scholarly journals Characteristics of Hydrochar and Liquid Products Obtained by Hydrothermal Carbonization and Wet Torrefaction of Poultry Litter in Mixture with Wood Sawdust

Processes ◽  
2021 ◽  
Vol 9 (11) ◽  
pp. 2082
Author(s):  
Rafail Isemin ◽  
Natalia Muratova ◽  
Sergey Kuzmin ◽  
Dmitry Klimov ◽  
Vadim Kokh-Tatarenko ◽  
...  
Keyword(s):  
Specific Surface ◽  
New Technologies ◽  
Liquid Fraction ◽  
Organic Fertilizer ◽  
Poultry Litter ◽  
Hydrothermal Carbonization ◽  
Industrial Applications ◽  
Added Value ◽  
Water Medium ◽  
Liquid Products

Poultry farms with floor-standing poultry generate large amounts of poultry litter waste. The direct application of this waste as an organic fertilizer does not ensure sustainable and cost-efficient utilization of all waste fractions, and can also be linked to environmental hazards. Therefore, the development of new technologies is required for processing poultry litter into a safe product with higher added value. In this work, the characteristics of activated carbon derived from hydrochar, along with the liquid products obtained from hydrothermal carbonization (HTC) and the wet torrefaction (WT) of poultry litter, were investigated. Poultry litter (PL) was applied in a mixture with sawdust (SD) in the following ratios: 1:0 (PL/SD 1:0), 1:1 (PL/SD 1:1), 1:2 (PL/SD 1:2), and 2:1 (PL/SD 2:1). WT processing took place in an innovative fluidized bed system in a superheated steam medium with low overpressure (less than 0.07 MPa) at 300 °C and 350 °C for 30–45 min. Conventional HTC processing was performed in a water medium at 220 °C for 1–4 h. The hydrochar produced in the experiments was activated with steam for 1 h at 450–750 °C. The porosity characteristics of activated hydrochar were measured, including pore size, pore volume, and specific surface area, in view of potential industrial applications as an adsorbent. Additionally, the contents of 5-hydroxymethylfurfural (HMF), as high-value product, were determined in the liquid products obtained from HTC processing, as well as in the condensate obtained after WT processing. Specific surface areas of the activated hydrochars may still be too low for application as adsorbent material. Hence, its use as a biofertilizer and soil improver should be preferred. Interestingly, the liquid fraction obtained from the innovative WT process displayed a significantly higher 5-HMF content compared to the conventional HTC process.

scholarly journals A New Technique for Improved Use of Thermal Energy from Waste Effluents

Agronomy ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 97
Author(s):  
José Manuel Magide-Ameijide ◽  
Hiram Varela-Rodríguez ◽  
Adolfo López-Fabal
Keyword(s):  
Energy Efficiency ◽  
Organic Fertilizer ◽  
Industrial Applications ◽  
Added Value ◽  
New Technique ◽  
Industrial Processes ◽  
Waste Energy ◽  
Waste Effluents ◽  
A New Technique ◽  
Process Fluid

Energy sustainability and environmental protection in general are at the heart of engineering and industry discussions. Countless efforts have been devoted to improving the energy efficiency of industrial processes and specifically to harnessing their waste energy sources. One such source is waste from agro-industrial processes, which is frequently characterized by increased temperatures and high polluting potential. There are multiple available choices for exploiting energy from such waste, but this paper proposes a new alternative technique that substantially improves the efficiency. Based on the technology of leveraging a hot liquid effluent for heating a process fluid, this system introduces a third liquid to be revalorized by drying that is placed in between the hot and cold liquids. By adding stirrers inside the heat exchanger, the thermal resistance of the third fluid is reduced to a negligible level. Thus, this system has almost the same advantages as the previous one, but with the added benefit that it allows drying of a third fluid. One of the specific applications of this proposed technology is using heat from waste effluents to obtain dried food products. In the present work, it was used to dry slaughterhouse blood to obtain so-called “blood meal”, a product with a high added value that is used as pet food or organic fertilizer, and also has many other industrial applications. As shown here, the new technique outperforms existing alternatives in terms of energy efficiency and economic profitability.

