Basics of Metals Theory of Extraction by Means of Chemical Water Solutions Filtration through Underground Ores

2014 ◽  
Vol 1020 ◽  
pp. 472-477 ◽  
Author(s):  
Vruyr Sargsyan ◽  
Emil Saratikyan
Keyword(s):  
Molecular Diffusion ◽  
Water Saturation ◽  
Water Injection ◽  
Mining Industry ◽  
Extraction Methods ◽  
Ore Deposits ◽  
Metal Salts ◽  
Chemical Reagents ◽  
Ore Body ◽  
Waste Dumps

Abstract. Geo-technological extraction methods recently are widely used in the mining industry. Removing the metals from underground ore deposits is carried out by injecting chemicals (solvents, oxidants, reducing agents) into wells drilled in them, and the subsequent extraction of metals from saturated solutions. Particularly, this method utilized for the extraction of uranium from flooded sediments and copper from poor (substandard) ores, as well as some non-ferrous and rare metals from waste dumps and tailings of substandard ore mines and processing enterprises. The paper discusses methods developed for prediction of moisture content (water saturation) in rocks under filtration of liquid with incomplete saturation of pores while changing the concentration of the metal in the liquid phase (in an ore body), as well as problems of dissolution and desorption of metal salts on the surface cracks or pores on ore body based on molecular diffusion equation of metal salts. The present work conducted for developing the methods for calculating the liquid filtration through underground deposits of minerals and forecasting of dissolving and washing out metals. It is shown that the processes which take place with the use of chemical reagents are different comparing to the similar processes with water injection. These data allow to predict the changes in the concentration of salts and metals in the liquid and solid phases depending on time.

Mapping Magmatic and Hydrothermal Processes from Routine Exploration Geochemical Analyses

2020 ◽  
Vol 115 (3) ◽  
pp. 489-503 ◽  
Author(s):  
Scott Halley
Keyword(s):  
Inductively Coupled Plasma ◽  
Mining Industry ◽  
Analysis Data ◽  
Ore Deposits ◽  
Mineral Deposits ◽  
Geochemical Data ◽  
High Quality ◽  
Inductively Coupled ◽  
Hydrothermal Processes ◽  
Geochemical Analyses

Abstract Analytical methods used by commercial assay laboratories have improved enormously in recent years. Inductively coupled plasma-atomic emission spectroscopy and inductively coupled plasma-mass spectrometry methods now report analyses for half of the periodic table with exceptional detection limits and precision. It is becoming commonplace for mining companies to use such methods routinely for the analysis of drill samples throughout mineral deposits. Improvements in software and computing power now allow rapid interrogation of upward of 100,000 assay samples. Geochemical analyses are quantitative, are independent of observer bias, and can form the basis for robust geologic and mineralogical models of mineral deposits, as well as shed light on scientific questions. In particular, consistently collected, high-quality geochemical analyses can significantly improve and systematize logging of lithological and hydrothermal alteration mineralogic changes within drill core. In addition, abundant, high-quality geochemical data provide insights into magmatic and hydrothermal processes that were previously difficult to recognize and that have obvious applications to mineral exploration and improved genetic models of ore deposits. This paper describes a workflow that mining industry geologists can apply to their multielement analysis data to extract more information about magma compositions and gangue mineralogy.

scholarly journals Shale volume and permeability of the Miocene unconsolidated turbidite sands of Bonga oil field, Niger delta, Nigeria

2017 ◽  
Vol 5 (1) ◽  
pp. 37 ◽  
Author(s):  
Inyang Namdie ◽  
Idara Akpabio ◽  
Agbasi Okechukwu .E.
Keyword(s):  
Niger Delta ◽  
Gamma Ray ◽  
Water Saturation ◽  
Strong Dependence ◽  
Water Injection ◽  
Oil Field ◽  
Reservoir Properties ◽  
Injection Wells ◽  
Log Data ◽  
Shale Volume

