scholarly journals Potential Sources of Ammonium-Nitrogen in the Coastal Groundwater Determined from a Combined Analysis of Nitrogen Isotope, Biological and Geological Parameters, and Land Use

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 25
Author(s):  
Anna Fadliah Rusydi ◽  
Shin-Ichi Onodera ◽  
Mitsuyo Saito ◽  
Fujio Hyodo ◽  
Morihiro Maeda ◽  
...  
Keyword(s):  
Land Use ◽  
Cation Exchange ◽  
Nitrogen Isotope ◽  
Ammonium Nitrogen ◽  
Sodium Cation ◽  
Anthropogenic Sources ◽  
Coliform Bacteria ◽  
Elevated Concentration ◽  
Coastal Groundwater ◽  
Potential Sources

The origin of ammonium-nitrogen in Indonesian coastal groundwater has not been intensively examined, meanwhile the elevated concentration remains a concern. This research aims at tracing the potential sources of ammonium-nitrogen in the groundwater of Indramayu, Indonesia where groundwater is vital for livelihood. From results, a combined examination of nitrogen isotope, coliform bacteria, land-use, and geology confirmed the natural and anthropogenic origins of ammonium-nitrogen in the groundwater. In the brackish-water aquaculture region, groundwater has δ15NNH4 values from +1.8 to +4.8‰ signifying that ammonium-nitrogen is derived from mineralization of organic nitrogen to ammonium. Furthermore, ammonium has a significantly positive relationship with sodium indicating the exchangeable ammonium is mobilized to groundwater via cation exchange. Meanwhile ammonium-nitrogen from anthropogenic waste was detected in agricultural and residential region. The groundwater has more varied δ15NNH4 values, from −2.9 to +16.1‰, which implies attenuation of ammonium-nitrogen from several sources namely manure, mineral fertilizer, sewage, and pit latrines. Also, the presence of E. coli confirms the indication of human and animal waste contamination. However, since ammonium has no relationship with sodium, cation exchange is not feasible and ammonium-nitrogen flows into the groundwater from anthropogenic sources along with liquid wastes.

scholarly journals Evaluation of the Antimicrobial Protection of Pharmaceutical Kaolin and Talc Modified with Copper and Zinc

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1173
Author(s):  
Fotini Martsouka ◽  
Konstantinos Papagiannopoulos ◽  
Sophia Hatziantoniou ◽  
Martin Barlog ◽  
Giorgos Lagiopoulos ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Photoelectron Spectroscopy ◽  
Antimicrobial Properties ◽  
Exchange Capacity ◽  
Elevated Concentration ◽  
Chemical Mapping ◽  
Exchange Method ◽  
X Ray ◽  
Copper And Zinc ◽  
Antimicrobial Protection

Six pharmaceutical pastes were prepared using chemically modified kaolin and talc powders. Tests were conducted to determine their structural and chemical characteristics as well as their antimicrobial protection, thus rendering them suitable for cosmetic and pharmaceutical uses. Kaolin and talc were treated chemically via the cation exchange method to load the clay particles with copper and zinc ions, two cations well known for their antimicrobial properties. Mineralogical analyses were conducted by using X-ray diffraction (XRD) before and after the modification, confirming the mineralogical purity of the samples. Scanning electron microscopy was also used in conjunction with energy dispersed spectroscopy (SEM-EDS) to obtain chemical mapping images, revealing the dispersion of the added metals upon the clay minerals surfaces. Moreover, chemical analysis has been performed (XRF) to validate the enrichment of the clays with each metal utilizing the cation exchange capacity. All modified samples showed the expected elevated concentration in copper or zinc in comparison to their unmodified versions. From the X-ray photoelectron spectroscopy (XPS), the chemical state of the samples’ surfaces was investigated, revealing the presence of salt compounds and indicating the oxidation state of adsorbed metals. Finally, the resistance of pastes in microbial growth when challenged with bacteria, molds, and yeasts was assessed. The evaluation is based on the European Pharmacopeia (EP) criteria.

