scholarly journals Process of Obtaining Chromium Nitride in the Combustion Mode under Conditions of Co-Flow Filtration

Processes ◽  
2020 ◽  
Vol 8 (9) ◽  
pp. 1056
Author(s):  
Nikolay Evseev ◽  
Mansur Ziatdinov ◽  
Vladimir Romandin ◽  
Alexander Zhukov ◽  
Aidos Tolynbekov ◽  
...  
Keyword(s):  
Gas Flow ◽  
Combustion Process ◽  
Combustion Products ◽  
Chromium Nitride ◽  
Gas Flow Rate ◽  
Chromium Powder ◽  
Burning Temperature ◽  
Superadiabatic Heating ◽  
Argon Mixture ◽  
Flow Filtration

In this work, the combustion process of chromium powder in the co-flow filtration mode was studied. The effect of nitrogen-containing gas flow rate on the nitridation of combustion products is shown. The effect of the amount of argon in the nitrogen–argon mixture on the burning rate and the burning temperature of the chromium powder is shown. It was found that an increase in the percentage of argon in the nitrogen–argon mixture can lead to the formation of an inverse combustion wave. The actual burning temperature is higher than adiabatic burning temperature in the co-flow filtration mode, thus the phenomenon of superadiabatic heating is observed. The phase composition of the obtained combustion products was studied. It was shown that the forced filtration mode allows for synthesizing non-stoichiometric Cr2N nitride.

SCIENTIFIC AND ENGINEERING PRINCIPLES OF EFFICIENT FUEL USE AND ENVIRONMENTALLY FRIENDLY GAS COMBUSTION IN STOVE PLATES. PART 1. MODERN STATE-OF-THE-ART AND DIRECTIONS FOR IMPROVEMENT THE GAS BURNING IN DOMESTIC GAS COOKERS

2017 ◽  
pp. 3-18 ◽  
Author(s):  
B.S. Soroka ◽  
V.V. Horupa
Keyword(s):  
Natural Gas ◽  
Flow Rate ◽  
Gas Flow ◽  
Renewable Energy Sources ◽  
Combustion Process ◽  
Orifice Diameter ◽  
Firing Process ◽  
Gas Flow Rate ◽  
Gas Combustion ◽  
Gas Stoves

Natural gas NG consumption in industry and energy of Ukraine, in recent years falls down as a result of the crisis in the country’s economy, to a certain extent due to the introduction of renewable energy sources along with alternative technologies, while in the utility sector the consumption of fuel gas flow rate enhancing because of an increase the number of consumers. The natural gas is mostly using by domestic purpose for heating of premises and for cooking. These items of the gas utilization in Ukraine are already exceeding the NG consumption in industry. Cooking is proceeding directly in the living quarters, those usually do not meet the requirements of the Ukrainian norms DBN for the ventilation procedures. NG use in household gas stoves is of great importance from the standpoint of controlling the emissions of harmful components of combustion products along with maintenance the satisfactory energy efficiency characteristics of NG using. The main environment pollutants when burning the natural gas in gas stoves are including the nitrogen oxides NOx (to a greater extent — highly toxic NO2 component), carbon oxide CO, formaldehyde CH2O as well as hydrocarbons (unburned UHC and polyaromatic PAH). An overview of environmental documents to control CO and NOx emissions in comparison with the proper norms by USA, EU, Russian Federation, Australia and China, has been completed. The modern designs of the burners for gas stoves are considered along with defining the main characteristics: heat power, the natural gas flow rate, diameter of gas orifice, diameter and spacing the firing openings and other parameters. The modern physical and chemical principles of gas combustion by means of atmospheric ejection burners of gas cookers have been analyzed from the standpoints of combustion process stabilization and of ensuring the stability of flares. Among the factors of the firing process destabilization within the framework of analysis above mentioned, the following forms of unstable combustion/flame unstabilities have been considered: flashback, blow out or flame lifting, and the appearance of flame yellow tips. Bibl. 37, Fig. 11, Tab. 7.

