scholarly journals Use of Ferric Chloride and Chitosan as Coagulant to Remove Turbidity and Color from Landfill Leachate

2015 ◽  
Vol 773-774 ◽  
pp. 1163-1167 ◽  
Author(s):  
Siti Fatihah Ramli ◽  
Hamidi Abdul Aziz

Coagulation and flocculation are two of the most common chemical treatment methods used in leachate treatment. Existing coagulants are mainly based on Al and Fe salts. The use of non-chemical based coagulants, especially natural polymers, in leachate treatment has not been thoroughly investigated. Natural coagulants have less harmful effects to human health compared with metal salts. This study aimed to investigate the effectiveness of ferric chloride (FeCl3) and chitosan as coagulant in removing the turbidity and color from landfill leachate. Leachate was collected from the Matang Landfill site located at Taiping, Perak, Malaysia. When used as the main coagulant in this study, FeCl3was able to remove 97.78% of the turbidity and 95.54% of the color of the leachate at an optimum dosage of 3600 mg/L. At a dosage of 60 mg/L, chitosan only removed 23.52% of the turbidity and 14.67% of the color at pH levels of 9 and 4, respectively. The optimum pH value for FeCl3was 6. Therefore, FeCl3 is an effective coagulant that can help to remove the colour and turbidity compared to chitosan.

Teknik ◽  
2016 ◽  
Vol 37 (2) ◽  
pp. 78 ◽  
Author(s):  
Arya Rezagama ◽  
Mochtar Hadiwidodo ◽  
Purwono Purwono ◽  
Nurul Fajri Ramadhani ◽  
Mia Yustika

Air lindi yang meresap ke dalam tanah yang berpotensi bercampur dengan air tanah sehingga menimbulkan pencemaran tanah, air tanah dan air permukaan. Komposisi limbah lindi dari berbagai TPA berbeda-beda bergantung pada musim, jenis limbah, umur TPA. Proses dalam TPA menghasilkan molekul organik recalcitrant yang ditunjukkan dengan rendahnya rasio BOD/COD dan tingginya nilai NH3-N. Belum optimalnya pengolahan air lindi di Jatibarang membutuhkan pretreatment sebagai bentuk upaya alternatif dalam proses pengolahan air lindi sebelum masuk ke dalam proses aerated lagun. Penelitian ini bertujuan untuk menganalisa pengaruh koagulan kimia pada penyisihan bahan organik air lindi TPA Jatibarang. Penelitian dilakukan pada bulan April- Agustus 2016. Karaktersitik air lindi TPA Jatibarang termasuk dalam kategori "moderately stable" dan lindi muda. Penyisihan bahan organik dengan menggunakan kuagulan kimia FeCl3 dan Al2SO4 menunjukkan nilai yang cukup signifikan untuk parameter COD, BOD, TSS. Penggunaan dosis optimal terjadi pada 16 g/L FeCl3 serta 16 g/L Al2SO4 dapat menurunkan nilai COD sebesar 51% dan 65%, BOD sebesar 50% dan 56%, dan TSS sebesar 24% dan 21%. Perubahan nilai pH akibat penambahan koagulan berpengaruh positif terhadap tingkat penyisihan, namun memberikan dampak negatif yaitu buih yang cukup banyak. Penurunan beban organik menguntungkan bagi sistem pengolahan lindi eksisting TPA Jatibarang. [Title: Removal of Lindi Water Organic Waste of TPA Jatibarang using Chemical Coagulation- Floculation] Leachate grounding into the soil that potentially could mix with the groundwater caused contamination of soil, groundwater and surface water. The composition of waste landfill leachate from the various location is depending on the season, the type of waste, and landfill age. Process in the TPA produces recalcitrant organic molecules as indicated by the low ratio of BOD/COD and NH3-N high value. The ineffective treatment of leachate at Jatibarang require a pretreatment as a form of alternative effort in the processing of leachate prior to entry into the aerated lagoon process. This study aims to analyze the influence of chemical coagulants on grounding organic material Jatibarang landfill leachate. The study was conducted in April-August 2016. Jatibarang landfill leachate characteristics were categorized as "moderately stable" and young leachate. Allowance for organic materials using chemical coagulants of FeCl3 and Al2SO4 showed significant values for the parameters of COD, BOD, and TSS. The use of optimal dose occurs at 16 g/L FeCl3 and 16 g/L Al2SO4 which can reduce the COD value by 51% and 65%, BOD by 50% and 56%, and TSS at 24% and 21%. PH value changes due to the addition of coagulant positive effect on the level of the allowance, but a negative effect that is quite a lot of froth. The decline in organic load favorable for existing landfill leachate treatment systems Jatibarang. 


