Chemiresistive Gas Sensors Based on Conducting Polymers

Author(s):  
Sajad Pirsa

Chemiresistive gas sensor based on conducting polymer is a type of sensors that presents gas sensors with excellent characters; low-cost fabrication, fast detection, simultaneous determination (array gas sensor), portable devices and so. Theses gas sensors are commonly based on polyaniline (PANI), polypyrrole (PPy), polythiophene (PTh) and their derivatives as a transducer. Common configuration and response mechanism of these sensors are reported in this section. Some factors that induce selectivity to these sensors are discussed. Different materials (conductor or insulant) can be used as a substrate of polymerization. Type of substrate, selective membranes, surface modification of conducting polymer and so can change response behavior of these sensors.

Author(s):  
Sajad Pirsa

Chemiresistive gas sensor based on conducting polymer is a type of sensors that presents gas sensors with excellent characters; low-cost fabrication, fast detection, simultaneous determination (array gas sensor), portable devices and so. Theses gas sensors are commonly based on polyaniline (PANI), polypyrrole (PPy), polythiophene (PTh) and their derivatives as a transducer. Common configuration and response mechanism of these sensors are reported in this section. Some factors that induce selectivity to these sensors are discussed. Different materials (conductor or insulant) can be used as a substrate of polymerization. Type of substrate, selective membranes, surface modification of conducting polymer and so can change response behavior of these sensors.


2002 ◽  
Vol 750 ◽  
Author(s):  
G. Korotcenkov ◽  
V. Macsanov ◽  
Y. Boris ◽  
V. Brinzari ◽  
V. Tolstoy ◽  
...  

ABSTRACTThe possibilities of SILD (successive ionic layer deposition) technology for modification of surface properties of nano-scaled SnO2 films for gas sensor applications were studied and are discussed in this article. Samples of SnO2 with thickness ranging from 30–40 nm were deposited by spray pyrolysis from SnCl4-water solutions. Nano-clusters of Pd and Ag, deposited by the SILD method were applied for surface modification. PdCl2 and AgNO3 were used as precursors for Pd and Ag deposition on the SnO2 surface.It was found that the method of surface modification by SILD can be used for improving both the sensitivity and the rate of gas response of SnO2-based gas sensors to CO and H2. At the same time, the presence of Pd and Ag clusters on the surface of SnO2 depresses the gas response to ozone.


2020 ◽  
Vol 2 (1) ◽  
pp. 66
Author(s):  
Sergio Masa ◽  
María José Mena ◽  
Esther Hontañón ◽  
Jesús Lozano ◽  
Siamak Eqtesadi ◽  
...  

In this work, we investigate the electrospray technique for the preparation of graphene layers for use in chemiresistive gas sensors. A dispersion of reduced graphene oxide (rGO) in isopropyl alcohol (0.1 mg/mL) is electrosprayed and the rGO flakes are deposited onto a polymeric substrate with printed interdigitated electrodes. The surface area of the substrate covered with rGO is mainly determined by the distance between the needle and the substrate, while the rGO deposition pattern strongly depends on the flowrate and the applied voltage. Homogeneous layers of rGO are obtained in a stable cone-jet regime, and the room temperature detection behavior of the sensors towards NO2, O3 and CO is assessed. The sensors were not capable of detecting CO (up to 5 ppm), but they detected 0.2 ppm NO2 and 0.05 ppm O3. The results are encouraging regarding the use of electrospray for the production of low-cost and low-power gas sensors based on graphene for air quality applications.


2018 ◽  
Vol 24 (8) ◽  
pp. 3291-3297 ◽  
Author(s):  
K. G. Girija ◽  
S. Chakraborty ◽  
M. Menaka ◽  
R. K. Vatsa ◽  
Anita Topkar

2013 ◽  
Vol 543 ◽  
pp. 239-242 ◽  
Author(s):  
Faramarz Hossein-Babaei ◽  
Amir Amini

Generic gas sensors are commonly used for the detection of different airborne contaminants due to their high sensitivity, long life and low cost, but they generally suffer from the variety of drifts and the lack of selectivity. Different techniques have been developed for selectivity enhancement in metal oxide gas sensors, among which operating temperature modulation is well known. It has been observed that sharp pallet temperature changes provide more analyte-related information. Due to the high thermal capacitance of the device, applying step voltage pulses to a bulk tin oxide gas sensor fails to provide step pallet temperature variations. On the other hand, the low thermal capacity of the custom made microheater gas sensors renders them vulnerable to all kinds of thermal noise and agitations. A novel technique is reported for temperature modulation, which facilitates sharp temperature rises of the gas sensitive pallets in generic gas sensors [. In this technique, a sharp heating voltage spike, considerably surpassing the nominal heating voltage, is applied prior to each heating voltage step. The thermal impact of these spikes is adjusted by controlling v2dt for obtaining the closest variations to the ideal temperature profile. Here, the advantages and effectiveness of the technique are demonstrated by differentiating among iso-butanol, tert-butanol, 1-butanol and 2-butanol contaminations in a wide concentration range in air using only a single generic tin oxide gas sensor.


