scholarly journals Graphene composites with dental and biomedical applicability

2018 ◽  
Vol 9 ◽  
pp. 801-808 ◽  
Author(s):  
Sharali Malik ◽  
Felicite M Ruddock ◽  
Adam H Dowling ◽  
Kevin Byrne ◽  
Wolfgang Schmitt ◽  
...  

Pure graphene in the form of few-layer graphene (FLG) – 1 to 6 layers – is biocompatible and non-cytotoxic. This makes FLG an ideal material to incorporate into dental polymers to increase their strength and durability. It is well known that graphene has high mechanical strength and has been shown to enhance the mechanical, physical and chemical properties of biomaterials. However, for commercial applicability, methods to produce larger than lab-scale quantities of graphene are required. Here, we present a simple method to make large quantities of FLG starting with commercially available multi-layer graphene (MLG). This FLG material was then used to fabricate graphene dental-polymer composites. The resultant graphene-modified composites show that low concentrations of graphene (ca. 0.2 wt %) lead to enhanced performance improvement in physio-mechanical properties – the mean compressive strength increased by 27% and the mean compressive modulus increased by 22%. Herein we report a new, cheap and simple method to make large quantities of few-layer graphene which was then incorporated into a common dental polymer to fabricate graphene-composites which shows very promising mechanical properties.

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Eduardo Sadot Herrera-Sosa ◽  
Gonzalo Martínez-Barrera ◽  
Carlos Barrera-Díaz ◽  
Epifanio Cruz-Zaragoza

In polymer reinforced concrete, the Young’s modulus of both polymers and cement matrix is responsible for the detrimental properties of the concrete, including compressive and tensile strength, as well as stiffness. A novel methodology for solving such problems is based on use of ionizing radiation, which has proven to be a good tool for improvement on physical and chemical properties of several materials including polymers, ceramics, and composites. In this work, particles of 0.85 mm and 2.80 mm obtained from waste tire were submitted at 250 kGy of gamma radiation in order to modify their physicochemical properties and then used as reinforcement in Portland cement concrete for improving mechanical properties. The results show diminution on mechanical properties in both kinds of concrete without (or with) irradiated tire particles with respect to plain concrete. Nevertheless such diminutions (from 2 to 16%) are compensated with the use of high concentration of waste tire particles (30%), which ensures that the concrete will not significantly increase the cost.


MRS Advances ◽  
2016 ◽  
Vol 2 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Eunice Cunha ◽  
Fernando Duarte ◽  
M. Fernanda Proença ◽  
M. Conceição Paiva

ABSTRACTGraphite nanoplates (GnP) have recently attracted attention as an economically viable alternative for the development of functional and structural nanocomposites. The incorporation of GnP into waterborne polyurethane (WPU) with loadings from 0.1 to 10 wt.% was studied. The mechanical properties of the composite films were assessed by tensile testing showing an increase of the Young’s modulus up to 48%. The electrical conductivity increased by 9 orders of magnitude and the water vapor permeability of the composite films decreased 57% for composites containing 5.0 wt.% of GnP.


2021 ◽  
Vol 316 ◽  
pp. 51-55
Author(s):  
Tamara I. Shishelova ◽  
Vadim V. Fedchishin ◽  
Mikhail A. Khramovskih

Rapid expansion of technologies poses higher requirements to structural materials and items made of them. Conventional materials are being replaced by composite materials (composites). Different additives enhancing the properties of initial materials are used as reinforcement fibers of composites. Utilization of micro-and nanosize particles for production of present-day materials is paid much attention to. Whiskers are among such materials. These crystals have high strength, high chemical and temperature resistance. But for rational utilization of whickers of different chemical composition in composite materials one should know their physical and chemical properties. Objectives of the paper: to study physical and chemical properties of whiskers in different compounds, their composition and structure; to prove experimentally the feasibility of utilizing whiskers as a reinforcement fiber of composite materials. Object of study: specimens of whiskers of silicon nitride (Si3N4), aluminum oxide (Al2O3), aluminum nitride (AlN), and mullite (Al6Si2O13). Methods of investigation: thermal study of specimens, study of mechanical properties and chemical strength, and IR-spectroscopy. Results of study: specimens of whiskers have been studied and their mechanical properties have been tabulated for comparison. Extensive thermal investigation was followed by deduction of regularities and identification of chemical properties of whiskers. IR-spectra of whiskers have been studied and conclusions on molecular composition and on presence of impurities in some whiskers have been made.


Author(s):  
Tjokorda Gde Tirta Nindhia ◽  
Zdenek Knejzlík ◽  
Tomáš Ruml ◽  
I Wayan Surata ◽  
Tjokorda Sari Nindhia

Silk can be produced by spider or insect and have prospect as biomaterial for regenerative healing in medical treatment. Silk having physical and chemical properties that support biocompatibility in the living things..In this research, silk that was obtained from Indonesia natural resource of Attacus atlas silkmoth was explored and then will be  developed for biocompatible biomaterial. The treatment with NaOH was developed to separate the fiber from the cocoon. The obtained fiber is investigated its mechanical property by performing tensile test for single fiber. The biocompatibility testing was conducted with human cell (osteosarccoma) cultivation. The result identify that separation by using NaOH yield better better mechanical properties comparing konvenstional method with boiling in hot water. Biocompatibility testing indicate that the the fiber having good biocompatibility.


