scholarly journals CaCO3 Polymorphs Used as Additives in Filament Production for 3D Printing

Polymers ◽  
2022 ◽  
Vol 14 (1) ◽  
pp. 199
Author(s):  
Lucie Zárybnická ◽  
Radek Ševčík ◽  
Jaroslav Pokorný ◽  
Dita Machová ◽  
Eliška Stránská ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Polymeric Materials ◽  
Common Type ◽  
Organic Additives ◽  
Fused Filament Fabrication ◽  
Industrial Sectors ◽  
Beneficial Impact ◽  
Testing Techniques ◽  
Enhanced Properties

Nowadays, additive manufacturing—also called 3D printing—represents a well-established technology in the field of the processing of various types of materials manufacturing products used in many industrial sectors. The most common type of 3D printing uses the fused filament fabrication (FFF) method, in which materials based on thermoplastics or elastomers are processed into filaments. Much effort was dedicated to improving the properties and processing of such printed filaments, and various types of inorganic and organic additives have been found to play a beneficial role. One of them, calcium carbonate (CaCO3), is standardly used as filler for the processing of polymeric materials. However, it is well-known from its different applications that CaCO3 crystals may represent particles of different morphologies and shapes that may have a crucial impact on the final properties of the resulting products. For this reason, three different synthetic polymorphs of CaCO3 (aragonite, calcite, and vaterite) and commercially available calcite powders were applied as fillers for the fabrication of polymeric filaments. Analysis of obtained data from different testing techniques has shown significant influence of filament properties depending on the type of applied CaCO3 polymorph. Aragonite particles showed a beneficial impact on the mechanical properties of produced filaments. The obtained results may help to fabricate products with enhanced properties using 3D printing FFF technology.

scholarly journals Polyamide 12/Multiwalled Carbon Nanotube and Carbon Black Nanocomposites Manufactured by 3D Printing Fused Filament Fabrication: A Comparison of the Electrical, Thermoelectric, and Mechanical Properties

2021 ◽  
Vol 7 (2) ◽  
pp. 38
Author(s):  
Nectarios Vidakis ◽  
Markos Petousis ◽  
Lazaros Tzounis ◽  
Emmanuel Velidakis ◽  
Nikolaos Mountakis ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Carbon Black ◽  
Large Scale ◽  
Fracture Mechanisms ◽  
Fused Filament Fabrication ◽  
Melt Mixing ◽  
Multiwalled Carbon ◽  
Electrically Conductive ◽  
Polyamide 12

In this study, nanocomposites with polyamide 12 (PA12) as the polymer matrix and multiwalled carbon nanotubes (MWCNTs) and carbon black (CB) at different loadings (2.5, 5.0, and 10.0 wt.%) as fillers, were produced in 3D printing filament form by melt mixing extrusion process. The filament was then used to build specimens with the fused filament fabrication (FFF) three-dimensional (3D) printing process. The aim was to produce by FFF 3D printing, electrically conductive and thermoelectric functional specimens with enhanced mechanical properties. All nanocomposites’ samples were electrically conductive at filler loadings above the electrical percolation threshold. The highest thermoelectric performance was obtained for the PA12/CNT nanocomposite at 10.0 wt.%. The static tensile and flexural mechanical properties, as well as the Charpy’s impact and Vickers microhardness, were determined. The highest improvement in mechanical properties was observed for the PA12/CNT nanocomposites at 5.0 wt.% filler loading. The fracture mechanisms were identified by fractographic analyses of scanning electron microscopy (SEM) images acquired from fractured surfaces of tensile tested specimens. The nanocomposites produced could find a variety of applications such as; 3D-printed organic thermoelectric materials for plausible large-scale thermal energy harvesting applications, resistors for flexible circuitry, and piezoresistive sensors for strain sensing.

Fused filament fabrication: A comprehensive review

2020 ◽  
pp. 089270572097062
Author(s):  
Sudhir Kumar ◽  
Rupinder Singh ◽  
TP Singh ◽  
Ajay Batish
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Smart Materials ◽  
Low Cost ◽  
Processing Parameters ◽  
View Point ◽  
Fused Filament Fabrication ◽  
Comprehensive Review ◽  
Smart Composites ◽  
Complex Design

Fused filament fabrication (FFF) is one of the low cost additive manufacturing (AM) techniques capable of printing complex design (both with commercial and non-commercial feedstock filaments by using different processing parameters). In this paper a comprehensive review has been prepared on FFF operating capabilities from thermoplastics material’s view point. Various thermoplastic materials and composites available commercially and prepared at laboratory scale have been categorized based upon the reported studies performed (for thermal stability, mechanical properties etc.). It was observed that the nano composite based feed stock filament (prepared at lab scale) have edge over the micro-composites from thermo-mechanical properties view point. Further it has been noticed that the 3D printing is in changing phase and moving towards 4D printing of smart composites and designs. But hitherto little has been reported on printing of smart material with FFF platform. Further studies may be focused on printing of smart materials (both micro and nano composites) with FFF, as the low cost 3D printing solution in different engineering applications.

