Activities of Activated Sludge Affected by Pharmaceutical Wastewater in a Membrane Bioreactor

2012 ◽  
Vol 610-613 ◽  
pp. 1426-1431 ◽  
Author(s):  
Yuan Hong Ding ◽  
Qing Wang ◽  
Hong Qiang Ren
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Organic Compounds ◽  
Membrane Bioreactor ◽  
Ammonia Nitrogen ◽  
Nitrifying Bacteria ◽  
Pharmaceutical Wastewater ◽  
Submerged Membrane Bioreactor ◽  
High Concentrations ◽  
Final Effluent

a submerged membrane bioreactor was used to treat the effluent of a pharmaceutical wastewater treatment system, the treated water is rich in ammonia nitrogen and organic compounds (NH4-N, averaged in 78.1 mg/L; COD, averaged in 189.5 mg/L), the final effluent of membrane bioreactor was stably below 50 mg/L COD and 40 mg/L NH4-N respectively, the activity of nitrifying bacteria was inhibited by high concentrations of organic compounds and ammonia nitrogen, a rapid declination of filtration was probably resulted form high concentrations of organic compounds and biomass.

High-strength nitrogen removal of opto-electronic industrial wastewater in membrane bioreactor - a pilot study

2003 ◽  
Vol 48 (1) ◽  
pp. 191-198 ◽  
Author(s):  
T.K. Chen ◽  
C.H. Ni ◽  
J.N. Chen ◽  
J. Lin
Keyword(s):  
Wastewater Treatment ◽  
Industrial Wastewater ◽  
Organic Nitrogen ◽  
Membrane Bioreactor ◽  
High Strength ◽  
Experimental Period ◽  
Ammonia Nitrogen ◽  
Nitrifying Bacteria ◽  
Biological Degradation ◽  
The Past

The membrane bioreactor (MBR) system has become more and more attractive in the field of wastewater treatment. It is particularly attractive in situations where long solids retention times are required, such as nitrifying bacteria, and physical retention critical to achieving more efficiency for biological degradation of pollutant. Although it is a new technology, the MBR process has been applied for industrial wastewater treatment for only the past decade. The opto-electronic industry, developed very fast over the past decade in the world, is high technology manufacturing. The treatment of the opto-electronic industrial wastewater containing a significant quantity of organic nitrogen compounds with a ratio over 95% in organic nitrogen (Org-N) to total nitrogen (T-N) is very difficult to meet the discharge limits. This research is mainly to discuss the treatment capacity of high-strength organic nitrogen wastewater, and to investigate the capabilities of the MBR process. A 5 m3/day capacity of MBR pilot plant consisted of anoxic, aerobic and membrane bioreactor was installed for evaluation. The operation was continued for 150 days. Over the whole experimental period, a satisfactory organic removal performance was achieved. The COD could be removed with an average of over 94.5%. For TOC and BOD5 items, the average removal efficiencies were 96.3 and 97.6%, respectively. The nitrification and denitrification was also successfully achieved. Furthermore, the effluent did not contain any suspended solids. Only a small concentration of ammonia nitrogen was found in the effluent. The stable effluent quality and satisfactory removal performance mentioned above were ensured by the efficient interception performance of the membrane device incorporated within the biological reactor. The MBR system shows promise as a means of treating very high organic nitrogen wastewater without dilution. The effluent of TKN, NOx-N and COD can fall below 20 mg/L, 30 mg/L and 50 mg/L.

Application of a membrane bioreactor system for opto-electronic industrial wastewater treatment - a pilot study

2003 ◽  
Vol 48 (8) ◽  
pp. 195-202 ◽  
Author(s):  
T.K. Chen ◽  
J.N. Chen ◽  
C.H. Ni ◽  
G.T. Lin ◽  
C.Y. Chang
Keyword(s):  
Wastewater Treatment ◽  
Industrial Wastewater ◽  
Organic Nitrogen ◽  
Membrane Bioreactor ◽  
Manufacturing Industry ◽  
Ammonia Nitrogen ◽  
Nitrifying Bacteria ◽  
Biological Degradation ◽  
Industrial Wastewater Treatment ◽  
The Past

