Preparation and Property Research of PC/PLA Composites Modified By ABS Blending

2011 ◽  
Vol 66-68 ◽  
pp. 1902-1907 ◽  
Author(s):  
Yi Chen ◽  
Guang Sheng Zeng ◽  
Ping Jiang ◽  
Xiang Gang Li ◽  
Yu Gang Huang
Keyword(s):  
Mechanical Properties ◽  
Impact Resistance ◽  
Compound System ◽  
Melt Blending ◽  
Crystallization Ability ◽  
Great Performance ◽  
Optimum Proportion ◽  
Properties Of Materials ◽  
The Impact ◽  
Thermal Stability Of

PC/PLA composite material introduces the degradability of PLA to PC with great performance, but their compatibility and impact resistance are poor. Aiming at this deficiency, ABS is used to modify PC/PLA. This paper established the ternary compound system of PC/PLA/ABS by melt blending and studied the impact of adding ABS and compatibilizer ABS-g-MAH on the composite’s morphology, thermal properties, rheology and mechanical properties. The results showed that: ABS bettered the brittle fracture of PC/PLA and improved the impact strength of composite with the optimum proportion of 30% of PC/PLA mass. In addition, ABS-g-MAH effectively improved the compatibility of the composites as well as mechanical properties of materials. With the increase of ABS, the crystallization ability of PLA in the composite improved and the thermal stability of the system deteriorated slightly, the melt shear viscosity of composite also decreased.

scholarly journals Preparation and Characteristic of PC/PLA/TPU Blends by Reactive Extrusion

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Yueyun Zhou ◽  
Lifa Luo ◽  
Wenyong Liu ◽  
Guangsheng Zeng ◽  
Yi Chen
Keyword(s):  
Mechanical Properties ◽  
Fracture Behavior ◽  
Reactive Extrusion ◽  
Uniform Structure ◽  
Intrinsic Properties ◽  
Elongation At Break ◽  
The Poor ◽  
Properties Of Materials ◽  
The Impact ◽  
Thermal Stability Of

To overcome the poor toughness of PC/PLA blends due to the intrinsic properties of materials and poor compatibility, thermoplastic urethane (TPU) was added to PC/PLA blends as a toughener; meantime, catalyst di-n-butyltin oxide (DBTO) was also added for catalyzing transesterification of components in order to modify the compatibility of blends. The mechanical, thermal, and rheological properties of blends were investigated systematically. The results showed that the addition of TPU improves the toughness of PC/PLA blends significantly, with the increase of TPU, the elongation at break increases considerably, and the impact strength increases firstly and then falls, while the tensile strength decreases significantly and the blends exhibit a typical plastic fracture behavior. Meantime, TPU is conducive to the crystallinity of PLA in blends which is inhibited seriously by PC and damages the thermal stability of blends slightly. Moreover, the increased TPU makes the apparent viscosity of blends melt decrease due to the well melt fluidity of TPU; the melt is closer to the pseudoplasticity melt. Remarkably, the transesterification between the components improves the compatibility of blends significantly, and more uniform structure results in a higher crystallinity and better mechanical properties.

Study on Mechanical Properties of Styrene-ethylene/butylene-styrene/polystyrene Blends

2011 ◽  
Vol 396-398 ◽  
pp. 1422-1425
Author(s):  
Xiao Ming Sang ◽  
Lei Zhang ◽  
Run Zeng Wang ◽  
Xing Gang Chen ◽  
Man An ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Impact Resistance ◽  
Melt Blending ◽  
Maximum Value ◽  
Izod Impact ◽  
The Impact ◽  
Resistance Tests ◽  
Scanning Electron ◽  
Number Of Particles

The styrene-ethylene/butylene-styrene/polystyrene (SEBS/PS) blends were prepared by melt blending. The mechanical properties of PS/SEBS blends were influenced by the increase of SEBS contents. When the content of SEBS increased to 13 wt%, the impact strength of SEBS/PS blends boosted the maximum value. Young’s modulus and tensile strength of SEBS/PS blends decreased with the increase of SEBS. The fracture surfaces obtained during Izod impact resistance tests were obtained by scanning electron microscopy (SEM). The results indicated that the number of particles of SEBS dispersed in PS matrix. The diameters of particles of SEBS were about 1.5-3 µm. SEBS/PS blends absorbed more energy than pure PS during impact resistance tests.

