Investigation of Blends of sPS/B30, B30/iPP and sPS/iPP/B30: Mechanical and Thermal Properties

2014 ◽  
Vol 541-542 ◽  
pp. 288-292
Author(s):  
Xiao Yu Yang ◽  
Xin Hua Wu ◽  
Yang Feng Zhao ◽  
Qi Gu Huang

The mechanical and thermal properties of B30/iPP, B30/sPS and sPS/iPP/B30 blends were investigated by unnotched izod impact tester, DSC and tensile strength tester. The results showed that the mechanical properties of B30/iPP, B30/sPS and sPS/iPP/B30 blends were better than that of homopolymer B30 and sPS. The blend of sPS/B30 with the ratio of 80/20, unnotched izod impact strength was 41.2 KJ/m2, tensile strength 32.5 MPa. The blend of B30/iPP with the ratio of 90 to 10, the unnotched izod impact strength was 46.2 KJ/m2 and the tensile strength 27.2 MPa; and the blend of sPS/iPP/B30 with the ratio of 90/10/10, the unnotched izod impact strength was 42.3 KJ/m2, and the tensile strength 33.7 MPa. DSC result showed that in the blend system of B30/iPP and sPS/iPP/B30 the iPP-Tg region shifted toward the sPS-Tg. However, the sPS-Tg shifted inward slightly.

Author(s):  
Himanshu Gupta ◽  
Kamal Kanaujiya ◽  
Syed Mazher Abbas Rizvi

To determine the possibility of using sugar- cane bagasse (SCB)and ground nut shell particulate(GNSP) waste as reinforcing ?ller in the thermo plastic polymer matrix, SCB&GNSP-reinforced polypropylene (PP) composites were prepared. The PP and SCB and GNSP composites were prepared by the extrusion of PP and GNSP with 5, 10, 15, and 20 wt % of SCB and GNSP with 3,6,9 and 12% filler in a co rotating twin screw extruder.. The extruded strands were cut into pellets and injection molded to make test specimens. These specimens were tested for physical and mechanical properties such as tensile, flexural, Izod impact strength shore D hardness and water absorption. It was found that the Tensile strength increased from 29.06 to 31.38 MPa, Flexural strength increased from 28.62 to 43.56 MPa, Izod impact strength decreased from 35.11 to 30.93 J/m, and Shore D Hardness increased from 64.88 to 77.89, with increase in filler loading from 5 to 20% in the PP matrix. The decrease in Izod Impact strength and elongation with addition of SCB & GNSP filler to PP matrix follows the general trend of filler effects on polymer matrix. However, the main purpose of this work was to study the effect of SCB & GNSP waste on the mechanical properties of the PP Composites. The SCB and GNSP waste can be used as filler in the PP composites, which will reduce cost and give environmental benefits.


2019 ◽  
Vol 956 ◽  
pp. 229-236
Author(s):  
Jian Lin Xu ◽  
Zhou Chen ◽  
Lei Niu ◽  
Cheng Hu Kang ◽  
Xiao Qi Liu

In this paper, Sb2O3/PP composite specimens were prepared by ball milling and melt blending. The effects of Sb2O3 particle size and filling amount on the toughening, reinforcing effect and crystallinity of PP composites were analyzed by notch impact test, tensile test, SEM, XRD and DSC characterization. The experimental results show that the filling of Sb2O3 particles can improve the mechanical properties and crystallization properties of Sb2O3/PP composites. With the increase of filling amount of Sb2O3 particles, the tensile strength and impact strength of Sb2O3/PP composite increased first and then decreased. When the content of Sb2O3 is 2 wt.%, the tensile strength and impact strength of Sb2O3/PP composites reach the maximum. When the filling amount is the same, the crystallization and mechanical properties of nanoSb2O3/PP composites are better than those of micron Sb2O3/PP composites.


2017 ◽  
Vol 79 (6) ◽  
Author(s):  
Ruhal Pervez Memon ◽  
Abdul Rahman Mohd. Sam ◽  
A. S. M. Abdul Awal ◽  
Lemar Achekzai

 Industrialization in developing countries has resulted in an increase in agricultural output and consequent accumulation of unmanageable agro wastes. Pollution arising from such wastes is a matter of concern for many developing nations. The aim of this study is to investigate the behavior of lightweight concrete and the utilization of sawdust as waste material in concrete. This paper focuses on the manufacturing of concrete which possess long duration heat transfer by using sawdust waste. In this research, cement to sawdust ratio of 1:1, 1:2 and 1:3 by volume was prepared for sawdust concrete, and the ratio of sand was kept constant that is 1. At these ratios, the mechanical and thermal properties like density, workability, strength and heat transfer were measured after, 7, 28 and 56 days of air curing. The tests results show that with the increase in the amount of sawdust, the workability, compressive strength, tensile strength and flexural strength decreased. It also resulted in reduction of heat transfer of sawdust concrete. Taking into account the overall physical and mechanical properties, sawdust concrete can be used in construction technology. 