The membrane bioreactor (MBR) system has become more and more attractive in the field of wastewater treatment. It is particularly attractive in situations where long solids retention times are required, such as nitrifying bacteria, and physical retention is critical to achieving more efficiency for biological degradation of pollutants. Although it is a new technology, the MBR process has been applied to industrial wastewater treatment for only the past decade. The opto-electronic industry, developed very fast over the past decade in the world, is a high technological manufacturing industry. The treatment of the opto-electronic industrial wastewater containing a significant quantity of organic nitrogen compounds, with a ratio over 95% in organic nitrogen (Org-N) to total nitrogen (T-N), is very difficult to meet the discharge limits. The purpose of this research is mainly to discuss the treatment capacity of high-strength organic nitrogen wastewater, and to investigate the capabilities of the MBR process. A 2 m3/day capacity MBR pilot plant consisting of anoxic and aerobic tanks and a membrane bioreactor was installed for evaluation. The operation was continued for 130 days. Over the whole experimental period, a satisfactory organic removal performance was achieved. The COD could be removed with an average of over 94.5%. For TOC and BOD5, the average removal efficiencies were 96.3 and 97.6%, respectively. The nitrification and denitrification were also successfully achieved. The effluent did not contain any suspended solids. Only a small concentration of ammonia nitrogen was found in the effluent. The stable effluent quality and satisfactory removal performance mentioned above were ensured by the efficient interception performance of the membrane device incorporated within the biological reactor. The MBR system shows promise as a means of treating very high organic nitrogen wastewater without dilution. The effluent of TKN, NOx-N and COD can fall below 20 mg/L, 30 mg/L and 50 mg/L.

Removal of pharmaceuticals and personal care products in a membrane bioreactor wastewater treatment plant

2014 ◽  
Vol 69 (11) ◽  
pp. 2221-2229 ◽  
Author(s):  
M. Kim ◽  
P. Guerra ◽  
A. Shah ◽  
M. Parsa ◽  
M. Alaee ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Wastewater Treatment Plant ◽  
Membrane Bioreactor ◽  
Personal Care Products ◽  
Treatment Plant ◽  
Dry Weight ◽  
Personal Care ◽  
High Concentrations ◽  
Final Effluent

Ninety-nine pharmaceuticals and personal care products (PPCPs) were analyzed in influent, final effluent, and biosolids samples from a wastewater treatment plant employing a membrane bioreactor (MBR). High concentrations in influent were found for acetaminophen, caffeine, metformin, 2-hydroxy-ibuprofen, paraxanthine, ibuprofen, and naproxen (104–105 ng/L). Final effluents contained clarithromycin, metformin, atenolol, carbamazepine, and trimethoprim (>500 ng/L) at the highest concentrations, while triclosan, ciprofloxacin, norfloxacin, triclocarban, metformin, caffeine, ofloxacin, and paraxanthine were found at high concentrations in biosolids (>103 ng/g dry weight). PPCP removals varied from −34% to >99% and 23 PPCPs had ≥90% removal. Of the studied PPCPs, 26 compounds have been rarely or never studied in previous membrane bioreactor (MBR) investigations. The removal pathway showed that acetaminophen, 2-hydroxy-ibuprofen, naproxen, ibuprofen, codeine, metformin, enalapril, atorvastatin, caffeine, paraxanthine, and cotinine exhibited high degradation/transformation. PPCPs showing strong sorption to solids included triclocarban, triclosan, miconazole, tetracycline, 4-epitetracycline, norfloxacin, ciprofloxacin, doxycycline, paroxetine, and ofloxacin. Trimethoprim, oxycodone, clarithromycin, thiabendazole, hydrochlorothiazide, erythromycin-H2O, carbamazepine, meprobamate, and propranolol were not removed during treatment, and clarithromycin was even formed during treatment. This investigation extended our understanding of the occurrence and fate of PPCPs in an MBR process through the analysis of the largest number of compounds in an MBR study to date.

