Preparation of Hexaphenylamine Cyclotriphosphazene and its Green Flame Retardance on Epoxy Molding Compound for Large-Scale Integrated Circuit Packaging

2011 ◽  
Vol 239-242 ◽  
pp. 1386-1390
Author(s):  
Ming Shan Yang ◽  
Lin Kai Li

The hexaphenylamine cyclotriphosphazene (HPACTPZ) was synthesized using titrating technology of hexachlorocyclotriphosphazene solution and the synthesis parameters were investigated, and the structure of HPACTPZ was analyzed by FTIR and NMR in this paper. Using HPACTPZ synthesized in the work as flame retardant, the epoxy molding compound(EMC) for packaging of large-scale integrated circuits with halogen-free flame retardance was prepared. The results have shown that the flame retardance of EMC flame-retardanced by HPACTPZ was up to UL 94 V0 rating(3.2mm) and the oxygen index of the EMC was up to 35.8%, which indicates that HPACTPZ has much better flame retardance for EMC than traditional halogen flame-retardants. Meanwhile, HPACTPZ accelerated the curing reaction rate of EMC, which can be used for manufacturing the quick-curing EMCs or afterward-curing-free EMCs.

2011 ◽  
Vol 216 ◽  
pp. 474-478 ◽  
Author(s):  
Ming Shan Yang ◽  
Jian Wei Liu ◽  
Lin Kai Li

The tri(o-phenylenediamine) cyclotriphosphazene (TPCTP) was synthesized using titrating technology of hexachlorocyclotriphosphazene solution and the synthesis parameters were investigated, and the structure of TPCTP was analyzed by FTIR in this paper. Using TPCTP synthesized in the work as flame retardant, the epoxy molding compound(EMC) for packaging of large-scale integrated circuits with halogen-free flame retardance was prepared. The results have shown that the flame retardance of EMC flame-retardanced by TPCTP was up to UL 94 V0 rating(1.6mm) and the oxygen index of the EMC was up to 34.5%, which indicates that TPCTP has much better flame retardance for EMC than traditional halogen flame-retardants. Meanwhile, TPCTP accelerated the curing reaction rate of EMC, which can be used for manufacturing the quick-curing EMCs or afterward-curing-free EMCs.


2014 ◽  
Vol 692 ◽  
pp. 272-276
Author(s):  
Yan Fang Cheng ◽  
Ying Zhou ◽  
Ran Yan ◽  
Yuan Kai Chen ◽  
Ming Liang ◽  
...  

The transparent epoxy molding compound (EMC) for integrated circuits (IC) packaging was prepared by using tetrahydromethyl-1,3-isobenzofurandione as curing agent, respectively using 2-methyl imidazole and triphenyl phosphine as curing accelerator. The effect of curing accelerator type on curing behavior of EMC was investigated by non-isothermal DSC method in this paper. Based on Kissinger method, Crane method and Ozawa method, the kinetic parameters such as activation energy and reaction order of the curing reaction were obtained. The characteristic temperatures of the curing process such as gel temperature, curing temperature and post-curing temperature were calculated by extrapolation. The results showed that EMC with 2-methyl imidazole had a lower activation energy compared to EMC with triphenyl phosphine, which provided the basic data for the optimal recipe of EMC and the determination of IC packaging technologies.


2015 ◽  
Vol 1 (8) ◽  
pp. e1500257 ◽  
Author(s):  
Chuang Zhang ◽  
Chang-Ling Zou ◽  
Yan Zhao ◽  
Chun-Hua Dong ◽  
Cong Wei ◽  
...  

A photonic integrated circuit (PIC) is the optical analogy of an electronic loop in which photons are signal carriers with high transport speed and parallel processing capability. Besides the most frequently demonstrated silicon-based circuits, PICs require a variety of materials for light generation, processing, modulation, and detection. With their diversity and flexibility, organic molecular materials provide an alternative platform for photonics; however, the versatile fabrication of organic integrated circuits with the desired photonic performance remains a big challenge. The rapid development of flexible electronics has shown that a solution printing technique has considerable potential for the large-scale fabrication and integration of microsized/nanosized devices. We propose the idea of soft photonics and demonstrate the function-directed fabrication of high-quality organic photonic devices and circuits. We prepared size-tunable and reproducible polymer microring resonators on a wafer-scale transparent and flexible chip using a solution printing technique. The printed optical resonator showed a quality (Q) factor higher than 4 × 105, which is comparable to that of silicon-based resonators. The high material compatibility of this printed photonic chip enabled us to realize low-threshold microlasers by doping organic functional molecules into a typical photonic device. On an identical chip, this construction strategy allowed us to design a complex assembly of one-dimensional waveguide and resonator components for light signal filtering and optical storage toward the large-scale on-chip integration of microscopic photonic units. Thus, we have developed a scheme for soft photonic integration that may motivate further studies on organic photonic materials and devices.


