosemary, raspberry, and pomegranate CO2 extracts were found to be active against selected bacterial strains that may extend the shelf life of food products. The coatings also offer antiviral activity, due to their influence on the activity of Φ6 bacteriophage, selected as a surrogate for SARS-CoV-2 particles. The mixture of these extracts could be incorporated into a polymer matrix to obtain a foil with antibacterial and antiviral properties. The initial goal of this work was to obtain active LDPE films containing a mixture of CO2 extracts of the aforementioned plants, incorporated into an LDPE matrix via an extrusion process. The second aim of this study was to demonstrate the antibacterial properties of the active films against Gram-positive and Gram-negative bacteria, and to determine the antiviral effect of the modified material on Φ6 bacteriophage. In addition, an analysis was made on the influence of the active mixture on the polymer physicochemical features, e.g., mechanical and thermal properties, as well as its color and transparency. The results of this research indicated that the LDPE film containing a mixture of raspberry, rosemary, and pomegranate CO2 extracts incorporated into an LDPE matrix inhibited the growth of Staphylococcus aureus. This film was also found to be active against Bacillus subtilis. This modified film did not inhibit the growth of Escherichia coli and Pseudomonas syringae cells; however, their number decreased significantly. The LDPE active film was also found to be active against Φ6 particles, meaning that the film had antiviral properties. The incorporation of the mixture of CO2 extracts into the polymer matrix affected its mechanical properties. It was observed that parameters describing mechanical properties decreased, although did not affect the transition of LDPE significantly. Additionally, the modified film exhibited barrier properties towards UV radiation. Modified PE/CO2 extracts films could be applied as a functional food packaging material with antibacterial and antiviral properties.

Surface Morphology and Mechanical Properties of Chitosan Film Incorporated with Marine Macroalgae by Casting Method

2014 ◽  
Vol 575 ◽  
pp. 26-30 ◽  
Author(s):  
Nor Faeqah Idrus ◽  
Norasmah Mohammed Manshor ◽  
Basil Giri Davis
Keyword(s):  
Mechanical Properties ◽  
Surface Morphology ◽  
Food Packaging ◽  
Brown Seaweed ◽  
Chitosan Film ◽  
Film Surface ◽  
Chitosan Solution ◽  
Marine Macroalgae ◽  
Chitosan Films ◽  
Tensile Strenght

Chitosan is capable to form films which may replace non-biodegradable food packaging plastics. Chitosan films need to be plasticized to enhance its properties. Chitosan films were incorporated with brown seaweed by casting chitosan solution and brown seaweed solution on Petri dishes and heated at 55 °C. The surface morphology characteristic and mechanical properties were investigated. Surface morphology analysis of seaweed incorporated into chitosan film has resulted in a rougher film surface. Flocculation of seaweed extract in the chitosan film indicates that the seaweed has low miscibility with chitosan. The tensile strenght of chitosan seaweed film was recorded at the value below 8MPa with 20% of elongation, E. In contrast, the tensile strenght and elongation of pure chitosan films are recorded at 55 MPa and 60% respectively. Thus, this research has suggested that the incorporation of seaweed into chitosan film has lowered the value of the film properties.

scholarly journals Methylation of guar gum for improving mechanical and barrier properties of biodegradable packaging films

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Jyoti Tripathi ◽  
Rupali Ambolikar ◽  
Sumit Gupta ◽  
Dheeraj Jain ◽  
Jitendra Bahadur ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Food Packaging ◽  
Guar Gum ◽  
Transmission Rate ◽  
Average Molecular Weight ◽  
Barrier Properties ◽  
Partial Replacement ◽  
Radius Of Gyration ◽  
Biodegradable Films ◽  
Gradual Improvement

Abstract Improving functional properties of biopolymers for use as environment friendly packaging is an area of current interest. Biodegradable films with improved barrier and mechanical properties were prepared from methylated guar gum. Methylation resulted in structural modification of guar gum (GG) promoting greater crystallization thereby enhancing thermal stability towards decomposition. Reduction in radius of gyration (Rg), weight average molecular weight (Mw), and an increase in polydispersity index (PDI) were also observed due to methylation. Methylated guar gum (MGG) films exhibited 40% lower water vapor transmission rate (WVTR) as compared to control purified guar gum (PGG) films. Films prepared by partial replacement of PGG with MGG (10, 25, 50, 75 and 100% w/w) showed gradual improvement in percent elongation. The study gives an insight on the role of methylation in enhancing barrier and mechanical properties of GG based biodegradable films for possible application in food packaging.

