Development and Characterization of SS316L Foam Prepared by Powder Metallurgy Route

2014 ◽  
Vol 534 ◽  
pp. 31-37 ◽  
Author(s):  
Fazimah Mat Noor ◽  
Khairur Rijal Jamaluddin ◽  
Sufizar Ahmad ◽  
Rosdi Ibrahim ◽  
Noor Idayu Mad Rosip

Open cell foams, made on the basis of polyurethane foams replication method are well known and had been widely used since decades. The advantage of the network-like metal foams is it exhibits a natural bone-like structure which enables ingrowth of bone cells and blood vessels. The aim of the present study is to develop SS316L foam with an open cell structure by using powder metallurgy routes via foam replication method. The SS316L slurry was produced by mixing SS316L powder with Polyethylene Glycol (PEG), Methylcellulose (CMC) and distilled water. The composition of the SS316L powder in the slurry was varied from 40 to 60 wt. %. Then, polymeric foam template was impregnated in SS316L slurry and dried at room temperature. Sintering was carried out in a high temperature vacuum furnace at 1300°C. The microstructure of the SS316L foam produced was observed by Scanning Electron Microscope (SEM) and the elemental analysis was carried by Energy Dispersive X-ray (EDX). It was found that pore size are within 200-400μm and the average pore size is 293μ. The detected elements in the SS316L foam were C, Al, Ca, O, Cr, Fe, Mo, Ni and Si.

2007 ◽  
Vol 534-536 ◽  
pp. 977-980
Author(s):  
Yasuo Yamada ◽  
Yun Cang Li ◽  
Takumi Banno ◽  
Zhen Kai Xie ◽  
Cui E Wen

Micro-porous nickel (Ni) with an open cell structure was fabricated by a special powder metallurgical process, which includes the adding of a space-holding material. The average pore size of the micro-porous Ni samples approximated 30 μm and 150 μm, and the porosity ranged from 60 % to 80 %. The porous characteristics of the Ni samples were observed using scanning electron microscopy (SEM) and the mechanical properties were evaluated using compressive tests. For comparison, porous Ni samples with a macro-porous structure prepared by both powder metallurgy (pore size 800 μm) and the traditional chemical vapour deposition (CVD) method (pore size 1300 μm) were also presented. Results indicated that the porous Ni samples with a micro-porous structure exhibited different deformation behaviour and dramatically increased mechanical properties, compared to those of the macro-porous Ni samples.


2015 ◽  
Vol 1087 ◽  
pp. 232-235
Author(s):  
Fazimah Mat Noor ◽  
N.I. Mad Rosip ◽  
Khairur Rijal Jamaludin ◽  
Sufizar Ahmad

Foam replication method is capable of producing foams with a highly porous structure with adjustable pore dimension, shape and size. In this work, this method has been used to prepare stainless steel 316L foam and sintered at 1200°C, 1250°C and 1300°C in a vacuum furnace. The microstructure and elemental analysis of the sample were examined using scanning electron microscope (SEM) and Energy Dispersive X–Ray (EDX), while the mechanical properties of the samples was determined by using compression test. It was found that the average pore size was in the range of 330µm-350µm. The yield strength and elastic modulus are in the range of 58-66 GPa and 0.46-0.50GPa respectively.


2014 ◽  
Vol 606 ◽  
pp. 213-216 ◽  
Author(s):  
Zuzana Vilčeková ◽  
Monika Kašiarová ◽  
Magdaléna Domanická ◽  
Miroslav Hnatko ◽  
Pavol Šajgalík

Local mechanical properties, particularly the hardness and Youngs modulus of highly porous silicon nitride based foams were studied in this work. Silicon nitride foams were prepared using polyurethane foam replication method to obtain appropriate cellular structure suitable for bio-application. Two types of the polyurethane foams were used (with average pore size 0.48 mm and 0.62 mm). Some of these samples were prepared by single or multiple infiltrations. The effects of structures, temperature of calcination, volume fraction of Si3N4 powder and number of the infiltrations on the local mechanical properties were investigated. The Youngs modulus of studied samples range from 12 to 46 GPa at the macroscopic scale measured by resonant frequency technique and from 10 to 28 GPa at the microscopic scale measured by instrumented indentation. Results showed increase of the hardness and Youngs modulus with increasing of the calcination temperature, with increasing of the number of infiltrations and also with increasing of volume fraction of Si3N4 powder in suspension. The results obtained from nanoindentation carry out lower values in comparison with the values measured by resonant frequency technique.


