Two-Way Shape Memory Behavior of Electrospun Non-Woven Mats Prepared from Sol-Gel Crosslinked Poly(ε-Caprolactone)

2016 ◽  
Vol 97 ◽  
pp. 100-105 ◽  
Author(s):  
Stefano Pandini ◽  
Silvia Agnelli ◽  
Andrea Merlettini ◽  
Chiara Gualandi ◽  
Maria Letizia Focarete ◽  
...  
Keyword(s):  
Shape Memory ◽  
Microstructural Evolution ◽  
Sol Gel ◽  
Sem Analysis ◽  
Electrospinning Process ◽  
Ex Situ ◽  
Crosslinking Reaction ◽  
Cyclic Response ◽  
Heating And Cooling ◽  
Training Cycle

Non-woven fibrous mats based on semicrystalline networks were prepared starting from poly(ε-caprolactone) and by combining electrospinning process and sol-gel crosslinking reaction. The mats were subjected to proper thermo-mechanical cycles to investigate their two-way shape memory capabilities (i.e. the possibility to change between two distinguished shapes upon heating and cooling), and an improvement of the two-way behaviour was researched through the application of a training cycle. An ex-situ SEM analysis described the microstructural evolution accompanying the two-way shape memory cyclic response.

scholarly journals Reproduction of melting behavior for vitrified hillforts based on amphibolite, granite, and basalt lithologies

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
John S. McCloy ◽  
José Marcial ◽  
Jack S. Clarke ◽  
Mostafa Ahmadzadeh ◽  
John A. Wolff ◽  
...  
Keyword(s):  
Iron Age ◽  
Glass Production ◽  
Melting Behavior ◽  
Source Rocks ◽  
Ex Situ ◽  
Maximum Temperature ◽  
Heating And Cooling ◽  
Heat Treated ◽  
Granitoid Rocks ◽  
Dark Glass

AbstractEuropean Bronze and Iron Age vitrified hillforts have been known since the 1700s, but archaeological interpretations regarding their function and use are still debated. We carried out a series of experiments to constrain conditions that led to the vitrification of the inner wall rocks in the hillfort at Broborg, Sweden. Potential source rocks were collected locally and heat treated in the laboratory, varying maximum temperature, cooling rate, and starting particle size. Crystalline and amorphous phases were quantified using X-ray diffraction both in situ, during heating and cooling, and ex situ, after heating and quenching. Textures, phases, and glass compositions obtained were compared with those for rock samples from the vitrified part of the wall, as well as with equilibrium crystallization calculations. ‘Dark glass’ and its associated minerals formed from amphibolite or dolerite rocks melted at 1000–1200 °C under reducing atmosphere then slow cooled. ‘Clear glass’ formed from non-equilibrium partial melting of feldspar in granitoid rocks. This study aids archaeological forensic investigation of vitrified hillforts and interpretation of source rock material by mapping mineralogical changes and glass production under various heating conditions.

scholarly journals Laboratory-Scale Processing and Performance Assessment of Ti–Ta High-Temperature Shape Memory Spring Actuators

2021 ◽  
Author(s):  
A. Paulsen ◽  
H. Dumlu ◽  
D. Piorunek ◽  
D. Langenkämper ◽  
J. Frenzel ◽  
...  
Keyword(s):  
High Temperature ◽  
Shape Memory ◽  
Detrimental Effect ◽  
Wire Drawing ◽  
Fast Heating ◽  
Heating And Cooling ◽  
Arc Melting ◽  
Ω Phase ◽  
And Performance

AbstractTi75Ta25 high-temperature shape memory alloys exhibit a number of features which make it difficult to use them as spring actuators. These include the high melting point of Ta (close to 3000 °C), the affinity of Ti to oxygen which leads to the formation of brittle α-case layers and the tendency to precipitate the ω-phase, which suppresses the martensitic transformation. The present work represents a case study which shows how one can overcome these issues and manufacture high quality Ti75Ta25 tensile spring actuators. The work focusses on processing (arc melting, arc welding, wire drawing, surface treatments and actuator spring geometry setting) and on cyclic actuator testing. It is shown how one can minimize the detrimental effect of ω-phase formation and ensure stable high-temperature actuation by fast heating and cooling and by intermediate rejuvenation anneals. The results are discussed on the basis of fundamental Ti–Ta metallurgy and in the light of Ni–Ti spring actuator performance.

