Equilibrium and Kinetic Studies on Removal of Binary Metal Ions Using Immobilized Saccharomyces cerevisiae

2014 ◽  
Vol 661 ◽  
pp. 39-44
Author(s):  
Nur Khalida Adibah Md Rodzi ◽  
Senusi Faraziehan ◽  
Alrozi Rasyidah
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Metal Ions ◽  
Copper Ions ◽  
Binding Capacity ◽  
Kinetic Studies ◽  
Suitable Model ◽  
Zinc Ions ◽  
Copper And Zinc ◽  
Maximum Sorption ◽  
Pseudo Second Order

In this study, biosorption of copper and zinc ions on Baker’s yeast, Saccharomyces Cerevisiae was investigated. The data of batch experiments was used to perform equilibrium and kinetic studies. The experimental results were fitted well to the Langmuir and Freundlich model isotherms. According to the parameters of Langmuir isotherm, the maximum biosorption capacities of copper and zinc ions onto immobilized yeast were 5.408mg/g and 1.479mg/g at 293 Kfor the treated beads. Competitive biosorption of two metal ions was investigated in terms of maximum sorption quantity. The binding capacity for copper ions is more than the zinc ions for both untreated and treated immobilized yeast.While, for the kinetic studies, the pseudo second order model was found the most suitable model for the present systems.

Gram-scale synthesis of monodisperse sulfonated polystyrene nanospheres for rapid and efficient sequestration of heavy metal ions

2017 ◽  
Vol 53 (95) ◽  
pp. 12766-12769 ◽  
Author(s):  
Bin Gong ◽  
Yaotian Peng ◽  
Ziyan Pan ◽  
Weiming Chen ◽  
Yi Shen ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Metal Ions ◽  
Heavy Metal Ions ◽  
Large Scale ◽  
Zinc Ions ◽  
Sulfonated Polystyrene ◽  
Copper And Zinc ◽  
Polystyrene Nanospheres

Large-scale monodisperse sulfonated polystyrene nanospheres are synthesized for the removal of lead, copper and zinc ions from aqueous solutions.

scholarly journals Efficient Removal of Metals from Synthetic and Real Galvanic Zinc–Containing Effluents by Brewer’s Yeast Saccharomyces cerevisiae

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3624 ◽  
Author(s):  
Inga Zinicovscaia ◽  
Nikita Yushin ◽  
Daler Abdusamadzoda ◽  
Dmitrii Grozdov ◽  
Margarita Shvetsova
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Metal Ions ◽  
High Efficiency ◽  
Zinc Ions ◽  
Brewer’S Yeast ◽  
Yeast Saccharomyces Cerevisiae ◽  
Brewer's Yeast ◽  
Biosorption Process ◽  
Metal Biosorption ◽  
Removal Of Metal Ions

The performance of the brewer’s yeast Saccharomyces cerevisiae to remove metal ions from four batch systems, namely Zn(II), Zn(II)-Sr(II)-Cu(II), Zn(II)-Ni(II)-Cu(II), and Zn(II)-Sr(II)-Cu(II)-Ba(II), and one real effluent was evaluated. Yeast biosorption capacity under different pH, temperature, initial zinc concentration, and contact time was investigated. The optimal pH for removal of metal ions present in the analyzed solution (Zn, Cu, Ni, Sr, and Ba) varied from 3.0 to 6.0. The biosorption process for zinc ions in all systems obeys Langmuir adsorption isotherm, and, in some cases, the Freundlich model was applicable as well. The kinetics of metal ions biosorption was described by pseudo-first-order, pseudo-second-order, and Elovich models. Thermodynamic calculations showed that metal biosorption was a spontaneous process. The two-stage sequential scheme of zinc ions removal from real effluent by the addition of different dosages of new sorbent allowed us to achieve a high efficiency of Zn(II) ions removal from the effluent. FTIR revealed that OH, C=C, C=O, C–H, C–N, and NH groups were the main biosorption sites for metal ions.