scholarly journals Effect of Porosity and Crystallinity on 3D Printed PLA Properties

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1487 ◽  
Author(s):  
Yuhan Liao ◽  
Chang Liu ◽  
Bartolomeo Coppola ◽  
Giuseppina Barra ◽  
Luciano Di Maio ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Polylactic Acid ◽  
Complex Geometry ◽  
Fused Filament Fabrication ◽  
3D Printed ◽  
Physical Changes ◽  
Crystalline Forms

Additive manufacturing (AM) is a promising technology for the rapid tooling and fabrication of complex geometry components. Among all AM techniques, fused filament fabrication (FFF) is the most widely used technique for polymers. However, the consistency and properties control of the FFF product remains a challenging issue. This study aims to investigate physical changes during the 3D printing of polylactic acid (PLA). The correlations between the porosity, crystallinity and mechanical properties of the printed parts were studied. Moreover, the effects of the build-platform temperature were investigated. The experimental results confirmed the anisotropy of printed objects due to the occurrence of orientation phenomena during the filament deposition and the formation both of ordered and disordered crystalline forms (α and δ, respectively). A heat treatment post-3D printing was proposed as an effective method to improve mechanical properties by optimizing the crystallinity (transforming the δ form into the α one) and overcoming the anisotropy of the 3D printed object.

scholarly journals A Review on Reinforcement Methods for Polymeric Materials Processed Using Fused Filament Fabrication (FFF)

Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 4022
Author(s):  
Juan Pratama ◽  
Sukmaji I. Cahyono ◽  
Suyitno Suyitno ◽  
Muhammad A. Muflikhun ◽  
Urip A. Salim ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fiber Reinforcement ◽  
Polymeric Materials ◽  
Short Fiber ◽  
Continuous Fiber ◽  
Fused Filament Fabrication ◽  
Automotive Components ◽  
The Poor ◽  
Powder Addition ◽  
Processed Products

Over the last few years, fused filament fabrication (FFF) has become one of the most promising and widely used techniques for the rapid prototyping process. A number of studies have also shown the possibility of FFF being used for the fabrication of functional products, such as biomedical implants and automotive components. However, the poor mechanical properties possessed by FFF-processed products are considered one of the major shortcomings of this technique. Over the last decade, many researchers have attempted to improve the mechanical properties of FFF-processed products using several strategies—for instance, by applying the short fiber reinforcement (SFR), continuous fiber reinforcement (CFR), powder addition reinforcement (PAR), vibration-assisted FFF (VA-FFF) methods, as well as annealing. In this paper, the details of all these reinforcement techniques are reviewed. The abilities of each method in improving tensile, flexural, and compressive strength are discussed.

scholarly journals The research of the thermal and mechanical properties of materials produced by 3D printing method

2019 ◽  
Vol 23 (Suppl. 4) ◽  
pp. 1211-1216
Author(s):  
Adam Gnatowski ◽  
Agnieszka Kijo-Kleczkowska ◽  
Henryk Otwinowski ◽  
Piotr Sikora
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
3D Printing ◽  
Thermoplastic Polyurethane ◽  
Polymeric Materials ◽  
Poly Lactic Acid ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
Properties Of Materials ◽  
Butadiene Styrene

A comparative analysis of thermal properties of semi-crystalline and amorphous polymeric materials was carried out. Samples were produced using 3D printing technology on the SIGNAL-ATMAT printer. The following polymeric materials were used to make the samples: thermoplastic polyurethane elastomer, acryloni-trile-butadiene-styrene copolymer, Laywood, ethylene terephthalate, poly (lactic acid). The materials were tested for their thermal and mechanical properties. The research included the analysis of thermal properties by differential scanning calorimetry of manufactured materials. The tensile strength also was determined.

scholarly journals 3D Printing of Aramid Nanofiber Composites by Stereolithography

2021 ◽  
Author(s):  
Sachini Perera ◽  
Alejandra Durand-Silva ◽  
Ashele Remy ◽  
Shashini Diwakara ◽  
Ronald Smaldone
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Exchange Process ◽  
Polymeric Materials ◽  
Solvent Exchange ◽  
High Quality ◽  
Filler Dispersion ◽  
Printing Method ◽  
Quality Surface ◽  
High Quality Surface

Vat photopolymerization is a versatile 3D printing method that produces parts using polymeric materials with uniform mechanical properties, high quality surface finish and high-resolution features. However, it is challenging to make composite materials with vat photopolymerization mainly due to the imperfect filler dispersion in the photo resin. Herein, we describe a methodology to incorporate aramid nanofibers (ANFs) into a 3D printable photoresin as a dispersion, followed by a solvent exchange process that limits anisotropic shrinkage and cracking of the printed polymer. By incorporating 0.60 wt.% of ANFs, both the tensile strength and toughness increased by 264 % and 219 % respectively, while the Young’s modulus had a 406 % increase compared to the control photoresin.