Shape memory properties and microstructural evolution of rapidly solidified CuAlBe alloys

2013 ◽  
Vol 80 ◽  
pp. 92-97 ◽  
Author(s):  
Semra Ergen ◽  
Orhan Uzun ◽  
Fikret Yilmaz ◽  
M. Fatih Kiliçaslan
Keyword(s):  
Shape Memory ◽  
Microstructural Evolution ◽  
Shape Memory Properties ◽  
Rapidly Solidified

PREPARATION AND FERROELECTRIC PROPERTY OF (100)-ORIENTED Ca0.4Sr0.6Bi4Ti4O15 THIN FILM ON Pt/Ti/SiO2/Si SUBSTRATE

2010 ◽  
Vol 17 (05n06) ◽  
pp. 445-449 ◽  
Author(s):  
SUHUA FAN ◽  
QUANDE CHE ◽  
FENGQING ZHANG
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Ferroelectric Property ◽  
Remanent Polarization ◽  
Sol Gel ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
Si Substrate ◽  
Degree Of Orientation ◽  
Equiaxed Grains

The (100)-oriented Ca0.4Sr0.6Bi4Ti4O15(C0.4S0.6BTi ) thin film was successfully prepared by a sol-gel method on Pt/Ti/SiO2/Si substrate. The orientation and formation of thin films under different annealing schedules were studied using XRD and SEM. XRD analysis indicated that (100)-oriented C0.4S0.6BTi thin film with degree of orientation of I(200)/I(119) = 1.60 was prepared by preannealing the film at 400°C for 3 min followed by rapid thermal annealing at 800°C for 5 min. SEM analysis further indicated that the (100)-oriented C0.4S0.6BTi thin film with a thickness of about 800 nm was mainly composed of equiaxed grains. The remanent polarization and coercive field of the film were 16.1 μC/cm2 and 85 kV/cm, respectively.

scholarly journals Biocomposite of Cassava Starch Reinforced with Cellulose Pulp Fibers Modified with Deposition of Silica (SiO2) Nanoparticles

2015 ◽  
Vol 2015 ◽  
pp. 1-9 ◽  
Author(s):  
Joabel Raabe ◽  
Alessandra de Souza Fonseca ◽  
Lina Bufalino ◽  
Caue Ribeiro ◽  
Maria Alice Martins ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Sol Gel ◽  
Fiber Surface ◽  
Sio2 Nanoparticles ◽  
Thermoplastic Starch ◽  
Cassava Starch ◽  
Sem Analysis ◽  
Pulp Fibers ◽  
Moisture Adsorption ◽  
Cellulose Pulp

Eucalyptuspulp cellulose fibers were modified by the sol-gel process for SiO2superficial deposition and used as reinforcement of thermoplastic starch (TPS). Cassava starch, glycerol, and water were added at the proportion of 60/26/14, respectively. For composites, 5% and 10% (by weight) of modified and unmodified pulp fibers were added before extrusion. The matrix and composites were submitted to thermal stability, tensile strength, moisture adsorption, and SEM analysis. Micrographs of the modified fibers revealed the presence of SiO2nanoparticles on fiber surface. The addition of modified fibers improved tensile strength in 183% in relation to matrix, while moisture adsorption decreased 8.3%. Such improvements were even more effective with unmodified fibers addition. This result was mainly attributed to poor interaction between modified fibers and TPS matrix detected by SEM analysis.

scholarly journals Oxazoline-based crosslinking reaction for coatings

2021 ◽  
Author(s):  
Philipp Knospe ◽  
Patrick Böhm ◽  
Jochen Gutmann ◽  
Michael Dornbusch
Keyword(s):  
Mechanical Properties ◽  
Loss Modulus ◽  
New Technology ◽  
Sol Gel ◽  
Polymer Network ◽  
Time Dependent ◽  
Crosslinking Reaction ◽  
Coating Materials ◽  
Rheological Measurements ◽  
Excellent Adhesion

AbstractNowadays, coating materials must meet high demands in terms of mechanical, chemical and optical properties in all areas of application. Amongst others, amines and isocyanates are used as crosslinking components for curing reactions, meeting the highly demanding properties of the coatings industry. In this work, a new crosslinking reaction for coatings based on oxazoline chemistry is investigated with the objective to overcome disadvantages of established systems and fulfill the need for sustainable coating compounds. The oxazoline-group containing resin, synthesized from commercially available substances, undergoes cationic self-crosslinking polymerization to build up a network based on urethane and amide moieties. NMR-, IR- and ES-mass spectroscopy are suitable techniques to characterize the synthesized oxazoline monomers, which are linked to polyisocyanates and polymerized afterwards via self-polymerization. The progress of crosslinking is followed by changes in IR spectra and by rheological measurements to calculate time dependent values for storage and loss modulus. The glass transition temperature of the resulting coating is determined, too. Furthermore, sol–gel-analysis is performed to determine the degree of crosslinking. After application on steel and aluminium panels, application tests are performed. In addition to excellent adhesion to the substrate, the polymer network shows promising mechanical properties and with that it could represent a new technology for the coatings industry.