Adsorption of CuCl2 on Mg-Al HTlc: Effect of EDTA and Addition Sequences

2012 ◽  
Vol 573-574 ◽  
pp. 150-154
Author(s):  
Yun Bo Zang ◽  
Nai Ying Wu
Keyword(s):  
Aqueous Solutions ◽  
Sorption Capacity ◽  
Contact Time ◽  
Room Temperature ◽  
Copper Ions ◽  
Sorption Process ◽  
Langmuir Model ◽  
Maximum Sorption Capacity ◽  
Maximum Sorption ◽  
Pseudo Second Order

In this study, removal of copper ions from aqueous solutions by synthetic Mg-Al-HTlc was investigated as a function of contact time, EDTA and addition sequences at room temperature. It is found that HTlc could reduced copper ions concentration effectively. The kinetics closely fit pseudo-second order kinetics with necessary time 9 h to reach equilibrium. The sorption process followed langmuir model. The maximum sorption capacity calculated was found to be 39.4 mg/g. The presence of EDTA and addition sequences could affect sorption of Cu(II) onto HTlc.

scholarly journals Metal Removal from Complex Copper Containing Effluents by Waste Biomass of Saccharomyces cerevisiae

2020 ◽  
Vol 27 (3) ◽  
pp. 415-435
Author(s):  
Inga Zinicovscaia ◽  
Nikita Yushin ◽  
Dmitrii Grozdov ◽  
Konstantin Vergel ◽  
Tatiana Ostrovnaya ◽  
...  
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Metal Removal ◽  
Waste Biomass ◽  
Maximum Sorption ◽  
Intra Particle Diffusion ◽  
Iron And Zinc ◽  
Equilibrium Profile ◽  
Iron Nickel ◽  
Pseudo Second Order ◽  
Experimental Kinetics

AbstractSaccharomyces cerevisiae, waste biomass originated from beer fermentation industry, was used to remove metal ions from four copper-containing synthetic effluents: Cu-Fe, Cu-Fe-Ni, Cu-Fe-Zn, and Cu-Fe-Ni-Zn. The characterization of the biomass surface was investigated by Scanning Electron Microscopy and Fourier-transform Infrared Spectroscopy. The adsorption behavior of Saccharomyces cerevisiae for copper, iron, nickel and zinc ions in aqueous solution was studied as a function of pH, initial copper concentration, equilibrium time, and temperature. Langmiur, Freundlich, Temkin and Dubinin-Radushkevich equilibrium models have been assessed to describe the experimental sorption equilibrium profile, while pseudo-first order, pseudo-second order, Elovich and the intra-particle diffusion models were applied to describe experimental kinetics data. Maximum sorption capacities have been calculated by means of Langmuir equilibrium model and mean free sorption energies through the Dubinin-Radushkevich model. Thermodynamic analysis results showed that the adsorption of copper, iron and zinc was spontaneous and endothermic in nature, while of nickel exothermic. Saccharomyces cerevisiae can be successfully applied for complex wastewater treatment.

scholarly journals Removal of zinc ions as zinc chloride complexes from strongly acidic aqueous solutions by ionic exchange

2014 ◽  
Vol 12 (8) ◽  
pp. 821-828 ◽  
Author(s):  
Emilia Gîlcă ◽  
Andrada Măicăneanu ◽  
Petru Ilea
Keyword(s):  
Kinetic Studies ◽  
Sorption Kinetics ◽  
Exchange Capacity ◽  
Second Order ◽  
Isotherm Models ◽  
Ionic Exchange ◽  
Order Kinetic ◽  
Zinc Ions ◽  
Chloride Complexes ◽  
Pseudo Second Order