scholarly journals Development of Chitosan Films from Edible Crickets and Their Performance as a Bio-Based Food Packaging Material

2021 ◽  
Vol 2 (4) ◽  
pp. 744-758
Author(s):  
Morgan Malm ◽  
Andrea M. Liceaga ◽  
Fernanda San Martin-Gonzalez ◽  
Owen G. Jones ◽  
Jose M. Garcia-Bravo ◽  
...  
Keyword(s):  
Food Packaging ◽  
Water Vapor Permeability ◽  
Barrier Properties ◽  
Nutritional Composition ◽  
Packaging Material ◽  
Acheta Domesticus ◽  
Light Transmittance ◽  
Vapor Permeability ◽  
Chitosan Films ◽  
Chitin And Chitosan

Edible insects have gained attention due to their impressive nutritional composition, as well as their efficient use of natural resources. However, a research gap remains on the applications of insect chitosan, especially as it relates to their potential use as food packaging material. Chitosan from two reared cricket species (Acheta domesticus and Gryllodes sigillatus) was evaluated for use as food packaging material. Cricket chitosan films (CCF) were structurally similar to commercial shrimp chitosan films (SCF) at controlled glycerol levels, as seen by shared spectral peaks in FT-IR analyses. Mechanical properties of CCF showed they had equal or greater tensile strength when compared to commercial SCF, although flexibility was lower. Scanning electron microscopy showed increased roughness of microstructure, likely increasing the tortuosity. As a result, CCF had improved water vapor permeability compared to commercial SCF. Melanin complexes present in cricket chitin and chitosan increased hydrophobicity and decreased light transmittance. This study also revealed that intrinsic species differences, which occur during insect and crustacean exoskeleton development, could have effects on the functionality of chitosan packaging materials. Overall, CCF were found to be as effective as commercial SCF, while providing additional advantages. CCF derived from reared crickets have good mechanical and barrier properties, and improved water resistance and light barrier characteristics. Edible cricket chitosan has the potential to be used as bio-based packaging material for food and pharmaceutical applications.

scholarly journals Development of Chitosan/Peptide Films: Physical, Antibacterial and Antioxidant Properties

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1193
Author(s):  
Chen Li ◽  
Jiliu Pei ◽  
Shengyu Zhu ◽  
Yukang Song ◽  
Xiaohui Xiong ◽  
...  
Keyword(s):  
Food Packaging ◽  
Radical Scavenging Activity ◽  
Antioxidant Properties ◽  
Radical Scavenging ◽  
Barrier Properties ◽  
Surface Hydrophobicity ◽  
Elongation At Break ◽  
Chitosan Films ◽  
Dpph Scavenging

Chitosan/peptide films were prepared by incorporating peptides (0.4%, w/v) from soy, corn and caseins into chitosan films. The presence of peptides significantly affected the physical, antibacterial and antioxidative properties of chitosan films. Among these films, those containing corn peptide showed the best water vapor barrier properties, and the tensile strength and elongation at break increased to 24.80 Mpa and 23.94%, respectively. Characterization of surface hydrophobicity and thermal stability suggested the strongest intermolecular interactions between corn peptides and chitosan. Moreover, films containing casein peptides showed the highest antibacterial activity and radical scavenging activity. The DPPH scavenging rate of films containing casein peptides reached 46.11%, and ABTS scavenging rate reached 66.79%. These results indicate the chitosan/peptide films may be promising food packaging materials.

scholarly journals Relationship Between Crystallization, Mechanical and Gas Barrier Properties of Poly(ethylene furanoate) (PEF) in Multinanolayered PLA-PEF and PET-PEF Films

2021 ◽  
Author(s):  
Alain Guinault ◽  
Tiphaine Messin ◽  
Gilbert Anderer ◽  
Stefan Krawielitzki ◽  
Cyrille Sollogoub ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Dioxide Emissions ◽  
Food Packaging ◽  
Barrier Properties ◽  
Industrial Applications ◽  
High Price ◽  
Gas Barrier ◽  
Ecological Requirements ◽  
Poly Ethylene ◽  
Gas Barrier Properties

