Use KMnO4 to Control Bromate Formation during Drinking Water Ozonation: Influencing Factors

2012 ◽  
Vol 499 ◽  
pp. 405-408
Author(s):  
Xu Kang ◽  
Guang Ming Zhang

This formation of bromate during ozonation of polluted source water has long caused great concerns. This paper used KMnO4 to control the bromate formation during water ozonation. KMnO4 was added 10 min prior ozone to oxidize the organic pollutants. The initial Br- concentration was 1000 μg/L. The results showed that the bromate formation efficiency was low (<5%) during KMnO4-ozone oxidation. Among KMnO4 dose, ozone dose, and source water TOC, the single most important factor for bromate formation was the ozone dose. When the ozone dose was 3 mg/L or higher, the bromate concentration exceeded the national standard no matter what level of KMnO4 was used. The organic pollution level had little influence on the bromate formation.

2019 ◽  
Vol 98 ◽  
pp. 09029
Author(s):  
Ying Sun ◽  
Jinlong Zhou ◽  
Yinzhu Zhou ◽  
Yanyan Zeng ◽  
Yunfei Chen

To study the status and influencing factors of groundwater organic pollution around the Bosten Lake area (Kaidu River-Kongque River Basin), Xinjiang, China, the pollution index method was applied to 82 groundwater samples and 15 lake water samples for comprehensive pollution evaluation. Results showed that the detection rates of organic pollutants in groundwater and lake water samples in the study area are 24.4% and 6.7%, respectively, but all the water samples have concentrations of organic pollutants less than the standard water quality limits. There are 11 unpolluted groundwater samples, 8 mildly polluted groundwater samples and one mid-polluted groundwater sample, accounting for 13.4%, 9.8% and 1.2% of total groundwater samples, respectively. The detection points of groundwater organic pollutants in the study area are mainly distributed in the piedmont plain area in the northern Yanqi Basin, the Yanqi County and the northwestern plain area of Bosten Lake. Some points sporadically distributed in the urban area in Korla. Groundwater organic pollution around the Bosten Lake area is mainly affected by industrial pollution, agricultural pollution, domestic pollution, vadose zone lithology, surface water quality and land utilization type.


2012 ◽  
Vol 499 ◽  
pp. 152-155
Author(s):  
Guang Ming Zhang ◽  
Qian Qing Shen

A novel three-stage catalytic ozonation-BAC process is proposed to treat highly polluted source water. A pilot study of 120 m3/d was performed in south China and lasted 9 months. The results showed that catalysts improved the THMsFP reduction efficiency by around 18% for BAC step and reduced the effluent bromate by 20%-77%; reduced NH4-N to below 1 mg/L; The effluent COD met the national standard under all circumstances.


2010 ◽  
Vol 113-116 ◽  
pp. 784-787
Author(s):  
Chang Long Pang ◽  
Fang Ma ◽  
Li Wang ◽  
Li Wei

Conventional drinking water treatment has low removal efficiencies for micro-organic pollutants, which made it important to study new technologies of water treatment. The purification efficiency and mechanisms of micro polluted drinking water by Ozone/Immobilized Biological Activated Carbon (O3/IBAC) was investigated. The GAC (Granular Activated Carbon) has become IBAC by using the twelve strains of efficient engineering bacterium. A GC/MS analysis revealed that conventional treatment processes could not remove micro-organic pollutants efficiently. The O3-IBAC has a high performance of the organic pollutants removal. 16 kinds of the organic pollutants have been removed completely after the process of IBAC, and the variety of the typical toxic pollutants has decreased from 6 to 2. The amount of the total organic pollutants of the IBAC effluent has decreased 89.7% while that in the conventional treatment effluent was less than 40%. The safety and health of drinking water can be ensured by the O3-IBAC process.


