Behavior of CO2 Corrosion of API 5L X52 Steel in NaCl Solution under Turbulent Flow Condition

2013 ◽  
Vol 789 ◽  
pp. 476-483
Author(s):  
Andi Rustandi ◽  
Nitiyoga Adhika ◽  
Tezar Prima ◽  
Nur Aziz

The presence of carbon dioxide (CO2) and water in the fluid can cause severe internal corrosion in the pipelines. This study aims to observe corrosion behavior during the changes in flow rate and acidity conditions in order to obtain the relationship between the parameters by the measured corrosion rate. Corrosion rate measurements were performed for API 5L X52 steel material by using polarization method in 3.5% NaCl solution with saturated CO2 injection. Solution with different acidity were applied which has pH 4, 5, and 6 respectively. To simulate the flow rate, a Rotating Cylinder Electrode RCE was used at various rotation rates 0, 375, 750, 1500, and 3000 rpm, at room temperature (25°C) and atmospheric pressure. Based on testing results, the changes in rotation converted to flow rate showed that the corrosion mechanism of API 5L X52 steel in NaCl solution with saturated CO2 content was mainly controlled by mass transport at pH=4 whereas chemically controlled involved both at pH=5 and pH=6 conditions.

2019 ◽  
Vol 9 (9) ◽  
pp. 1092-1099
Author(s):  
Fenghong Cao ◽  
Chang Chen ◽  
Zhenyu Wang

The corrosion characteristics and corrosion mechanism of the extruded ZK80 alloy with different states soaking in 3.5% NaCl solution at room temperature were analyzed via OM, SEM, EDS, XRD and static weightlessness method and other experimental analysis methods. The results show that when the aging temperature is constant, and the corrosion rate decreases with the lengthen of aging time, while when the corrosion time is constant, the corrosion rate increases with the increase in aging time. Appropriate aging treatment not only refines the grain of the alloy, but also precipitates the Mg–Zn phase which can effectively prevent the corrosion process and improve the anti-corrosion properties of the alloy. The main corrosion characteristics of the alloy are filamentary corrosion and pitting corrosion.


Author(s):  
Budi Prasojo ◽  
Hendri Budi Kurniyanto ◽  
R Tarikh Azis ◽  
Subagio So’im ◽  
Asfiem Rahmat Haqin

2013 ◽  
Vol 17 (5) ◽  
pp. 1517-1520
Author(s):  
Qian Miao ◽  
Rong-Chao Yang ◽  
Qing Zhang ◽  
Jing Cheng ◽  
Jia-Cun Shao ◽  
...  

The volume flow rate measured by air flow plate is influenced by the ambient conditions during the calibration. A series of numerical examples are conducted for the relationship and the outcomes demonstrated that the calibration is quite sensitive to the atmospheric pressure and the ambient temperature, but insensitive to relative humidity. The experiment model has been applied to calibration results with wide ranging ambient conditions. In conclusion, the results of this study demonstrate the benefits to calibration data of minimizing the effects of ambient conditions.


2019 ◽  
Vol 2 (2) ◽  
pp. 63
Author(s):  
L.P. Xuan ◽  
M.A. Anwar ◽  
T. Kurniawan ◽  
H. M. Ayu ◽  
R. Daud ◽  
...  

Corrosion inhibitors are substances that added to the environment in small concentration and can effectively reduce the corrosion rate that of a metal surface. Natural inhibitors are one types of inhibitor being researched as it brings less environmental impact on the environment. This research was focused on the application of caffeine as inhibitor for corrosion of mild steel in seawater condition. The objective of this project was to develop the relationship between caffeine concentration on the corrosion of mild carbon steel in both static and moving solution contained 3.5-wt% NaCl. Three types of solution were prepared, which are NaCl without addition of caffeine, NaCl with 1-wt% of caffeine and NaCl with 2-wt% of caffeine. Corrosion testing was carried out by weight loss measurement. The microstructures of corroded mild steel specimens were observed under optical microscope. The experimental results indicated that by adding caffeine into the environment medium, weight loss of mild steel specimen was reduced. The corrosion rate of specimens was decreased when more caffeine was added to the environment. From optical microscopic observation, caffeine performed its inhibition effect likely by forming a protective layer which acts as barrier to prevent further corrosion of mild steel in NaCl solution.


