Properties Evaluation of Micro-Crystalline Cellulose and Starch as Bio-Filler in Rubber Compounding

2016 ◽  
Vol 1133 ◽  
pp. 593-597 ◽  
Author(s):  
Mohd Khairulniza Mansor ◽  
Ruslimie Che Ali
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Filler Loading ◽  
Tensile Fracture ◽  
Crystalline Cellulose ◽  
Tensile Fracture Surface ◽  
Homogenous Distribution ◽  
Cure Time ◽  
Internal Mixer ◽  
Scanning Electron

Effects of filler loading on the mechanical properties of Epoxidised natural rubber (ENR) filled with bio-fillers were studied. The compounds with different filler loadings (0, 30, 50, 70 phr) were prepared in a Haake internal mixer. Result showed that the viscosity of the compounds increased with filler loading and exhibited longer cure time with higher loading of the bio-filler. The mechanical properties of starch-filled vulcanisates present better tensile strength at 50 phr when compared to micro-crystalline cellulose (MCC) filled vulcanisates at similar filler loadings. The scanning electron microscopy (SEM) of tensile fracture surface of 50 phr starch-filled vulcanisates illustrated a homogenous distribution in comparison with MCC-filled compounds.

Scanning Electron Microscopy Studies of Nitrile Rubber Fractured Surfaces

1980 ◽  
Vol 53 (2) ◽  
pp. 321-326 ◽  
Author(s):  
A. K. Bhowmick ◽  
S. Basu ◽  
S. K. De
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Fracture Surface ◽  
Polymer Fibers ◽  
Tensile Fracture ◽  
Flow Lines ◽  
Tensile Fracture Surface ◽  
Test Conditions ◽  
Heat Buildup ◽  
Scanning Electron

Abstract The fracture surfaces of a NBR vulcanizate after different test conditions have been studied by scanning electron microscopy. It has been shown that failure surfaces manifest typical characteristics dependent on the nature of the test. Tensile fracture surface shows occurrence of two different tear rates in the case of a filled NBR vulcanizate, while tear fracture is characterized by a few long flow lines. De Mattia flexing leads to layering of polymer fibers. Heat buildup and abrasion tests generate a ribbed structure on the surface.

Effects of Filler Incorporation Routes on Mechanical Properties of Low Density Polyethylene/Natural Rubber/Silica (LDPE/NR/Si) Composites

2014 ◽  
Vol 679 ◽  
pp. 154-157 ◽  
Author(s):  
Pei Ying Teoh ◽  
Abdulbaset Mohamed Erfeida ◽  
Xuan Viet Cao ◽  
Du Ngoc Uy Lan
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Tensile Properties ◽  
Low Density Polyethylene ◽  
Tensile Fracture ◽  
Low Density ◽  
Tensile Fracture Surface ◽  
Roll Mill ◽  
Typical Morphology ◽  
Internal Mixer

Low density polyethylene (LDPE) and natural rubber (NR) filled silica composites were prepared by using internal mixer (Brabender) at 150°C and 50 rpm for 10 minutes. Silica was incorporated into polymer matrix by three mixing routes by using Brabender. In mixing I, filler was added into LDPE/NR blend. In mixing II, filler was added prior to LDPE, which was further compounded with NR. In mixing III, filled was pre-dispersed into NR using two-roll mill, after that the compound is blended with LDPE. The effects of filler incorporation routes on the morphological and tensile properties of prepared composites were studied. Observation from SEM result showed that silica tended to localize in NR phase than LDPE phase in the composite. In addition, silica filled LDPE/NR composite exhibited the highest tensile strength in mixing II and lowest in mixing III. Tensile fracture surface of the composites showed typical morphology of LDPE and NR phase depending on mixing methods. KEYWORDS: LDPE/NR, silica, mixing order, tensile properties, morphology

Microstructure and Mechanical Properties of AZ91D Alloy by Three Types of Forging Process

2019 ◽  
Vol 285 ◽  
pp. 87-91
Author(s):  
Wen Tong Tian ◽  
Hui Yang
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
High Strength ◽  
Tensile Fracture ◽  
Az91d Alloy ◽  
Forging Process ◽  
Highly Uniform ◽  
Fracture Morphologies ◽  
Scanning Electron

Forging processes, such as liquid forging, rheoforging and thixoforging process, were used in this study as an effective method for manufacturing high-strength, finely-dispersed and highly-uniform AZ91D alloy parts. It has been found that although the microstructures of the three forging parts are all composed of α-Mg and β-Mg17Al12 phases, their shapes, sizes, numbers and distributions are all different, which also influences their mechanical properties. The tensile fracture morphologies were observed and their energy spectrums were analyzed by scanning electron microscopy. The results show that the cracks are mainly originated from the brittle fracture of the β-Mg17Al12 eutectic phases, whereas their fracture morphologies are greatly different, which indicate the direction for providing a reasonable forging process.

