Evaluation of Welding Metal Zones in the Case Welded with 0.5 Mo Filler Metal to Forged Steel for Piston Crown Material

2014 ◽  
Vol 887-888 ◽  
pp. 1294-1300
Author(s):  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Dong Hyun Park ◽  
Sung Yul Lee ◽  
Yun Hae Kim ◽  
...  
Keyword(s):  
Weld Metal ◽  
Combustion Chamber ◽  
Base Metal ◽  
Current Density ◽  
Heavy Oil ◽  
Heat Affected Zone ◽  
Corrosion Current Density ◽  
Filler Metal ◽  
Corrosion Current ◽  
Piston Crown

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the most parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, 0.5Mo filler metal was welded with SMAW method in the forged steel which would be generally used with piston crown material. And the corrosion properties of weld metal zone, heat affected zone and base metal zone were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The heat affected and base metal zones exhibited the highest and lowest values of hardness respectively. And, the corrosion current density of the heat affected zone indicated the lowest value, having the highest value of hardness. It appeared that the corrosive products with red color was wholly covered on the surface of the base metal zone, while its products was not observed in the heat affected zone. The microstructure of the pearlite with black color was more or less observed in the base metal zone with patterns such as crystal and needle, in particular, the crystal pattern of ferrite microstructure with white color was considerably included in the base metal and heat affected zone, and the ferrite microstructure was significantly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve associated with corrosion resistance property were well in good agreement with each other. Keywords: Forged steel, Microstructure, 0.5Mo filler metal, SMAW, Weld metal zone, Electrochemical method, Corrosion current density, Hardness.

Characteristics of Inconel 718 Filler Metal Affecting to Welding Metal Zones of Cast Steel for Piston Crown Material

2014 ◽  
Vol 887-888 ◽  
pp. 1084-1090
Author(s):  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Dong Hyun Park ◽  
Sung Yul Lee ◽  
Yun Hae Kim ◽  
...  
Keyword(s):  
Weld Metal ◽  
Base Metal ◽  
Heat Affected Zone ◽  
Inconel 718 ◽  
Corrosion Current Density ◽  
Filler Metal ◽  
Cast Steel ◽  
Corrosion Current ◽  
Piston Crown ◽  
Red Color

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the most parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 718 filler metal was welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal zone, heat affected zone and base metal zone were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone indicated the lowest value, having the highest value of hardness. The corrosive products with red color was more or less observed in the base metal zone, while the weld metal zone exhibited the general corrosion without corrosive products of red color. The microstructure of the pearlite with black color was predominantly observed in the base metal zone, however, the microstructure of ferrite with white color increased increasingly in the heat affected zone, and the microstructure of ferrite with white color was significantly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Keywords : Repair welding, Inconel 718 filler metal, GTAW, Weld metal zone, Electrochemical method, Corrosion current density, Hardness. Microstructure

Characteristics Evaluation of Weld and Deposited Metal Zones in the Case of Welded with Inconel 718 Filler Metal to Cast Steel for Piston Crown Material

2014 ◽  
Vol 941-944 ◽  
pp. 2083-2088
Author(s):  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Dong Hyun Park ◽  
Yun Hae Kim ◽  
Jae Hyun Jeong ◽  
...  
Keyword(s):  
Weld Metal ◽  
Combustion Chamber ◽  
Heavy Oil ◽  
Inconel 718 ◽  
Corrosion Potential ◽  
Filler Metal ◽  
Cast Steel ◽  
Cyclic Voltammogram ◽  
Piston Crown ◽  
Deposited Metal

Since the oil price has been significantly jumped for recent some years, the diesel engine of the merchant ship has been mainly used the heavy oil of low quality. Thus, it has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of a combustion chamber is getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the enginet parts surrounded with combustion chamber is more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 718 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. In this case, the mechanical and corrosion properties between weld metal zone (WM) welded to the groove which were artificially made in the base metal and deposited metal zone (DM) only welded on the surface of the base metal by Inconel 718 filler metal were investigated using electrochemical methods, such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The deposited metal zone exhibited a lower value of hardness compared to the weld metal zone. Moreover, the corrosion current density also indicated significantly a lower value in the deposited metal zone compared to the weld metal zone, showing a nobler corrosion potential than the weld metal zone. The corrosive products was not observed both in the weld and deposited metal zones. The microstructure of the pearlite with black color was hardly observed in the weld metal zone, while, the microstructure of ferrite with white color indicated nearly mostly in the weld metal zone. However, ferrite microstructure considerably appeared in the deposited metal zone with crystal pattern, and pearlite microstructure was more or less observed in the deposited metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogram associated with corrosion resistance property were well in good agreement with each other.