scholarly journals Process Water Recirculation During Hydrothermal Carbonization as a Promising Process Step Towards the Production of Nitrogen-Doped Carbonaceous Materials

2021 ◽  
Author(s):  
Wüst Dominik ◽  
Arauzo Pablo ◽  
Habicht Sonja ◽  
Cazaña Fernando ◽  
Fiori Luca ◽  
...  
Keyword(s):  
Hydrothermal Carbonization ◽  
Added Value ◽  
Process Water ◽  
Carbonaceous Materials ◽  
Process Step ◽  
Nitrogen Doped ◽  
Physico Chemical ◽  
Spent Grains ◽  
Liquid Products ◽  
Water Recirculation

AbstractHydrothermal Carbonization (HTC) refers to the conversion of biogenic wastes into char-like solids with promising perspectives for application, but a process water (PW) results which is difficult to dispose untreated. Thus, a biorefinery approach including one or two recirculation steps with the additional objective of improving the physico-chemical characteristics of the solid was performed in this study. During HTC, constitutive molecules such as saccharides, proteins and lignin of Brewer’s Spent Grains decompose into hundreds of organic compounds, following complex reactions. To get deeper insights a combination of proximate, ultimate and structural analysis for solid products as well as liquid chromatography for liquid products were the choice. The main reactions could be identified by key compounds of low and high molecular weight resulting from hydrolysis, dehydration, decarboxylation, deamination as well as amide formation and condensation reactions. Their intensity was influenced by the feedwater pH and reaction temperature. Via reactions of Maillard character up to around 90% of the dissolved nitrogen of the recirculated process water at 200, 220 and 240 °C result in the formation of nitrogen containing heterocycles or rather Quartnernary nitrogen incorporated into the hydrochar (HC). Thus, already one recirculation step during HTC at 240 °C promises the fabrication of high added-value materials, i.e. nitrogen doped carbonaceous materials. Graphic Abstract

scholarly journals Process Water Recirculation During Hydrothermal Carbonization as a Promising Process Step Towards the Production of N-doped Carbonaceous Materials

2021 ◽  
Author(s):  
Dominik Wüst ◽  
Pablo Arauzo ◽  
Sonja Habicht ◽  
Fernando Cazana ◽  
Luca Fiori ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Hydrothermal Carbonization ◽  
Added Value ◽  
Process Water ◽  
Chemical Characteristics ◽  
Carbonaceous Materials ◽  
Process Step ◽  
Physico Chemical ◽  
Liquid Products ◽  
Water Recirculation

Abstract Hydrothermal Carbonization (HTC) refers to the conversion of biogenic wastes into char-like solids with promising perspectives for application, but a process water (PW) results which is difficult to dispose untreated. Thus, a biorefinery approach including one or two recirculation steps with the additional objective of improving the physico-chemical characteristics of the solid was performed. During HTC, constitutive biomass molecules decompose into hundreds of organic compounds, following complex reactions. To get deeper insights a combination of proximate, ultimate and structural analysis for solid products as well as liquid chromatography for liquid products were the choice. The main reactions could be identified by key compounds of low and high molecular weight resulting from hydrolysis, dehydration, decarboxylation, deamination as well as amide formation and condensation reactions. Their intensity was influenced by the feedwater pH and reaction temperature. Reactions of Maillard character result in N-containing heterocycles incorporated into the hydrochar (HC), which promises the fabrication of high added-value materials, i.e. N-doped carbonaceous materials.

scholarly journals Muscle Protein Hydrolysates and Amino Acid Composition in Fish

