scholarly journals Ultramicroelectrode Array Based Sensors: A Promising Analytical Tool for Environmental Monitoring

Sensors ◽  
2010 ◽  
Vol 10 (1) ◽  
pp. 475-490 ◽  
Author(s):  
Jahir Orozco ◽  
César Fernández-Sánchez ◽  
Cecilia Jiménez-Jorquera

The particular analytical performance of ultramicroelectrode arrays (UMEAs) has attracted a high interest by the research community and has led to the development of a variety of electroanalytical applications. UMEA-based approaches have demonstrated to be powerful, simple, rapid and cost-effective analytical tools for environmental analysis compared to available conventional electrodes and standardised analytical techniques. An overview of the fabrication processes of UMEAs, their characterization and applications carried out by the Spanish scientific community is presented. A brief explanation of theoretical aspects that highlight their electrochemical behavior is also given. Finally, the applications of this transducer platform in the environmental field are discussed.

Author(s):  
Sandro Bimonte

Spatial OLAP (SOLAP) systems are powerful GeoBusiness Intelligence tools for analysing massive volumes of geo-referenced datasets. Therefore, these technologies are receiving considerable attention in the research community and in the database industry as well. Applications of these technologies are current in several domains such as ad marketing, healthcare, and urban development, to name a few. Contrary to other application domains, in the context of agri-environmental data and analysis, SOLAP systems have been underexploited. Therefore, in this paper, the author makes an exhaustive survey of most of the published studies in the domain of the SOLAP analysis of agri-environmental data with an emphasis on the reasons why only few recent works investigate the use of SOLAP systems in the agri-environmental context. In particular, the author focuses on the complexity of the spatio-multidimensional model and its implementation. Moreover, based on surveying the state of the art in this domain, this paper identifies some general guidelines that must be considered by the scientific community to design and implement efficient SOLAP approaches to the analysis of geo-referenced agri-environmental datasets. Finally, open issues about warehousing and OLAPing agri-environmental data are also shown in the paper.


Author(s):  
Sandro Bimonte

Spatial OLAP (SOLAP) systems are powerful GeoBusiness Intelligence tools for analysing massive volumes of geo-referenced datasets. Therefore, these technologies are receiving considerable attention in the research community and in the database industry as well. Applications of these technologies are current in several domains such as ad marketing, healthcare, and urban development, to name a few. Contrary to other application domains, in the context of agri-environmental data and analysis, SOLAP systems have been underexploited. Therefore, in this paper, the author makes an exhaustive survey of most of the published studies in the domain of the SOLAP analysis of agri-environmental data with an emphasis on the reasons why only few recent works investigate the use of SOLAP systems in the agri-environmental context. In particular, the author focuses on the complexity of the spatio-multidimensional model and its implementation. Moreover, based on surveying the state of the art in this domain, this paper identifies some general guidelines that must be considered by the scientific community to design and implement efficient SOLAP approaches to the analysis of geo-referenced agri-environmental datasets. Finally, open issues about warehousing and OLAPing agri-environmental data are also shown in the paper.


2017 ◽  
Vol 47 (188) ◽  
pp. 453-470 ◽  
Author(s):  
Hans-Peter Büttner

While the majority of the scientific community holds Marxian Value and Price Theory to be internally inconsistent because of the so-called “transformation problem”, these claims can be sufficiently refuted. The key to the solution of the “transformation problem” is quite simple, so this contribution, because it requires the rejection of simultanism and physicalism, which represent the genuine method of neoclassical economics, a method that is completely incompatible with Marxian Critique of Political Economy. Outside of the iron cage of neoclassical equilibrium economics, Marxian ‘Capital’ can be reconstructed without neoclassical “pathologies” and offers us a whole new world of analytical tools for a critical theory of capitalist societies and its dynamics.


Author(s):  
Deepak Goyal

Abstract Next generation assembly/package development challenges are primarily increased interconnect complexity and density with ever shorter development time. The results of this trend present some distinct challenges for the analytical tools/techniques to support this technical roadmap. The key challenge in the analytical tools/techniques is the development of non-destructive imaging for improved time to information. This paper will present the key drivers for the non-destructive imaging, results of literature search and evaluation of key analytical techniques currently available. Based on these studies requirements of a 3D imaging capability will be discussed. Critical breakthroughs required for development of such a capability are also summarized.


