Composite Materials Based on Natural Rubber Modified Epoxy Resin and Sisal Fiber

2011 ◽  
Vol 410 ◽  
pp. 43-46
Author(s):  
Sawitri Srisuwan ◽  
N. Prasoetsopha ◽  
Nitinat Suppakarn ◽  
Pranee Chumsamrong
Keyword(s):  
Impact Strength ◽  
Natural Rubber ◽  
Epoxy Resin ◽  
Flexural Modulus ◽  
Neat Epoxy ◽  
Proton Nuclear Magnetic Resonance ◽  
Sisal Fiber ◽  
Resonance Spectroscopy ◽  
H Nmr ◽  
The Impact

In the present work, bisphenol-A based epoxy resin was blended with methyl methacrylate (MMA)/glycidyl methacrylate (GMA) grafted depolymerized natural rubber (GDNR). GDNR/epoxy resin blend was composite with woven sisal fiber. GDNR was prepared by solution grafting MMA/GMA (90/10 w/w%) onto depolymerized natural rubber (DNR). The occurrence of GDNR was confirmed by proton nuclear magnetic resonance spectroscopy (1H-NMR). Amount of GDNR in the blend was 1 part per hundred resins. Impact strength of epoxy resin was increased by 62% when GDNR was added. Composites of GDNR/epoxy resin and woven sisal fiber were prepared by hand-lay up process. Amounts of woven sisal fiber in the composite were 3, 5 and 7% by weight (wt%). The flexural modulus of the composites was higher than that of neat epoxy resin and increased with increasing amount of woven sisal fiber. Nevertheless, flexural strength of all composites was lower than those of neat epoxy resin and the blend. Compared to neat epoxy resin, the impact strength of the composite containing 7 wt% woven sisal fiber was further increased to 114%.

Effects of Weave Type and Fiber Content on Physical Properties of Sisal Fiber/Epoxy Composites

2010 ◽  
Vol 123-125 ◽  
pp. 1139-1142 ◽  
Author(s):  
Sawitri Srisuwan ◽  
Pranee Chumsamrong
Keyword(s):  
Impact Strength ◽  
Physical Properties ◽  
Epoxy Resin ◽  
Flexural Modulus ◽  
Fiber Content ◽  
Epoxy Composites ◽  
Sisal Fiber ◽  
Pure Epoxy ◽  
Sisal Fibers ◽  
The Impact

In this study, the effects of weave type and fiber content on the physical properties of woven sisal fiber/epoxy composites were investigated. Sisal fibers used in this work were obtained from Nakhon Ratchasima, Thailand. Both untreated and alkali-treated fibers were employed. The woven sisal fibers were manufactured by hand weaving process. The fiber content in sisal fiber/epoxy composites were 3 wt.%, 5 wt.% and 10 wt.%. The composites were cured at room temperatures. In order to determine mechanical properties of the composites, flexural and impact tests were applied. Flexural strength and flexural modulus of all composites were higher than those of pure epoxy resin and tended to increase with increasing fiber content. The impact strength of all composites was lower than that of pure epoxy resin. The composites containing 10 wt.% sisal fibers showed the highest impact strength. There was no definite influence of weave type on flexural properties of the composites. At 3 and 5 wt.% fiber, the composites containing plain weave fibers seemed to show a higher impact strength than the composites containing other weave types.

scholarly journals Performance of Novel Engineered Materials from Epoxy Resin with Modified Epoxidized Natural Rubber and Nanocellulose or Nanosilica

2020 ◽  
Vol 2020 ◽  
pp. 1-11 ◽  
Author(s):  
Aunnuda Lanna ◽  
Montri Suklueng ◽  
Chainuson Kasagepongsan ◽  
Sunisa Suchat
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Natural Rubber ◽  
Epoxy Resin ◽  
Epoxidized Natural Rubber ◽  
Accelerated Weathering ◽  
Gravimetric Analysis ◽  
Degradation Behaviour ◽  
Wear Rates ◽  
The Impact