Characteristics of Inconel 625 Filler Metal Affecting to Weld and Deposited Metal Zones in the Case of Welded to Forged Steel for Piston Crown Material

2014 ◽  
Vol 1004-1005 ◽  
pp. 1114-1119
Author(s):  
Sung Yul Lee ◽  
Kyung Man Moon ◽  
Jong Pil Won ◽  
Jae Hyun Jeong ◽  
Tae Sil Baek
Keyword(s):  
Corrosion Resistance ◽  
Weld Metal ◽  
Base Metal ◽  
Anodic Polarization ◽  
Corrosion Potential ◽  
Filler Metal ◽  
Polarization Curves ◽  
Inconel 625 ◽  
Piston Crown ◽  
Deposited Metal

Recently, wear and corrosion of the engine parts surrounded with combustion chamber is more serious compared to the other parts of the engine due to using of heavy oil of low quality. Therefore, an optimum repair welding for these parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal was welded with GTAW method in the forged steel which would be generally used with piston crown material. In this case, the mechanical and corrosion properties between weld metal zone (WM) welded to the groove which were artificially made in the base metal and deposited metal zone (DM) only welded by Inconel 625 filler metal on the surface of the base metal were investigated using electrochemical methods, such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% H2SO4 solution. The deposited metal zone exhibited a better corrosion resistance compared to the weld metal zone, furthermore, its corrosion potential was a nobler value rather than that of the weld metal zone. However, the hardness indicated more or less higher value in the weld metal zone. The corrosive products after measurement of anodic polarization curves was hardly observed both in the weld and deposited zones, while, the morphologies of the corroded surfaces exhibited general and pitting corrosion in the weld and deposited metal zones respectively. The fine pearlite microstructure was a little observed in the weld metal zone, moreover, the microstructure of ferrite with elliptical pattern was significantly increased in the deposited metal zone. As a result, it is considered that the amount of Cr, Mo and Ni having a high corrosion resistance diffuse and migrate from the weld metal zone to the base metal zone, thus, the deposited metal zone indicated a better corrosion resistance than the weld metal zone because the amount of Cr, Mo and Ni were much involved in deposited metal zone compared to the weld metal zone.

scholarly journals An electrochemical method to investigate the effects of compound composition on gold dissolution in thiosulfate solution

2020 ◽  
Vol 9 (1) ◽  
pp. 496-502 ◽  
Author(s):  
Zhaohui Zhang ◽  
Bailong Liu ◽  
Mei Wu ◽  
Longxin Sun
Keyword(s):  
Dissolution Rate ◽  
Current Density ◽  
Polarization Resistance ◽  
Electrochemical Method ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Gold Dissolution ◽  
Tafel Polarization ◽  
Edta Solution

AbstractThe electrochemical behavior of gold dissolution in the Cu2+–NH3–S2O32−–EDTA solution has been investigated in detail by deriving and analyzing the Tafel polarization curve, as this method is currently widely implemented for the electrode corrosion analysis. The dissolution rate of gold in Cu2+–NH3–S2O32−–EDTA solution was determined based on the Tafel polarization curves, and the effects of various compound compositions in a Cu2+–NH3–S2O32−–EDTA mixture on the corrosion potential and corrosion current density were analyzed. The results showed that the corrosion potential and polarization resistance decreased, whereas the corrosion current density increased for certain concentrations of S2O32−–NH3–Cu2+ and EDTA, indicating that the dissolution rate of gold had changed. The reason for promoting the dissolution of gold is also discussed.

scholarly journals Properties of a thick-section narrow-gap gas tungsten arc weld of cast Haynes 282

2021 ◽  
Author(s):  
Michael Santella ◽  
X. Frank Chen ◽  
Philip Maziasz ◽  
Jason Rausch ◽  
Jonathan Salkin
Keyword(s):  
Base Metal ◽  
Heat Affected Zone ◽  
Reference Data ◽  
Filler Metal ◽  
Stress Rupture ◽  
Narrow Gap ◽  
Weld Deposit ◽  
Gas Tungsten Arc ◽  
Gas Tungsten ◽  
Weld Heat

AbstractA 50.8-mm-deep gas tungsten arc weld was made with matching filler metal in cast Haynes 282 alloy. The narrow-gap joint was filled with 104 weld beads. Visual and dye-penetrant inspection of cross-weld specimens indicated that the cast base metal contained numerous casting defects. No visible indications of physical defects were found in the weld deposit. The weld heat-affected zone was characterized by microcracking and localized recrystallization. The cause of the cracking could not be determined. Hardness testing showed that a softened region in the as-welded heat-affected zone was nearly eliminated by post-weld heat treatment. Tensile testing up to 816 °C showed that cross-weld specimen strengths ranged from 57 to 79% of the cast base metal tensile strength. The stress-rupture strengths of cross-weld specimens are within 20% of base metal reference data. Failures of both tensile and stress-rupture specimens occurred in the base metal.