Coatings ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 298
Author(s):  
Miriam Truffa Giachet ◽  
Julie Schröter ◽  
Laura Brambilla

The application of varnishes on the surface of metal objects has been a very common practice since antiquity, both for protective and aesthetic purposes. One specific case concerns the use of tinted varnishes on copper alloys in order to mimic gilding. This practice, especially flourishing in the 19th century for scientific instruments, decorative objects, and liturgical items, results in large museum collections of varnished copper alloys that need to be preserved. One of the main challenges for conservators and restorers deals with the identification of the varnishes through non-invasive and affordable analytical techniques. We hereby present the experimental methodology developed in the framework of the LacCA and VERILOR projects at the Haute École ARC of Neuchâtel for the identification of gold varnishes on brass. After extensive documentary research and analytical campaigns on varnished museum objects, various historic shellac-based varnishes were created and applied by different methods on a range of brass substrates with different finishes. The samples were then characterized by UV imaging and infrared spectroscopy before and after artificial ageing. The comparative study of these two techniques was performed for different thicknesses of the same varnish and for different shellac grades in order to implement an identification methodology based on simple non-invasive examination and analytical tools, which are accessible to conservators.


2015 ◽  
Vol 69 (1) ◽  
Author(s):  
Pawan Jolly ◽  
Nello Formisano ◽  
Pedro Estrela

AbstractThe use of aptamers in biosensing has attracted considerable attention as an alternative to antibodies because of their unique properties such as long-term stability, cost-effectiveness and adjustability to various applications. Among cancers, the early diagnosis of prostate cancer (PCa) is one of the greatest concerns for ageing men worldwide. One of the most commonly used biomarkers for PCa is prostate-specific antigen (PSA), which can be found in elevated levels in patients with cancer. This review presents the gradual transition of research from antibody-based to aptamerbased biosensors, specifically for PSA. A brief description on aptamer-based biosensing for other PCa biomarkers is also presented. Special attention is given to electrochemical methods as analytical techniques for the development of simple, sensitive and cost-effective biosensors. The review also focuses on the different surface chemistries exploited for fabrication and their applications in clinical samples. The use of aptamers represents a promising tool for the development of point-ofcare biosensors for the early detection of prostate cancer. In view of the unmatched upper hand of aptamers, future prospects are also discussed, not only in the point-of-care format but also in other novel applications.


2021 ◽  
Vol 11 (5) ◽  
pp. 2307
Author(s):  
João Lincho ◽  
Rui C. Martins ◽  
João Gomes

Parabens are widely used in different industries as preservatives and antimicrobial compounds. The evolution of analytical techniques allowed the detection of these compounds in different sources at µg/L and ng/L. Until today, parabens were already found in water sources, air, soil and even in human tissues. The impact of parabens in humans, animals and in ecosystems are a matter of discussion within the scientific community, but it is proven that parabens can act as endocrine disruptors, and some reports suggest that they are carcinogenic compounds. The presence of parabens in ecosystems is mainly related to wastewater discharges. This work gives an overview about the paraben problem, starting with their characteristics and applications. Moreover, the dangers related to their usage were addressed through the evaluation of toxicological studies over different species as well as of humans. Considering this, paraben detection in different water sources, wastewater treatment plants, humans and animals was analyzed based on literature results. A review of European legislation regarding parabens was also performed, presenting some considerations for the use of parabens.