Performance of new engineered material from epoxy resins with modified epoxidized natural rubber (ENR) and nanofillers were investigated. ENR from renewable natural crop resources is a type of green material with potential to partially substitute or replace and toughen petrochemical-based polymers. Nanocomposites (epoxy resin/ENR/fillers nanoparticles) were characterized with Fourier transform infrared spectroscopy (FTIR), dynamic light scattering (DLS), atomic force microscope (AFM), and scanning electron microscopy (SEM). Comparison of characterized and mechanical properties of nanofiller reinforced with both nanocellulose and nanosilica were studied. The nanocomposites were characterized for their mechanical properties (e.g., impact strength, tensile strength) and thermal degradation behaviour by thermal gravimetric analysis (TGA). Mechanical property investigation results show that, the impact strength of nanocomposites, can be improved by blending in ENR 50 mixed with nanofiller, relative to the baseline nanocomposite mixers. The nanofiller loading in epoxy composite showed the highest improvement in mechanical properties at 0.75 phr (parts per hundred of resin). Effects of accelerated weathering aging were evaluated, and the observed changes were larger with nanosilica than with nanocellulose filler. Here, the accelerated aging increase in tensile properties was found to be 10% after 14 days in both nanofillers, while the other mechanical properties did not change significantly. These nanocomposites are expected to have high wear rates limiting their service life.

scholarly journals MECHANICAL PROPERTIES OF THE VIET NAM SISAL FIBRE REINFORCED POLYPROPYLENE COMPOSITE

2011 ◽  
Vol 14 (2) ◽  
pp. 29-36
Author(s):  
Nieu Huu Nguyen ◽  
Binh Thanh Phan ◽  
Sau Huynh
Keyword(s):  
Mechanical Properties ◽  
Impact Strength ◽  
Loss Modulus ◽  
Flexural Modulus ◽  
Dynamic Mechanical Properties ◽  
Sisal Fiber ◽  
Sisal Fibre ◽  
Dynamic Mechanical ◽  
Sisal Fibers ◽  
The Impact

The static mechanical and dynamic mechanical properties of the treated sisal fiber reinforced polypropylene composites were improved by adding the compatiblizer PPgMA (polypropylene-grafted-maleic anghydride). The mechanical properties of the composites have been evaluated. By increasing PPgMA dosages from 2% and 3.5% by weight of PP matrix; the impact strength of the composites were significantly improved by 27% and 38%; the elongation increased by 21% and 36%; the tensile strength increased by 35% and 95%; the elastic modulus increased by 21% and 94% and the flexural modulus increased by 2% and 83% respectively. The dynamic mechanical properties (the storage modulus E’, the loss modulus E” and the loss factor tanδ) have been investigated in relation to the compatibility between the PP matrix and the treated sisal fibers. E’ and E” increased by increasing dosage of PPgMA and Tg decreased a little when increasing the contents of PPgMA. At higher temperatures, tanδ increased and at lower temperature tanδ decreased when increasing dosage of PPgMA. It is shown that PP/treated sisal fibers/PPgMA composites have shown the effects of cohesion when increasing the PPgMA. The fiber dispersion was studied by the transmission optical microscope (TOM). The morphology of the composites samples fractured by the impact strength tests have been studied using scanning electronic microscopy (SEM). The results show the improvement of the interaction forces between treated sisal fibers and PP matrix at higher levels of PPgMA.

Enhanced toughness and shape memory behaviors of toughed epoxy resin

2012 ◽  
Vol 24 (8) ◽  
pp. 702-709 ◽  
Author(s):  
Chun-Hua Zhang ◽  
Hui-Ge Wei ◽  
Yu-Yan Liu ◽  
Hui-Feng Tan ◽  
Zhanhu Guo
Keyword(s):  
Impact Strength ◽  
Shape Memory ◽  
Epoxy Resin ◽  
Neat Epoxy ◽  
Resin Matrix ◽  
Polypropylene Glycol ◽  
Resin System ◽  
Shape Memory Behavior ◽  
Epoxy Resin System ◽  
The Impact

