scholarly journals Preparation of Quasi-Three-Dimensional Porous Ag and Ag-NiO Nanofibrous Mats for SERS Application

Sensors ◽  
2018 ◽  
Vol 18 (9) ◽  
pp. 2862 ◽  
Author(s):  
Huixiang Wu ◽  
Xiangcheng Sun ◽  
Changjun Hou ◽  
Jingzhou Hou ◽  
Yu Lei

In this study, two new quasi-three-dimensional Surface Enhanced Raman Scattering (SERS) substrates, namely porous Ag and Ag-NiO nanofibrous mats, were prepared using a simple, electrospinning-calcination, two-step synthetic process. AgNO3/polyvinyl pyrrolidone (PVP) and AgNO3/Ni(NO3)2/PVP composites serving as precursors were electrospun to form corresponding precursory nanofibers. Porous Ag and Ag-NiO nanofibers were successfully obtained after a 3-h calcination at 500 °C under air atmosphere, and analyzed using various material characterization techniques. Synthesized, quasi-three-dimensional porous Ag and Ag-NiO nanofibrous mats were applied as SERS substrates, to measure the model compound Rhodamine 6G (R6G), and investigate the corresponding signal enhancement. Furthermore, porous Ag and Ag-NiO nanofibrous mats were employed as SERS substrates for melamine and methyl parathion respectively. Sensitive detection of melamine and methyl parathion was achieved, indicating their feasibility as an active SERS sensing platform, and potential for food safety and environmental monitoring. All the results suggest that the electrospinning-calcination, two-step method offers a new, low cost, high performance solution in the preparation of SERS substrates.

RSC Advances ◽  
2019 ◽  
Vol 9 (38) ◽  
pp. 21771-21776 ◽  
Author(s):  
Nan Zhao ◽  
Hefu Li ◽  
Cunwei Tian ◽  
Yanru Xie ◽  
Zhenbao Feng ◽  
...  

Three-dimensional (3D) plasmonic structures have been intensively investigated as high performance surface enhanced Raman scattering (SERS) substrates.


NANO ◽  
2017 ◽  
Vol 12 (05) ◽  
pp. 1750052 ◽  
Author(s):  
Xiuhua Li ◽  
Jian Lin ◽  
Junhong Zhao

A novel composite nanostructure which is made up of TiO2 three dimensionally ordered macroporous (3DOM) nanostructure and TiO2 nanorods (NRs) has been successfully synthesized through a combination of colloidal crystal template technology and hydrothermal method, then we achieved its combination with Ag nanoparticles (NPs) via a silver mirror reaction. We studied the SERS (Surface-Enhanced Raman Scattering) performance of the obtained structure, the results show that our samples are very sensitive substrates when being used to detect dye R6G molecules, with a low detection concentration of 10[Formula: see text] M. This proves that it is a promising material in the area of analyzing and molecule-level detecting as a kind of novel and low-cost SERS substrate.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 886
Author(s):  
Massimo Rippa ◽  
Riccardo Castagna ◽  
Domenico Sagnelli ◽  
Ambra Vestri ◽  
Giorgia Borriello ◽  
...  

Brucella is a foodborne pathogen globally affecting both the economy and healthcare. Surface Enhanced Raman Spectroscopy (SERS) nano-biosensing can be a promising strategy for its detection. We combined high-performance quasi-crystal patterned nanocavities for Raman enhancement with the use of covalently immobilized Tbilisi bacteriophages as high-performing bio-receptors. We coupled our efficient SERS nano-biosensor to a Raman system to develop an on-field phage-based bio-sensing platform capable of monitoring the target bacteria. The developed biosensor allowed us to identify Brucella abortus in milk by our portable SERS device. Upon bacterial capture from samples (104 cells), a signal related to the pathogen recognition was observed, proving the concrete applicability of our system for on-site and in-food detection.


Author(s):  
Marcel Simsek ◽  
Nongnoot Wongkaew

AbstractNon-enzymatic electrochemical sensors possess superior stability and affordability in comparison to natural enzyme-based counterparts. A large variety of nanomaterials have been introduced as enzyme mimicking with appreciable sensitivity and detection limit for various analytes of which glucose and H2O2 have been mostly investigated. The nanomaterials made from noble metal, non-noble metal, and metal composites, as well as carbon and their derivatives in various architectures, have been extensively proposed over the past years. Three-dimensional (3D) transducers especially realized from the hybrids of carbon nanomaterials either with metal-based nanocatalysts or heteroatom dopants are favorable owing to low cost, good electrical conductivity, and stability. In this critical review, we evaluate the current strategies to create such nanomaterials to serve as non-enzymatic transducers. Laser writing has emerged as a powerful tool for the next generation of devices owing to their low cost and resultant remarkable performance that are highly attractive to non-enzymatic transducers. So far, only few works have been reported, but in the coming years, more and more research on this topic is foreseeable. Graphical abstract


