Chemistry and microbiology in sugar extraction

2021 ◽  
pp. 574-581
Author(s):  
Jan Maarten de Bruijn

The stability of the sucrose molecule and the firmness of the tissue structure in the cossettes are of major concern when optimizing the operating conditions for the extraction system. For a given extraction system the retention time is more or less fixed, but the actual pH values and temperatures to be set across the system largely determine the extent to which both sugar gets lost by hydrolysis and the cossette structure deteriorates, particularly by dissolution of pectin. Furthermore, potential sugar loss by microbial infection in the extraction system needs to be controlled too. The influence of the pH value and temperature on these undesirable chemical and microbial reactions will be outlined in this paper, including the consequences for the subsequent processing steps. It can be concluded that the recommended optimal pH values and temperatures for operating the extraction system are a compromise between good and bad.

2019 ◽  
Author(s):  
Ji Liu ◽  
Michael Nolan

<div>In the atomic layer deposition (ALD) of Cobalt (Co) and Ruthenium (Ru) metal using nitrogen plasma, the structure and composition of the post N-plasma NHx terminated (x = 1 or 2) metal surfaces are not well known but are important in the subsequent metal containing pulse. In this paper, we use the low-index (001) and (100) surfaces of Co and Ru as models of the metal polycrystalline thin films. The (001) surface with a hexagonal surface structure is the most stable surface and the (100) surface with a zigzag structure is the least stable surface but has high reactivity. We investigate the stability of NH and NH2 terminations on these surfaces to determine the saturation coverage of NHx on Co and Ru. NH is most stable in the hollow hcp site on (001) surface and the bridge site on the (100) surface, while NH2 prefers the bridge site on both (001) and (100) surfaces. The differential energy is calculated to find the saturation coverage of NH and NH2. We also present results on mixed NH/NH2-terminations. The results are analyzed by thermodynamics using Gibbs free energies (ΔG) to reveal temperature effects on the stability of NH and NH2 terminations. Ultra-high vacuum (UHV) and standard ALD</div><div>operating conditions are considered. Under typical ALD operating conditions we find that the most stable NHx terminated metal surfaces are 1 ML NH on Ru (001) surface (350K-550K), 5/9 ML NH on Co (001) surface (400K-650K) and a mixture of NH and NH2 on both Ru (100) and Co (100) surfaces.</div>


Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 337
Author(s):  
Sara Mesa Medina ◽  
Ana Rey ◽  
Carlos Durán-Valle ◽  
Ana Bahamonde ◽  
Marisol Faraldos

Two commercial activated carbon were functionalized with nitric acid, sulfuric acid, and ethylenediamine to induce the modification of their surface functional groups and facilitate the stability of corresponding AC-supported iron catalysts (Fe/AC-f). Synthetized Fe/AC-f catalysts were characterized to determine bulk and surface composition (elemental analysis, emission spectroscopy, XPS), textural (N2 isotherms), and structural characteristics (XRD). All the Fe/AC-f catalysts were evaluated in the degradation of phenol in ultrapure water matrix by catalytic wet peroxide oxidation (CWPO). Complete pollutant removal at short reaction times (30–60 min) and high TOC reduction (XTOC = 80 % at ≤ 120 min) were always achieved at the conditions tested (500 mg·L−1 catalyst loading, 100 mg·L−1 phenol concentration, stoichiometric H2O2 dose, pH 3, 50 °C and 200 rpm), improving the results found with bare activated carbon supports. The lability of the interactions of iron with functionalized carbon support jeopardizes the stability of some catalysts. This fact could be associated to modifications of the induced surface chemistry after functionalization as a consequence of the iron immobilization procedure. The reusability was demonstrated by four consecutive CWPO cycles where the activity decreased from 1st to 3rd, to become recovered in the 4th run. Fe/AC-f catalysts were applied to treat two real water matrices: the effluent of a wastewater treatment plant with a membrane biological reactor (WWTP-MBR) and a landfill leachate, opening the opportunity to extend the use of these Fe/AC-f catalysts for complex wastewater matrices remediation. The degradation of phenol spiked WWTP-MBR effluent by CWPO using Fe/AC-f catalysts revealed pH of the reaction medium as a critical parameter to obtain complete elimination of the pollutant, only reached at pH 3. On the contrary, significant TOC removal, naturally found in complex landfill leachate, was obtained at natural pH 9 and half stoichiometric H2O2 dose. This highlights the importance of the water matrix in the optimization of the CWPO operating conditions.