Food packaging films must be reinvented in order to answer the new demanding ecological requirements. Biobased and/or biodegradable polymers appear as an interesting alternative to reduce petroleum dependence and carbon dioxide emissions. Poly(ethylene furanoate) (PEF) appears today as a new promising biopolymer thanks to its good gas barrier and mechanical properties, despite its high price that could limit its industrial applications. Its combination with other polymers is thus of great interest and for the first time, film coextrusion process is used to create PLA-PEF and PET-PEF multi-micro/nano layered films. A new PEF grade developed by AVA Biochem in the H2020 Mypack program, has been used and firstly analysed in terms of melt processability, mechanical, thermal and gas barrier properties. Our major results confirmed the good gas barrier as well as mechanical properties of amorphous PEF. Post-extrusion PEF bulk thermal crystallization led to very brittle material making gas barrier measurements impossible. Micro/nanolayered PLA-PEF and PET-PEF films with different PEF layer thicknesses have been processed and post-extrusion annealing treatment was carried out. The relationship between crystallinity, mechanical and gas barrier properties will be investigated.

MODELISATION DE L'INFLUENCE DU TRAITEMENT THERMIQUE SUR LES PROPRIETES MECANIQUES DES ALLIAGES ALUMINIUM-CUIVRE (Al-Cu)

2015 ◽  
Vol 10 (2) ◽  
pp. 2753-2761
Author(s):  
Saad El Madani ◽  
S. ELHAMZI ◽  
A. IBNLFASSI ◽  
L. ZERROUK ◽  
O. BEN LENDA ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Behavior ◽  
Solidification Process ◽  
Traitement Thermique ◽  
Homogenization Process ◽  
Fundamental Reason ◽  
Segregation Phenomenon ◽  
Proprietes Mecaniques ◽  
Cooling Velocity ◽  
Copper Effect

In order to master and improve the quality and properties of the final products, the major industrial challenge lies in the possibility of controlling the morphology, size of microstructures that reside within the molded pieces, as well as their defects; this is the fundamental reason according to which we are more and more interested in mastering the growth and germination of such alloys, as well as the developing structures, at the time of solidification process. The modeling reveals as a valuable aid in the mastery of the formation of such heterogeneousness: segregation cells that are incompatible with industrial requirements.   The whole work focuses upon the modeling of the segregation phenomenon of the four hypoeutectic alloys, Al1%Cu, Al2%Cu, Al3%Cu et Al4%Cu, as well as the copper effect upon certain mechanical properties of aluminum. Usually, the microstructure and mechanical behavior of such alloys as Al-Cu are directly influenced by some parameters such as composition, cooling velocity and homogenization process.

scholarly journals Low-Density Polyethylene Films Carrying ferula asafoetida Extract for Active Food Packaging: Thermal, Mechanical, Optical, Barrier, and Antifungal Properties

2020 ◽  
Vol 2020 ◽  
pp. 1-15
Author(s):  
Razieh Niazmand ◽  
Bibi Marzieh Razavizadeh ◽  
Farzaneh Sabbagh
Keyword(s):  
Polymer Matrix ◽  
Food Packaging ◽  
Barrier Properties ◽  
Low Density Polyethylene ◽  
Low Density ◽  
Optical Barrier ◽  
Leaf Extracts ◽  
Polyethylene Films ◽  
Active Food Packaging ◽  
Ferula Asafoetida

The physical, thermal, mechanical, optical, microstructural, and barrier properties of low-density polyethylene films (LDPE) containing ferula asafoetida leaf and gum extracts were investigated. Results showed a reduction in elasticity and tensile strength with increasing extract concentration in the polymer matrix. The melting temperature and enthalpy increased with increasing concentration of extracts. The films containing extracts had lower L∗ and a∗ and higher b∗ indices. The films containing leaf extract had more barrier potential to UV than the gum extracts. The oxygen permeability in films containing 5% of leaf and gum extracts increased by 2.3 and 2.1 times, respectively. The morphology of the active films was similar to bubble swollen islands, which was more pronounced at higher concentrations of gum and leaf extracts. FTIR results confirmed some chemical interactions of ferula extracts with the polymer matrix. At the end of day 14th, the growth rate of Aspergillus niger and Saccharomyces cerevisea in the presence of the PE-Gum-5 reduced more than PE-Leaf-5 (3.7 and 2.4 logarithmic cycles, respectively) compared to the first day. Our findings showed that active LDPE films have desire thermo-mechanical and barrier properties for food packaging.

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