2013 ◽  
Vol 756-759 ◽  
pp. 533-541
Author(s):  
Zhi Jian Tian ◽  
Fa Yong Zhao

To cope with increasingly rigorous challenges that large scale digital integrated circuit testing is confronted with, a comprehensive compression scheme consisting of test-bit rearrangement algorithm, run-length assignment strategy and symmetrical code is proposed. The presented test-bit rearrangement algorithm can fasten dont-care bits, 0s or 1s in every test pattern on one of its end to the greatest extent so as to lengthen end-run blocks and decrease number of short run-lengths. A dynamical dont-care assignment strategy based on run-lengths can be used to specify the remaining dont-care bits after the test-bit rearrangement, which can decrease run-length splitting and maximize length of run-lengths. The symmetrical code benefits from long run-lengths and only uses 2 4-bit short code words to identify end-run blocks almost as long as a test pattern, and hence the utilization ratio of code words can be heightened. The presented experiment results show that the proposed comprehensive scheme can obtain very higher data compression ratios than other compression ones published up to now, especially for large scale digital integrated circuits, and considerably decrease test power dissipations.


2019 ◽  
Vol 9 (20) ◽  
pp. 4212 ◽  
Author(s):  
Mingqiang Huang ◽  
Xingli Wang ◽  
Guangchao Zhao ◽  
Philippe Coquet ◽  
Bengkang Tay

With the approaching end of Moore’s Law (that the number of transistors in a dense integrated circuit doubles every two years), the logic data density in modern binary digital integrated circuits can hardly be further improved due to the physical limitation. In this aspect, ternary logic (0, 1, 2) is a promising substitute to binary (0, 1) because of its higher number of logic states. In this work, we carry out a systematical study on the emerging two-dimensional (2D) materials (MoS2 and Black Phosphorus)-based ternary logic from individual ternary logic devices to large scale ternary integrated circuits. Various ternary logic devices, including the standard ternary inverter (STI), negative ternary inverter (NTI), positive ternary inverter (PTI) and especially the ternary decrement cycling inverter (DCI), have been successfully implemented using the 2D materials. Then, by taking advantage of the optimized ternary adder algorithm and the novel ternary cycling inverter, we design a novel ternary ripple-carry adder with great circuitry simplicity. Our design shows about a 50% reduction in the required number of transistors compared to the existing ternary technology. This work paves a new way for the ternary integrated circuits design, and shows potential to fulfill higher logic data density and a smaller chip area in the future.


Photonics ◽  
2018 ◽  
Vol 5 (3) ◽  
pp. 21 ◽  
Author(s):  
Charidimos Chaintoutis ◽  
Behnam Shariati ◽  
Adonis Bogris ◽  
Paul Dijk ◽  
Chris Roeloffzen ◽  
...  

Data centers are continuously growing in scale and can contain more than one million servers spreading across thousands of racks; requiring a large-scale switching network to provide broadband and reconfigurable interconnections of low latency. Traditional data center network architectures, through the use of electrical packet switches in a multi-tier topology, has fundamental weaknesses such as oversubscription and cabling complexity. Wireless intra-data center interconnection solutions have been proposed to deal with the cabling problem and can simultaneously address the over-provisioning problem by offering efficient topology re-configurability. In this work we introduce a novel free space optical interconnect solution for intra-data center networks that utilizes 2D optical beam steering for the transmitter, and high bandwidth wide-area photodiode arrays for the receiver. This new breed of free space optical interconnects can be developed on a photonic integrated circuit; offering ns switching at sub-μW consumption. The proposed interconnects together with a networking architecture that is suitable for utilizing those devices could support next generation intra-data center networks, fulfilling the requirements of seamless operation, high connectivity, and agility in terms of the reconfiguration time.


2017 ◽  
Vol 901 ◽  
pp. 012090 ◽  
Author(s):  
Jirayu Tachapitunsuk ◽  
Kessararat Ugsornrat ◽  
Warayoot Srisuwitthanon ◽  
Panakamon Thonglor

1988 ◽  
Vol 144 ◽  
Author(s):  
Han-Tzong Yuan

ABSTRACTThe status and progress of AlGaAs/GaAs heterojunction bipolar transistor integrated circuits are reviewed. The challenge of fabricating large-scale integrated circuits using heterojunction bipolar transistors is discussed. Specifically, the issues related to low defect epitaxial materials, localized impurity doping techniques, simple and reliable ohmic contacts, and multilevel interconnects are examined.


1992 ◽  
Vol 70 (10-11) ◽  
pp. 943-945
Author(s):  
Paul R. Jay.

The last few years have seen a significant emergence of real product applications using gallium arsenide metal semi-conductor field effect transistor technology. These applications range from large volume consumer markets based on small low-cost GaAs integrated circuits to high-end supercomputer products using very large scale integrated GaAs chips containing up to 50 000 logic gates. This situation represents substantial advances in many areas: materials technology, device and integrated circuit process technology, packaging and high speed testing, as well as appropriate system design to obtain maximum benefit from the GaAs technology. This paper reviews some recent commercial successes, and considers commonalities existing between them in the context of recent technological developments.


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