scholarly journals Microstructure and Mechanical Properties of Al-3 Vol% CNT Nanocomposites Processed by High-Pressure Torsion

2017 ◽  
Vol 62 (2) ◽  
pp. 1109-1112 ◽  
Author(s):  
H. Asgharzadeh ◽  
H.S. Kim
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
High Pressure ◽  
Room Temperature ◽  
High Pressure Torsion ◽  
Tensile Ductility ◽  
Tensile Tests ◽  
Tensile Fracture ◽  
Tensile Fracture Surface ◽  
Transmission Electron

Abstract Al-3 vol% CNT nanocomposites were processed by high-pressure torsion (HPT) at room temperature under the pressure in the range of 2.5-10 GPa for up to 10 turns. Optical microscopy, scanning electron microscopy, and transmission electron microscopy (TEM) were used to investigate the microstructural evolutions upon HPT. Mechanical properties of the HPT-processed disks were studied using tensile tests and microhardness measurements. The results show gradual evolutions in the density, microstructure, and hardness with increasing the number of turns and applied presure. Nanostructured and elongated Al grains with an average grain thickness of ~40 nm perpendicular to the compression axis of HPT and an aspect ratio of ~3 are formed after 10 turns under 6 GPa. Evaluating the mechanical properties of the 10-turn processed Al/CNT nanocomposites indicates a tensile strength of 321 MPa and a hardness of 122 Hv. The tensile fracture surface of the Al/CNT nanocomposite mostly demonstrates a smooth fracture manner with fine dimples resulting in a low tensile ductility of ~1.5%.

Electron Microscopic Observation of the Longitudinal Organization of Poly (p-Phenylene Terephthalamide) Fibers

1982 ◽  
Vol 40 ◽  
pp. 680-681
Author(s):  
Li Li-Sheng ◽  
L.F. Allard ◽  
W.C. Bigelow
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Microscopic Observation ◽  
Electron Microscopic Observation ◽  
Electron Microscopic ◽  
Aromatic Polyamides ◽  
Radial Arrangement ◽  
Scanning Electron ◽  
Better Than

The aromatic polyamides form a class of fibers having mechanical properties which are much better than those of aliphatic polyamides. Currently, the accepted morphology of these fibers as proposed by M.G. Dobb, et al. is a radial arrangement of pleated sheets, with the plane of the pleats parallel to the axis of the fiber. We have recently obtained evidence which supports a different morphology of this type of fiber, using ultramicrotomy and ion-thinning techniques to prepare specimens for transmission and scanning electron microscopy.

scholarly journals Analysis of PLA Composite Filaments Reinforced with Lignin and Polymerised-Lignin-Treated NFC

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2174
Author(s):  
Diana Gregor-Svetec ◽  
Mirjam Leskovšek ◽  
Blaž Leskovar ◽  
Urška Stanković Elesini ◽  
Urška Vrabič-Brodnjak
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Glassy State ◽  
Nanofibrillated Cellulose ◽  
Dynamic Mechanical Properties ◽  
Initial Modulus ◽  
Surface Modified ◽  
Scanning Electron

Polylactic acid (PLA) is one of the most suitable materials for 3D printing. Blending with nanoparticles improves some of its properties, broadening its application possibilities. The article presents a study of composite PLA matrix filaments with added unmodified and lignin/polymerised lignin surface-modified nanofibrillated cellulose (NFC). The influence of untreated and surface-modified NFC on morphological, mechanical, technological, infrared spectroscopic, and dynamic mechanical properties was evaluated for different groups of samples. As determined by the stereo and scanning electron microscopy, the unmodified and surface-modified NFCs with lignin and polymerised lignin were present in the form of plate-shaped agglomerates. The addition of NFC slightly reduced the filaments’ tensile strength, stretchability, and ability to absorb energy, while in contrast, the initial modulus slightly improved. By adding NFC to the PLA matrix, the bending storage modulus (E’) decreased slightly at lower temperatures, especially in the PLA samples with 3 wt% and 5 wt% NFC. When NFC was modified with lignin and polymerised lignin, an increase in E’ was noticed, especially in the glassy state.

scholarly journals Corrosion Behavior and Mechanical Properties of a Nanocomposite Superhydrophobic Coating

Coatings ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 652
Author(s):  
Divine Sebastian ◽  
Chun-Wei Yao ◽  
Lutfun Nipa ◽  
Ian Lian ◽  
Gary Twu
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Atomic Force Microscopy ◽  
Nanocomposite Coating ◽  
Superhydrophobic Coating ◽  
Force Microscopy ◽  
Atomic Force ◽  
Microscopy Images ◽  
Scanning Electron