2010 ◽  
Vol 62 (6) ◽  
pp. 1240-1247 ◽  
Author(s):  
Jenjira Saetang ◽  
Sandhya Babel

This paper investigated treatment of landfill leachate collected from Nonthaburi landfill site, Thailand, by using immobilized white rot fungi, namely, Trametes versicolor BCC 8725 and Flavodon flavus BCC 17421. Effects of pH and co-substrates were investigated at different contact times. Three types of co-substrates as carbon source used in this study are glucose, corn starch and cassava. Treatment efficiency was evaluated based on color, BOD, and COD removal. Initial BOD and COD were found to be 5,600 and 34,560 mg/L, respectively. The optimum pH was found to be 4, the optimum co-substrate concentration (glucose, corn starch and cassava) was 3 g/L and the optimum contact time was 10 days for both types of fungi. Addition of glucose, corn starch and cassava as co-substrate at optimum conditions could remove 78, 74, and 66% of color, respectively for T. versicolor and 73, 68, and 60%, respectively, for F. flavus. Moreover, for T. versicolor, BOD and COD reduction of 69 and 57%, respectively, could be achieved at optimum conditions when using glucose as a co-substrate. For F. flavus, BOD and COD reduction of 66 and 52%, respectively were obtained when using glucose as a co-substrate. White rot fungi can be considered potentially useful in the treatment of landfill leachate as they can help in removing color, BOD and COD due to their biodegradative abilities.


1997 ◽  
Vol 35 (4) ◽  
pp. 239-248 ◽  
Author(s):  
Soo-M. Kim ◽  
Sven-U. Geissen ◽  
Alfons Vogelpohl

A combination of the classical Fenton reaction (Fe(II)+H2O2) with UV light, the photoassisted Fenton reaction, has been investigated for the treatment of landfill leachate. The investigation has been carried out with an experimental set-up to establish the optimal treatment conditions. The degradation rate of organic pollutants is strongly promoted by the photoassisted Fenton reaction. The degradation rate depends on the amount of H2O2 and Fe(II) added, pH value, and radiation intensity. At a specific energy input of 80 kW m−3 the oxidation rate was increased to six times the rate without radiation (0 kW m−3). At the higher radiation intensity of 160 kW m−3 the degradation rate was about two times faster than at that of 80 kW m−3. Due to the regeneration of the consumed Fe(II) ions through the irradiation, the amount of ferrous salt to be added can be remarkably reduced. The optimum conditions were obtained with 1.0 × 10−3 mol 1−1 Fe(II) added, a pH value of 3, and a molar ratio of COD: H2O2 = 1:1. At a COD volume loading of less than 0.6 kg m−3 h−1, a COD degradation of more than 70% could be obtained with an energy input of 80 kW m−3.


2014 ◽  
Vol 955-959 ◽  
pp. 2322-2325
Author(s):  
Li Hua Liang ◽  
Su Lin Kuang ◽  
Ting Wang ◽  
Yuan Jing Ji ◽  
Sai Zhang

The biological treatment process of landfill leachate in Beijing Liulitun landfill is a multistage A/O technology, in which a large amount of ANAMMOX (Anaerobic ammonia oxidation, ANAMMOX) bacteria were found in the sludge. There are several factors impacting the activity of ANAMMOX bacteria, including pH value, temperature and HRT which in this process are suitable for the survival of ANAMMOX bacteria. Especially, low dissolved oxygen is an essential factor as the provider of electron donor for nitrite formation. Although the high concentrations of organic matter, ammonia nitrogen and nitrite will inhibit the occurrence of ANAMMOX, ANAMMOX bacteria can self-detoxification by forming a low-poison habitat by consuming ammonia and nitrite as well as organic matter by heterotrophic ANAMMOX bacteria.