2021 ◽  
Vol 13 (11) ◽  
pp. 6388
Author(s):  
Karim M. El-Sharawy ◽  
Hatem Y. Diab ◽  
Mahmoud O. Abdelsalam ◽  
Mostafa I. Marei

This article presents a control strategy that enables both islanded and grid-tied operations of a three-phase inverter in distributed generation. This distributed generation (DG) is based on a dramatically evolved direct current (DC) source. A unified control strategy is introduced to operate the interface in either the isolated or grid-connected modes. The proposed control system is based on the instantaneous tracking of the active power flow in order to achieve current control in the grid-connected mode and retain the stability of the frequency using phase-locked loop (PLL) circuits at the point of common coupling (PCC), in addition to managing the reactive power supplied to the grid. On the other side, the proposed control system is also based on the instantaneous tracking of the voltage to achieve the voltage control in the standalone mode and retain the stability of the frequency by using another circuit including a special equation (wt = 2πft, f = 50 Hz). This utilization provides the ability to obtain voltage stability across the critical load. One benefit of the proposed control strategy is that the design of the controller remains unconverted for other operating conditions. The simulation results are added to evaluate the performance of the proposed control technology using a different method; the first method used basic proportional integration (PI) controllers, and the second method used adaptive proportional integration (PI) controllers, i.e., an Artificial Neural Network (ANN).


2017 ◽  
Vol 139 (4) ◽  
Author(s):  
Samuel F. Asokanthan ◽  
Soroush Arghavan ◽  
Mohamed Bognash

Effect of stochastic fluctuations in angular velocity on the stability of two degrees-of-freedom ring-type microelectromechanical systems (MEMS) gyroscopes is investigated. The governing stochastic differential equations (SDEs) are discretized using the higher-order Milstein scheme in order to numerically predict the system response assuming the fluctuations to be white noise. Simulations via Euler scheme as well as a measure of largest Lyapunov exponents (LLEs) are employed for validation purposes due to lack of similar analytical or experimental data. The response of the gyroscope under different noise fluctuation magnitudes has been computed to ascertain the stability behavior of the system. External noise that affect the gyroscope dynamic behavior typically results from environment factors and the nature of the system operation can be exerted on the system at any frequency range depending on the source. Hence, a parametric study is performed to assess the noise intensity stability threshold for a number of damping ratio values. The stability investigation predicts the form of threshold fluctuation intensity dependence on damping ratio. Under typical gyroscope operating conditions, nominal input angular velocity magnitude and mass mismatch appear to have minimal influence on system stability.


Author(s):  
J. Sans ◽  
M. Resmini ◽  
J.-F. Brouckaert ◽  
S. Hiernaux

Solidity in compressors is defined as the ratio of the aerodynamic chord over the peripheral distance between two adjacent blades, the pitch. This parameter is simply the inverse of the pitch-to-chord ratio generally used in turbines. Solidity must be selected at the earliest design phase, i.e. at the level of the meridional design and represents a crucial step in the whole design process. Most of the existing studies on this topic rely on low-speed compressor cascade correlations from Carter or Lieblein. The aim of this work is to update those correlations for state-of-the-art controlled diffusion blades, and extend their application to high Mach number flow regimes more typical of modern compressors. Another objective is also to improve the physical understanding of the solidity effect on compressor performance and stability. A numerical investigation has been performed using the commercial software FINE/Turbo. Two different blade profiles were selected and investigated in the compressible flow regime as an extension to the low-speed data on which the correlations are based. The first cascade uses a standard double circular arc profile, extensively referenced in the literature, while the second configuration uses a state-of-the-art CDB, representative of low pressure compressor stator mid-span profile. Both profiles have been designed with the same inlet and outlet metal angles and the same maximum thickness but the camber and thickness distributions, the stagger angle and the leading edge geometry of the CDB have been optimized. The determination of minimum loss, optimum incidence and deviation is addressed and compared with existing correlations for both configurations and various Mach numbers that have been selected in order to match typical booster stall and choke operating conditions. The emphasis is set on the minimum loss performance at mid-span. The impact of the solidity on the operating range and the stability of the cascade are also studied.


