scholarly journals Enhanced Treatment of Pharmaceutical Wastewater by an Improved A2/O Process with Ozone Mixed Municipal Wastewater

Water ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2771
Author(s):  
Jian Wang ◽  
Cong Du ◽  
Feng Qian ◽  
Yonghui Song ◽  
Liancheng Xiang
Keyword(s):  
Municipal Wastewater ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Cod Removal ◽  
Microbial Community Analysis ◽  
Ozone Treatment ◽  
Pharmaceutical Wastewater ◽  
Nitrogen And Phosphorus ◽  
Hydrolysis Acidification

A pilot-scale experiment is carried out for treating mixed wastewater containing pharmaceutical wastewater (PW) and domestic wastewater (DW), by a process that is a combination of hydrolysis acidification-ozone-modified anaerobic–anoxic–aerobic-ozone (A2/O) (pre-ozone) or hydrolysis acidification-modified A2/O-ozone (post-ozone). The effects of different mixing ratios of PW and DW and pre-ozone treatment or post-ozone treatment on the removal of nitrogen and phosphorus and chemical oxygen demand (COD) are compared and studied. The optimal ratio of PW in mixing wastewater is 30%, which has the optimal COD removal efficiency and minimum biotoxicity to biological treatment. The pre-ozone treatment shows more advantages in removing nitrogen and phosphate but the post-ozone treatment shows more advantages in COD removal. Analysis of dissolved organic matter (DOM) demonstrates that post-ozone treatment has a more significant effect on the removal of fulvic acid and humic acid than the effect from the pre-ozone treatment, so the COD removal is better. Overall DOM degradation efficiency by post-ozone treatment is 55%, which is much higher than the pre-ozone treatment efficiency of 38%. Microbial community analysis reveals that the genus Thauera and the genus Parasegetibacter take great responsibility for the degradation of phenolics in this process. All the results show that the post-ozone treatment is more efficient for the mixed wastewater treatment in refractory organics removal.

The effect of operational conditions on the performance of UASB reactors for domestic wastewater treatment

2005 ◽  
Vol 52 (1-2) ◽  
pp. 299-305 ◽  
Author(s):  
R.C. Leitão ◽  
J.A. Silva-Filho ◽  
W. Sanders ◽  
A.C. van Haandel ◽  
G. Zeeman ◽  
...  
Keyword(s):  
Removal Efficiency ◽  
Municipal Wastewater ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Cod Removal ◽  
Upflow Anaerobic Sludge Blanket ◽  
Anaerobic Sludge ◽  
Operational Conditions ◽  
Cod Removal Efficiency ◽  
Uasb Reactors

In this investigation, the performance of Upflow Anaerobic Sludge Blanket (UASB) reactors treating municipal wastewater was evaluated on the basis of: (i) COD removal efficiency, (ii) effluent variability, and (iii) pH stability. The experiments were performed using 8 pilot-scale UASB reactors (120 L) from which some of them were operated with different influent COD (CODInf ranging from 92 to 816 mg/L) and some at different hydraulic retention time (HRT ranging from 1 to 6 h). The results show that decreasing the CODInf, or lowering the HRT, leads to decreased efficiencies and increased effluent variability. During this experiment, the reactors could treat efficiently sewage with concentration as low as 200 mg COD/L. They could also be operated satisfactorily at an HRT as low as 2 hours, without problems of operational stability. The maximum COD removal efficiency can be achieved at CODInf exceeding 300 mg/L and HRT of 6 h.

Anaerobic hydrolysis of a municipal wastewater in a pilot-scale digester

2003 ◽  
Vol 47 (12) ◽  
pp. 223-230 ◽  
Author(s):  
J.A. Álvarez ◽  
C.A. Zapico ◽  
M. Gómez ◽  
J. Presas ◽  
M. Soto
Keyword(s):  
Volatile Fatty Acids ◽  
Municipal Wastewater ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Organic Load ◽  
Active Volume ◽  
Santiago De Compostela ◽  
Load Rate ◽  
Pre Treatment