Bonga oil field is located 120km (75mi) southeast of the Niger Delta, Nigeria. It is a subsea type development located about 3500ft water depth and has produced over 330 mmstb of hydrocarbon till date with over 16 oil producing and water injection wells. The producing formation is the Middle to Late Miocene unconsolidated turbidite sandstones with lateral and vertical homogeneities in reservoir properties. This work, analysis the petrophysical properties of the reservoir units for the purpose of modeling the effect of shale content on permeability in the reservoir. Turbidite sandstones are identified by gamma-ray log signatures as intervals with 26-50 API, while sonic, neutron, resistivity, caliper and other log data are applied to estimate volume of shale ranging between 0.972 v/v for shale intervals and 0.0549 v/v for turbidite sands, water saturation of 0.34 v/v average in most sand intervals, porosity range from 0.010 for shale intervals to 0.49 v/v for clean sands and permeability values for the send interval 11.46 to2634mD, for intervals between 7100 to 9100 ft., Data were analyzed using the Interactive Petrophysical software that splits the whole curve into sand and shale zones and estimates among other petrophysical parameters the shale contents of the prospective zones. While Seismic data revealed reservoir thickness ranging from 25ft to over 140ft well log data within the five wells have identified sands of similar thickness and estimated average permeability of700mD. Within the sand units across the five wells, cross plots of estimated porosity, volume of shale and permeability values reveal strong dependence of permeability on shale volume and a general decrease in permeability in intervals with shale volume. It is concluded that sand units with high shale contents that are from0.500 to0.900v/v will not provide good quality reservoir in the field.

scholarly journals Experimental Investigation on Oil Enhancement Mechanism of Hot Water Injection in tight reservoirs

Open Physics ◽  
2016 ◽  
Vol 14 (1) ◽  
pp. 703-713 ◽  
Author(s):  
Hao Yongmao ◽  
Lu Mingjing ◽  
Dong Chengshun ◽  
Jia Jianpeng ◽  
Su Yuliang ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Water Saturation ◽  
Water Injection ◽  
Hot Water ◽  
Water Flooding ◽  
Water Displacement ◽  
Pore Characteristics ◽  
Irreducible Water Saturation ◽  
Tight Reservoirs ◽  
Oil Water

AbstractAimed at enhancing the oil recovery of tight reservoirs, the mechanism of hot water flooding was studied in this paper. Experiments were conducted to investigate the influence of hot water injection on oil properties, and the interaction between rock and fluid, petrophysical property of the reservoirs. Results show that with the injected water temperature increasing, the oil/water viscosity ratio falls slightly in a tight reservoir which has little effect on oil recovery. Further it shows that the volume factor of oil increases significantly which can increase the formation energy and thus raise the formation pressure. At the same time, oil/water interfacial tension decreases slightly which has a positive effect on production though the reduction is not obvious. Meanwhile, the irreducible water saturation and the residual oil saturation are both reduced, the common percolation area of two phases is widened and the general shape of the curve improves. The threshold pressure gradient that crude oil starts to flow also decreases. It relates the power function to the temperature, which means it will be easier for oil production and water injection. Further the pore characteristics of reservoir rocks improves which leads to better water displacement. Based on the experimental results and influence of temperature on different aspects of hot water injection, the flow velocity expression of two-phase of oil and water after hot water injection in tight reservoirs is obtained.

scholarly journals Characterization and Modeling Study on Softening and Seepage Behavior of Weakly Cemented Sandy Mudstone after Water Injection

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Junting Guo ◽  
Teng Teng ◽  
Xiaoyan Zhu ◽  
Yuming Wang ◽  
Zhaolong Li ◽  
...  
Keyword(s):  
Water Saturation ◽  
Water Injection ◽  
Experimental Studies ◽  
Friction Angle ◽  
Engineering Practice ◽  
Permeability Evolution ◽  
Exponential Relationship ◽  
Softening Effect ◽  
Negative Exponential ◽  
Sandy Mudstone

