Bioceramic Composite Coatings Fabricated by Nd-YAG Laser Cladding Process on Ti6Al4V Substrate

2012 ◽  
Vol 198-199 ◽  
pp. 68-71 ◽  
Author(s):  
Ying Chun Wang ◽  
Yu Yong Yang ◽  
Mei Chun Wang
Keyword(s):  
Calcium Phosphate ◽  
Composite Coating ◽  
Laser Cladding ◽  
Composite Coatings ◽  
Mechanism Analysis ◽  
Yag Laser ◽  
Ti6al4v Substrate ◽  
Metallurgical Bonding ◽  
Laser Cladding Process ◽  
Modification Procedure

Laser cladding technology was adopted to fabricate hydroxyapatite(HAP) and calcium phosphate compound coating according to the feature that a metallurgical bonding can be formed by laser cladding process. Compared with CO2laser, Nd-YAG laser has different wavelength(the former is 1.06μm and the latter is 10.06μm). Metal and ceramic material has quite different absorbance ability towards them and thus they can generate different laser cladding products by these two laser surface processings with different wavelength. This paper presents a new process and mechanism analysis to obtain bioceramic composite coating on Ti6Al4V substrate by Nd-YAG laser cladding. A bioceramic composite coating including HAP，Ca2P2O7，Ca3(PO4)2and calcium titanates and was successfully obtained by Nd-YAG laser cladding with pre-depositing mixed powders of CaHPO4•2H2O and CaCO3directly on Ti6Al4V substrate. Nd-YAG laser transmits mixed powders of CaHPO4•2H2O and CaCO3and the laser power is absorbed by Ti6Al4V substrate to produce a thin layer of molten region. There are mainly two kinds of chemical reaction systems in the coating during laser cladding processing. When CaHPO4•2H2O and CaCO3react together, they make calcium phosphate bioceramic products; The microstructure of the bioceramic composite coating is even and minute because of the rapid solidification in laser processing. A chemical metallergical bonding is formed between the boceramic composite coating and Ti6Al4V substrate. It can also be expected that Nd-YAG laser cladding technology can be used as a further modification procedure to enhance HAp/metal interface property.

Research on the Fabrication of Bioceramic Composite Coatings Fabricated by Nd-YAG Laser Cladding

2015 ◽  
Vol 723 ◽  
pp. 852-855
Author(s):  
Ying Chun Wang ◽  
Xiang Fei Lv ◽  
Deng Jie Zhu ◽  
Shao Min Qu
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Composite Coatings ◽  
New Technology ◽  
Scanning Speed ◽  
Processing Technique ◽  
Yag Laser ◽  
Cladding Layer ◽  
Ti6al4v Substrate ◽  
Average Grain Size

Laser surface cladding is a material processing technique to overlay the precursor material with the substrate to form a sound chemical and metallurgical bonding. Recently, laser cladding technique has been introduced in the bioceramic coating field. This paper presents a new technology to obtain bioceramic composite coating on Ti6Al4V substrate by Nd-YAG laser cladding. The microstructures of the mixed powders and cladding layer were investigated by scanning electron microscopy, and the compositions were analyzed by electron diffraction spectroscopy. The phases of the mixed powders and cladding layer were clarified by X-ray diffraction technology. Composite coating including HAP,Ca2P2O7,Ca3(PO4)2 and calcium titanates was successfully obtained by Nd-YAG laser cladding with pre-depositing mixed powders of CaHPO4·2H2O and CaCO3 directly on Ti6Al4V substrate. The average grain size of the mixed powders is 3μm from the image analyse software. The most important parameter that affected the completion of laser cladding was the scanning speed.

