Emulsion Fuels Production between Diesel and Bio-Oil Middle Fraction from Molecular Distillation

2012 ◽  
Vol 534 ◽  
pp. 151-155 ◽  
Author(s):  
Xiang Yu Wang ◽  
Zuo Gang Guo ◽  
Shu Rong Wang

In this paper, emulsification study on bio-oil middle fraction and diesel was carried out. Mechanical and ultrasound emulsification technologies were used to prepare emulsion fuels between bio-oil middle fraction and diesel with different hydrophile and lipophile balance (HLB) values. It was found that the stability curve of emulsions had two peaks corresponding to the HLB values of 4.3 and 6, respectively. Comparable to the mechanical emulsions, the ultrasound emulsions had longer stable time. The stable time for ultrasound emulsions at the HLB values of 4.3 and 6 were 215 minutes and 143 minutes, respectively. Then the effects of surface tension and droplet size distribution on the stability of emulsions were investigated. It was found that the emulsion fuels with lower surface tension and smaller droplet size had longer stable time.

2021 ◽  
Vol 117 (3) ◽  
pp. 1
Author(s):  
Donyo Hristov GANCHEV

<p class="042abstractstekst">The investigation about surface tension of water used for preparation of pesticide solutions reveals it is quite diverse and changeable without any logical correlation towards location, time, and type of water source. Moreover, spraying with solutions with lower surface tension give bigger flow rates due to the lower resistance of fluid to the nozzles. The conducted trials show that plant surfaces with more rough texture require to be sprayed with pesticide solutions with lower surface tension. The wax content of the surfaces has no significant impact on surface tension requirement.</p><p> </p>


2018 ◽  
Vol 844 ◽  
pp. 162-186 ◽  
Author(s):  
Abdulrahman B. Aljedaani ◽  
Chunliang Wang ◽  
Aditya Jetly ◽  
S. T. Thoroddsen

We investigate experimentally the breakup of the Edgerton crown due to Marangoni instability when a highly viscous drop impacts on a thin film of lower-viscosity liquid, which also has different surface tension than the drop liquid. The presence of this low-viscosity film modifies the boundary condition, giving effective slip to the drop along the solid substrate. This allows the high-viscosity drop to form a regular bowl-shaped crown, which rises vertically away from the solid and subsequently breaks up through the formation of a multitude of Marangoni holes. Previous experiments have proposed that the breakup of the crown results from a spray of fine droplets ejected from the thin low-viscosity film on the solid, e.g. Thoroddsen et al. (J. Fluid Mech., vol. 557, 2006, pp. 63–72). These droplets can hit the inner side of the crown forming spots with lower surface tension, which drives a thinning patch leading to the hole formation. We test the validity of this assumption with close-up imaging to identify individual spray droplets, to show how they hit the crown and their lower surface tension drive the hole formation. The experiments indicate that every Marangoni-driven patch/hole is promoted by the impact of such a microdroplet. Surprisingly, in experiments with pools of higher surface tension, we also see hole formation. Here the Marangoni stress changes direction and the hole formation looks qualitatively different, with holes and ruptures forming in a repeatable fashion at the centre of each spray droplet impact. Impacts onto films of the same liquid, or onto an immiscible liquid, do not in general form holes. We furthermore characterize the effects of drop viscosity and substrate-film thickness on the overall evolution of the crown. We also measure the three characteristic velocities associated with the hole formation: i.e. the Marangoni-driven growth of the thinning patches, the rupture speed of the resulting thin films inside these patches and finally the growth rate of the fully formed holes in the crown wall.


1997 ◽  
Vol 273 (5) ◽  
pp. L907-L912 ◽  
Author(s):  
N. J. Gross ◽  
R. Veldhuizen ◽  
F. Possmayer ◽  
R. Dhand

A serine-active enzyme, “surfactant convertase,” is required for the conversion of surfactant from the tubular myelin (TM) form to the small vesicular (SV) form. This transformation involves at least two steps, the conversion of TM to a surface-active film at the air-fluid interface and the reorientation of the film into the surface-inactive SV form; we asked if convertase was required for the first of these steps. Rat and mouse TMs were pretreated with diisopropyl fluorophosphate (DFP) to inactivate endogenous convertase activity or with vehicle and then were analyzed for their ability to lower surface tension in vitro as an index of the conversion of TM to a surface film. DFP pretreatment did not alter the ability of TM preparations to lower surface tension, as assessed by pulsating bubble, and it did not affect the behavior of TM in a surface balance. In an experiment designed to test the ability of TM to feed a surface film to exhaustion, TMs that had been pretreated with DFP or vehicle performed similarly. These experiments show that convertase activity is not required for the conversion of TM to a monolayer and suggest, instead, that convertase acts at a post surface film stage.