AbstractThe aim of this study was to compare several anion exchangers and to investigate the capacity of Amberlite IRA410 to remove zinc as chloride [ZnCl3]− from hydrochloric solutions (1 M). Influence of the process parameters such as stirring rate, resin quantity and zinc initial concentration over the removal process, was considered. The highest experimental ionic exchange capacity between the considered anionic exchangers, in the same working conditions (500 rpm, 5 g resin and 500 mg L−1), was obtained for Amberlite IRA410, 8.34 mg g−1. With an increase of zinc ions concentration, ionic exchange capacity increased up to 19.31 mg g−1 (1100 mg L−1). The experimental data were analysed using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. The results were also analyzed using sorption kinetics models, pseudo-first-, pseudo-second-order, intra-particle and film diffusion models. From the Dubinin-Radushkevich and Temkin isotherm models the mean free energy and heat of sorption were calculated to be 7.45 kJ mol−1, respectively 1×10−4 kJ mol−1, which indicates that zinc sorption is characterized by a physisorption process. Kinetic studies showed that the adsorption followed a pseudo-second-order kinetic model.

Kinetic studies of Cd (II) and Pb (II) ions biosorption from aqueous media using untreated and chemically treated biosorbents

2014 ◽  
Vol 69 (11) ◽  
pp. 2230-2236 ◽  
Author(s):  
G. K. Bakyayita ◽  
A. C. Norrström ◽  
M. Nalubega ◽  
R. N. Kulabako
Keyword(s):  
Metal Ions ◽  
Aqueous Media ◽  
Kinetic Studies ◽  
Efficiency Enhancement ◽  
Musa Spp ◽  
Biosorption Mechanism ◽  
Chemically Treated ◽  
Pseudo Second Order ◽  
Reduction Effect ◽  
Erythrina Abyssinica

Untreated and chemically treated Albizia coriaria, Erythrina abyssinica and Musa spp. were studied in batch for uptake of Cd2+ and Pb2+ ions at pH 2.0–9.0 and agitation time of 30–390 min. Optimum biosorption conditions were pH 4 for Pb2+ ions and pH 5 for Cd2+ ions, contact time was 3.5 hours at 24 ± 1 °C for 10 mg/L biosorbent dosage and initial metal ions concentration of 20 mg/L. Chemical treatment had a 10–17% biosorption efficiency enhancement for Cd2+ ions and a 1.6–2.3% reduction effect for Pb2+ ions. The sorption capacities for Cd2+ and Pb2+ ions for treated biosorbents were 1.760–1.738 mg g−1 compared to 1.415–1.539 mg g−1 for untreated materials. The pseudo second-order model suitably fitted the Cd2+ and Pb2+ ions biosorption data with regression coefficients (R2) of 0.9784–0.9999. Fitting of the Ho model to the experimental data showed that the biosorption mechanism for both metal ions studied was mainly a chemisorption process. Therefore, treated A. coriaria, E. abyssinica and Musa spp. were potential biosorbents for remediation of Cd2+ ions and the untreated materials suitable for removing Pb2+ ions from contaminated aqueous media.

Isolation and Biomass Production of a Saccharomyces cerevisiae Strain Binding Copper and Zinc Ions

2008 ◽  
Vol 157 (1) ◽  
pp. 85-97 ◽  
Author(s):  
Aurore Stroobants ◽  
Jean-Marc Delroisse ◽  
Franck Delvigne ◽  
Julien Delva ◽  
Daniel Portetelle ◽  
...  
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Biomass Production ◽  
Zinc Ions ◽  
Copper And Zinc

scholarly journals Comparison of Heavy Metals Removal from Aqueous Solution by Moringa oleifera Leaves and Seeds

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 508
Author(s):  
Mohamed Abatal ◽  
M. T. Olguin ◽  
Ioannis Anastopoulos ◽  
Dimitrios A. Giannakoudakis ◽  
Eder Claudio Lima ◽  
...  
Keyword(s):  
Metal Ions ◽  
Moringa Oleifera ◽  
Low Cost ◽  
X Ray Diffraction ◽  
Order Model ◽  
Metals Removal ◽  
Batch Technique ◽  
Maximum Sorption ◽  
Moringa Oleifera Leaves ◽  
Pseudo Second Order