Microstructure and Tribological Properties of Self-Lubricating Graphite/Ni60 Composite Coatings Prepared by Laser Cladding

2012 ◽  
Vol 583 ◽  
pp. 27-31 ◽  
Author(s):  
Jiao Xi Yang ◽  
Zhi Cheng Wang ◽  
Xuan He Miao ◽  
Xi Bing Wang
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Solid Lubricants ◽  
Composition Analysis ◽  
Metallurgical Bonding ◽  
Lubricating Property ◽  
Increasing Temperature

Ni60 superhard alloy with the additions of graphite solid lubricants was successfully prepared on 45 carbon steel substrate by means of laser cladding. The quality of coating was relatively high and had metallurgical bonding with the substrate. The morphology of laser cladding layer was observed by SEM, composition analysis was applied by EDS. Elevated temperature frictional behaviors of graphite/Ni60 composites coatings were investigated on MMG-10 wear machine. The results showed that the friction coefficient of graphite/Ni60 composite coating was obviously decreased from 0.55 to 0.20 with increasing temperature. The wear mechanism transformed from adhesion to oxidation with the increase of temperature. The graphite/Ni60 composite coating material showed the optimum self-lubricating property at 500°C.

scholarly journals Isothermal Oxidation Performance of Laser Cladding Assisted with Preheat (LCAP) Tribaloy T-800 Composite Coatings Deposited on EN8

Coatings ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 843
Author(s):  
Sipiwe Trinity Nyadongo ◽  
Sisa Lesley Pityana ◽  
Eyitayo Olatunde Olakanmi
Keyword(s):  
Iron Oxide ◽  
Composite Coating ◽  
Laser Cladding ◽  
Composite Coatings ◽  
Parabolic Rate Constant ◽  
Mass Gain ◽  
Isothermal Oxidation ◽  
Operational Parameters ◽  
Temperature Oxidation ◽  
Service Environments

It is anticipated that laser cladding assisted with preheat (LCAP)-deposited Tribaloy (T-800) composite coatings enhances resistance to structural degradation upon exposure to elevated-temperature oxidation service environments. The oxidation kinetics of LCAP T-800 composite coatings deposited on EN8 substrate and its mechanisms have not been explored in severe conditions that are similar to operational parameters. The isothermal oxidation behaviour of the T-800 composite coating deposited on EN8 via LCAP was studied at 800 °C in air for up to 120 h (5 × 24 h cycles) and contrasted to that of uncoated samples. The mass gain per unit area of the coating was eight times less than that of the uncoated EN8 substrate. The parabolic rate constant (Kp) for EN8 was 6.72 × 10−12 g2·cm−4·s−1, whilst that for the T-800 composite coating was 8.1 × 10−13 g2·cm−4·s−1. This was attributed to a stable chromium oxide (Cr2O3) layer that formed on the coating surface, thereby preventing further oxidation, whilst the iron oxide film that formed on the EN8 substrate allowed the permeation of the oxygen ions into the oxide. The iron oxide (Fe2O3) film that developed on EN8 spalled, as evidenced by the cracking of oxide when the oxidation time was greater than 72 h, whilst the Cr2O3 film maintained its integrity up to 120 h. A parabolic law was observed by the T-800 composite coating, whilst a paralinear law was reported for EN8 at 800 °C up to 120 h. This coating can be used in turbine parts where temperatures are <800 °C.

Study on the Wear Resistance of Micro-Nanostructured WC Composite Coating Sintered by Induced Heating

2007 ◽  
Vol 280-283 ◽  
pp. 1489-1492
Author(s):  
Zhen Ting Wang ◽  
Hua Hui Chen
Keyword(s):  
Wear Resistance ◽  
Composite Coating ◽  
Solid Solutions ◽  
Composite Coatings ◽  
Micro Hardness ◽  
Q235 Steel ◽  
Metallurgical Bonding ◽  
Sintering Method

Micro-nanostructured WC composite coatings were successfully fabricated by induced heating sintering method on the surface of Q235 steel .The microstructure, micro-hardness and the wear resistance of the composite coatings were studied .The results show that the microstructure of induced heat layer is mainly composed of Ni-based solid solutions and WC particles. And there exists excellent metallurgical bonding between coating and substrate. The wear resistance of micro-nanostructured WC Composite Coatings is increased by 1.5 times on an average as compared with that of micron.