Marine Drugs ◽  
2021 ◽  
Vol 19 (7) ◽  
pp. 377
Author(s):  
Bomi Ryu ◽  
Kyung-Hoon Shin ◽  
Se-Kwon Kim
Keyword(s):  
Amino Acid ◽  
Amino Acid Composition ◽  
Acid Composition ◽  
Muscle Protein ◽  
Fish Muscle ◽  
Amino Acid Profile ◽  
Industrial Applications ◽  
Protein Hydrolysates ◽  
Added Value ◽  
Degree Of Hydrolysis

Fish muscle, which accounts for 15%–25% of the total protein in fish, is a desirable protein source. Their hydrolysate is in high demand nutritionally as a functional food and thus has high potential added value. The hydrolysate contains physiologically active amino acids and various essential nutrients, the contents of which depend on the source of protein, protease, hydrolysis method, hydrolysis conditions, and degree of hydrolysis. Therefore, it can be utilized for various industrial applications including use in nutraceuticals and pharmaceuticals to help improve the health of humans. This review discusses muscle protein hydrolysates generated from the muscles of various fish species, as well as their amino acid composition, and highlights their functional properties and bioactivity. In addition, the role of the amino acid profile in regulating the biological and physiological activities, nutrition, and bitter taste of hydrolysates is discussed.

scholarly journals Development and Characterization of Composite Carbon Adsorbents with Photocatalytic Regeneration Ability: Application to Diclofenac Removal from Water

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 173
Author(s):  
Velma Beri Kimbi Yaah ◽  
Satu Ojala ◽  
Hamza Khallok ◽  
Tiina Laitinen ◽  
Marcin Selent ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Functional Groups ◽  
Specific Surface Area ◽  
Palm Kernel ◽  
Hydrothermal Carbonization ◽  
Carbon Composite ◽  
Carbon Adsorbents ◽  
Regeneration Ability ◽  
Activation Temperature

This paper presents results related to the development of a carbon composite intended for water purification. The aim was to develop an adsorbent that could be regenerated using light leading to complete degradation of pollutants and avoiding the secondary pollution caused by regeneration. The composites were prepared by hydrothermal carbonization of palm kernel shells, TiO2, and W followed by activation at 400 °C under N2 flow. To evaluate the regeneration using light, photocatalytic experiments were carried out under UV-A, UV-B, and visible lights. The materials were thoroughly characterized, and their performance was evaluated for diclofenac removal. A maximum of 74% removal was observed with the composite containing TiO2, carbon, and W (HCP25W) under UV-B irradiation and non-adjusted pH (~5). Almost similar results were observed for the material that did not contain tungsten. The best results using visible light were achieved with HCP25W providing 24% removal of diclofenac, demonstrating the effect of W in the composite. Both the composites had significant amounts of oxygen-containing functional groups. The specific surface area of HCP25W was about 3 m2g−1, while for HCP25, it was 160 m2g−1. Increasing the specific surface area using a higher activation temperature (600 °C) adversely affected diclofenac removal due to the loss of the surface functional groups. Regeneration of the composite under UV-B light led to a complete recovery of the adsorption capacity. These results show that TiO2- and W-containing carbon composites are interesting materials for water treatment and they could be regenerated using photocatalysis.

scholarly journals New EAF Slag Characterization Methodology for Strategic Metal Recovery

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1513
Author(s):  
Nour-Eddine Menad ◽  
Nassima Kana ◽  
Alain Seron ◽  
Ndue Kanari
Keyword(s):  
New Technologies ◽  
Slag Sample ◽  
Steel Slag ◽  
Analytical Techniques ◽  
Added Value ◽  
Metal Extraction ◽  
Magnetic Fraction ◽  
Magnetic Components ◽  
Physico Chemical ◽  
Hematite Fe2o3