2020 ◽  
Vol 21 (1) ◽  
pp. 68-78
Author(s):  
Nusa Idaman Said ◽  
Wahyu Widayat ◽  
Rudi Nugroho

ABSTRACTSurabaya River is a source of raw water for the needs of the community in Surabaya and its surrounding areas, including for industrial and the Surabaya water supply company. Along with the rapid growth of settlements and the development of the industrial sector, the Surabaya River pollution level has increased so that the quality of the water does not meet the quality standards required as raw water for drinking water. The most potential parameter that causes the level of pollution is organic pollutants. The concentration of some water quality parameters including organic pollutants in the Surabaya River has exceeded class I water quality standards based on Government Regulation (PP) No. 82 of 2001, namely for allotment of raw water for drinking water. The purpose of this study was to improve the raw water quality such as parameters of suspended solids (TSS), organic substances, detergents and manganese (Mn) through the application of biofilter technology. The study was conducted by operating a biofilter pilot plant consisting of a lamella-type settling tank and a biofilter reactor filled with wasp-type nesting media. The results showed that the biofilter process used can reduce the concentration of TSS, organic matter, detergents and Mn in raw water. In general, the longer the hydraulic residence time (HRT) in the biofilter pilot plant, the greater the efficiency of removing TSS, organic matter, and detergent in raw water. The experiments results at the conditions of the shortest total HRT of 81 minutes, including HRT of 36 minutes in the settling tank and HRT of 45 minutes in the biofilter reactor, could obtain TSS removal efficiency of 46.92%, 15.97% for organic matter, and 55% for detergent, where the concentration of these parameters meets the quality standards for drinking water.Keywords: biofiltration, HRT, drinking water, water qualityABSTRAKSungai Surabaya merupakan sumber air baku untuk kebutuhan masyarakat di wilayah Surabaya dan sekitarnya, termasuk untuk kebutuhan industri dan air baku PDAM kota Surabaya. Seiring pesatnya pertumbuhan pemukiman dan perkembangan sektor industri, mengakibatkan tingkat pencemaran Sungai Surabaya semakin tinggi sehingga kualitas airnya tidak memenuhi ketentuan baku mutu yang dipersyaratkan sebagai air baku air minum. Parameter yang paling potensial menyebabkan tingkat pencemaran tersebut adalah polutan organik. Konsentrasi beberapa parameter kualitas air termasuk polutan organik di sungai Surabaya telah melebihi baku mutu air kelas I berdasarkan Peraturan Pemerintah (PP) No 82 tahun 2001, yakni untuk peruntukan air baku air minum. Tujuan dari penelitian ini adalah untuk melakukan peningkatan kualitas air baku seperti parameter padatan tersuspensi (TSS), zat organik, deterjen dan mangan (Mn) melalui penerapan teknologi biofilter. Penelitian dilakukan dengan mengoperasikan pilot plant biofilter yang terdiri dari bak pengendap tipe lamella dan reaktor biofilter yang diisi dengan media plastik tipe sarang tawon. Hasil penelitian menujukkan bahwa proses biofilter yang digunakan dapat menurunkan konsentrasi TSS, zat organik, deterjen dan Mn di dalam air baku. Secara umum semakin lama waktu tinggal di dalam pilot plant biofilter, efisiensi penghilangan TSS, zat organik, dan deterjen di dalam air baku semakin besar. Hasil percobaan pada kondisi total waktu tinggal terpendek (total HRT) 81 menit, meliputi HRT di bak pengendap 36 menit dan HRT di reaktor biofilter 45 menit, didapatkan efisensi penghilangan TSS 46,92 %, zat organik 15,97 %, dan deterjen 55 %, dimana konsentrasi parameter-parameter tersebut memenuhi baku mutu untuk air minum.Kata kunci: biofiltrasi, HRT, air minum, kualitas air


2006 ◽  
Vol 6 (2) ◽  
pp. 125-130
Author(s):  
C.-H. Hung ◽  
K.-H. Tsai ◽  
Y.-K. Su ◽  
C.-M. Liang ◽  
M.-H. Su ◽  
...  