1992 ◽  
Vol 270 ◽  
Author(s):  
F-M. Kong ◽  
S.S. Hulsey ◽  
C.T. Alviso ◽  
R.W. Pekala

ABSTRACTCarbon aerogels are synthesized via the polycondensation of resorcinol and formaldehyde, followed by supercritical drying and pyrolysis at 1050 °C in nitrogen. Because of their interconnected porosity, ultrafine cell structure and high surface area, carbon aerogels have many potential applications, such as in supercapacitors, battery electrodes, catalyst supports, and gas filters. The performance of carbon aerogels in the latter two applications depends on the permeability or gas flow conductance in these materials. By measuring the pressure differential across a thin specimen and the nitrogen gas flow rate in the viscous regime, we calculated the permeability of carbon aerogels from equations based upon Darcy's law. Our measurements show that carbon aerogels have apparent permeabilities on the order of 10−12 to 10−10 cm2 for densities ranging from 0.44 to 0.05 g/cm3. Like their mechanical properties, the permeability of carbon aerogels follows a power law relationship with density and average pore size. Such findings help us to estimate the average pore sizes of carbon aerogels once their densities are known. This paper reveals the relationships among permeability, pore size and density in carbon aerogels.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2187
Author(s):  
Gabriele M. Cimmarusti ◽  
Abhishek Shastry ◽  
Matthieu N. Boone ◽  
Veerle Cnudde ◽  
Karl Braeckman ◽  
...  

The applications of polymeric sponges are varied, ranging from cleaning and filtration to medical applications. The specific properties of polymeric foams, such as pore size and connectivity, are dependent on their constituent materials and production methods. Nuclear magnetic resonance imaging (MRI) and X-ray micro-computed tomography (µCT) offer complementary information about the structure and properties of porous media. In this study, we employed MRI, in combination with µCT, to characterize the structure of polymeric open-cell foam, and to determine how it changes upon compression, µCT was used to identify the morphology of the pores within sponge plugs, extracted from polyurethane open-cell sponges. MRI T2 relaxation maps and bulk T2 relaxation times measurements were performed for 7° dH water contained within the same polyurethane foams used for µCT. Magnetic resonance and µCT measurements were conducted on both uncompressed and 60% compressed sponge plugs. Compression was achieved using a graduated sample holder with plunger. A relationship between the average T2 relaxation time and maximum opening was observed, where smaller maximum openings were found to have a shorter T2 relaxation times. It was also found that upon compression, the average maximum opening of pores decreased. Average pore size ranges of 375–632 ± 1 µm, for uncompressed plugs, and 301–473 ± 1 µm, for compressed plugs, were observed. By determining maximum opening values and T2 relaxation times, it was observed that the pore structure varies between sponges within the same production batch, as well as even with a single sponge.


Author(s):  
Yi-tong Yao ◽  
Yue Yang ◽  
Qi Ye ◽  
Shan-shan Cao ◽  
Xin-ping Zhang ◽  
...  

AbstractTo find out the optimal porosity and pore size of porous titanium (Ti) regarding the cytocompatibility and osteogenic differentiation. Six groups of porous Ti samples with different porosities and pore sizes were fabricated by the powder metallurgy process. The microstructure and compressive mechanical properties were characterized. The cytocompatibility was examined by a series of biological tests as protein absorption with BCA assay kit, cell attachment with laser scanning confocal microscopy and vinculin expression, cell proliferation with CCK-8 assay. Cell differentiation and calcification were detected by qPCR and Alizarin Red S dying respectively. Pores distributed homogeneously throughout the porous Ti samples. The compressive test results showed that Young’s modulus ranged from 2.80 ± 0.03 GPa to 5.43 ± 0.34 GPa and the compressive strength increased from 112.4 ± 3.6 MPa to 231.1 ± 9.4 MPa. Porous Ti with high porosity (53.3 ± 1.2%) and small pore size (191.6 ± 3.7 μm) adsorbed more proteins. More MC3T3-E1 cells adhered onto dense Ti samples than onto any other porous ones already after culture and no difference was identified within the porous groups. The porous structure of porous Ti with a porosity of 53.3 ± 1.2% and an average pore size of 191.6 ± 3.7 μm facilitated cell differentiation and calcification. Small pores were not beneficial to the osteo-initiation at the very beginning. Porous Ti with a porosity of 53.3 ± 1.2% and an average pore size of 191.6 ± 3.7 μm fabricated by powder metallurgy process showed the expected mechanical property and improved osseointegration as implants in dental treatment.