In this work, a mechanically durable anticorrosion superhydrophobic coating is developed using a nanocomposite coating solution composed of silica nanoparticles and epoxy resin. The nanocomposite coating developed was tested for its superhydrophobic behavior using goniometry; surface morphology using scanning electron microscopy and atomic force microscopy; elemental composition using energy dispersive X-ray spectroscopy; corrosion resistance using atomic force microscopy; and potentiodynamic polarization measurements. The nanocomposite coating possesses hierarchical micro/nanostructures, according to the scanning electron microscopy images, and the presence of such structures was further confirmed by the atomic force microscopy images. The developed nanocomposite coating was found to be highly superhydrophobic as well as corrosion resistant, according to the results from static contact angle measurement and potentiodynamic polarization measurement, respectively. The abrasion resistance and mechanical durability of the nanocomposite coating were studied by abrasion tests, and the mechanical properties such as reduced modulus and Berkovich hardness were evaluated with the aid of nanoindentation tests.

Effect of Sintering Temperature on Microstructure and Mechanical Properties of Al2O3-TiC-ZrO2 Ceramic Composites

2012 ◽  
Vol 476-478 ◽  
pp. 1031-1035
Author(s):  
Wei Min Liu ◽  
Xing Ai ◽  
Jun Zhao ◽  
Yong Hui Zhou
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Fracture Toughness ◽  
Flexural Strength ◽  
Relative Density ◽  
Sintering Temperature ◽  
Ceramic Composites ◽  
X Ray Diffraction ◽  
X Ray ◽  
Scanning Electron

Al2O3-TiC-ZrO2ceramic composites (ATZ) were fabricated by hot-pressed sintering. The phases and microstructure of the composites were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The relative density and mechanical properties (flexural strength, fracture toughness and Vicker’s hardness) of the composites were tested. The results show that the microstructure of the composites was the gray core-white rim. With the increase of sintering temperature, the relative density and mechanical properties of the composites increased first and then decreased. The composite sintered at 1705°C has the highest synthetical properties, and its relative density, flexural strength, fracture toughness and Vickers hardness are 98.3%,970MPa,6.0 MPa•m1/2and 20.5GPa, respectively.

Research on compatibility and surface of high impact bio-based polyamide

2021 ◽  
pp. 095400832110055
Author(s):  
Yang Wang ◽  
Yuhui Zhang ◽  
Yuhan Xu ◽  
Xiucai Liu ◽  
Weihong Guo
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Differential Scanning Calorimetry ◽  
Crystallization Behavior ◽  
High Impact ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Scanning Electron

The super-tough bio-based nylon was prepared by melt extrusion. In order to improve the compatibility between bio-based nylon and elastomer, the elastomer POE was grafted with maleic anhydride. Scanning Electron Microscopy (SEM) and Thermogravimetric Analysis (TGA) were used to study the compatibility and micro-distribution between super-tough bio-based nylon and toughened elastomers. The results of mechanical strength experiments show that the 20% content of POE-g-MAH has the best toughening effect. After toughening, the toughness of the super-tough nylon was significantly improved. The notched impact strength was 88 kJ/m2 increasing by 1700%, which was in line with the industrial super-tough nylon. X-ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC) were used to study the crystallization behavior of bio-based PA56, and the effect of bio-based PA56 with high crystallinity on mechanical properties was analyzed from the microstructure.

Microstructure Evolution and Mechanical Properties of an Al-Cu-Mg Alloy at Elevated Temperature

2014 ◽  
Vol 1004-1005 ◽  
pp. 148-153
Author(s):  
Min Hao ◽  
Ji Gang Ru ◽  
Ming Liu ◽  
Kun Zhang ◽  
Liang Wang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Elevated Temperature ◽  
Elevated Temperatures ◽  
Shear Fracture ◽  
S Phase ◽  
Mg Alloy ◽  
Transmission Electron ◽  
Fracture Features ◽  
Scanning Electron

Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were utilized to study the microstructure and mechanical behavior of an Al-Cu-Mg alloy after tensile test at 125°C, 150°C, 175°C and 200 °C, respectively. The yield strength and ultimate tensile strength decreased with the increase of temperature, while the elongation increased firstly and then decreased. The S and S′ precipitate after tension at elevated temperatures. When the temperature was higher than 175°C, the precipitate coarsens rapidly. The alloys displayed a shear fracture features at elevated temperature. The larger S′ and S phase coarsened and dropped which forming crack in the grain boundaries and precipitate interfaces, resulting in the decrease of the elongation of the alloy.

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