Due to the extensive application of artificial nitrogen-based fertilizers on land, groundwater from the central part of Taiwan faces problems of increasing concentrations of nitrate, which were measured to be well above 30 mg/L all year round. For meeting the 10 mg/L nitrate standard, optimal operations for a heterotrophic denitrification pilot plant designed for drinking water treatment was investigated. Ethanol and phosphate were added for bacteria growing on anthracite to convert nitrate to nitrogen gas. Results showed that presence of high dissolved oxygen (around 4 mg/L) in the source water did not have a significantly negative effect on nitrogen removal. When operated under a C/N ratio of 1.88, which was recommended in the literature, nitrate removal efficiency was measured to be around 70%, sometimes up to 90%. However, the reactor often underwent severe clogging problems. When operated under C/N ratio of 1.0, denitrification efficiency decreased significantly to 30%. Finally, when operated under C/N ratio of 1.5, the nitrate content of the influent was almost completely reduced at the first one-third part of the bioreactor with an overall removal efficiency of 89–91%. Another advantage for operating with a C/N ratio of 1.5 is that only one-third of the biosolids was produced compared to a C/N value of 1.88.


Author(s):  
Chen-Jing Sun ◽  
Li-Ping Zhao ◽  
Rui Wang

: With the development of industrialization, the global environmental pollution and energy crisis are becoming increasingly serious. Organic pollutants pose a serious health threat to human beings and other organisms. The removal of organic pollutants in environment has become a global challenge. The photocatalytic technology has been widely used in the degradation of organic pollutants with its characteristics of simple process, high efficiency, thorough degradation and no secondary pollution. However, the single photocatalyst represented by TiO2 has disadvantages of low light utilization rate and high recombination rate of photocarriers. Building heterojunction is considered one of the most effective methods to enhance the photocatalytic performance of single photocatalyst, which can improve the separation efficiency of photocarriers and utilization of visible light. The classical heterojunction can be divided into four different cases: type I, typeⅡ, p–n heterojunctions and Z-scheme junction. In this paper, the recent progress in the treatment of organic pollution by heterostructure photocatalysts is summarized and the mechanism of heterostructure photocatalysts for the treatment of organic pollutants is reviewed. It is expected that this paper can deepen the understanding of heterostructure photocatalysts and provide guidance for high efficient photocatalytic degradation of organic pollutants in the future.


2018 ◽  
Vol 16 (2) ◽  
pp. 84
Author(s):  
G A Blagodatsky ◽  
A A Bass ◽  
M M Gorokhov ◽  
D S Ponomarev

Работа посвящена системному анализу данных показателей исходной воды при производстве питьевой воды в системе центрального водоснабжения крупного населенного пункта. На сегодняшний день на фоне увеличивающегося негативного антропогенного воздействия на окружающую среду наблюдается ухудшение состояния многих источников питьевого водоснабжения в широком спектре показателей, в частности, таких как органолептические свойства воды. Как следствие, возникает проблема и для питьевой воды. В работе приводится процесс подготовки данных о параметрах исходной воды, забираемой из водохранилища, которые ежемесячно (с 2002 по 2014 год) учитывались на предприятии при дезодорации воды. Приведенные параметры оказывают существенное влияние на органолептические свойства конечной воды. Подготовка данных для анализа проводится методом главных компонент К. Пирсона. Данные, полученные в пространстве R9, переводятся в пространство меньшей размерности R3. Понижение размерности позволяет снизить автокорреляцию между компонентами. Отбор компонент в пространство R3 проводится по правилу Парето. В пространстве R3 методом сферической кластеризации данных «Форель» с постоянным радиусом группировки проводится кластеризация. Приводится пошаговое визуальное представление алгоритма кластеризации в пространстве R3. В работе показано, что в данных показателях качества исходной воды имеются кластеры. Проводится корреляционно-регрессионный анализ данных, представленных в главных компонентах. Строятся регрессионные зависимости показателей органолептических свойств от главных компонент из пространства R3.


Author(s):  
Jordan Roszell ◽  
Po-Shun Chan ◽  
Brian Petri ◽  
Ted Mao ◽  
Kathleen Nolan ◽  
...  

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