scholarly journals Structure, Corrosion Resistance, Mechanical and Tribological Properties of ZrB2 and Zr-B-N Coatings

Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1194
Author(s):  
Philipp Kiryukhantsev-Korneev ◽  
Alina Sytchenko ◽  
Yuriy Kaplanskii ◽  
Alexander Sheveyko ◽  
Stepan Vorotilo ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Tribological Properties ◽  
Current Density ◽  
Corrosion Current Density ◽  
Elastic Recovery ◽  
Optical Emission ◽  
Corrosion Current ◽  
Impact Testing ◽  
Total Oxidation ◽  
Mechanical And Tribological Properties

The coatings ZrB2 and Zr-B-N were deposited by magnetron sputtering of ZrB2 target in Ar and Ar–15%N2 atmospheres. The structure and properties of the coatings were investigated via scanning and transmission electron microscopy, energy dispersion analysis, optical profilometry, glowing discharge optical emission spectroscopy and X-ray diffraction analysis. Mechanical and tribological properties of the coatings were investigated using nanoindentation, “pin-on-disc” tribological testing and “ball-on-plate” impact testing. Free corrosion potential and corrosion current density were measured by electrochemical testing in 1N H2SO4 and 3.5%NaCl solutions. The oxidation resistance of the coatings was investigated in the 600–800 °С temperature interval. The coatings deposited in Ar contained 4–11 nm grains of the h-ZrB2 phase along with free boron. Nitrogen-containing coatings consisted of finer crystals (1–4 nm) of h-ZrB2, separated by interlayers of amorphous a-BN. Both types of coatings featured hardness of 22–23 GPa; however, the introduction of nitrogen decreased the coating’s elastic modulus from 342 to 266 GPa and increased the elastic recovery from 62 to 72%, which enhanced the wear resistance of the coatings. N-doped coatings demonstrated a relatively low friction coefficient of 0.4 and a specific wear rate of ~1.3 × 10−6 mm3N−1m−1. Electrochemical investigations revealed that the introduction of nitrogen into the coatings resulted in the decrease of corrosion current density in 3.5% NaCl and 1N H2SO4 solution up to 3.5 and 5 times, correspondingly. The superior corrosion resistance of Zr-В-N coatings was related to the finer grains size and increased volume of the BN phase. The samples ZrB2 and Zr-B-N resisted oxidation at 600 °C. N-free coatings resisted oxidation (up to 800 °С) and the diffusion of metallic elements from the substrate better. In contrast, Zr-B-N coatings experienced total oxidation and formed loose oxide layers, which could be easily removed from the substrate.

Evaluation on the Addition of Inhibitor and Surface Treatment to Corrosion Behavior of the Reinforced Steel Bar Embedded in Mortar Specimen

2017 ◽  
Vol 744 ◽  
pp. 114-120
Author(s):  
Kyung Man Moon ◽  
Sung Yul Lee ◽  
Jae Hyun Jeong ◽  
Myeong Hoon Lee
Keyword(s):  
Current Density ◽  
Test Specimen ◽  
Corrosion Current Density ◽  
Corrosion Current ◽  
Corrosion Properties ◽  
Mortar Specimen ◽  
Steel Bar ◽  
Steel Bars ◽  
Reinforced Steel ◽  
One Year

In this study, seven types of mortar test specimens were manufactured with parameters, that is, the surface of the reinforced steel bar was treated with hot dip galvanizing (Zn) and the surface of the test specimen was coated with underwater paint, and four types of inhibitors (DAW, MCI, DCI, and Silcon) were added in mortars respectively. And, the seven types of mortar test specimens were immersed in seawater for 4 years. The corrosion properties of the reinforced steel bars embedded in mortar test specimens were investigated using electrochemical methods. The corrosion potentials of the test specimens with painting on the surface of the specimen and Zn coating on the surface of the steel bar exhibited the noblest and lowest values respectively after one year, however, after 4 years, the specimens of underwater painting and of addition of Silcon inhibitor indicated the noblest and lowest values of corrosion potentials respectively. Furthermore, the painting specimen exhibited the smallest values of corrosion probability as welll as of the corrosion current density, while, addition of MCI inhibitor showed the highest values of both corrosion probability and corrosion current density. Moreover, the painting specimen showed the smallest value of neutralization degree among all the specimens, and the largest value of neutralization degree was observed at the specimen of natural condition (no adding of inhibitor, no painting and no Zn coating). As a result, it is considered that the addition of inhibitors, coating with hot dip galvanizing (Zn), and painting on the surface have the effects not only to inhibit the neutralization degree but also to increase the corrosion resistance of the embedded steel bar.