Langmuir ◽  
1996 ◽  
Vol 12 (10) ◽  
pp. 2570-2579 ◽  
Author(s):  
Aldert R. van Buuren ◽  
D. Peter Tieleman ◽  
Jacob de Vlieg ◽  
Herman J. C. Berendsen

2011 ◽  
Vol 347-353 ◽  
pp. 2709-2712 ◽  
Author(s):  
Zuo Gang Guo ◽  
Qian Qian Yin ◽  
Shu Rong Wang

Ultrasound was adopted to prepare emulsion fuels between bio-oil and 0# diesel. The effects of ultrasound power and treating time on the stability of emulsion fuels were investigated. Excellent stability with stable time as long as 35 hours was obtained under an ultrasound power of 80W and a treating time of 3 minutes. Malvern nanometer particle size analyzer (Zetasizer Nano S90) was used to study the droplet size of emulsion fuels. The emulsion fuels with smaller droplet size had longer stable time. And the droplet size of the optimal emulsion fuel was around 0.4 um.


1922 ◽  
Vol 35 (4) ◽  
pp. 575-597 ◽  
Author(s):  
P. Lecomte du Noüy

1. Over 3,000 measurements of surface tension of sera have been made with the ring method, and they have yielded a new phenomenon, the spontaneous and rapid decrease of the surface tension of a serum in function of the time. 2. Generally, after 10 minutes the surface tension reaches a value which is practically constant. At least, the decrease is very much slower. After stirring, a rise occurs and a similar phenomenon takes place; but stability is not obtained as rapidly, requiring about 25 minutes. By stirring again, the same thing happens repeatedly, the slope of the curve being less marked each time, the rise in surface tension being slightly below each previous value, and the phenomenon undergoing a sort of damping. 3. An equation was established which expresses the experimental facts with an accuracy of about 0.2 per cent. It applies to the whole phenomenon, before and after stirring. It has only one characteristic constant, See PDF for Equation This formula, by simply changing t to c (concentration), expresses satisfactorily in general the phenomenon of adsorption in the surface layer; that is, the decrease in surface tension in function of the concentration. 4. Prolonged heat, at 55°C., and time seem to inhibit this phenomenon. 5. When precipitation occurs in a serum, the bottom of the liquid, which contains the precipitate, has the highest surface tension. When stirred, the surface tension rises a little every time. The upper part, clear, with lower surface tension, shows the reverse phenomenon; after every stirring, the surface tension becomes a little lower.


Agronomy ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1321
Author(s):  
Estefania Gomiero Polli ◽  
Guilherme Sousa Alves ◽  
Joao Victor de Oliveira ◽  
Greg Robert Kruger

Dicamba plus glyphosate tank mixture have been largely adopted for postemergence weed control after the development of dicamba-tolerant crops. Ammonium sulfate is commonly used as water conditioner (WC) to increase glyphosate efficacy, but its use is restricted for dicamba herbicides. The use of non-AMS water conditioner and other adjuvants could be a way to optimize efficacy of this tank mixture while mitigating herbicide off-target movement. The objective of this study was to determine the physical–chemical properties and droplet size distribution of dicamba and glyphosate solutions with and without non-AMS WC alone and tank mixed with other adjuvants and evaluate the response of weed species to these solutions under greenhouse and field conditions. The adjuvants mostly increased density and viscosity and decreased contact angle and surface tension of herbicide solutions. In presence of WC, except for the adjuvants containing drift reducing agent, Dv0.5 decreased with the addition of adjuvants. Under greenhouse conditions, biomass reduction increased up to 47 and 33 percentage points for velvetleaf and c. waterhemp when adjuvants were added to solutions without WC, respectively. No increase in control of horseweed and Palmer amaranth was observed with the use of adjuvants under field conditions.


1991 ◽  
Vol 29 (12) ◽  
pp. 46.1-46

It has been known for about 30 years that lack of surface tension reducing substances (‘surfactant’) in the lungs of premature infants is largely responsible for the development of hyaline membrane disease or respiratory distress syndrome (RDS). About 50% of premature babies develop RDS, characteristically showing tachypnoea, chest retractions and worsening cyanosis. Many babies die of it or suffer complications. Mechanical ventilation is the main treatment, supporting respiratory function until maturing alveolar lining cells synthesise adequate surfactant. Despite its inherent risks it has proved very successful, but drugs which can lower surface tension in the lungs may improve outcome further.


1996 ◽  
Vol 11 (6) ◽  
pp. 313-325 ◽  
Author(s):  
Elisabeth A. Mates ◽  
Jacob Hildebrandt ◽  
Jacob Hildebrandt

Liquid Ventilation with perfluorochemicals (PFC) violates many of our long-held assumptions about how the lung functions. However, the technique has been so successful in animal models of lung disease that it is currently being tested in clinical trials for the treatment of infant and acute (“adult”) respiratory distress syndrome in newborns, children, and adults. A common feature of both infant and acute respiratory distress syndromes is an inability of the lung's surfactant system to adequately lower surface tension, leading to regions of atelectasis. Liquid ventilation with PFC appears to ameliorate the disease process by lowering interfacial tension in the lung, opening regions of atelectasis, and improving gas exchange. To understand how gas exchange is successful during liquid ventilation requires careful re-evaluation of the assumptions underlying our current models of gas exchange physiology during normal gas ventilation. These assumptions must then be examined in light of the alterations in pulmonary physiology during liquid ventilation.


ChemPhysChem ◽  
2014 ◽  
Vol 15 (13) ◽  
pp. 2834-2843 ◽  
Author(s):  
M. Soledade C. S. Santos ◽  
João Carlos R. Reis

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