2018 ◽  
Vol 10 (1) ◽  
Author(s):  
Rasneet S Kumar ◽  
Jessica R White

Objective: To evaluate the effect and implications of changing the chief complaint field during the National Syndromic Surveillance Program (NSSP) transition from BioSense 2.0 analytical tools to BioSense Platform – ESSENCEIntroduction: In January 2017, the NSSP transitioned their BioSense analytical tools to Electronic Surveillance System for Early Notification of Community-Based Epidemics (ESSENCE). The chief complaint field in BioSense 2.0 was a concatenation of the record’s chief complaint, admission reason, triage notes, and diagnostic impression. Following the transition to ESSENCE, the chief complaint field was comprised of the first chief complaint entered or the first admission reason, if the chief complaint was blank. Furthermore, the ESSENCE chief complaint field was electronically parsed (i.e., the original chief complaint text was altered to translate abbreviations and remove punctuation). This abstract highlights key findings from Maricopa County Department of Public Health’s evaluation of the new chief complaint field, its impact on heat-related illness syndromic surveillance, and implications for ongoing surveillance efforts.Methods: For this evaluation, we used the heat-related illness query recommended in Council of State and Territorial Epidemiologists’ (CSTE)2016 Guidance Document for Implementing Heat-Related Illness Syndromic Surveillance. Before the transition, we used BioSense 2.0’s, phpMyAdmin analytical tool to generate a list of patients who visited Maricopa County emergency departments or inpatient hospitals between 5/1/2016 – 9/30/2016 due to heat-related illness. After the transition, we used the CC and DD Category “Heat-related Illness, v1” in ESSENCE, which was based on the CSTE heat-related illness query, to generate a list of patients for the same time period. We compared the line-lists and time-series trends from phpMyAdmin and ESSENCE.Results: The phpMyAdmin analytical tool identified 785 heat-related illness records with the query (Figure). 642 (82%) of these heat-related illness records were also captured by ESSENCE. Reasons for 143 (18%) records not being identified by ESSENCE included: the patient’s admission reason field contained keywords that were not available in the ESSENCE chief complaint field (n=94, 66%); data access changed, which disabled access to patients who resided in zip codes that crossed a county border (30, 21%); discrepancies between ESSENCE parsing and text in the original chief complaint (11, 8%); heat-related illness discharge diagnoses were removed by the facility after the phpMyAdmin line-list for heat-related illness was extracted (7, 5%); and one record was undetermined. Conversely, ESSENCE captured 36 additional heat-related illness records, not previously captured by phpMyAdmin. Reasons included: a query exclusion term was located in the patient’s admission reason but not the ESSENCE chief complaint field (16, 44%); a heat-related illness discharge diagnosis code was added by the facility after the data were extracted by phpMyAdmin (4, 11%); and 16 (44%) were undetermined. Time-series trend evaluation revealed a significant correlation between the two surveillance tools (Pearson coefficient = 0.97, p < 0.01).Conclusions: Though the data trends over time were not significantly affected by changes in the chief complaint field, differences in the field’s composition have important implications for syndromic surveillance practitioners. Free-text queries designed to search the chief complaint field in ESSENCE may not retrieve records previously identified with BioSense 2.0 analytical tools, which may limit individual case-finding capacity. The elimination of admission reason from the chief complaint field in ESSENCE has the greatest effect on case-finding capacity. Furthermore, surveillance reports produced by ESSENCE cannot be directly compared to reports that were previously published with data from BioSense 2.0. These limitations may be addressed if ESSENCE creates a feature that allows users to easily query fields (e.g., admission reason) in addition to the chief compliant field.


Foods ◽  
2018 ◽  
Vol 7 (9) ◽  
pp. 141 ◽  
Author(s):  
Geetesh Mishra ◽  
Abbas Barfidokht ◽  
Farshad Tehrani ◽  
Rupesh Mishra

Rapid and precise analytical tools are essential for monitoring food safety and screening of any undesirable contaminants, allergens, or pathogens, which may cause significant health risks upon consumption. Substantial developments in analytical techniques have empowered the analyses and quantitation of these contaminants. However, conventional techniques are limited by delayed analysis times, expensive and laborious sample preparation, and the necessity for highly-trained workers. Therefore, prompt advances in electrochemical biosensors have supported significant gains in quantitative detection and screening of food contaminants and showed incredible potential as a means of defying such limitations. Apart from indicating high specificity towards the target analytes, these biosensors have also addressed the challenge of food industry by providing high analytical accuracy within complex food matrices. Here, we discuss some of the recent advances in this area and analyze the role and contributions made by electrochemical biosensors in the food industry. This article also reviews the key challenges we believe biosensors need to overcome to become the industry standard.


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