Study on the Kinetics of Chemical Looping Combustion of Copper-Based Oxygen Carrier

2013 ◽  
Vol 724-725 ◽  
pp. 1140-1144
Author(s):  
Yong Qiang Liu ◽  
Zhi Qi Wang ◽  
Jing Li Wu ◽  
Jin Hu Wu
Keyword(s):  
Particle Size ◽  
Reaction Temperature ◽  
Flow Rate ◽  
Conversion Rate ◽  
Gas Flow ◽  
Oxygen Carrier ◽  
Combustion Process ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Gas Flow Rate

Kinetics is the study of rates of chemical processes, which includes investigations of how different experimental conditions can influence the speed of a chemical reaction and the reactions mechanism. In this paper, the influences of several parameters including particle size and mass of copper-based oxygen carrier, reaction gas flow rate and temperature on the conversion rate of oxygen carrier in chemical looping combustion was investigated. The results of experiment reveal that the conversion rate of oxygen carrier is influenced by the reaction temperature, mass of the oxygen carrier and the reaction gas flow rate. The conversion rate of oxygen carrier is improved with decreasing the mass of the oxygen carrier and increasing the reaction gas flow rate within a certain extent in the chemical looping combustion process. The particle size has very little effect on the conversion rate, and 800 °C is an advisable reaction temperature for chemical looping combustion process of copper-based oxygen carrier with methane and air.

On the Influence of Fluctuating Flow Rate Upon the Performance and Behaviour of Isothermal Reacting Systems

1998 ◽  
Vol 63 (6) ◽  
pp. 881-898
Author(s):  
Otakar Trnka ◽  
Miloslav Hartman
Keyword(s):  
Flow Rate ◽  
Gas Flow ◽  
Fluidized Bed Reactor ◽  
Computational Techniques ◽  
Continuous Stirred Tank Reactor ◽  
Gas Flow Rate ◽  
Solid Reaction ◽  
Continuous Stirred Tank ◽  
And Performance ◽  
Reacting Systems

Three simple computational techniques are proposed and employed to demonstrate the effect of fluctuating flow rate of feed on the behaviour and performance of an isothermal, continuous stirred tank reactor (CSTR). A fluidized bed reactor (FBR), in which a non-catalytic gas-solid reaction occurs, is also considered. The influence of amplitude and frequency of gas flow rate fluctuations on reactant concentrations at the exit of the CSTR is shown in four different situations.

scholarly journals Dependence of the Flue Gas Flow on the Setting of the Separation Baffle in the Flue Gas Tract

2021 ◽  
Vol 11 (7) ◽  
pp. 2961
Author(s):  
Nikola Čajová Kantová ◽  
Alexander Čaja ◽  
Marek Patsch ◽  
Michal Holubčík ◽  
Peter Ďurčanský
Keyword(s):  
Particulate Matter ◽  
Flue Gas ◽  
Gas Flow ◽  
Negative Impact ◽  
Combustion Process ◽  
Cfd Simulations ◽  
Piv Measurements ◽  
Computational Fluid Dynamics Cfd ◽  
Particle Imaging ◽  
Combustion Of Solid Fuels

With the combustion of solid fuels, emissions such as particulate matter are also formed, which have a negative impact on human health. Reducing their amount in the air can be achieved by optimizing the combustion process as well as the flue gas flow. This article aims to optimize the flue gas tract using separation baffles. This design can make it possible to capture particulate matter by using three baffles and prevent it from escaping into the air in the flue gas. The geometric parameters of the first baffle were changed twice more. The dependence of the flue gas flow on the baffles was first observed by computational fluid dynamics (CFD) simulations and subsequently verified by the particle imaging velocimetry (PIV) method. Based on the CFD results, the most effective is setting 1 with the same boundary conditions as those during experimental PIV measurements. Setting 2 can capture 1.8% less particles and setting 3 can capture 0.6% less particles than setting 1. Based on the stoichiometric calculations, it would be possible to capture up to 62.3% of the particles in setting 1. The velocities comparison obtained from CFD and PIV confirmed the supposed character of the turbulent flow with vortexes appearing in the flue gas tract, despite some inaccuracies.