Treatment of High Salinity Wastewater Using an Intermittently Aerated Membrane Bioreactor

2015 ◽  
Vol 1092-1093 ◽  
pp. 1033-1036
Author(s):  
Kang Xie ◽  
Jing Song ◽  
Si Qing Xia ◽  
Li Ping Qiu ◽  
Jia Bin Wang ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Membrane Bioreactor ◽  
Municipal Wastewater ◽  
High Salinity ◽  
Treatment Plant ◽  
Ammonia Nitrogen ◽  
Municipal Wastewater Treatment ◽  
Removal Efficiencies ◽  
Salinity Wastewater

In this study, high salinity wastewater was treated by an intermittently aerated membrane bioreactor (IAMBR) and the salinity loadings were set at 35g/L. The activated sludge was inoculated from the municipal wastewater treatment plant. The influent salinity level gradually increased from 0 to 35 g/L with every 5 g/L. With the salt concentration increased to 35 g/L, the performance of IAMBR was significantly affected by higher salinity. The removal efficiencies of the total organic carbon (TOC), ammonia nitrogen (NH4+-N) and total nitrogen (TN) were about 83%, 70% and 51%, respectively. It is indicated that the domestication of activated sludge from municipal wastewater treatment cannot obtain a better performance at high salinity.

scholarly journals Fate and Occurrence of Pharmaceutically Active Organic Compounds during Typical Pharmaceutical Wastewater Treatment

2019 ◽  
Vol 2019 ◽  
pp. 1-12
Author(s):  
Qiao Luo ◽  
Jing Wang ◽  
JianHui Wang ◽  
Yu Shen ◽  
Peng Yan ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Organic Compound ◽  
Organic Compounds ◽  
Wastewater Treatment Plants ◽  
Physicochemical Characteristics ◽  
Relative Content ◽  
Wastewater Effluent ◽  
Organosilicon Compounds ◽  
Pharmaceutical Wastewater ◽  
High Concentrations

The chemical composition, distribution, and fate of pharmaceutically active compounds (PhACs) present in typical pharmaceutical wastewater treatment plants were investigated with the aim of effectively removing these pollutants while minimizing waste of resources and energy. The results of this study indicate that the relative content of an organic compound class is unrelated to the number of organic compounds in the influent and effluent, yet it is directly proportional to the pollution contribution in pharmaceutical wastewater. In wastewater influent, the organic compound classes with the highest relative contents and pollution contributions were acids (relative content = 63.65%, contribution to pollution = 67.22%), esters (44.96%, 41.24%), and heterocyclic compounds (30.24%, 35.23%); in wastewater effluent, these classes were organic acids (62.54%, 65.13%), esters (52.66%, 59.02%), and organosilicon compounds (42.46%, 37.45%). The different physicochemical characteristics of these pollutants result in different removal efficiencies. For example, N,N-dimethylformamide, 4-methyloctane, N-ethylmorpholine, and 4-amino-N,N- and N,N-diethylbenzamide are refractory and are not degraded by microorganisms; thus, these compounds are discharged into the aquatic environment. Other organic compound classes including organosilicon compounds, acids, esters, heterocycles, and alcohols are mostly biodegraded, which leads to high concentrations of hydrocarbons in the wastewater effluent. The results of this study provide a foundation for the improvement of pharmaceutical wastewater treatment.

Characterization of sludge structure and activity in submerged membrane bioreactor

2005 ◽  
Vol 52 (10-11) ◽  
pp. 401-408 ◽  
Author(s):  
M. Spérandio ◽  
A. Masse ◽  
M.C. Espinosa-Bouchot ◽  
C. Cabassud
Keyword(s):  
Activated Sludge ◽  
Organic Compounds ◽  
Membrane Bioreactor ◽  
Operating Conditions ◽  
Second Phase ◽  
Submerged Membrane Bioreactor ◽  
Half Saturation Constant ◽  
Significant Difference ◽  
Excess Substrate ◽  
Biomass Activity