Raw domestic wastewater from the city of Santiago de Compostela (Northwest Spain) was fed into a pilot-scale hydrolytic up flow sludge bed (HUSB) digester with an active volume of 25.5 m3. The total influent chemical oxygen demand (COD) ranged from 360 to 470 mg/l, the influent SS varied from 190 to 370 mg/l, and the temperature was between 17° and 20°C. The organic load rate (OLR) applied increased step by step from 1.2 to 3.9 kgCOD/m3.d, while the hydraulic retention time (HRT) decreased from 7.1 h to 2.9 h. A high suspended solids (SS) removal of about 82-85% from the influent was reached, most of which (81 to 88%) was eliminated by hydrolysis, while the rest remained in the purge stream. The total COD removal ranged from 46 to 59%. On the other hand, a high acidification of the COD remaining in the effluent was obtained, so the percent COD in the form of volatile fatty acids (VFACOD) with respect to total effluent COD was about 43% for the highest HRT applied, and about 27% for the lowest HRT. The soluble to total COD ratio (CODs/CODt) increased from 25-32% for the influent to 71-86% for the effluent. The results obtained confirm the viability and interest of direct anaerobic hydrolytic pre-treatment of domestic wastewater.

scholarly journals Fouling membrane in an anaerobic membrane bioreactor treating municipal wastewater

2017 ◽  
Vol 12 (2) ◽  
pp. 314-321 ◽  
Author(s):  
A. Cerón-Vivas ◽  
A. Noyola
Keyword(s):  
Membrane Fouling ◽  
Municipal Wastewater ◽  
Scale Up ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Cod Removal ◽  
Anaerobic Sludge ◽  
Nitrogen Gas ◽  
Gas Bubbling ◽  
Anaerobic Sludge Blanket

An anaerobic membrane reactor (AnMBR) treating municipal wastewater was evaluated. The experiments were performed using a pilot-scale up-flow anaerobic sludge blanket reactor with a submerged tubular ultrafiltration membrane at a hydraulic retention time of 8 hours. The system worked at an intermittent filtration mode (4 min on/1 min off) with and without nitrogen gas bubbling during the relaxation time (IF4NP and IF4P, respectively). The chemical oxygen demand (COD) removal achieved by the AnMBR was 68.6% and 87.9% for IF4P and IF4NP. Nitrogen bubbling also improved the filtration performance, as the elapsed time to reach 40 kPa for IF4NP and IF4P were 443 and 108 hours, respectively. Results show that intermittent filtration combined with nitrogen bubbling during the period of relaxation was an effective operation strategy in order to minimize membrane fouling and to increase COD removal.

A model for organic matter removal in free water surface constructed wetlands

1998 ◽  
Vol 38 (1) ◽  
pp. 369-377 ◽  
Author(s):  
C. Polprasert ◽  
N. R. Khatiwada ◽  
J. Bhurtel
Keyword(s):  
Organic Matter ◽  
Constructed Wetlands ◽  
Water Surface ◽  
Oxygen Demand ◽  
Free Water ◽  
Domestic Wastewater ◽  
Pilot Scale ◽  
Cod Removal ◽  
Model Parameters ◽  
Free Water Surface

This study was conducted to determine performance of free water surface (FWS) constructed wetlands located in the tropics in the removal of organic matter and to assess the importance of biofilm bacteria in the overall kinetics of organic matter (or chemical oxygen demand, COD) removal. Because constructed wetlands normally contain both biofilm and suspended bacteria, a kinetic model incorporating the activities of these two bacteria groups, dispersion number and hydraulic retention time, was employed. The model parameters essential for the calculation of COD removal in FWS constructed wetlands were determined from the experiments and some from the literature. The model was found satisfactory in predicting COD removal efficiencies in a pilot-scale FWS constructed wetland unit treating a domestic wastewater.

Effects of recirculation and separation times on nitrogen removal in baffled membrane bioreactor (B-MBR)

2018 ◽  
Vol 77 (12) ◽  
pp. 2803-2811 ◽  
Author(s):  
T. Miyoshi ◽  
T. Tsumuraya ◽  
T. P. Nguyen ◽  
K. Kimura ◽  
Y. Watanabe
Keyword(s):  
Removal Efficiency ◽  
Nitrogen Removal ◽  
Membrane Bioreactor ◽  
Municipal Wastewater ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Operating Conditions ◽  
Nitrogen And Phosphorus ◽  
Experimental Apparatus ◽  
Do Concentration

Abstract In this study, we investigated the effects of recirculation and separation times on removals of organic matter, nitrogen, and phosphorus in a baffled membrane bioreactor (B-MBR) treating real municipal wastewater. A pilot-scale B-MBR experimental apparatus was operated under two different sets of recirculation and separation times. The results revealed that, irrespective of operating conditions, the biochemical oxygen demand (BOD) and concentration of total nitrogen (T-N) in the treated water can be lowered to less than 3 and 5 mg/L, respectively. Although T-N was effectively removed in the two different operating conditions, increase in the fraction of recirculation time results in tiny deterioration of nitrogen removal efficiency in the B-MBR. Phosphorus removal efficiency was also slightly decreased as the fraction of recirculation time (ratio between recirculation and separation times) was increased. The results of the measurement of dissolved oxygen (DO) profiles at different points of the B-MBR apparatus indicate that the increase in DO concentration in the anoxic zone of the B-MBR becomes much more pronounced by increasing recirculation intensity. On the basis of the results obtained in this study, it can be concluded that efficient removal of BOD, T-N, and total phosphorus can be achieved by the B-MBR as long as appropriate recirculation intensity is selected.