2016 ◽  
Vol 67 (2) ◽  
pp. 149-151 ◽  
Author(s):  
Petr Machac ◽  
Tomas Hrebicek

Abstract graphene is a promising material with excellent electrical, thermal, optical and mechanical properties. Therefore, it is a material of high relevance for various applications in many branches of technique. Graphene has received much attention recently in scientific community. The contribution reports formation and characterization of few-layer graphene (FLG) films on a SiC substrate from nickel silicide supersaturated with carbon by annealing at a favourable low temperature.


Author(s):  
Mingjian Zhang ◽  
Feng Huang ◽  
Qing Chen ◽  
Le Wang ◽  
Haisheng Wang ◽  
...  

A mathematical model was established to predict the mean value and variance of tobacco strip during drying processing, based that the physical and chemical properties of tobacco strip as agriculture products show probability distributions. The results show that the model can predict the mean value of moisture content at different times, and there is a certain deviation in predicting the variance of moisture content at initial stage of drying process. However, the prediction value of the variance of tobacco strip is much more accurate while the moisture content is between 8% and 10%, which is the interval of quality requirements.Keywords: tobacco strip; drying; mean value;variance model.  


Ionics ◽  
2016 ◽  
Vol 22 (9) ◽  
pp. 1575-1584 ◽  
Author(s):  
Jun Zong ◽  
Yuqi Diao ◽  
Fei Ding ◽  
Wei Feng ◽  
Xingjiang Liu

2020 ◽  
Vol 81 (6) ◽  
pp. 1273-1282 ◽  
Author(s):  
Hangdao Qin ◽  
Hao Cheng ◽  
Chenggui Long ◽  
Xiaogang Wu ◽  
Yanhong Chen ◽  
...  

Abstract N, S co-doped MnFe2O4@C magnetic nanoparticles were successfully synthesized by a simple method involving the preparation of MnFe2O4 nanoparticles and subsequent pyrolysis treatment. The physical and chemical properties of MnFe2O4, MnFe2O4@C and MnFe2O4@C–NS nanoparticles were characterized by X-ray diffraction (XRD), vibrating sample magnetometry (VSM), transmission electron microscopy (TEM), N2 adsorption–desorption and the pH at the point of zero charge. Their performances in the adsorption of Hg(II) from water were investigated. The adsorption process followed pseudo-second-order kinetics and the experimental data of equilibrium isotherms fitted well with the Langmuir model. MnFe2O4@C–NS showed the highest adsorption capacity of 108.56 mg/g, increasing more than 1.7 times compared to MnFe2O4. The enhanced adsorption performance was attributed to the larger specific surface area as well as the complexation of N and S ligands on the surface. The thermodynamic parameters of ΔH°, ΔS° and ΔG° at 30 °C were −24.39 kJ/mol, −0.046 kJ/mol K and −10.45 kJ/mol, respectively, which indicated that the adsorption of Hg(II) on MnFe2O4@C–NS was exothermic and spontaneous in nature. Moreover, MnFe2O4@C–NS showed superior selectivity towards Hg(II) compared with other metal ions generally present in mercury-containing industrial wastewater.


Biologia ◽  
2016 ◽  
Vol 71 (3) ◽  
Author(s):  
Agnieszka Józefowska ◽  
Anna Miechówka ◽  
Jan Frouz

AbstractThe impact of different geographical regions (Silesian Foothills, region 1 and Maly Beskids, region 2), and method of soil use (arable field and grassland) on the main soil properties and biological activity was studied. Earthworm biomass, density and diversity, as well as dehydrogenase activity, were analysed. Significant soil physical and chemical properties were more affected by regions, whereas the type of land use had a greater impact on the biological properties. The mean earthworm density was 213 ind. m


1966 ◽  
Vol 46 (2) ◽  
pp. 155-160 ◽  
Author(s):  
G. R. Saini ◽  
A. A. MacLean ◽  
J. J. Doyle

The relationship of the mean weight diameter of water-stable aggregates to certain soil properties (clay, organic matter, free iron, free aluminum, and polysaccharide contents) and the relationship of the increase in aggregation caused by VAMA to the same properties of 24 New Brunswick soils were evaluated by correlation and regression analyses.Simple correlation coefficients relating aggregation to soil properties indicated that organic matter (r = 0.627), polysaccharides (r = 0.602), and aluminum (r = 0.679) were the most important factors. However, when the influence of each factor was separated by partial correlation, the coefficients were not significant. On the other hand, the combined effects of all factors as indicated by the multiple correlation coefficient (r = 0.743) was significant at the 1% level. The effect of the same soil properties on response to VAMA, as shown by increase in mean weight diameter, indicated that clay exerted the greatest influence. The relationship with other factors was nonsignificant.


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