Water injection-induced rock softening and the associated water seepage characteristics are the common and basic problems in underground reservoir construction and the prevention of mine water disaster. In this paper, a series of experimental studies was carried out to investigate these characteristics with the weakly cemented sandy mudstone collected from Shendong Buertai coal mine, China. The characteristics of water softening and the stress-seepage interactions in water-saturated weakly cemented sandy mudstone were directly obtained. Then, a modification method of the constitutive model for rock mass considering the softening effect and a stress-damage-driven model for permeability evolution were established. Research results show that water saturation reduces the tensile strength, compressive strength, and cohesion by 56% and reduces the elastic modulus by 28%. The hydraulic effects on Poisson’s ratio and internal friction angle are negligible. The relationship between the permeability of weakly cemented sandy mudstone with complete compaction deformation is to be divided into three stages of seepage shielding, seepage surge, and seepage recovery. Rock permeability in each stage has a negative exponential relationship with the effective stress. This research provides a theoretical basis for the researches of hydromechanical couplings on weakly cemented sandy mudstone, which is insightful for rock engineering practice.

scholarly journals Characterization and Modeling Study on Softening and Seepage Behavior of Weakly Cemented Sandy Mudstone After Water Injection

2021 ◽  
Author(s):  
Junting Guo ◽  
Teng Teng ◽  
Xiaoyan Zhu ◽  
Yuming Wang ◽  
Zhaolong Li
Keyword(s):  
Water Saturation ◽  
Water Injection ◽  
Friction Angle ◽  
Engineering Practice ◽  
Permeability Evolution ◽  
Exponential Relationship ◽  
Softening Effect ◽  
Hard Roof ◽  
Negative Exponential ◽  
Sandy Mudstone

Abstract Water injection induced rock softening and the associated water seepage characteristics are the common and basic problems in hard roof pressure relief, underground reservoir construction and the prevention of mine water disaster. In this paper, a series of laboratory studies was carried out to investigate these characteristics with the weakly cemented sandy mudstone collected from Shendong Buertai coal mine, China. The characteristics of water softening and the stress-seepage interactions in saturated weekly cemented sandy mudstone were directly obtained. Then a modification method of the constitutive model for rock mass considering the softening effect and a stress-damage-driven model for permeability evolution were established. Research results show that water saturation reduces the tensile strength, compressive strength and cohesion by 56%, and reduces the elastic modulus by 28%. The hydraulic effect on Poisson’s ratio and internal friction angle is negligible. The relationship between the permeability of weakly cemented sandy mudstone with complete compaction deformation is to be divided into three stages of seepage shielding, seepage surge and seepage recovery. Rock permeability in each stage has a negative exponential relationship with the effective stress. This research provides a theoretical basis for the researches of hydro-mechanical couplings on weakly cemented sandy mudstone, which is insightful for rock engineering practice.

Laboratory experiments of water injection coupled with ultrasonic monitoring reveal wave-induced fluid flow in microporous carbonate rock

2021 ◽  
Author(s):  
Davide Geremia ◽  
Christian David ◽  
Christophe Barnes ◽  
Beatriz Menéndez ◽  
Jérémie Dautriat ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Large Scale ◽  
Laboratory Experiments ◽  
Water Saturation ◽  
Water Injection ◽  
Experimental Results ◽  
P Wave ◽  
Propagation Time ◽  
Relaxation Processes ◽  
Ultrasonic Monitoring