scholarly journals Laser Cladding of Ni-Co-W Composite Coating on Stainless Steel to Enhance Wear Resistance

2021 ◽  
Author(s):  
Linlin ZHANG ◽  
Dawei ZHANG
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Composite Coating ◽  
Laser Cladding ◽  
Composite Coatings ◽  
Eutectic Structure ◽  
Wear Properties ◽  
Fine Grained ◽  
Noticeable Improvement ◽  
Enhance Wear Resistance

Ni-Co-W composite coatings modified by different contents of Co-based alloy powder in the Ni-based alloy with 35 wt.% WC (Ni35WC) were deposited on stainless steel by laser cladding. The influence of compositional and microstructural modification on the wear properties has been comparatively investigated by XRD, SEM, and EDS techniques. It was found that the austenite dendrites in the modified coating adding 50 wt.% Co-based alloy were refined and a lot of Cr23C6 or M23(C, B)6 compounds with fine lamellar feature were formed around austenitic grain boundaries or in the intergranular regions. The contribution of element Co to the modification of Ni35WC coating is that it cannot only promote the formation of more hard compounds to refine austenite grains, but also refine the size of precipitates, and change the phase type of eutectic structure as a result of disappeared Cr boride brittle phases. A noticeable improvement in wear resistance is obtained in the Ni35WC coating with 50 wt.% Co-based alloy, which makes the wear rate decreased by about 53 % and 30% by comparison to that of the substrate and the Ni35WC coating, respectively. It is suggested that the improvement is closely related to the composite coating being strengthened owing to the increase of coating hardness, formation of a fine-grained microstructure caused by Co, and fine hard precipitate phases in the eutectic structure.

Wear Resistance of Laser Cladded NiCrFeSiB Self-Fluxing Composite Coatings

2016 ◽  
Vol 254 ◽  
pp. 290-295
Author(s):  
Iosif Hulka ◽  
Ion Dragoş Uţu ◽  
Viorel Aurel Şerban ◽  
Alexandru Pascu ◽  
Ionut Claudiu Roată
Keyword(s):  
Wear Resistance ◽  
Laser Cladding ◽  
Wear Behavior ◽  
Protective Coatings ◽  
Steel Substrate ◽  
Composite Coatings ◽  
Base Material ◽  
Laser Cladding Process ◽  
Metallurgical Bond ◽  
Feedstock Material

Laser cladding process is used to obtain protective coatings using as heat source a laser. This melts the substrate and the feedstock material to create a protective coating and provides a strong metallurgical bond with minimal dilution of the base material and reduced heat affected zone. In the present study a commercial NiCrSiFeB composition was deposited by laser cladding process using different parameters onto the surface of a steel substrate. The obtained coatings were investigated in terms of microstructure, hardness and wear behavior. The experimental results revealed that the laser power had a considerable influence on the wear resistance of NiCrSiFeB coatings.

Microstructure and Wear Properties of Laser Clad (Ti,Mo)C Multiple Carbide Reinforced Fe-Based Composite Coating

2010 ◽  
Vol 132 (4) ◽  
Author(s):  
Xinhong Wang ◽  
Min Zhang ◽  
Shiyao Qu
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Surface Coating ◽  
Pattern Analysis ◽  
Volume Fraction ◽  
Wear Properties ◽  
Selective Area ◽  
Laser Cladding Process ◽  
Carbide Size ◽  
Cubic Structure

(Ti,Mo)C multiple carbide reinforced Fe-based composite coating was produced by laser melting a precursor mixture graphite, ferrotitanium (Fe–Ti), and ferromolybdenum (Fe–Mo) powders. The results showed that flowerlike and cubic type (Ti,Mo)C multiple carbides were formed during laser cladding process. The selective area diffraction pattern analysis indicated that (Ti,Mo)C crystallizes with cubic structure, which indicates that (Ti,Mo)C carbides were multiple carbides with Mo dissolved in the TiC structure. The formation of (Ti,Mo)C particles was achieved via a nucleation-growth mechanism during the laser cladding process. Increasing the amount of Fe–Mo in the reactants led to a decrease of carbide size and an increase of volume fraction of carbides. The coating possessed good cracking resistance when the amount of Fe–Mo was controlled within a range of 15 wt %. The Fe-based surface coating reinforced by (Ti,Mo)C multiple carbides gave an excellent wear resistance.