2011 ◽  
Vol 64 (4) ◽  
pp. 967-973
Author(s):  
S. Koyunluoglu-Aynur ◽  
R. Riffat ◽  
S. Murthy

The objective of the present work was to evaluate the effect of hydraulic retention time (HRT) on hydrolysis and acidogenesis for the pretreatment processes: acid phase digestion (APD) and autothermal thermophilic aerobic digestion (ATAD) using blended municipal sludge. The effect of the different pretreatment steps on mesophilic anaerobic digestion (MAD) was evaluated in terms of methane yield, keeping the operating conditions of the MAD the same for all systems. Best operating conditions for both APD and ATAD were observed for 2.5 d HRT with high total volatile fatty acids (tVFA), and the highest methane yield observed for MAD. No significant difference was observed between the two processes in terms of overall volatile solids (VS) reduction with same total HRT. The autothermal process produced heat of 14,300 J/g VS removed from hydrolytic and acetogenic reactions without compromising overall methane yields when the HRT was 2.5 d or lower and the total O2 used was 0.10 m3 O2/g VS added or lower. However, the process needs the input of oxygen and engineering analysis should balance these differences when considering the relative merits of the two pretreatment processes. This is the first study of its kind directly comparing these two viable pretreatment processes with the same sludge.


2001 ◽  
Author(s):  
Davide Valtorta ◽  
Khaled E. Zaazaa ◽  
Ahmed A. Shabana ◽  
Jalil R. Sany

Abstract The lateral stability of railroad vehicles travelling on tangent tracks is one of the important problems that has been the subject of extensive research since the nineteenth century. Early detailed studies of this problem in the twentieth century are the work of Carter and Rocard on the stability of locomotives. The linear theory for the lateral stability analysis has been extensively used in the past and can give good results under certain operating conditions. In this paper, the results obtained using a linear stability analysis are compared with the results obtained using a general nonlinear multibody methodology. In the linear stability analysis, the sources of the instability are investigated using Liapunov’s linear theory and the eigenvalue analysis for a simple wheelset model on a tangent track. The effects of the stiffness of the primary and secondary suspensions on the stability results are investigated. The results obtained for the simple model using the linear approach are compared with the results obtained using a new nonlinear multibody based constrained wheel/rail contact formulation. This comparative numerical study can be used to validate the use of the constrained wheel/rail contact formulation in the study of lateral stability. Similar studies can be used in the future to define the limitations of the linear theory under general operating conditions.


Author(s):  
Radka JÍROVÁ ◽  
Lubomír PEŠÍK

Vibroisolation systems of base desks for machine and testing facilities usually cannot effect efficient changing of their own frequencies according to operating conditions. Especially in the case of the automotive industry, the possibility of changing natural frequencies is very desirable. During varying operating conditions, the vibroisolation system needs to be regulated easily and quickly regarding the minimisation of dynamical forces transmitted to the ground and to ensure the stability of the testing process. This paper describes one of the options of tuning the base desk at a relatively short time and by sufficient change of own frequencies, which decides the dynamical behaviour of the whole system.


2014 ◽  
Vol 755 ◽  
pp. 705-731 ◽  
Author(s):  
Sasan Sarmast ◽  
Reza Dadfar ◽  
Robert F. Mikkelsen ◽  
Philipp Schlatter ◽  
Stefan Ivanell ◽  
...  