2013 ◽  
Vol 594-595 ◽  
pp. 344-349 ◽  
Author(s):  
Ain Nihla Kamarudzaman ◽  
Alice Dandun Anak Gana ◽  
Mohd Faizal Ab Jalil ◽  
Roslaili Abdul Aziz

A laboratory-scale study was conducted using a combination of SSF and FWS constructed wetland planted with Limnocharis flava and Eichhornia crassipes to treat landfill leachate. The effects of hydraulic loading rate (HLR) on pollutant removal in landfill leachate as well as the difference in performance between the planted and control system were investigated. The HLR in the system was varied at 0.39 m/d and 0.55 m/d. The results showed that the SSF-FWS constructed wetland was successful in reducing the pH value, TSS and turbidity. The removal efficiency of TSS and turbidity were achieved 98.32% and 97.43%, respectively at 0.39 m/d HLR. The study concluded that different HLR and the presence of wetland plants have given significant effects on the constructed wetland performance.


1978 ◽  
Vol 5 (1) ◽  
pp. 83-97 ◽  
Author(s):  
Robert D. Cameron

The use of cheap, locally available peat as a treatment method for landfill leachate was investigated by passing leachate through plexiglass columns filled with an amorphous-granular peat. Preliminary adjustment of pH showed that reducing pH to 4.8 dramatically reduced adsorption. Increasing the pH to 8.4, metal removal was increased owing to filtration of precipitated metals. The best adsorption of metals occurred at the 'natural' pH of 7.1. Manganese was found to be the limiting pollutant. At the 0.05 mg/ℓ maximum acceptable manganese concentration 94% of the total metals were removed, requiring 159 kg of peat per 1000 ℓ of leachate.Resting the peat for 1 month did significantly increase removal capacity.Desorption of some contaminants occurred when water was percolated through the peat. The desorption test effluent was not toxic to fish although iron, lead and COD (chemical oxygen demand) exceeded acceptable values.Chemical pretreatment using lime and ferric chloride achieved significant iron, manganese and calcium removals. Chemical pretreatment followed by peat adsorption offered no advantage other than reducing toxicity to fish.Peat treatment alone was effective in reducing concentrations to a level that was non-toxic to fish.


2021 ◽  
Vol 11 (11) ◽  
pp. 5009
Author(s):  
Mayk Teles de Oliveira ◽  
Ieda Maria Sapateiro Torres ◽  
Humberto Ruggeri ◽  
Paulo Scalize ◽  
Antonio Albuquerque ◽  
...  

Sanitary landfill leachate (LL) composition varies according to climate variables variation, solid waste characteristics and composition, and landfill age. Leachate treatment is essentially carried out trough biological and physicochemical processes, which have showed variability in efficiency and appear a costly solution for the management authorities. Electrocoagulation (EC) seems a suitable solution for leachate treatment taking into account the characteristics of the liquor. One of the problems of EC is the electrode passivation, which affects the longevity of the process. One solution to this problem could be the replacement of the electrode by one made of recyclable material, which would make it possible to change it frequently and at a lower cost. The objective of the present work was to evaluate the removal of heavy metals (As, Ba, Cd, Cr, Cu, Fe, Pb, Mn, Ni, Se and Zn) and coliforms from a LL by EC using electrodes made from steel swarf (SfE) up to 8 h. Removal efficiencies of detected heavy metals were 51%(Cr), 59%(As), 71%(Cd), 72%(Zn), 92%(Ba), 95%(Ni) and >99%(Pb). The microbial load of coliforms in leachate was reduced from 10.76 × 104 CFU/mL (raw leachate) to less than 1 CFU/mL (after treatment with SfE) (i.e., approximately 100% reduction). The use of SfE in EC of LL is very effective in removing heavy metals and coliforms and can be used as alternative treatment solution for such effluents.


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