scholarly journals Water quality of the reservoirs used for irrigation in São José dos Pinhais, Paraná State, Brazil

2016 ◽  
Vol 46 (4) ◽  
pp. 626-631
Author(s):  
Tiago Miguel Jarek ◽  
Jorge Luiz Moretti de Souza ◽  
Nerilde Favaretto ◽  
Lucimeris Ruaro
Keyword(s):  
Water Quality ◽  
Land Use ◽  
Coliform Bacteria ◽  
Environmental Preservation ◽  
Quality Of Water ◽  
Average Rainfall ◽  
Agricultural Potential ◽  
Thermotolerant Coliforms ◽  
Type Of Land Use

ABSTRACT: Land use outside its agricultural potential and low vegetation cover in the watershed impair the quality of water used for irrigation and may contribute to the spread of pathogenic coliform bacteria. The objective of this study was to relate the quality of irrigation water with the intensity and type of land use and the rainfall in a vegetable-producing region of São José dos Pinhais, Paraná. Water samples were collected monthly in 2013 from two reservoirs and one preserved source. After collection, the samples were chilled in Styrofoam boxes and transported to the laboratory for analyses of the total and thermotolerant coliforms. Effect of land use was analyzed by probability estimation trees. High land use and weekly above average rainfall increased the probability of thermo tolerant coliforms exceeding the limit allowed under legislation. In regards to thermo tolerant coliforms in the analyzed period, the water from only one reservoir was in accordance with the legislation for the quality of water to irrigate vegetables that are consumed raw. Results of this study are an alert to the local government for the necessity of environmental preservation to maintain the water quality of the county.

The Chao Phraya River Basin: water quality and anthropogenic influences

2018 ◽  
Vol 19 (5) ◽  
pp. 1287-1294 ◽  
Author(s):  
Nuanchan Singkran ◽  
Pitchaya Anantawong ◽  
Naree Intharawichian ◽  
Karika Kunta
Keyword(s):  
Water Quality ◽  
Land Use ◽  
River Basin ◽  
River Mouth ◽  
Oxygen Demand ◽  
Quality Parameters ◽  
Paddy Fields ◽  
Coliform Bacteria ◽  
Wet Season ◽  
Chao Phraya River

Abstract Land use influences and trends in water quality parameters were determined for the Chao Phraya River, Thailand. Dissolved oxygen (DO), biochemical oxygen demand (BOD), and nitrate-nitrogen (NO3-N) showed significant trends (R2 ≥ 0.5) across the year, while total phosphorus (TP) and faecal coliform bacteria (FCB) showed significant trends only in the wet season. DO increased, but BOD, NO3-N, and TP decreased, from the lower section (river kilometres (rkm) 7–58 from the river mouth) through the middle section (rkm 58–143) to the upper section (rkm 143–379) of the river. Lead and mercury showed weak/no trends (R2 < 0.5). Based on the river section, major land use groups were a combination of urban and built-up areas (43%) and aquaculture (21%) in the lower river basin, paddy fields (56%) and urban and built-up areas (21%) in the middle river basin, and paddy fields (44%) and other agricultural areas (34%) in the upper river basin. Most water quality and land use attributes had significantly positive or negative correlations (at P ≤ 0.05) among each other. The river was in crisis because of high FCB concentrations. Serious measures are suggested to manage FCB and relevant human activities in the river basin.

scholarly journals Benzo[<i>a</i>]pyrene in urban environments of eastern Moscow: pollution levels and critical loads

2017 ◽  
Vol 17 (3) ◽  
pp. 2217-2227 ◽  
Author(s):  
Nikolay S. Kasimov ◽  
Natalia E. Kosheleva ◽  
Elena M. Nikiforova ◽  
Dmitry V. Vlasov
Keyword(s):  
Land Use ◽  
Critical Loads ◽  
Significant Contribution ◽  
Urban Environments ◽  
Anthropogenic Sources ◽  
Average Intensity ◽  
Pollution Levels ◽  
Local Background ◽  
Polycyclic Aromatic ◽  
The Mean