2007 ◽  
Vol 539-543 ◽  
pp. 1833-1838 ◽  
Author(s):  
Yasuo Yamada ◽  
Takumi Banno ◽  
Zhen Kai Xie ◽  
Yun Cang Li ◽  
Cui E Wen

In the present study, nickel foams with an open cell microporous structure were fabricated by the so-called space-holding particle sintering method, which included the adding of a particulate polymeric material (PMMA). The average pore size of the nickel foams approximated 10.5 μm; and the porosity ranged from 70 % to 80 %. The porous characteristics of the nickel foams were observed using scanning electron microscopy and the mechanical properties were evaluated using compressive tests. For comparison, nickel foams with an open-cell macroporous structure (pore size approximately 1.3 mm) were also presented. Results indicated that the nickel foams with a microporous structure possess enhanced mechanical properties than those with a macroporous structure.


2017 ◽  
Vol 54 (3) ◽  
pp. 181-201
Author(s):  
Rebecca Johnson ◽  
Mark Longman ◽  
Brian Ruskin

The Three Forks Formation, which is about 230 ft thick along the southern Nesson Anticline (McKenzie County, ND), has four “benches” with distinct petrographic and petrophysical characteristics that impact reservoir quality. These relatively clean benches are separated by slightly more illitic (higher gamma-ray) intervals that range in thickness from 10 to 20 ft. Here we compare pore sizes observed in scanning electron microscope (SEM) images of the benches to the total porosity calculated from binned precession decay times from a suite of 13 nuclear magnetic resonance (NMR) logs in the study area as well as the logarithmic mean of the relaxation decay time (T2 Log Mean) from these NMR logs. The results show that the NMR log is a valid tool for quantifying pore sizes and pore size distributions in the Three Forks Formation and that the T2 Log Mean can be correlated to a range of pore sizes within each bench of the Three Forks Formation. The first (shallowest) bench of the Three Forks is about 35 ft thick and consists of tan to green silty and shaly laminated dolomite mudstones. It has good reservoir characteristics in part because it was affected by organic acids and received the highest oil charge from the overlying lower Bakken black shale source rocks. The 13 NMR logs from the study area show that it has an average of 7.5% total porosity (compared to 8% measured core porosity), and ranges from 5% to 10%. SEM study shows that both intercrystalline pores and secondary moldic pores formed by selective partial dissolution of some grains are present. The intercrystalline pores are typically triangular and occur between euhedral dolomite rhombs that range in size from 10 to 20 microns. The dolomite crystals have distinct iron-rich (ferroan) rims. Many of the intercrystalline pores are partly filled with fibrous authigenic illite, but overall pore size typically ranges from 1 to 5 microns. As expected, the first bench has the highest oil saturations in the Three Forks Formation, averaging 50% with a range from 30% to 70%. The second bench is also about 35 ft thick and consists of silty and shaly dolomite mudstones and rip-up clast breccias with euhedral dolomite crystals that range in size from 10 to 25 microns. Its color is quite variable, ranging from green to tan to red. The reservoir quality of the second bench data set appears to change based on proximity to the Nesson anticline. In the wells off the southeast flank of the Nesson anticline, the water saturation averages 75%, ranging from 64% to 91%. On the crest of the Nesson anticline, the water saturation averages 55%, ranging from 40% to 70%. NMR porosity is consistent across the entire area of interest - averaging 7.3% and ranging from 5% to 9%. Porosity observed from samples collected on the southeast flank of the Nesson Anticline is mainly as intercrystalline pores that have been extensively filled with chlorite clay platelets. In the water saturated southeastern Nesson Anticline, this bench contains few or no secondary pores and the iron-rich rims on the dolomite crystals are less developed than those in the first bench. The chlorite platelets in the intercrystalline pores reduce average pore size to 500 to 800 nanometers. The third bench is about 55 ft thick and is the most calcareous of the Three Forks benches with 20 to 40% calcite and a proportionate reduction in dolomite content near its top. It is also quite silty and shaly with a distinct reddish color. Its dolomite crystals are 20 to 50 microns in size and partly abraded and dissolved. Ferroan dolomite rims are absent. This interval averages 7.1% porosity and ranges from 5% to 9%, but the pores average just 200 nanometers in size and occur mainly as microinterparticle pores between illite flakes in intracrystalline pores in the dolomite crystals. This interval has little or no oil saturation on the southern Nesson Anticline. Unlike other porosity tools, the NMR tool is a lithology independent measurement. The alignment of hydrogen nuclei to the applied magnetic field and the subsequent return to incoherence are described by two decay time constants, longitudinal relaxation time (T1) and transverse relaxation time (T2). T2 is essentially the rate at which hydrogen nuclei lose alignment to the external magnetic field. The logarithmic mean of T2 (T2 Log Mean) has been correlated to pore-size distribution. In this study, we show that the assumption that T2 Log Mean can be used as a proxy for pore-size distribution changes is valid in the Three Forks Formation. While the NMR total porosity from T2 remains relatively consistent in the three benches of the Three Forks, there are significant changes in the T2 Log Mean from bench to bench. There is a positive correlation between changes in T2 Log Mean and average pore size measured on SEM samples. Study of a “type” well, QEP’s Ernie 7-2-11 BHD (Sec. 11, T149N, R95W, McKenzie County), shows that the 1- to 5-micron pores in the first bench have a T2 Log Mean relaxation time of 10.2 msec, whereas the 500- to 800-nanometer pores in the chlorite-filled intercrystalline pores in the second bench have a T2 Log Mean of 4.96 msec. This compares with a T2 Log Mean of 2.86 msec in 3rd bench where pores average just 200 nanometers in size. These data suggest that the NMR log is a useful tool for quantifying average pore size in the various benches of the Three Forks Formation.