Optimization of Design Process of Fused Filament Fabrication (FFF) 3D Printing

2018 ◽  
Author(s):  
Jaeyoon Kim ◽  
Bruce S. Kang
Keyword(s):  
Mechanical Properties ◽  
Carbon Fiber ◽  
3D Printing ◽  
Design Process ◽  
Design Methodology ◽  
Tool Path ◽  
Fiber Reinforced ◽  
Fused Filament Fabrication ◽  
Principal Directions

Fused Filament Fabrication (FFF) is one of the most common Additive Manufacturing (AM) technologies for thermoplastic materials. PLA, ABS, and nylon have generally been used for prototype development. With the development of carbon fiber reinforced polymer (CFRP) filament for FFF, AM parts with improved strength and functionality can be realized. While mechanical properties of various CFRP have been well studied, design methodology for structural optimization of CFRP parts remains an active research area. In this paper, a systematic optimization of design process of FFF 3D printing methodology is proposed for CFRP. Starting with standard coupon specimen tests including tensile, bending, and creep tests to obtain mechanical properties of CFRP. Finite element analyses (FEA) are conducted to find principal directions of the AM part and computed principal directions are utilized as fiber orientations. Then, the connecting lines of principal directions are used to develop a customized tool-path in FFF 3D printing to extrude fibers aligned with principal directions. Since currently available infill-patterns in 3D printing cannot precisely draw customized lines, a specific tool-path algorithm has been developed to distribute fibers with the desired orientations. To predict/assess mechanical behavior of the AM part, 3D printing process was simulated followed by FEA to obtain the anisotropic structural behavior induced by the customized tool-path. To demonstrate the design/manufacturing methodology, spur gears of a ball milling machine were selected as a case study and carbon fiber reinforced nylon filament was chosen as the AM materials. Relevant compression tests were conducted to assess their performance compared with those printed at regular tool-path patterns. Preliminary results show that CFRP gear printed by customized tool-path has about 8% higher stiffness than those printed by regular patterns. Also, flow distribution of printed fibers was verified using scanning electron microscope (SEM). SEM images showed that approximately 91% of fibers were oriented as intended. In summary, assisted by FEA, a customized 3D printing tool-path for CFRP has been developed with a case study to verify the proposed AM design methodology.

scholarly journals Poly(Lactic) Acid Reinforced with Alkaline Lignin Biocomposites Prepared by Thermal Extrusion for Sustainable 3D Printing Process

2021 ◽  
Vol 2129 (1) ◽  
pp. 012003
Author(s):  
Nurul Amirah Abd Rahman ◽  
Hazleen Anuar ◽  
Fathilah Ali ◽  
Jonghwan Suhr
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
3D Printing ◽  
Natural Fiber ◽  
Tensile Tests ◽  
Poly Lactic Acid ◽  
Fused Filament Fabrication ◽  
3D Printed ◽  
Functional Components ◽  
Thermal Extrusion

Abstract The focus of this work is the mechanical characterization of biomaterials produced by 3D printing based on fused filament fabrication (FFF) process that has been mainly used for prototype rather than functional components due to the limited mechanical properties of pure thermoplastics parts. Addition of reinforcements from natural fiber has been adopted to improve the mechanical properties of the 3D printed parts. In this study, alkaline lignin powder that has been extracted from oil palm empty fruit bunches (OPEFB) via alkaline extraction process were used as filler in the production of biocomposites with poly(lactic) acid (PLA). Poly(lactic) acid filaments filled with 1% of alkaline lignin powder and has been compared with the presence of 5% of epoxidized palm oil (EPO) by means of thermal extrusion and further proceed with 3D printing. The samples were mechanically characterized using tensile tests and the fractography were observed. Tensile test that has been done on the filaments reveal that the filament with addition of lignin and EPO shows improved mechanical properties with higher tensile strength as well as lower stiffness. The 3D printed samples of the filament compositions also exhibit similar trend where the said filament has the best mechanical properties when the EPO is incorporated in the filament.

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