Polyurethanes ◽  
2016 ◽  
Vol 1 (1) ◽  
Author(s):  
P. Ross ◽  
G. Sevilla ◽  
J. Quagliano

AbstractPolyurethane formulations utilized as liners for composite propellants were prepared by the reaction of toluene-2,4-diisocyanate (TDI) and isophorone diisocyanate (IPDI) with hydroxyl terminated polybutadiene (HTPB), while polymer chains were further extended with neopentyl glycol diol, NPG triol and two different triols (monoglyceryl ricinoleate, MRG and trimethylolpropane, TMP). Liners were formulated with micronized titanium dioxide mechanically dispersed in hydroxyl-terminated polybutadiene (HTPB). The molecular structures of liners were confirmed by FT-IR. Thermal properties indicated that the nature of chain extender (crosslinker) only slightly affected the temperatures for decomposition of liners. Two main thermal changes were found at 370∘C and another at around 440–500∘C, depending on the chain extender utilized. On the other side, mechanical properties varied within the range of 0,7-1,8 MPa, consistent with this kind of elastomers. Tensile strength at break was only significantly affected with TMP and MRG-chain extended liners at the lowest concentrations tested of 1,3 and 2% (w/w), respectively. However, the behaviour depended on whether TDI or IPDI isocyanate was utilized for curing. TMP 1,3% crosslinked liner cured with TDI had a tensile strength of 1,82MPa whileMRG-crosslinked liner cured with IPDI had a tensile strength of 1,56 MPa. It was observed that at the higher NCO/OH ratios essayed, tensile strength and hardness increased, improving mechanical properties. Our results confirmed that TMP and MRG triols together with NPG diols can be used to tailor mechanical and thermal properties of liners, considering their different hydroxyl functionalities and chain lengths.


2008 ◽  
Vol 44-46 ◽  
pp. 677-684
Author(s):  
Joseph I. Achebo ◽  
A.O. Akii Ibhadode

A new flux based on NaCl – CaCl2 – CaF2 – Na3AlF6 was developed for the gas welding of aluminium and its alloys. The flux was generated by the application of the Hadamard multivariate chemical composition model. The model uses a 8 x 8 matrix and a full factorial analysis to generate several compositions within given ranges of the constituent flux elements. Mechanical and field tests were carried out on weldments made with the flux. The tensile strength, Izod impact strength and hardness of the all – weld metal were 310MPa, 5.35J and 100BHN. The weld deposition efficiency was 90.3%.The new flux and two popular commercial fluxes were given to five expert aluminium welders to use for three months, and were requested to rate the performances. The results showed that there was an agreement between the responses of the welders that the new flux performed better than the commercial versions available in Nigeria.


2013 ◽  
Vol 12 (06) ◽  
pp. 1350039
Author(s):  
L. G. FURLAN ◽  
RICARDO V. B. OLIVEIRA ◽  
ANDRÉIA C. E. MELLO ◽  
SUSANA A. LIBERMAN ◽  
MAURO A. S. OVIEDO ◽  
...  

The preparation of high-impact polypropylene nanocomposites with different organo-montmorillonite (O-MMT) contents by means of meltprocessing was investigated. The nanocomposite properties were evaluated by transmission electron microscopy (TEM), flexural modulus, izod impact strength, dynamic mechanical analysis (DMA), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). It was noticed that the PP/O-MMT nanocomposites properties were affected by clay content. Exceptional improvements in impact strength were obtained (maximum of 185%) by the use of low O-MMT content. The results showed that higher enhancement on mechanical/thermal properties was obtained by 3 wt.% of O-MMT instead of higher quantities.


e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Deng Xu ◽  
V. Sridhar ◽  
Thanh Tu Pham ◽  
Jin Kuk Kim

AbstractThe potential of exfoliated graphite nano platelets (xGnP™) as reinforcing fillers in flouroelastomer has been investigated. The dispersion of the nano graphite platelets in the polymer matrix has been investigated by WAXD, SEM, TEM, EPMA and AFM. WAXD studies indicated that the processing of composites did not change the inter-gallery distance (d-spacing) of the graphite platelets. The effect of increasing nano graphite loadings on mechanical properties like tensile strength, modulus and tear resistance has been studied. Formation of weld lines on the fracture surface of the composite has been observed by SEM. The thermal stability was determined using thermogravimetric analysis. The composites showed higher thermal stability in comparison with nonreinforced polymer.


RSC Advances ◽  
2015 ◽  
Vol 5 (106) ◽  
pp. 87589-87597 ◽  
Author(s):  
Nisha Bagotia ◽  
Bhanu Pratap Singh ◽  
Veena Choudhary ◽  
D. K. Sharma

The notched izod impact strength of PC/EMA blends showed a positive blending effect and increased 381% with incorporation of a very little amount of EMA (5%) with a marginal decrease in tensile strength of PC.


2014 ◽  
Vol 1004-1005 ◽  
pp. 497-500
Author(s):  
Wang Wang Yu ◽  
Dong Xue

In this study, silvergrass (SV) reinforced high density polyethylene (HDPE) composites were prepared. The effects of slivergrass fibers (SV) content on the mechanical properties, crystalline properties of wood plastic composites (WPCs) before and after water absorption were investigated. It was found that compared with the untreated WPCs after immersed into water, the tensile strength of PMDI treated composites were higher. Silvergrass can be the nucleating agent with treated by PMDI. The Xc of PMDI treated WPCs after immersed into water was also increased. However, this improved Xc has negative effect on mechanical properties.


2012 ◽  
Vol 472-475 ◽  
pp. 1937-1940
Author(s):  
Dong Yan Ren ◽  
Xiao Hong Li ◽  
Zhi Hua Li

Polyurethane-modified epoxy resin was prepared with Polyurethane prepolymer(PUP). The effects of the PUP content and epoxy resin type on mechanical and thermal properties of materials were discussed. The results indicate that the tensile strength and impact strength of the material increase to maximum successively, and then decrease with the increasing addition of PUP. When the mass fraction of PUP was 15%, the tensile strength and the impact strength of materials were all the best. There were significant differences in mechanical and thermal properties of material for different epoxy, and the best results were cured epoxy TDE-85.


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