scholarly journals Preparation of Ti–Zr-Based Conversion Coating on 5052 Aluminum Alloy, and Its Corrosion Resistance and Antifouling Performance

Coatings ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 397 ◽  
Author(s):  
Hehong Zhang ◽  
Xiaofeng Zhang ◽  
Xuhui Zhao ◽  
Yuming Tang ◽  
Yu Zuo
Keyword(s):  
Corrosion Resistance ◽  
Surface Modification ◽  
Aluminum Alloy ◽  
Current Density ◽  
Corrosion Current Density ◽  
Salt Water ◽  
Water Immersion ◽  
Chemical Conversion ◽  
Corrosion Current ◽  
Conversion Coating

A chemical conversion coating on 5052 aluminum alloy was prepared by using K2ZrF6 and K2TiF6 as the main salts, KMnO4 as the oxidant and NaF as the accelerant. The surface morphology, structure and composition were analyzed by SEM, EDS, FT–IR and XPS. The corrosion resistance of the conversion coating was studied by salt water immersion and polarization curve analysis. The influence of fluorosilane (FAS-17) surface modification on its antifouling property was also discussed. The results showed that the prepared conversion coating mainly consisted of AlF3·3H2O, Al2O3, MnO2 and TiO2, and exhibited good corrosion resistance. Its corrosion potential in 3.5 wt % NaCl solution was positively shifted about 590 mV and the corrosion current density was dropped from 1.10 to 0.48 μA cm−2. By sealing treatment in NiF2 solution, its corrosion resistance was further improved yielding a corrosion current density drop of 0.04 μA cm−2. By fluorosilane (FAS-17) surface modification, the conversion coating became hydrophobic due to low-surface-energy groups such as CF2 and CF3, and the contact angle reached 136.8°. Moreover, by FAS-17 modification, the corrosion resistance was enhanced significantly and its corrosion rate decreased by about 25 times.

Electrochemical Characteristics of Lanthanum Hexaboride in the Environments Containing S2-

2010 ◽  
Vol 663-665 ◽  
pp. 473-476
Author(s):  
Shu Qi Zheng ◽  
Chang Feng Chen ◽  
Rui Jing Jiang ◽  
Dan Ni Wang
Keyword(s):  
Partial Pressure ◽  
Corrosion Behavior ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Lanthanum Hexaboride ◽  
Electrochemical Characteristics

In the environment with H2S/CO2 or Na2S, the corrosion behavior of Lanthanum hexaboride (LaB6) was investigated by electrochemistry methods. The results indicated that the corrosion potential (Ecorr) and Rf of LaB6 increased as the partial pressure of H2S increased, while the corrosion current density (Icorr) decreased. In the environment containing Na2S, as the content of Na2S increased, the corrosion potential (Ecorr) and Rf of LaB6 decreased, while the corrosion current density (Icorr) increased. Thus, the addition of H2S into the environment with H2S/CO2 would inhibit the corrosion of LaB6; while in the environment containing Na2S, the increasing of the content of Na2S would accelerate the corrosion of LaB6.

An experimental study on correlation between concrete resistivity and reinforcement corrosion rate

2014 ◽  
Vol 61 (3) ◽  
pp. 158-165 ◽  
Author(s):  
Shamsad Ahmad
Keyword(s):  
Reinforced Concrete ◽  
Corrosion Rate ◽  
Current Density ◽  
Corrosion Current Density ◽  
Corrosion Current ◽  
Empirical Correlation ◽  
Reinforcement Corrosion ◽  
Content Type ◽  
Wide Range ◽  
Concrete Resistivity

Purpose – The purpose of this paper was to explore the possibility of establishing an empirical correlation between concrete resistivity and reinforcement corrosion rate utilizing the experimental data generated by measuring corrosion current density of reinforced concrete specimens subjected to chloride-induced corrosion at different levels of concrete resistivity. Design/methodology/approach – To generate concrete resistivity vs corrosion current density data in a wide range, ten reinforced concrete specimens were prepared and allowed to corrode under severe chloride exposure. After significantly corroding the specimens, they were removed from the chloride exposure and were subjected to different moisture levels for achieving variation in the resistivity of concrete so that reasonably good number of resistivity vs corrosion rate data can be obtained. Resistivity and corrosion current density tests were conducted for all the ten specimens and their values were measured in wide ranges of 0.8-65 kΩ·cm and 0.08-11 μA/cm2, respectively. Findings – Data generated through this study were utilized to obtain an empirical relationship between concrete resistivity and corrosion current density. The trend of results obtained using the empirical correlation model developed in the present study was in close agreement with that obtained using a theoretical model reported in literature. Originality/value – The empirical correlation between concrete resistivity and reinforcement corrosion rate obtained under this work can be used for evaluation of reinforcement corrosion utilizing the resistivity values measured non-destructively.

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