Sludge characteristics of a submerged membrane bioreactor (MBR) and an activated sludge process (AS) were compared, during a first phase at the same operating conditions (low MLSS and conventional SRT) and in a second phase with a high sludge retention time (SRT) in the membrane bioreactor. During the first phase, a bimodal flocs size distribution was observed in the MBR with simultaneously a macro-flocs population (240μm) bigger than the flocs of activated sludge due to the absence of recirculating pump, and also more microflocs (1 to 15μm) and free suspended cells retained by the membrane. It is shown that the membrane leads to an accumulation of proteins and polysaccharides in the sludge supernatant which is probably responsible for the high fouling propensity of the sludge during the starting period of MBR. These compounds are partially degraded after 50 to 60 days of operation. In the first phase respirometric experiments didn't demonstrate a significant difference in the maximal removal rates of either MBR or AS biomass (with excess substrate), except in the dynamic period during which the membrane retention gave an advantage by increasing the biomass activity. On the other hand, the respirometry shows that the half saturation constant for nitrification was significantly higher in the MBR process, suggesting higher substrate transfer limitation. During the last phase, it is shown that an increase of SRT from 9 to 106 days leads to a diminution of average macro-flocs size in the MBR from about 240 to 70μm. With the SRT increase, modification in the organic compounds is also observed (proteins, polysaccharides and COD) in the sludge supernatant. Increasing the SRT from 9 to 40 days seems to slightly reduce the level of organic compounds (probable biodegradation), but the concentrations increased when SRT changes from 40 days to 106 days (probable accumulation of non biodegradable compounds).

scholarly journals Toxic Effect of Ammonium Nitrogen on the Nitrification Process and Acclimatisation of Nitrifying Bacteria to High Concentrations of NH4-N in Wastewater

Energies ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5329
Author(s):  
Iwona Beata Paśmionka ◽  
Karol Bulski ◽  
Piotr Herbut ◽  
Elżbieta Boligłowa ◽  
Frederico Márcio C. Vieira ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Wastewater Treatment Plants ◽  
Ammonium Nitrogen ◽  
Treatment System ◽  
Treated Wastewater ◽  
Nitrifying Bacteria ◽  
Nitrification Process ◽  
High Concentrations ◽  
Acclimated Activated Sludge

The aim of the conducted research was to assess the effectiveness of the nitrification process, at different concentrations of ammonium nitrogen, in biologically treated wastewater in one of the largest municipal and industrial wastewater treatment plants in Poland. The studies also attempted to acclimate nitrifying bacteria to the limited concentration of ammonium nitrogen and determined the efficiency of nitrification under the influence of acclimated activated sludge in the biological wastewater treatment system. The obtained results indicate that the concentration of ammonium nitrogen above 60.00 mg·dm−3 inhibits nitrification, even after increasing the biomass of nitrifiers. The increase in the efficiency of the nitrification process in the tested system can be obtained by using the activated sludge inoculated with nitrifiers. For this purpose, nitrifiers should be preacclimated, at least for a period of time, allowing them to colonize the activated sludge. The acclimated activated sludge allows reducing the amount of ammonium nitrogen in treated sewage by approx. 35.0%. The process of stable nitrification in the biological treatment system was observed nine days after introducing the acclimated activated sludge into the aeration chamber.

Wastewater treatment and fouling control in an electro algae-activated sludge membrane bioreactor

2021 ◽  
pp. 147475
Author(s):  
Mary Vermi Aizza Corpuz ◽  
Laura Borea ◽  
Vincenzo Senatore ◽  
Fabiano Castrogiovanni ◽  
Antonio Buonerba ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Activated Sludge ◽  
Membrane Bioreactor ◽  
Fouling Control

Hydrogen-driven denitrification of wastewater in an anaerobic submerged membrane bioreactor: potential for water reuse

2006 ◽  
Vol 54 (11-12) ◽  
pp. 207-214 ◽  
Author(s):  
B. Rezania ◽  
J.A. Oleszkiewicz ◽  
N. Cicek
Keyword(s):  
Organic Carbon ◽  
Water Reuse ◽  
Biological Treatment ◽  
Membrane Bioreactor ◽  
Hydrogen Transfer ◽  
Produced Water ◽  
Treatment Unit ◽  
Submerged Membrane Bioreactor ◽  
Delivery Unit ◽  
Final Effluent

An anaerobic submerged membrane bioreactor was coupled with a novel hydrogen delivery system for hydrogenotrophic denitrification of municipal final effluent containing nitrate. The biological treatment unit and hydrogen delivery unit were proven successful in removing nitrate and delivering hydrogen, respectively. Complete hydrogen transfer resulted in reducing nitrate below detectable levels at a loading of 0.14 kg N m−3 d−1. The produced water met all drinking water guidelines except for color and organic carbon. However, the organic carbon was removed by 72% mostly by membrane rejection. To reduce the organic carbon and color of the effluent, post treatment of the produced water is required.

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