Author(s):  
John Butchko ◽  
Bruce T. Gillette

Abstract Autoclave Stress failures were encountered at the 96 hour read during transistor reliability testing. A unique metal corrosion mechanism was found during the failure analysis, which was creating a contamination path to the drain source junction, resulting in high Idss and Igss leakage. The Al(Si) top metal was oxidizing along the grain boundaries at a faster rate than at the surface. There was subsurface blistering of the Al(Si), along with the grain boundary corrosion. This blistering was creating a contamination path from the package to the Si surface. Several variations in the metal stack were evaluated to better understand the cause of the failures and to provide a process solution. The prevention of intergranular metal corrosion and subsurface blistering during autoclave testing required a materials change from Al(Si) to Al(Si)(Cu). This change resulted in a reduced corrosion rate and consequently prevented Si contamination due to blistering. The process change resulted in a successful pass through the autoclave testing.


2001 ◽  
Vol 1 (3) ◽  
pp. 91-96 ◽  
Author(s):  
L.J. Hem ◽  
E.A. Vik ◽  
A. Bjørnson-Langen

In 1995 the new Skullerud water treatment plant was put into operation. The new water treatment includes colour removal and corrosion control with an increase of pH, alkalinity and calcium concentration in addition to the old treatment, which included straining and chlorination only. Comparative measurements of internal corrosion were conducted before and after the installation of the new treatment plant. The effect of the new water treatment on the internal corrosion was approximately a 20% reduction in iron corrosion and a 70% reduction in copper corrosion. The heavy metals content in standing water was reduced by approximately 90%. A separate internal corrosion monitoring programme was conducted, studying the effects of other water qualities on the internal corrosion rate. Corrosion coupons were exposed to the different water qualities for nine months. The results showed that the best protection of iron was achieved with water supersaturated with calcium carbonate. Neither a high content of free carbon dioxide or the use of the corrosion inhibitor sodium silicate significantly reduced the iron corrosion rate compared to the present treated water quality. The copper corrosion rate was mainly related to the pH in the water.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Satoshi Miyamoto ◽  
Zu Soh ◽  
Shigeyuki Okahara ◽  
Akira Furui ◽  
Taiichi Takasaki ◽  
...  

AbstractThe need for the estimation of the number of microbubbles (MBs) in cardiopulmonary bypass surgery has been recognized among surgeons to avoid postoperative neurological complications. MBs that exceed the diameter of human capillaries may cause endothelial disruption as well as microvascular obstructions that block posterior capillary blood flow. In this paper, we analyzed the relationship between the number of microbubbles generated and four circulation factors, i.e., intraoperative suction flow rate, venous reservoir level, continuous blood viscosity and perfusion flow rate in cardiopulmonary bypass, and proposed a neural-networked model to estimate the number of microbubbles with the factors. Model parameters were determined in a machine-learning manner using experimental data with bovine blood as the perfusate. The estimation accuracy of the model, assessed by tenfold cross-validation, demonstrated that the number of MBs can be estimated with a determinant coefficient R2 = 0.9328 (p < 0.001). A significant increase in the residual error was found when each of four factors was excluded from the contributory variables. The study demonstrated the importance of four circulation factors in the prediction of the number of MBs and its capacity to eliminate potential postsurgical complication risks.


2021 ◽  
Vol 2 (1) ◽  
pp. 61-77
Author(s):  
Hamid Reza Jafari ◽  
Ali Davoodi ◽  
Saman Hosseinpour

In this work, the corrosion behavior and surface reactivity of as-cast and heat-treated nickel aluminum bronze casting alloy (UNS C95800) in 3.5 wt% NaCl solution is investigated under stagnant and flow conditions. Increasing flow rate conditions are simulated using a rotating disk electrode from 0 to 9000 revolutions per minute (rpm). Optical micrographs confirm the decrease in the phase fraction of corrosion-sensitive β phase in the microstructure of C95800 after annealing, which, in turn, enhances the corrosion resistance of the alloy. Electrochemical studies including open circuit potentiometry, potentiodynamic polarization, and electrochemical impedance spectroscopy are performed to assess the effect of flow rate and heat treatment on the corrosion of samples at 25 and 40 °C in 3.5 wt% NaCl solution. For both as-cast and heat-treated samples, increasing the flow rate (i.e., electrode rotating rate) linearly reduces the corrosion resistance, indicating that the metal dissolution rate is significantly affected by hydrodynamic flow. Increasing the solution temperature negatively impacts the corrosion behavior of the as-cast and heat-treated samples at all flow conditions.


1990 ◽  
Vol 04 (03) ◽  
pp. 201-209
Author(s):  
A. GIEROSZYŃSKI

It was found that OSEE kinetics from electron bombarded cryosolidified NaCl solution, depend on electric charging of the sample surface. It was shown that from the relationship between the maximum surface potential and the parameters of OSEE kinetic, intensities of electric fields in the emitter layer could be estimated. It is supposed that nonhomogeneous electric fields existing in the emitter surface region, influence the emission levels responsible for the course of OSEE kinetics.


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