Abstract. Polycyclic aromatic hydrocarbons (PAHs), particularly benzo[a]pyrene (BaP), are toxic compounds emitted from various anthropogenic sources. Understanding the BaP concentrations, dynamics and decomposition in soil is required to assess the critical loads of BaP in urban environments. This study is the first attempt to evaluate all major input and output components of benzo[a]pyrene (BaP) balance and to calculate the permissible load on the urban environment in different land-use zones in the Eastern district of Moscow. BaP contamination of the snow cover in the Eastern district of Moscow was related to daily BaP fallout from the atmosphere. In 2010, the mean content of the pollutant in the snow dust was 1942 ng g−1, whereas the average intensity of its fallout was 7.13 ng m−2 per day. Across the territory, BaP winter fallout intensities varied from 0.3 to 1100 ng m−2 per day. The average BaP content in the surface (0–10 cm) soil horizons was 409 ng g−1, which is 83 times higher than the local background value and 20 times higher than the maximum permissible concentration (MPC) accepted in Russia. The variations in soil and snow BaP concentrations among different land-use zones were examined. A significant contribution of BaP from the atmosphere to urban soils was identified. Based on the measurements of BaP atmospheric fallout and BaP reserves in the soils, the critical loads of BaP for the land-use zones in the Eastern district were calculated for different values of degradation intensity and different exposure times. It was established that at an annual degradation intensity of 1–10 %, ecologically safe BaP levels in the soils of all land-use zones, excluding the agricultural zone, will only be reached after many decades or centuries.

Nitrogen isotope composition of soils, C3 and C4 plants along land use gradients in southern Africa

2008 ◽  
Vol 72 (4) ◽  
pp. 326-337 ◽  
Author(s):  
J.N. Aranibar ◽  
I.C. Anderson ◽  
H.E. Epstein ◽  
C.J.W. Feral ◽  
R.J. Swap ◽  
...  
Keyword(s):  
Land Use ◽  
Southern Africa ◽  
Isotope Composition ◽  
Nitrogen Isotope ◽  
C4 Plants ◽  
C3 And C4 Plants ◽  
Nitrogen Isotope Composition

Environmental Acidification due to Soil Acid Changes of Different Land Use Patterns

2013 ◽  
Vol 361-363 ◽  
pp. 888-891
Author(s):  
Yue Shen ◽  
Yan Li Yi
Keyword(s):  
Land Use ◽  
Magnetic Susceptibility ◽  
Cation Exchange ◽  
Paddy Soil ◽  
Cation Exchange Capacity ◽  
Arable Land ◽  
Exchange Capacity ◽  
Land Use Patterns ◽  
Use Patterns ◽  
Orchard Soil

A survey was carried out to investigate the acidification due to acid changes of different land use patterns. The results showed that soil acidification happened in the arable land and forest land in topsoil of 0~10 cm depth, 0.42 and 0.24 pH unit-1 lower than that of in 80~100 cm depth. The lowest cation exchange capacity (CEC) (11.99 cmol·kg-1) was got in the topsoil of paddy soil, while the highest one was in the topsoil of grassland with 19.26 cmol·kg-1. A catastrophe point of cation exchange capacity of soils was found between 20~30 cm except for orchard soil. Organic matter in forest soil decreased sharply by 2.21% in 0~10 cm as compared with that of in 80~100 cm and little decrease about 0.97% was found in the orchard soil. The pH and magnetic susceptibility showed similar variation trend. Multiple linear regression analysis showed that there was a negative relationship between pH and low magnetic susceptibility. Our results also showed that the free iron, low magnetic susceptibility and amorphous ferric oxide were the main factors on the changes of pH in the arable land and forest soil, grassland and paddy soil, and the orchard soil, respectively.

scholarly journals Land Suitability Classification for Current Land Use in Akkar Plain- Tartous Governorate