This paper reports on an approach to enhance the toughness of shape memory epoxy by using polypropylene glycol diglycidyl ether (G) as the toughening agent. The mechanical properties and shape memory behavior of the toughened resin systems with different loading level of G were studied, respectively. Results of the torsional braid analysis (TBA) test indicated that G had good compatibility with the epoxy resin matrix and induced a decrease in the glass transition temperature, Tg, of the toughened systems when compared to that of the neat resin system; and the decrease in Tg scaled with the content of G added in the system. Impact strength tests showed that the impact strength was improved significantly by adding G into the resin system and it increased by a factor of 13.7 for the system with 13 wt.% content of G. In addition, the toughened systems were found to yield during the impact strength test whereas brittle fracture occurred for the neat epoxy resin system; this behavior could be further confirmed by the results of scanning electron microscopy (SEM). In the shape memory behavior tests, strain fixity ratio reached as high as 98.9% for toughened systems with 7, 9, 11, 13, and 15 wt.% of G. Toughened systems also displayed changed shape recovery behavior that was comparable with that of the neat epoxy resin system during shape memory process.

Impact Strength, Flexural Modulus and Wear Rate of PMMA Composites Reinforced by Eggshell Powders

2020 ◽  
Vol 38 (7A) ◽  
pp. 960-966
Author(s):  
Aseel M. Abdullah ◽  
Hussein Jaber ◽  
Hanaa A. Al-Kaisy
Keyword(s):  
Impact Strength ◽  
Wear Rate ◽  
Flexural Modulus ◽  
Matrix Material ◽  
Weight Fraction ◽  
Pure Pmma ◽  
Calcination Process ◽  
The Matrix ◽  
The Impact ◽  
Interface Bond

In the present study, the impact strength, flexural modulus, and wear rate of poly methyl methacrylate (PMMA) with eggshell powder (ESP) composites have been investigated. The PMMA used as a matrix material reinforced with ESP at two different states (including untreated eggshell powder (UTESP) and treated eggshell powder (TESP)). Both UTESP and TESP were mixed with PMMA at different weight fractions ranged from (1-5) wt.%. The results revealed that the mechanical properties of the PMMA/ESP composites were enhanced steadily with increasing eggshell contents. The samples with 5 wt.% of UTESP and TESP additions give the maximum values of impact strength, about twice the value of the pure PMMA sample. The calcination process of eggshells powders gives better properties of the PMMA samples compared with the UTESP at the same weight fraction due to improvements in the interface bond between the matrix and particles. The wear characteristics of the PMMA composites decrease by about 57% with increases the weight fraction of TESP up to 5 wt.%. The flexural modulus values are slightly enhanced by increasing of the ESP contents in the PMMA composites.

Preparation and properties of novel sulfonic graphene oxide–epoxy resin nanocomposites by resin transfer molding process

2016 ◽  
Vol 51 (9) ◽  
pp. 1197-1208 ◽  
Author(s):  
Wei Li ◽  
Hongyu Li ◽  
Xinguo Yang ◽  
Wei Feng ◽  
Hongyun Huang
Keyword(s):  
Graphene Oxide ◽  
Impact Strength ◽  
Epoxy Resin ◽  
Curing Temperature ◽  
Flexural Property ◽  
Oxide Content ◽  
Molding Process ◽  
One Pot ◽  
Epoxy Resin Nanocomposites ◽  
The Impact

This paper reported a facile one-pot strategy for fabrication of sulfonic graphene oxide–epoxy resin nanocomposites. The rheological and thermal properties were employed to characterize the viscosity and the curing temperature of epoxy resin. Fourier transform infrared spectra for sulfonic graphene oxide and nanocomposites indicated that the sulfonic graphene oxide contains chemical cross-linking responsible for better interactions with the epoxy resin. The state of dispersion was evaluated at different scales by still picture camera and scanning electron microscopy (SEM). Tensile property tests indicated that the tensile strength and elasticity modulus of sulfonic graphene oxide–epoxy resin nanocomposites decreased slowly with increasing of sulfonic graphene oxide content. The critical flexural property and impact strength of epoxy resin filled with sulfonic graphene oxide nanocomposites were measured. The content, size, and dispersion state of sulfonic graphene oxide were examined. It was found that the content of sulfonic graphene oxide has greater impact on both flexural property and impact strength of nanocomposites compared with other conditions. For instance, the impact strength increased by 113.0% and the flexural strength and modulus increased by 39.3% and 55.7% using 1 wt.% sulfonic graphene oxide as compared to neat epoxy resin.