In this work, biomass obtained from seeds (S-MO) and leaves (L-MO) of the Moringa oleifera plant were used as low-cost biosorbents to remove the Pb(II), Cd(II), Co(II), and Ni(II) from aqueous solutions. The biosorption of the heavy metal ions was done using the batch technique. The effects of contact time (30–1440 min), biosorbent dosage (10–50 g/L) (0.1–0.5 g), and initial concentration of metals (10–500 mg/L) on the sorption capacity of metal ions were investigated. The S-MO and L-MO samples’ characterization was performed using pHpzc, X-ray Diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR). It was found that the pHpzc was notably different between the seeds and leave-derived biosorbents. The removal process’s experimental kinetic data for both S-MO and L-MO were best described by the pseudo-second-order model for all metal ions, with R2 above 0.997 in all cases. Langmuir and Freundlich’s models were also used to analyze the isotherms parameters. Based on the Langmuir model, the maximum sorption capacities (Qm) for L-MO were found as follows: L-MO-Pb > L-MO-Cd > L-MO-Co ≥ L-MO-Ni, and for S-MO, the values of Qm values presented the following order: S-MO-Pb > S-MO-Co > S-MO-Cd > S-MO-Ni.

Equilibrium and Kinetic Studies of Copper Metal Ion Biosorption by Flavobacterium sp. as a Low-Cost Natural Biosorbent

2011 ◽  
Vol 322 ◽  
pp. 436-439 ◽  
Author(s):  
Xi Chan Zhang ◽  
Xing Guang Li
Keyword(s):  
Metal Ion ◽  
Binding Capacity ◽  
Low Cost ◽  
Kinetic Studies ◽  
Ion Concentration ◽  
Order Kinetic ◽  
Equilibrium Studies ◽  
Initial Ph ◽  
Order Kinetic Model ◽  
Pseudo Second Order

Present study deals with the evaluation of biosorptive removal of copper byFlavobacterium sp.Experiments have been carried out to find the effect of various parameters such as initial pH, contact time and initial metal ion concentration. Adsorption equilibrium studies showed that Cu(II) adsorption data followed the Langmuir model, the maximum binding capacity ofwas 55.20 mg/g at pH 6.0. Kinetics of copper biosorption by Flavobacterium sp. biomass is better described by pseudo second order kinetic model. It was also clearly observed that The present study indicated thatFlavobacterium sp.biomass may be used as a cost and effective biosorbent for the removal of Cu(II) ions from wastewater.

scholarly journals Adsorption for copper(II) ion with chitosan-SP/PET composite adsorbent enhanced by electric field

2019 ◽  
Vol 37 (3-4) ◽  
pp. 274-287 ◽  
Author(s):  
Yunfei Song ◽  
Aiqun Kong ◽  
Yanhong Ji ◽  
Benqiao He ◽  
Hong Wang ◽  
...  
Keyword(s):  
Electric Field ◽  
Metal Ions ◽  
Copper Ions ◽  
Removal Rate ◽  
Nonwoven Fabric ◽  
Order Kinetic ◽  
Composite Adsorbent ◽  
Trace Metal Ions ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

A method combining adsorption with electric field-driven ion enrichment to remove the trace metal ions in wastewater was investigated. Composite adsorbent prepared from chitosan (CS) and sodium phytate (SP) supported into polyethylene glycol terephthalate (PET) nonwoven fabric by nonsolvent induced phase separation was employed and located near the cathode in a pair of titanium plate electrodes. Results showed the removal rate of copper ions (Cu(II)) adsorbed onto CS-SP/PET adsorbent was increased from 56% to 88% for 10 mg L−1 Cu(II) solution when the applied voltage was from 0 to 1.2 V. The adsorption behavior was well correlated with the Langmuir isotherm model. And adsorption process fitted well for pseudo-second-order kinetic equation, suggesting that chemical adsorption was rate-limiting step. And the energy consumption was economical, about 4.35 × 10−3 kW·h for 1 m3 of water with 10 mg L−1 Cu(II). It was suggested that the adsorption performance for Cu(II) with CS-SP/PET adsorbent was enhanced due to the enrichment of Cu(II) under electric field. This work provides a new way to remove trace heavy metal ions from wastewater.

Sign in / Sign up

Export Citation Format

Share Document