<p>Monitoring of fluid movements in the crust is one of the most discussed topics in oil & gas industry as well as in geothermal systems and CO<sub>2</sub> storage, but still remains a challenge. The seismic method is one of the most common ways to detect the fluid migration. However, the use of ultrasonic monitoring at the sample scale in laboratory experiments persists as the most effective way to highlight large scale observations in which the boundary conditions are not well constrained.</p><p>To unravel the fluid effect on P-wave and S-wave velocity, we performed mechanical experiments coupled with ultrasonic monitoring on Obourg chalk from Mons basin (Belgium). Water injection tests under critical loading, imbibition tests and evaporation tests provided a full spectrum of observations of fluid-induced wave alteration in term of propagation time and attenuation.</p><p>The analysis of these experimental results showed that significant velocity dispersion and attenuation developed through variations in water saturation, and that these processes are linked to the presence of patches of water and air in the pore space.</p><p>We used the White’s formulation to model the relaxation effects due to spherical pockets of air homogeneously distributed in a water-saturated medium. In this framework, the pressure induced by the passing wave, produces a fluid flow across the water-air boundary with consequent energy loss.</p><p>This model reproduces both qualitatively and quantitatively the experimental results observed on the water injection tests. Indeed, it is shown that the progressive water saturation or desaturation of this chalk, generates a shift of the critical frequency (from the undrained relaxed towards unrelaxed regimes) which at some point matches the resonance frequency of the piezoelectric transducers used in the experimental setup (0.5 MHz). This phenomenon allowed us to get a continuous recording of the relaxation processes induced by saturation variations.</p><p>The outcomes of this work can significantly improve the actual knowledge on coupled effects of waves and fluids which is a crucial aspect of fluid monitoring in the context of reservoir evaluation and production.</p>

Technological Solutions to Environmental Problems in the Development of Quarries of Copper-Zinc Ore Deposits in the South Urals

2021 ◽  
Vol 25 (1) ◽  
pp. 54-59
Author(s):  
I.V. Zenkov ◽  
E.V. Loginova ◽  
N.E. Gilts ◽  
E.M. Sycheva ◽  
P.M. Kondrashov ◽  
...  
Keyword(s):  
Environmental Problems ◽  
Ore Deposits ◽  
South Urals ◽  
Opencast Mining ◽  
Ecological State ◽  
The South ◽  
Waste Dumps ◽  
Copper Zinc

The results of the study of the ecological state of disturbed lands in the course of opencast mining of copper-zinc ore deposits in the territory of two regions of the South Urals are presented. The necessity of reclamation of waste dumps has been substantiated. Technological and organizational regulations have been developed, the implementation of which will contribute to an increase in the efficiency of work to restore the eco-balance on the waste dumps of mining enterprises.

Re-saturation targets identified from 4D seismic softening responses in the Forties Field

2017 ◽  
Vol 8 (1) ◽  
pp. 473-483 ◽  
Author(s):  
Lyndsay Singer ◽  
Grant Byerley ◽  
Phil Rose
Keyword(s):  
Water Saturation ◽  
Water Injection ◽  
Hydrodynamic Interactions ◽  
Driving Mechanism ◽  
Pressure Measurements ◽  
Softening Effect ◽  
Average Water ◽  
Acoustic Softening ◽  
4D Seismic ◽  
Over Time

AbstractA novel 4D methodology by targeting softening responses, a decrease in impedance over time, is described from the Forties Field. It is demonstrated that these anomalies identified areas where oil had re-saturated previously swept rock. When first observed in some of the older vintages of 4D data, softening responses were dismissed as side lobes of underlying water-swept reservoirs. With improved 4D data quality, softening responses were seen to be clearly responding to an acoustic softening effect isolated in the reservoir. Pressure measurements ruled out hypotheses of gas exsolution or geomechanically induced dilatation of the overlying shale.At the time of writing 22 re-saturation targets had been drilled at Forties with an average water saturation (Sw) of 28%, close to virgin conditions. These results indicated that a previously swept sand can be re-saturated to near initial oil conditions.The driving mechanism behind the re-saturation is understood to be related to changes in both production offtake and water injection. The resulting complex hydrodynamic interactions appeared to be moving banks of oil around the field. From 2011 to year-end of 2015 re-saturation targets produced 14.6 MMBO and were a key target type at the Forties Field.

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