2018 ◽  
Vol 27 (2) ◽  
pp. 89-105
Author(s):  
Safwan A. Mohammed Safwan A. Mohammed
Keyword(s):  
Land Use ◽  
Cation Exchange ◽  
Soil Texture ◽  
Cation Exchange Capacity ◽  
Soil Analysis ◽  
Exchange Capacity ◽  
Land Suitability ◽  
Land Evaluation ◽  
Limiting Factors ◽  
Physical Factors

Land evaluation is one of the most important tools for integrated land use management for sustainable agricultural and land use planning. The aim of this study is to evaluate the land suitability for current land use in akkar plain- Tartous Governorate. Depending on the elevation and land use, nine soil profiles representing the main physiographic units have been chosen. Soil samples were collected for conducting some chemical and physical analyses such as: soil texture (sand%, silt% and clay%), the content of organic matter OM, Cation Exchange Capacity CEC (cmol(+)/kg -1clay). The results of the soil analysis showed that the soil texture was Clay, and the pH values were between 7.13-8.5. Furthermore, The cation exchange capacity were ranging from (12-33) (cmol(+)/kg -1clay). Results of land evaluation showed that the limiting factors either fertility factors such as high pH in the villages of Beit-kamouna, Majdaloun-albaher and Dier-hbash, or physical factors such as shallowness depth of soil. The study concluded that the suitability class ranged from S2 to N2, which emphasis the importance of reconsidering the type of land use in the study area.

EEC resources and strategies

1987 ◽  
Vol 321 (1561) ◽  
pp. 405-422 ◽  
Keyword(s):  
Land Use ◽  
European Community ◽  
Agricultural Policy ◽  
Common Agricultural Policy ◽  
Regional Differences ◽  
Solid Wastes ◽  
Timber Production ◽  
Potential Sources ◽  
The Common ◽  
Forestry Residues

In common with those of other regions, the major wastes of the European Community (EC) that may be regarded as potential sources of lignocellulose are animal manures, crop and forestry residues, domestic and industrial solid wastes and waste paper. The availability reflects the agricultural policy under the Common Agricultural Policy (CAP) as well as the shortfall in timber production within the EC. Significant regional differences exist due to variations in climate and both agricultural and industrial practices. Of particular importance in future will be policy in respect of land use and/or steps taken to reduce agricultural surpluses.

Elevated mercury levels in biota along an agricultural land use gradient in the Oldman River basin, Alberta

2012 ◽  
Vol 69 (7) ◽  
pp. 1202-1213 ◽  
Author(s):  
Lars Brinkmann ◽  
Joseph B. Rasmussen
Keyword(s):  
Land Use ◽  
River Basin ◽  
Total Mercury ◽  
Agricultural Land ◽  
Trophic Position ◽  
Urban Land Use ◽  
Anthropogenic Sources ◽  
Oldman River Basin ◽  
Catostomus Catostomus ◽  
Oldman River

This study examines relationships between anthropogenic influence and mercury concentrations in biota along an elevational river gradient with intensifying agricultural and urban land use in the Oldman River basin, Alberta, Canada. We use nitrogen stable isotope signatures (δ15N) indicative of anthropogenic sources of N to indicate the extent of land use influence on the river ecosystem. δ15N values in biota increased by 4.2‰ along the river gradient, consistent with increasing nitrogen sources from sewage and manure. Mercury concentrations in longnose dace ( Rhinichthys cataractae ), suckers ( Catostomus catostomus , Catostomus commersonii ), and net-spinning caddisfly larvae, the most abundant macroinvertebrates, all increased downstream; dace ranged from 0.023 ppm total mercury below the Oldman reservoir to 0.10 ppm total mercury downstream of Lethbridge. Dace consumed mostly insect larvae, and no increase in trophic position (as estimated by δ15N) was observed along the gradient. Fish directly exposed to agricultural and urban effluents had significantly lower mercury levels, or showed no difference, relative to reference sites, which suggests that these effluents play no significant role in elevating mercury levels in river food webs.

Sign in / Sign up

Export Citation Format

Share Document