2021 ◽  
Vol 13 (14) ◽  
pp. 7593
Author(s):  
Farooq Khan Niazi ◽  
Malik Adeel Umer ◽  
Ashfaq Ahmed ◽  
Muhammad Arslan Hafeez ◽  
Zafar Khan ◽  
...  

Ultrafiltration membranes offer a progressive and efficient means to filter out various process fluids. The prime factor influencing ultrafiltration to a great extent is the porosity of the membranes employed. Regarding membrane development, alumina membranes are extensively studied due to their uniform porosity and mechanical strength. The present research work is specifically aimed towards the investigation of nanoporous alumina membranes, as a function of sintering parameters, on ultrafiltration performance. Alumina membranes are fabricated by sintering at various temperatures ranging from 1200–1300 °C for different holding times between 5–15 h. The morphological analysis, conducted using Scanning electron microscopy (SEM), revealed a homogeneous distribution of pores throughout the surface and cross-section of the membranes developed. It was observed that an increase in the sintering temperature and time resulted in a gradual decrease in the average pore size. A sample with an optimal pore size of 73.65 nm achieved after sintering at 1250 °C for 15 h, was used for the evaluation of ultrafiltration performance. However, the best mechanical strength and highest stress-bearing ability were exhibited by the sample sintered at 1300 °C for 5 h, whereas the sample sintered at 1250 °C for 5 h displayed the highest strain in terms of compression. The selected alumina membrane sample demonstrated excellent performance in the ultrafiltration of sugarcane juice, compared to the other process liquids.


2012 ◽  
Vol 174-177 ◽  
pp. 1010-1014 ◽  
Author(s):  
Hong Bin Liu ◽  
Yang Ju ◽  
Kai Pei Tian ◽  
Jin Hui Liu ◽  
Li Wang ◽  
...  

The pore structure characteristics of reactive powder concrete (RPC) were investigated by means of the mercury injection method at seven temperature levels, namely, 20°C, 100°C, 150°C, 200°C, 250°C, 300°C, 350°C, respectively. The characteristic parameters such as porosity, pore volume, average pore size and threshold aperture varied with temperatures were analyzed. The results indicate that the porosity, pore volume, threshold aperture and other characteristic parameters of RPC increased with the temperature increasing.


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