Effect of combined drink cans and steel fibers on the impact resistance and mechanical properties of concrete

2020 ◽  
Vol 14 (2) ◽  
pp. 6734-6742
Author(s):  
A. Syamsir ◽  
S. M. Mubin ◽  
N. M. Nor ◽  
V. Anggraini ◽  
S. Nagappan ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Reinforced Concrete ◽  
Impact Resistance ◽  
Fiber Reinforced Concrete ◽  
Steel Fibers ◽  
Fiber Reinforced ◽  
Indirect Tensile ◽  
The Impact

This study investigated the combine effect of 0.2 % drink cans and steel fibers with volume fractions of 0%, 0.5%, 1%, 1.5%, 2%, 2.5% and 3% to the mechanical properties and impact resistance of concrete. Hooked-end steel fiber with 30 mm and 0.75 mm length and diameter, respectively was selected for this study.  The drinks cans fiber were twisted manually in order to increase friction between fiber and concrete. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the strength performance of concrete, especially the compressive strength, flexural strength and indirect tensile strength. The results of the experiment showed that the combination of steel fibers and drink cans fibers improved the compressive strength, flexural strength and indirect tensile strength by 2.3, 7, and 2 times as compare to batch 1, respectively. Moreover, the impact resistance of fiber reinforced concrete has increase by 7 times as compared to non-fiber concretes. Moreover, the impact resistance of fiber reinforced concrete consistently gave better results as compared to non-fiber concretes. The fiber reinforced concrete turned more ductile as the dosage of fibers was increased and ductility started to decrease slightly after optimum fiber dosage was reached. It was found that concrete with combination of 2% steel and 0.2% drink cans fibers showed the highest compressive, split tensile, flexural as well as impact strength.    

scholarly journals Effect of SWCNT-Tuball Paper on the Lightning Strike Protection of CFRPs and Their Selected Mechanical Properties

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3140
Author(s):  
Kamil Dydek ◽  
Anna Boczkowska ◽  
Rafał Kozera ◽  
Paweł Durałek ◽  
Łukasz Sarniak ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Copper Foil ◽  
Impact Resistance ◽  
Mechanical Analysis ◽  
Lightning Strike ◽  
Single Wall Carbon Nanotubes ◽  
Carbon Fibre Reinforced Polymer ◽  
The Impact

The main aim of this work was the investigation of the possibility of replacing the heavy metallic meshes applied onto the composite structure in airplanes for lightning strike protection with a thin film of Tuball single-wall carbon nanotubes in the form of ultra-light, conductive paper. The Tuball paper studied contained 75 wt% or 90 wt% of carbon nanotubes and was applied on the top of carbon fibre reinforced polymer before fabrication of flat panels. First, the electrical conductivity, impact resistance and thermo-mechanical properties of modified laminates were measured and compared with the reference values. Then, flat panels with selected Tuball paper, expanded copper foil and reference panels were fabricated for lightning strike tests. The effectiveness of lightning strike protection was evaluated by using the ultrasonic phased-array technique. It was found that the introduction of Tuball paper on the laminates surface improved both the surface and the volume electrical conductivity by 8800% and 300%, respectively. The impact resistance was tested in two directions, perpendicular and parallel to the carbon fibres, and the values increased by 9.8% and 44%, respectively. The dynamic thermo-mechanical analysis showed higher stiffness and a slight increase in glass transition temperature of the modified laminates. Ultrasonic investigation after lightning strike tests showed that the effectiveness of Tuball paper is comparable to expanded copper foil.

Phase Morphology, Thermal and Mechanical Properties of Compatibilized Nylon12/Natural Rubber Blends Using PS/MNR

2013 ◽  
Vol 844 ◽  
pp. 53-56
Author(s):  
Saravalee Saengthaveep ◽  
Sadhan C. Jana ◽  
Rathanawan Magaraphan
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Moisture Absorption ◽  
Rubber Particle ◽  
Impact Resistance ◽  
Phase Morphology ◽  
Thermal And Mechanical Properties ◽  
Binary Blend ◽  
Polyamide 12 ◽  
The Impact

To produce a tough material for application demanding high impact resistance and low moisture absorption, melt blending of Nylon12 (Polyamide 12, PA12) and natural rubber (NR) was carried out in a brabender plasticorder at 210 °C with rotor speed of 70 rpm in the presence of polystyrene/maleated natural rubber (PS/MNR) blend as a compatibilizer. The effect of compatibilizer content (1, 3, 5, 7 and 10 phr) on phase morphology, thermal, and mechanical properties of [Nylon12/NR]/[PS/MNR] blends was investigated by using SEM, DSC, and Izod impact tester, respectively. The result revealed that PS/MNR blend improved the compatibility of Nylon12/NR blends efficiently due to the presence of amide linkage at the interfaces from the reaction between the reactive groups of MNR and the NH2 end groups of Nylon12 during mixing. A fine phase morphology (good dispersion and small dispersed phase size of NR domains in Nylon12 matrix) of [Nylon12/NR]/[PS/MNR] blends was observed at the optimum compatibilizer content of 7 phr, relating to the improvement of mechanical property. The impact energy of [Nylon12/NR]/[PS/MNR] blends was 503 J/m higher than that of neat Nylon12 (115 J/m) and Nylon12/NR binary blend (241 J/m) due to the toughening effect of rubber and proper morphology. The melting temperature of all blends did not change obviously from thermal analysis. However, the presence of rubber particle obstructed the crystallization of Nylon12 phase, leading to the decreasing of %crystallinity from 93% to around 70%.