The grown demand of current and future development of new technologies for high added value and strategic metals, such as molybdenum, vanadium, and chromium, and facing to the depletion of basic primary resources of these metals, the metal extraction and recovery from industrial by-products and wastes is a promising choice. Slag from the steelmaking sector contains a significant amount of metals; therefore, it must be considered to be an abundant secondary resource for several strategic materials, especially chromium. In this work, the generated slag from electric arc furnace (EAF) provided by the French steel industry was characterized by using multitude analytical techniques in order to determine the physico-chemical characteristics of the targeted slag. The revealed main crystallized phases are larnite (Ca2SiO4), magnetite (Fe3O4), srebrodolskite (Ca2Fe2O5), wüstite (FeO), maghemite (Fe2.6O3), hematite (Fe2O3), chromite [(Fe,Mg)Cr2O4], and quartz (SiO2). The collected slag sample contains about 34.1% iron (48.5% Fe2O3) and 3.5% chromium, whilst the vanadium contents is around 1500 ppm. The Mössbauer spectroscopy suggested that the non-magnetic fraction represents 42 wt% of the slag, while the remainder (58 wt%) is composed of magnetic components. The thermal treatment of steel slag up to 900 °C indicated that this solid is almost stable and few contained phases change their structures.

scholarly journals Technologies and Extraction Methods of Polyphenolic Compounds Derived from Pomegranate (Punica granatum) Peels. A Mini Review

Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 236
Author(s):  
Dimitrios Lampakis ◽  
Prodromos Skenderidis ◽  
Stefanos Leontopoulos
Keyword(s):  
Electric Fields ◽  
Bioactive Compounds ◽  
New Technologies ◽  
Ohmic Heating ◽  
Punica Granatum ◽  
Extraction Methods ◽  
Added Value ◽  
Green Solvents ◽  
Ultrasound Assisted Extraction ◽  
Functional Product

The interest in using plant by-product extracts as functional ingredients is continuously rising due to environmental and financial prospects. The development of new technologies has led to the achievement of aqueous extracts with high bioactivity that is preferable due to organic solvents nonuse. Recently, widely applied and emerging technologies, such as Simple Stirring, Pressure-Applied Extraction, Enzymatic Extraction, Ultrasound-Assisted Extraction, Pulsed Electric Fields, High Hydrostatic Pressure, Ohmic Heating, Microwave Assistant Extraction and the use of “green” solvents such as the deep eutectic solvents, have been investigated in order to contribute to the minimization of disadvantages on the extraction of bioactive compounds. This review is focused on bioactive compounds derived from pomegranate (Punica granatum) peels and highlighted the most attractive extraction methods. It is believed that these findings could be a useful tool for the pomegranate juices industry to apply an effective and economically viable extraction process, transforming a by-product to a high added value functional product.

scholarly journals Multi-Sensor Fusion for Aerial Robots in Industrial GNSS-Denied Environments

2021 ◽  
Vol 11 (9) ◽  
pp. 3921
Author(s):  
Paloma Carrasco ◽  
Francisco Cuesta ◽  
Rafael Caballero ◽  
Francisco J. Perez-Grau ◽  
Antidio Viguria
Keyword(s):  
Sensor Fusion ◽  
Computational Efficiency ◽  
Probabilistic Approach ◽  
Laser Scanner ◽  
Industrial Applications ◽  
Experimental Results ◽  
Added Value ◽  
Aerial Robots ◽  
3D Localization ◽  
High Level

The use of unmanned aerial robots has increased exponentially in recent years, and the relevance of industrial applications in environments with degraded satellite signals is rising. This article presents a solution for the 3D localization of aerial robots in such environments. In order to truly use these versatile platforms for added-value cases in these scenarios, a high level of reliability is required. Hence, the proposed solution is based on a probabilistic approach that makes use of a 3D laser scanner, radio sensors, a previously built map of the environment and input odometry, to obtain pose estimations that are computed onboard the aerial platform. Experimental results show the feasibility of the approach in terms of accuracy, robustness and computational efficiency.

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