Synthesis of Macromolecular Coupling Agent and its Effects on Polystyrene Composites

2014 ◽  
Vol 1053 ◽  
pp. 268-275
Author(s):  
Hong Wen Zhang ◽  
Shi Long Zhou ◽  
Yang Zhang ◽  
Yan Jiang ◽  
Qiang Yu
Keyword(s):  
Composite Materials ◽  
Gel Permeation Chromatography ◽  
Ultraviolet Spectrum ◽  
Butyl Methacrylate ◽  
Coupling Agents ◽  
Resonance Spectroscopy ◽  
H Nmr ◽  
Comprehensive Performance ◽  
Ft Ir ◽  
The Impact

Different molecular weight of block coupling agents with well-defined structures have been synthesized successfully by atom transfer radical polymerization (ATRP) from styrene (St), butyl methacrylate (BMA) and 3-methoxyacryloyl-propyltrimethoxyl silicon (KH-570) are as monomer. The structures and compositions of macromolecular coupling agents have been characterized by means of infrared spectrum (FT-IR), ultraviolet spectrum (UV), nuclear magnetic resonance spectroscopy (1H-NMR) and gel permeation chromatography (GPC). And their effects on the polystyrene/silica (PS/SiO2) composite materials have been studied. The results show that interface compatibility and mechanical properties of composite materials containing macromolecule coupling agents are improved significantly. The composite materials with block macromolecular coupling agents possess more excellent comprehensive performance. Furthermore, the impact strength increased by 110% when comparing with composite materials which are not modified by the coupling agents.

Hybrid effects of carbon fiber and nanoclay as fillers on the performances of recycled wood-plastic composites

BioResources ◽  
2020 ◽  
Vol 15 (4) ◽  
pp. 7671-7686
Author(s):  
Young-Rok Seo ◽  
Sang-U Bae ◽  
Birm-June Kim ◽  
Min Lee ◽  
Qinglin Wu
Keyword(s):  
Carbon Fiber ◽  
Impact Strength ◽  
Carbon Fibers ◽  
Synergistic Effects ◽  
Flexural Modulus ◽  
Tensile Modulus ◽  
Raw Material ◽  
Scanning Electron Micrographs ◽  
Plastic Composite ◽  
The Impact

Waste wood-plastic composite (WPC) was used in this work as a raw material to produce recycled WPCs reinforced with carbon fiber and nanoclay. To evaluate the synergistic effects of carbon fiber and nanoclay, various performances (i.e., microstrucural, mechanical, thermal, water absorption, and electrical properties) were investigated. Scanning electron micrographs and X-ray diffraction analysis of the fillers (carbon fiber and nanoclay) present in the recycled WPCs showed that the nanoclays were properly intercalated when filled with carbon fibers. According to mechanical property analysis, hybrid incorporation of carbon fibers and nanoclays improved impact strength, tensile strength, and flexural strength. However, further incorporation of nanoclays reduced the impact strength and did not improve the tensile modulus or the flexural modulus. The carbon fibers present in the recycled WPCs improved the electrical conductivity of the composites, despite the various fillers that interfered with their electrical conduction. In addition, carbon fibers and nanoclays were mixed into the recycled WPCs to improve the thermal stability of the composites. Finally, the presence of nanoclays in recycled WPCs led to increased water uptake of the composites.

scholarly journals 1 H-NMR metabolomic study of whole blood from hatchling loggerhead sea turtles ( Caretta caretta ) exposed to crude oil and/or Corexit