scholarly journals Efficiency and Technological Reliability of Contaminant Removal in Household WWTPs with Activated Sludge

2021 ◽  
Vol 11 (4) ◽  
pp. 1889 ◽  
Author(s):  
Agnieszka Micek ◽  
Krzysztof Jóźwiakowski ◽  
Michał Marzec ◽  
Agnieszka Listosz ◽  
Tadeusz Grabowski
Keyword(s):  
Activated Sludge ◽  
Wastewater Treatment Plants ◽  
Oxygen Demand ◽  
Domestic Wastewater ◽  
Pollutant Removal ◽  
Treated Wastewater ◽  
Contaminant Removal ◽  
Nitrogen And Phosphorus ◽  
Wastewater Samples ◽  
Polish Law

The results of research on the efficiency and technological reliability of domestic wastewater purification in two household wastewater treatment plants (WWTPs) with activated sludge are presented in this paper. The studied facilities were located in the territory of the Roztocze National Park (Poland). The mean wastewater flow rate in the WWTPs was 1.0 and 1.6 m3/day. In 2017–2019, 20 series of analyses were done, and 40 wastewater samples were taken. On the basis of the received results, the efficiency of basic pollutant removal was determined. The technological reliability of the tested facilities was specified using the Weibull method. The average removal efficiencies for the biochemical oxygen demand in 5 days (BOD5) and chemical oxygen demand (COD) were 66–83% and 62–65%, respectively. Much lower effects were obtained for total suspended solids (TSS) and amounted to 17–48%, while the efficiency of total phosphorus (TP) and total nitrogen (TN) removal did not exceed 34%. The analyzed systems were characterized by the reliability of TSS, BOD5, and COD removal at the level of 76–96%. However, the reliability of TN and TP elimination was less than 5%. Thus, in the case of biogenic compounds, the analyzed systems did not guarantee that the quality of treated wastewater would meet the requirements of the Polish law during any period of operation. This disqualifies the discussed technological solution in terms of its wide application in protected areas and near lakes, where the requirements for nitrogen and phosphorus removal are high.

scholarly journals Catalytic wet oxidation of high concentration pharmaceutical wastewater with Fe3+ as catalyst

2018 ◽  
Vol 2017 (3) ◽  
pp. 661-666
Author(s):  
Xu Zeng ◽  
Jun Liu ◽  
Jianfu Zhao
Keyword(s):  
Oxygen Pressure ◽  
Batch Reactor ◽  
Oxygen Demand ◽  
Kinetic Studies ◽  
Cod Removal ◽  
Wet Oxidation ◽  
Catalytic Wet Oxidation ◽  
Pharmaceutical Wastewater ◽  
High Concentration ◽  
Temperature Time

Abstract Catalytic wet oxidation of high concentration pharmaceutical wastewater with Fe3+ as catalyst was carried out in a batch reactor. Results showed that the degradation of pharmaceutical wastewater was enhanced significantly by Fe3+. The effects of reaction parameters, such as the catalyst dose, reaction temperature, time, and initial oxygen pressure, were discussed. The chemical oxygen demand (COD) removal increased with the increases of catalyst dose, temperature, time and oxygen supply. With the initial COD 34,000–35,000 mg/L, approximately 70% COD removal can be achieved under the conditions of catalyst 1.0 g and oxygen pressure 1.0 MPa at 250 °C after 60 min. The results of kinetic studies showed that two reaction steps existed in this oxidation process, which followed an apparent first-order rate law. This process provides an effective approach for the pretreatment of high concentration pharmaceutical wastewater.