2019 ◽  
Vol 7 (39) ◽  
pp. 12343-12353 ◽  
Author(s):  
Omar Kassem ◽  
Mohamed Saadaoui ◽  
Mathilde Rieu ◽  
Jean-Paul Viricelle

In recent years, printed and flexible gas sensors have quickly emerged as an innovative area of great interest because of their lightness and low cost.


Micromachines ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1355
Author(s):  
Vignesh Gunasekaran ◽  
Soffian Yjjou ◽  
Eve Hennequin ◽  
Thierry Camps ◽  
Nicolas Mauran ◽  
...  

The development of “portable, low cost and low consumption” gas microsensors is one of the strong needs for embedded portable devices in many fields such as public domain. In this paper, a new approach is presented on making, on the same chip, a network of head-to-tail facing PN junctions in order to miniaturize the sensor network and considerably reduce the required power for heating each cell independently. This paper is about recognizing a device that integrates both sensing and self-heating. This first study aims to evaluate the possibilities of this type of diode network for use as a gas sensor. The first part concerns the description of the technological process that is based on a doped polysilicon wafer in which a thin layer of metal oxide (a gallium-doped zinc oxide in our case) is deposited by RF sputtering. An electrical model will be proposed to explain the operation and advantage of this approach. We will show the two types of tests that have been carried out (static and dynamic) as well as the first encouraging results of these electrical characterizations under variable atmospheres.


2013 ◽  
Vol 798-799 ◽  
pp. 553-556
Author(s):  
Tao Zhou ◽  
Qing Zhou

In order to eliminate or minimize the early instability of gas sensors, the aging process is needed. After aging,it is necessary to test stability parameters of gas sensors in a certain batch of the sensors for massive production. In this work, a system for the stability test of gas sensor array has been designed and developed both in hardware and software based ARM. Measurements demonstrate the quality and flexibility of it. It is low cost, excellent cost performance. The stability test system now works well in industrial applications and meets the need of industrial mass-production.


Sensors ◽  
2020 ◽  
Vol 20 (19) ◽  
pp. 5478
Author(s):  
Enric Perarnau Ollé ◽  
Josep Farré-Lladós ◽  
Jasmina Casals-Terré

In recent years, advancements in micromachining techniques and nanomaterials have enabled the fabrication of highly sensitive devices for the detection of odorous species. Recent efforts done in the miniaturization of gas sensors have contributed to obtain increasingly compact and portable devices. Besides, the implementation of new nanomaterials in the active layer of these devices is helping to optimize their performance and increase their sensitivity close to humans’ olfactory system. Nonetheless, a common concern of general-purpose gas sensors is their lack of selectivity towards multiple analytes. In recent years, advancements in microfabrication techniques and microfluidics have contributed to create new microanalytical tools, which represent a very good alternative to conventional analytical devices and sensor-array systems for the selective detection of odors. Hence, this paper presents a general overview of the recent advancements in microfabricated gas sensors and microanalytical devices for the sensitive and selective detection of volatile organic compounds (VOCs). The working principle of these devices, design requirements, implementation techniques, and the key parameters to optimize their performance are evaluated in this paper. The authors of this work intend to show the potential of combining both solutions in the creation of highly compact, low-cost, and easy-to-deploy platforms for odor monitoring.


Micromachines ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 345 ◽  
Author(s):  
Dima Shlenkevitch ◽  
Sara Stolyarova ◽  
Tanya Blank ◽  
Igor Brouk ◽  
Yael Nemirovsky

There is an ongoing effort to fabricate miniature, low cost, sensitive, and selective gas sensors for domestic and industrial uses. This paper presents a miniature combustion-type gas sensor (GMOS) based on a thermal sensor, where a micromachined CMOS–SOI transistor integrated with a catalytic reaction plate acts as a sensing element. This study emphasizes GMOS performance modeling, technological aspects, and sensing-selectivity issues. Two deposition techniques of a Pt catalytic layer suitable for wafer-level processing were compared, magnetron sputtering and nanoparticle inkjet printing. Both techniques have been useful for the fabrication of GMOS sensor, with good sensitivity to ethanol and acetone in the air. However, a printed Pt nanoparticle catalyst provides almost twice as much sensitivity as compared to that of the sputtered catalyst. Moreover, sensing selectivity in the ethanol/acetone gas mixture was demonstrated for the GMOS with a Pt nanoparticle catalyst. These advantages of GMOS allow for the fabrication of a low-cost gas sensor that requires a low power, and make it a promising technology for future smartphones, wearables, and Internet of Things (IoT) applications.


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