2017 ◽  
Vol 4 (11) ◽  
pp. 171433 ◽  
Author(s):  
Stasia A. Bembenek Bailey ◽  
Jennifer N. Niemuth ◽  
Patricia D. McClellan-Green ◽  
Matthew H. Godfrey ◽  
Craig A. Harms ◽  
...  
Keyword(s):  
Crude Oil ◽  
Whole Blood ◽  
Sea Turtles ◽  
Caretta Caretta ◽  
Proton Nuclear Magnetic Resonance ◽  
Resonance Spectroscopy ◽  
Loggerhead Sea Turtles ◽  
Blood Samples ◽  
H Nmr ◽  
Whole Blood Samples

We used proton nuclear magnetic resonance spectroscopy ( 1 H-NMR) to evaluate metabolic impacts of environmentally relevant crude oil and Corexit exposures on the physiology of hatchling loggerhead sea turtles ( Caretta caretta ). Sample extraction and data acquisition methods for very small volume whole blood samples and sources of variation between individual hatchlings were assessed. Sixteen unclotted, whole blood samples were obtained from 7-day-old hatchlings after a 4-day cutaneous exposure to either control seawater, crude oil, Corexit 9500A or a combination of crude oil and Corexit 9500A. After extraction, one- and two-dimensional 1 H-NMR spectra of the samples were obtained, and 17 metabolites were identified and confirmed in the whole blood spectra. Variation among samples due to the concentrations of metabolites 3-hydroxybutyrate, lactate, trimethylamine oxide and propylene glycol did not statistically correlate with treatment group. However, the characterization of the hatchling loggerhead whole blood metabolome provides a foundation for future metabolomic research with sea turtles and a basis for the study of tissues from exposed hatchling sea turtles.

scholarly journals Preparation and properties of flame-retardant epoxy resins containing reactive phosphorus flame retardant

2020 ◽  
Vol 15 ◽  
pp. 155892502090132
Author(s):  
Sang-Hoon Lee ◽  
Seung-Won Oh ◽  
Young-Hee Lee ◽  
Il-Jin Kim ◽  
Dong-Jin Lee ◽  
...  
Keyword(s):  
Impact Strength ◽  
Flame Retardant ◽  
Epoxy Resin ◽  
Flame Retardancy ◽  
Epoxy Resins ◽  
Phosphorus Content ◽  
Phosphorus Compound ◽  
Phosphorus Compounds ◽  
Limiting Oxygen Index ◽  
The Impact

To prepare flame-retardant epoxy resin, phosphorus compound containing di-hydroxyl group (10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ) was reacted with uncured epoxy resin (diglycidyl ether of bisphenol A, YD-128) and then cured using a curing agent (dicyandiamide, DICY). This study focused on the effect of phosphorus compound/phosphorus content on physical properties and flame retardancy of cured epoxy resin. The thermal decomposition temperature of the cured epoxy resins (samples: P0, P1.5, P2.0, and P2.5, the number represents the wt% of phosphorus) increased with increasing the content of phosphorus compound/phosphorus (0/0, 19.8/1.5, 27.8/2.0, and 36.8/2.5 wt%) based on epoxy resin. The impact strength of the cured epoxy resin increased significantly with increasing phosphorus compound content. As the phosphorus compound/phosphorus content increased from 0/0 to 36.8/2.5 wt%, the glass transition temperature (the peak temperature of loss modulus curve) increased from 135.2°C to 142.0°C. In addition, as the content of phosphorous compound increased, the storage modulus remained almost constant up to higher temperature. The limiting oxygen index value of cured epoxy resin increased from 21.1% to 30.0% with increasing phosphorus compound/phosphorus content from 0/0 to 36.8/2.5 wt%. The UL 94 V test result showed that no rating for phosphorus compounds less than 19.8 wt% and V-1 for 27.8 wt%. However, when the phosphorus compound was 36.8 wt%, the V-0 level indicating complete flame retardancy was obtained. In conclusion, the incorporation of phosphorus compounds into the epoxy chain resulted in improved properties such as impact strength and heat resistance, as well as a significant increase in flame retardancy.

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