Novel biofilm reactor for denitrification of municipal wastewater

2018 ◽  
Vol 78 (7) ◽  
pp. 1566-1575 ◽  
Author(s):  
S. S. Rathnaweera ◽  
B. Rusten ◽  
K. Korczyk ◽  
B. Helland ◽  
E. Rismyhr
Keyword(s):  
Carbon Source ◽  
Municipal Wastewater ◽  
Low Cost ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Biofilm Reactor ◽  
Treated Wastewater ◽  
Removal Rates ◽  
Good Filter ◽  
Solids Removal

Abstract A pilot-scale CFIC® (continuous flow intermittent cleaning) reactor was run in anoxic conditions to study denitrification of wastewater. The CFIC process has already proven its capabilities for biological oxygen demand removal with a small footprint, less energy consumption and low cost. The present study focused on the applicability for denitrification. Both pre-denitrification (pre-DN) and post-denitrification (post-DN) were tested. A mixture of primary treated wastewater and nitrified wastewater was used for pre-DN and nitrified wastewater with ethanol as a carbon source was used for post-DN. The pre-DN process was carbon limited and removal rates of only 0.16 to 0.74 g NOx-N/m²-d were obtained. With post-DN and an external carbon source, 0.68 to 2.2 g NO3-Neq/m²-d removal rates were obtained. The carrier bed functioned as a good filter for both the larger particles coming with influent water and the bio-solids produced in the reactor. Total suspended solids removal in the reactor varied from 20% to 78% (average 45%) during post-DN testing period and 9% to 70% (average 29%) for pre-DN. The results showed that the forward flow washing improves both the DN function and filtration ability of the reactor.

A proposed sustainable BNR plant with the emphasis on recovery of COD and phosphate

2003 ◽  
Vol 48 (1) ◽  
pp. 77-85 ◽  
Author(s):  
X.-D. Hao ◽  
M.C.M. van Loosdrecht
Keyword(s):  
Wastewater Treatment ◽  
Municipal Wastewater ◽  
Water Environment ◽  
Pilot Scale ◽  
Ammonium Oxidation ◽  
Municipal Wastewater Treatment ◽  
Nitrogen And Phosphorus ◽  
Water Problems ◽  
Sustainable Wastewater Treatment ◽  
The Impact

Water problems have to be solved in an integrated way, and sustainability has become a major issue. For this reason, developing more sustainable wastewater treatment processes is needed. New discoveries and good understanding on microbial conversions of nitrogen and phosphorus make more sustainable processes possible. New options for decentralized sustainable sanitation are generally compared to conventional sewage systems, we think that for a proper comparison also innovative centralized treatment schemes should be evaluated. In this article, a more sustainable WWTP is proposed for municipal wastewater treatment, mainly based on the principles of denitrifying dephosphatation and anaerobic ammonium oxidation (ANAMMOX). The proposed system consists of a first stage of the A/B process in which maximal sludge production is achieved. In this way, COD is regained as sludge for methanation. The following BCFS® and CANON processes can remove N and P with minimal or no COD need. As a potential fertiliser, struvite can easily be removed from the sludge water by adding magnesium compounds. A case study is done on the basis of the mass balance over the proposed plant. The effluent from the system has a good quality to be recycled. This could also make a contribution to meeting the world's water needs and lessening the impact on the world's water environment. Since all the separate units are already applied or tested on pilot-scale, no problems for technical implementation are foreseen.

scholarly journals Municipal Wastewater Treatment Using a Packed Bio-tower Approach

2020 ◽  
pp. 42-50
Author(s):  
Klaus Doelle ◽  
Qian Wang
Keyword(s):  
Wastewater Treatment ◽  
Flow Rate ◽  
Municipal Wastewater ◽  
Oxygen Demand ◽  
Pilot Scale ◽  
Continuous Operation ◽  
Growth Media ◽  
Municipal Wastewater Treatment ◽  
Bacteria Growth ◽  
Tower System

The study tested a designed and built pilot scale packed bio-tower system under continuous operation using pre-clarified municipal wastewater. Performance was evaluated by measuring the removal of chemical oxygen demand and nitrogen ammonia. The pilot scale packed bio-tower system had a diameter of 1209 mm (4 ft.) and a height of 3,962 mm (13 ft.) and contained Bentwood CF-1900 bacteria growth media with a surface area of 6,028.80 ft² (560.09 m²). The municipal residential sewage was fed into a 1,481 l (375 gal.) recirculation reservoir at a temperature of 15°C (59.0°F) and a flow rate between 7,571 l/d (2000 gal/d) and 90,850 l/d (24,000 gal/d) and recirculated through the bio-tower with a fixed recirculation rate of 75.7 l/min (20 gal/min). The influent COD value reduction achieved is between 63.4% and 84.8%, whereas the COD influent value varied between 87 mg/l and 140 mg/l. The influent NH3-N reduction achieved was between 99.8% and 91.8% whereas the influent NH3-N value was between 28.8 mg/l and 18.6 mg/l  at a flow rate between 7571 l/d (2000 gal/d) and 90,850 l/d (24,000 gal/d).

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