AbstractTwo modal decomposition techniques are employed to analyse the stability of wind turbine wakes. A numerical study on a single wind turbine wake is carried out focusing on the instability onset of the trailing tip vortices shed from the turbine blades. The numerical model is based on large-eddy simulations (LES) of the Navier–Stokes equations using the actuator line (ACL) method to simulate the wake behind the Tjæreborg wind turbine. The wake is perturbed by low-amplitude excitation sources located in the neighbourhood of the tip spirals. The amplification of the waves travelling along the spiral triggers instabilities, leading to breakdown of the wake. Based on the grid configurations and the type of excitations, two basic flow cases, symmetric and asymmetric, are identified. In the symmetric setup, we impose a 120° symmetry condition in the dynamics of the flow and in the asymmetric setup we calculate the full 360° wake. Different cases are subsequently analysed using dynamic mode decomposition (DMD) and proper orthogonal decomposition (POD). The results reveal that the main instability mechanism is dispersive and that the modal growth in the symmetric setup arises only for some specific frequencies and spatial structures, e.g. two dominant groups of modes with positive growth (spatial structures) are identified, while breaking the symmetry reveals that almost all the modes have positive growth rate. In both setups, the most unstable modes have a non-dimensional spatial growth rate close to $\def \xmlpi #1{}\def \mathsfbi #1{\boldsymbol {\mathsf {#1}}}\let \le =\leqslant \let \leq =\leqslant \let \ge =\geqslant \let \geq =\geqslant \def \Pr {\mathit {Pr}}\def \Fr {\mathit {Fr}}\def \Rey {\mathit {Re}}\pi /2$ and they are characterized by an out-of-phase displacement of successive helix turns leading to local vortex pairing. The present results indicate that the asymmetric case is crucial to study, as the stability characteristics of the flow change significantly compared to the symmetric configurations. Based on the constant non-dimensional growth rate of disturbances, we derive a new analytical relationship between the length of the wake up to the turbulent breakdown and the operating conditions of a wind turbine.


2021 ◽  
Vol 12 (2) ◽  
pp. 33-44
Author(s):  
Volodymyr Volkov ◽  
◽  
Igor Gritsuk ◽  
Tetiana Volkova ◽  
Volodymyr Kuzhel ◽  
...  

The article is devoted to the study of the influence of the brake control elements of passenger vehicles on the stability of their braking properties. The analysis of the influence of uneven braking forces on the wheels of one axle of vehicles on the deviation of the distribution of braking forces between the axles from its calculated value is carried out. When assessing the error in regulating the distribution of braking forces between the axles of vehicles, three components were taken into account: the theoretical error due to the imperfection of the selected control method (the difference between the actual calculated control characteristic from the ideal), the error created due to the instability of the ratio of the braking forces on the front and rear wheels, an additional error caused by the unevenness of the braking forces on the wheels of individual axles, since the fulfillment of the most stringent requirements of international and national standards for the efficiency of braking of vehicles and is inextricably linked with the need to increase the energy consumption of brake mechanisms. The energy consumption of braking mechanisms is understood as the ability of the latter to dissipate the greatest amount of energy of the braking machine without reducing the braking efficiency indicators to the minimum permissible level. Excessive heating of the braking mechanisms leads to a decrease in the friction coefficient μ of the friction surfaces and increased wear of the friction linings, and the brakes are the most unstable element of the braking control, which ensures the absorption and dissipation of the vehicle's energy during braking. The instability of the braking torques on the front and rear wheels, caused by a change in the coefficients of friction of friction pairs, leads not only to a change in the distribution of braking forces between the axles and individual wheels, but also to a decrease in the braking efficiency of vehicles under operating conditions. A method is proposed that makes it possible to assess the quality of regulation of the distribution of braking forces between the axles of a car, taking into account the instability of the braking forces on the wheels.


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