Experimental Validation and Numerical Simulation of Shape Memory Flat Wire Actuators

2014 ◽  
Author(s):  
Alexander Czechowicz ◽  
Sven Langbein
Keyword(s):  
Shape Memory Alloy ◽  
Boundary Conditions ◽  
Shape Memory ◽  
Smart Materials ◽  
Empirical Data ◽  
Dynamic Properties ◽  
Fatigue Behavior ◽  
Different Boundary Conditions ◽  
Heating And Cooling ◽  
Actual Shape

Shape memory alloys (SMA) are thermally activated smart materials. Due to their ability to change into a previously imprinted actual shape through the means of thermal activation, they are suitable as actuators for mechatronical systems. Despite of the advantages shape memory alloy actuators provide, these elements are only seldom integrated by engineers into mechatronical systems. Reasons are the complex characteristics, especially at different boundary conditions and the missing simulation- and design tools. Also the lack of knowledge and empirical data are a reason why development projects with shape memory actuators often lead to failures. This paper deals with the dynamic properties of SMA-actuators (Shape Memory Alloy) — characterized by their rate of heating and cooling procedures — that today can only be described insufficiently for different boundary conditions. Based on an analysis of energy fluxes into and out of the actuator, a numerical model of flat-wire used in a bow-like structure, implemented in MATLAB/SIMULINK, is presented. Different actuation parameters, depending on the actuator-geometry and temperature are considered in the simulation in real time. Additionally this publication sums up the needed empirical data (e.g. fatigue behavior) in order to validate the numerical two dimensional model and presents empirical data on SMA flat wire material.

Laser Metal Deposition of Fe- and Co-Based Shape-Memory Alloys

2021 ◽  
Vol 1161 ◽  
pp. 105-112
Author(s):  
Niklas Sommer ◽  
Gabriel Mienert ◽  
Malte Vollmer ◽  
Christian Lauhoff ◽  
Philipp Krooß ◽  
...  
Keyword(s):  
Shape Memory Alloys ◽  
Shape Memory ◽  
Microstructural Evolution ◽  
Microstructural Analysis ◽  
Metal Deposition ◽  
Thin Wall ◽  
Laser Metal Deposition ◽  
Wall Structures ◽  
Iron Based ◽  
First Time

In the present study, Iron-based FeMnAlNi and Cobalt-based CoNiGa shape-memory alloys (SMA) were processed by laser metal deposition for the first time. The materials show susceptibility to cracking upon processing when unheated substrates are employed. Pre-heating of the substrate materials eliminated cracking completely and enabled robust deposition of thin-wall structures. Microstructural analysis using optical microscopy revealed different microstructural evolution for the two materials considered.

Effect of cobalt doping on microstructures and dielectric properties of ZnO

2019 ◽  
Vol 97 (3) ◽  
pp. 227-232 ◽  
Author(s):  
Ye Zhao ◽  
Fan Tong ◽  
Mao Hua Wang
Keyword(s):  
Zno Nanoparticles ◽  
Sol Gel ◽  
Hexagonal Wurtzite Structure ◽  
Sem Analysis ◽  
Co Doping ◽  
In Doping ◽  
Zno Powders ◽  
Doped Zno ◽  
Zno Crystal ◽  
Co Doped

Pure and cobalt-doped ZnO nanoparticles (2.5, 5, 7.5, and 10 atom % Co) are synthesized by sol–gel method. The as-synthesized nanoparticles are characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and field emission scanning electron microscopy (FE-SEM) analysis. The nanoparticles of 0, 2.5, and 5 atom % Co-doped ZnO exhibited hexagonal wurtzite structure and have no other phases. Moreover, the (101) diffraction peaks position of Co-doped ZnO shift toward a smaller value of diffraction angle compared with pure ZnO powders. The results confirm that Co ions were well incorporated into ZnO crystal lattice. Simultaneously, Co doping also inhibited the growth of particles, and the crystallite size decreased from 43.11 nm to 36.63 nm with the increase in doping concentration from 0 to 10 atom %. The values of the optical band gap of all Co-doped ZnO nanoparticles gradually decreased from 3.09 eV to 2.66 eV with increasing Co content. Particular, the dielectric constant of all Co-doped ZnO ceramics gradually increased from 1.62 × 103 to 20.52 × 103, and the dielectric loss decreased from 2.36 to 1.28 when Co content increased from 0 to 10 atom %.

Sign in / Sign up

Export Citation Format

Share Document