scholarly journals Investigation on influences of loose gas on gas-solid flows in a circulating fluidized bed (CFB) reactor using full-loop numerical simulation

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Pengju Huo ◽  
Xiaohong Li ◽  
Yang Liu ◽  
Haiying Qi
Keyword(s):  
Numerical Simulation ◽  
Flow Rate ◽  
Gas Flow ◽  
Circulating Fluidized Bed ◽  
Separation Efficiency ◽  
Circulation Rate ◽  
Solid Mass ◽  
Gas Flow Rate ◽  
Gas Leakage ◽  
Mass Circulation

AbstractThe influences of loose gas on gas-solid flows in a large-scale circulating fluidized bed (CFB) gasification reactor were investigated using full-loop numerical simulation. The two-fluid model was coupled with the QC-energy minimization in multi-scale theory (EMMS) gas-solid drag model to simulate the fluidization in the CFB reactor. Effects of the loose gas flow rate, Q, on the solid mass circulation rate and the cyclone separation efficiency were analyzed. The study found different effects depending on Q: First, the particles in the loop seal and the standpipe tended to become more densely packed with decreasing loose gas flow rate, leading to the reduction in the overall circulation rate. The minimum Q that can affect the solid mass circulation rate is about 2.5% of the fluidized gas flow rate. Second, the sealing gas capability of the particles is enhanced as the loose gas flow rate decreases, which reduces the gas leakage into the cyclones and improves their separation efficiency. The best loose gas flow rates are equal to 2.5% of the fluidized gas flow rate at the various supply positions. In addition, the cyclone separation efficiency is correlated with the gas leakage to predict the separation efficiency during industrial operation.

Mass Transfer Coefficients during Steel Decarburization in a RH Degasser

2008 ◽  
Vol 273-276 ◽  
pp. 679-684
Author(s):  
Roberto Parreiras Tavares ◽  
André Afonso Nascimento ◽  
Henrique Loures Vale Pujatti
Keyword(s):  
Mass Transfer ◽  
Reynolds Number ◽  
Transfer Coefficient ◽  
Mass Transfer Coefficient ◽  
Gas Flow ◽  
Vacuum Chamber ◽  
Volumetric Mass Transfer Coefficient ◽  
Gas Flow Rate ◽  
Rh Process ◽  
Kinetics Of

The RH process is a secondary refining process that can simultaneously attain significant levels of removal of interstitial elements, such as carbon, nitrogen and hydrogen, from liquid steel. In the RH process, the decarburization rate plays a very important role in determining the productivity of the equipment. The kinetics of this reaction is controlled by mass transfer in the liquid phase. In the present work, a physical model of a RH degasser has been built and used in the study of the kinetics of decarburization. The effects of the gas flow rate and of the configurations of the nozzles used in the injection of the gas have been analyzed. The decarburization reaction of liquid steel was simulated using a reaction involving CO2 and caustic solutions. The concentration of CO2 in the solution was evaluated using pH measurements. Based on the experimental results, it was possible to estimate the reaction rate constant. A volumetric mass transfer coefficient was then calculated based on these rate constants and on the circulation rate of the liquid. The logarithm of the mass transfer coefficient showed a linear relationship with the logarithm of the gas flow rate. The slope of the line was found to vary according to the relevance of the reaction at the free surface in the vacuum chamber. A linear relationship between the volumetric mass transfer coefficient and the nozzle Reynolds number was also observed. The slopes of the lines changed according to the relative importance of the two reaction sites, gas-liquid interface in the upleg snorkel and in the vacuum. At higher Reynolds number, the reaction in the vacuum chamber tends to be more significant.

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