Flow Behavior of Composites of PA6/Kaolin Nanoparticles

2014 ◽  
Vol 703 ◽  
pp. 45-50
Author(s):  
Chao Wang ◽  
Ying Chun Li ◽  
Guo Sheng Hu
Keyword(s):  
Mechanical Properties ◽  
Flow Behavior ◽  
Acrylonitrile Butadiene Styrene ◽  
Nylon 6 ◽  
Mechanical Analysis ◽  
Melt Blending ◽  
Styrene Maleic Anhydride ◽  
The Impact ◽  
Scanning Electron ◽  
Butadiene Styrene

The blends of Nylon 6/Acrylonitrile-Butadiene-Styrene (ABS) with styrene-maleic anhydride (SMA) was prepared by melt blending as the compatilizer. Mechanical properties, dynamic mechanical analysis (DMA) and fracture appearances were determined. It was found that the impact and tensile strength firstly increased and then decreased along with the increase of the SMA content. The properties reached maximum values when the content of SMA was 1.5%. The results of DMA and scanning electron microscope (SEM) indicated that the addition of SMA can effectively enhance the compatibility of Nylon 6 and ABS. Key words: Nylon 6, ABS, SMA, blends, modification

Study on the Preparation and Mechanical Properties of Polystyrene/Y2O3 Composites

2011 ◽  
Vol 306-307 ◽  
pp. 1735-1740
Author(s):  
Yan Li Dou ◽  
Chun Ling Zhang ◽  
Guoen Sun ◽  
Wen Hui Xu
Keyword(s):  
Mechanical Properties ◽  
Wear Resistance ◽  
Melt Blending ◽  
Reinforcing Effect ◽  
Performance Improvements ◽  
Modify Effect ◽  
Blending Process ◽  
Y2o3 Content ◽  
The Impact ◽  
Composite Properties

Rare earth yttria (Y2O3) reinforced polystyrene composites were prepared by melt blending process. Mechanical properties, wear resistance of the PS/Y2O3 composites were characterized in contrast to neat PS. The improvement of the mechanical properties and wear resistance was attributed to the reinforcing effect of Y2O3 powder. Well distribution of Y2O3 powder in the PS matrix and good interfacial bonding were achieved by pretreated of Y2O3 using titanate coupling and dispersant followed by calcinations process. Results indicated that both of the Y2O3 powder pretreatment process and melt blending process have significant effects on the composite properties. When the Y2O3 content were 2.8wt%, the modify effect to PS was optimal. When the Y2O3 calcined at 900°C was used, the impact of the composites were best, other performance improvements have also been good. When the Y2O3 content of 1.4wt%, the wear resistance of the composites were best.

scholarly journals Effect of Three-dimensional Printing with Nanotubes on Impact Resistance

2019 ◽  
Author(s):  
Anne Schmitz
Keyword(s):  
Mechanical Properties ◽  
Lower Limb ◽  
Impact Resistance ◽  
Three Dimensional ◽  
Three Dimensional Printing ◽  
Impact Tester ◽  
The Impact ◽  
Dimensional Printing ◽  
Pendulum Impact ◽  
Pendulum Impact Tester

Abstract The types of biomedical devices that can be three-dimensional printed (3DP) is limited by the mechanical properties of the resulting materials. As a result, much research has focused on adding carbon nanotubes (CNT) to these photocurable polymers to make them stronger. However, there is little to no data on how CNTs affect the impact resistance of these polymers, an important property when designing and manufacturing lower limb prosthetics. The objective of this study was to expand the use of 3DP to prosthetics by testing the hypothesis that adding CNTs to a stereolithographic (SLA) photocurable resin will result in a cured polymer with increased impact resistance. Twenty-six total specimens: 13 with nanotubes and 13 without nanotubes, were printed on a Form2 SLA printer. Once all the specimens were printed, washed, and cured, the impact resistance was quantified using a pendulum impact tester in a notched Izod configuration. Contrary to the hypothesis, the specimens with SWCNTs (0.312 ± 0.036 ft*lb/in) had a significantly lower impact resistance compared to the non-SWCNT specimens (0.364 ± 0.055 ft*lb/in), U = 34.0, p = 0.004. This decreased impact resistance may be due to voids in the printed polymer around the aggregated nanotubes. Thus, SLA polymers still do not have the impact strength needed to be used for a full lower limb prosthetic.

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