Microstructure and property of Fe–Co–B–Si–C–Nb amorphous composite coating fabricated by laser cladding process

2013 ◽  
Vol 280 ◽  
pp. 50-54 ◽  
Author(s):  
Y.Y. Zhu ◽  
Z.G. Li ◽  
R.F. Li ◽  
M. Li ◽  
X.L. Daze ◽  
...  
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Laser Cladding Process

MICROSTRUCTURE AND WEAR RESISTANCE OF IN-SITU SYNTHESIZED TiB2–TiC/Fe COMPOSITE COATING BY LASER CLADDING

2020 ◽  
pp. 2050046
Author(s):  
TIANWEI YANG ◽  
ZHAOHUI WANG ◽  
SHIHAI TAN ◽  
FU GUO
Keyword(s):  
Wear Resistance ◽  
Laser Cladding ◽  
Composite Coatings ◽  
X Ray Diffraction ◽  
Mixed Powder ◽  
X Ray ◽  
Material Surfaces ◽  
Metallurgical Bonding ◽  
Steel Surfaces

To increase the strength and wear resistance of material surfaces, various combinations of B4C and 80TiFe powder were mixed into a Fe60 self-fluxing alloy powder; the composite coatings reinforced by TiB2–TiC were successfully prepared on Q235 steel surfaces by laser cladding. Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD) were used to study the microstructure and chemical and phase composition. Microhardness and wear testers were used to investigate the mechanical properties. The results show that the interfaces of composite coatings and substrate materials are excellent for metallurgical bonding. The block-like TiB2 particles and flower-like TiC particles are uniformly distributed in the cladding coating. When the mass fraction of the mixed powder is 30%, the average microhardness of the coating is approximately 1100 HV[Formula: see text], which is 50% higher than that without the mixed powder, and demonstrates the best wear with a performance twice as better as that of the substrate.

Technology and Antimicrobial Properties of Cu/TiB2 Composite Coating on 304 Steel Surface Prepared by Laser Cladding

2019 ◽  
Vol 944 ◽  
pp. 473-479 ◽  
Author(s):  
Yu Sun ◽  
Vannghia Tran ◽  
Dao Zhang ◽  
Wen Bin Wang ◽  
Sen Yang
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Abrasion Resistance ◽  
Composite Coatings ◽  
Pure Copper ◽  
Antimicrobial Properties ◽  
Scanning Speed ◽  
Atomic Ratio ◽  
Ti Powder

In this study, Cu/TiB2composite coating was in-situ prepared on 304 steel by laser cladding. This coating applies to hospitals, schools and some public places where cross infections happen more easily because of its good antimicrobial properties and abrasion resistance. Before laser cladding, pre-blend of Cu powder, Ti powder and B powder were undertaken by ball-milling in two different proportions (10% wt (Ti+B) and 20% wt (Ti+B)). And the atomic ratio of Ti and B was 1:2. After a series of experiments, the best parameters were achieved. They were laser power (950W), scanning speed (14mm/s) and spot diameter (3.8mm). Samples after laser cladding were characterized using optical microscopy, scanning electron microscopy and X-ray diffraction. The results showed that TiB2was fabricated in-situ. The dispersion degree of Cu was higher in the coating of 20% wt (Ti+B). The hardness of the 10% wt (Ti+B) coating was HRC57±4. With the increase of percentage of wt (Ti+B), the hardness of 20% wt (Ti+B) coating was HRC74±5. Both of them performed better than pure copper. Relative to pure copper, the abrasion resistance of Cu/TiB2composite coatings was more excellent. The results of antimicrobial experiments showed that, with the increase of percentage of wt (Ti+B), the antimicrobial properties were decreasing. But they still could to be considered favorable.

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