2021 ◽  
Author(s):  
revathy m s ◽  
D Murugesan ◽  
Naidu Dhanpal Jayram

Abstract Thin films and Surface Enhanced Raman spectroscopy have a strong bonding towards development of Sensors. From last 4 decades SERS has been used as effective tool for detection of toxic dyes, in food industry and agriculture world. To minimize the cost and fabrication over large surface is the most challenging task in substrate fabrication. In the present work an attempt has been made towards dual coatings, which could act as an effective SERS Substrates. An effective and facile approach of low cost bi-metallic Nanostructured film has been fabricated using thermal evaporation. Using the standard characterization techniques such as FE-SEM and XRD, the obtained films were Rhodamine 6G was used as an analyte for the SERS studies. The detection of R6G was up to 10− 10mol l− 1solution.The present bi-metallic coating can be serves as an excellent SERS active surface and provides a versatile pathway to fabricate anisotropic nanostructure on a glass film.


2022 ◽  
Vol 6 (1) ◽  
Author(s):  
Taikyu Kim ◽  
Cheol Hee Choi ◽  
Pilgyu Byeon ◽  
Miso Lee ◽  
Aeran Song ◽  
...  

AbstractAchieving high-performance p-type semiconductors has been considered one of the most challenging tasks for three-dimensional vertically integrated nanoelectronics. Although many candidates have been presented to date, the facile and scalable realization of high-mobility p-channel field-effect transistors (FETs) is still elusive. Here, we report a high-performance p-channel tellurium (Te) FET fabricated through physical vapor deposition at room temperature. A growth route involving Te deposition by sputtering, oxidation and subsequent reduction to an elemental Te film through alumina encapsulation allows the resulting p-channel FET to exhibit a high field-effect mobility of 30.9 cm2 V−1 s−1 and an ION/OFF ratio of 5.8 × 105 with 4-inch wafer-scale integrity on a SiO2/Si substrate. Complementary metal-oxide semiconductor (CMOS) inverters using In-Ga-Zn-O and 4-nm-thick Te channels show a remarkably high gain of ~75.2 and great noise margins at small supply voltage of 3 V. We believe that this low-cost and high-performance Te layer can pave the way for future CMOS technology enabling monolithic three-dimensional integration.


Author(s):  
Jifeng Wang ◽  
Qubo Li ◽  
Norbert Mu¨ller

A mechanical and optimal analyses procedure is developed to assess the stresses and deformations of Novel Wound Composite Axial-Impeller under loading conditions particular to centrifuge. This procedure is based on an analytical method and Finite Element Analysis (FEA, commercial software ANSYS) results. A low-cost, light-weight, high-performance, composite turbomachinery impeller from differently designed patterns will be evaluated. Such impellers can economically enable refrigeration plants using water as a refrigerant (R718). To create different complex patterns of impellers, MATLAB is used for creating the geometry of impellers, and CAD software UG is used to build three-dimensional impeller models. Available loading conditions are: radial body force due to high speed rotation about the cylindrical axis and fluid forces on each blade. Two-dimensional plane stress and three-dimensional stress finite element analysis are carried out using ANSYS to validate these analytical mechanical equations. The von Mises stress is investigated, and maximum stress and Tsai-Wu failure criteria are applied for composite material failure, and they generally show good agreement.


Author(s):  
Jiawei Wu ◽  
Jing Chen ◽  
Xiaodong Wang ◽  
An'an Zhou ◽  
Zhenglong Yang

For the higher safety and energy density, solid-state electrolyte with better mechanical strength, thermal and electrochemical stability is a perfect choice. To improve the performance of PEO, usage of low-cost...


NANO ◽  
2020 ◽  
Vol 15 (05) ◽  
pp. 2050062
Author(s):  
Zhaolei Meng ◽  
Xiaojian He ◽  
Song Han ◽  
Zijian Hu

Carbon materials are generally employed as supercapacitor electrodes due to their low- cost, high-chemical stability and environmental friendliness. However, the design of carbon structures with large surface area and controllable porous structure remains a daunt challenge. In this work, a three-dimensional (3D) hybrid aerogel with different contents of MoS2 nanosheets in 3D graphene aerogel (MoS2-GA) was synthesized through a facial hydrothermal process. The influences of MoS2 content on microstructure and subsequently on electrochemical properties of MoS2-GA are systematically investigated and an optimized mass ratio with MoS2: GA of 1:2 is chosen to achieve high mechanical robustness and outstanding electrochemical performance in the hybrid structure. Due to the large specific surface area, porous structure and continuous charge transfer network, such MoS2-GA electrodes exhibit high specific capacitance, good rate capability and excellent cyclic stability, showing great potential in large-scale and low-cost fabrication of high-performance supercapacitors.


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