Dielectric Spectra of BaTiO3-Based Ceramics Measured by Impedance Analyzer Using Micro Planar Electrodes

2006 ◽  
Vol 301 ◽  
pp. 129-134 ◽  
Author(s):  
Jianyong Li ◽  
Hirofumi Kakemoto ◽  
Satoshi Wada ◽  
Takaaki Tsurumi

A new measuring method and analyzing procedure were proposed to determine the complex dielectric permittivity of materials with relatively high permittivity using an RF-impedance analyzer. Samples used for the measurement were (Ba0.6Sr0.4)TiO3 and Ba(Zr0.25Ti0.75)O3 ceramics. Micro planar electrodes were used for the measurement of complex admittance of these samples. Electromagnetic simulations were carried out for determining the relative dielectric permittivity and dielectric loss. The complex dielectric permittivity vs. frequency curves of Ba(Zr0.25Ti0.75)O3 showed a broad dielectric relaxation, while that of (Ba0.6Sr0.4)TiO3 was almost flat up to 3 GHz.

Sensors ◽  
2019 ◽  
Vol 19 (7) ◽  
pp. 1646 ◽  
Author(s):  
Justyna Szerement ◽  
Aleksandra Woszczyk ◽  
Agnieszka Szypłowska ◽  
Marcin Kafarski ◽  
Arkadiusz Lewandowski ◽  
...  

This paper presents a novel seven-rod sensor used for time-domain reflectometry (TDR) and frequency-domain reflectometry (FDR) measurements of soil water content in a well-defined sample volume. The probe directly measures the complex dielectric permittivity spectrum and for this purpose requires three calibration media: air, water, and ethanol. Firstly, electromagnetic simulations were used to study the influence of the diameter of a container on the sensitivity zone of the probe with respect to the measured calibration media and isopropanol as a verification liquid. Next, the probe was tested in three soils—sandy loam and two silt loams—with six water contents from air-dry to saturation. The conversion from S 11 parameters to complex dielectric permittivity from vector network analyzer (VNA) measurements was obtained using an open-ended liquid procedure. The simulation and measurement results for the real part of the isopropanol dielectric permittivity obtained from four containers with different diameters were in good agreement with literature data up to 200 MHz. The real part of the dielectric permittivity was extracted and related to the moisture of the tested soil samples. Relations between the volumetric water content and the real part of the dielectric permittivity (by FDR) and apparent dielectric permittivity (by TDR) were compared with Topp’s equation. It was concluded that the best fit to Topp’s equation was observed in the case of a sandy loam. Data calculated according to the equation proposed by Malicki, Plagge, and Roth gave results closer to Topp’s calibration. The obtained results indicated that the seven-rod probe can be used to accurately measure of the dielectric permittivity spectrum in a well-defined sample volume of about 8 cm3 in the frequency range from 20 MHz to 200 MHz.


2020 ◽  
Author(s):  
Justyna Szerement ◽  
Hironobu Saito ◽  
Kahori Furuhata ◽  
Shin Yagihara ◽  
Agnieszka Szypłowska ◽  
...  

<p>Soil complex dielectric permittivity is frequency dependent. At low frequencies soil dielectric spectrum exhibits relaxation effects mainly due to interfacial phenomena caused by water strongly bounded to solid phase particles surfaces, double-layer effects and Maxwell-Wagner effect. At frequencies of several GHz and above, the influence of dielectric dispersion of free water dipoles can be observed.  Since dielectric soil moisture meters operate at frequencies from kHz up to several GHz, their output can be affected by these phenomena.</p><p>Currently, there is a variety of commercial sensors that operate at various frequencies from kHz up to several GHz. Most popular are TDR sensors with frequency band up to 1-2 GHz and capacitance/impedance sensors that operate at a single frequency usually from the range <br>1-150 MHz. Therefore, the knowledge of the broadband complex dielectric permittivity spectrum can help to improve the existing and develop new methods and devices for soil moisture and salinity estimation. Also, accurate characterization of complex dielectric permittivity spectrum of porous materials in the broadband frequency range is required for modeling of dielectric properties of materials in terms of moisture, salinity, density, mineralogy etc.</p><p>The aim of the study was to measure the complex dielectric permittivity of glass beads with 5% talc moistened with distilled water and saline water (electrical conductivity of 500, 1000, 1500 mS/m). The experiment was carried out using a seven-rod probe connected to an impedance analyzer (IA) and a vector network analyzer (VNA) using a multiplexer in the frequency range from 40Hz to 110MHz (IA) and 10MHz to 500MHz (VNA). The glass beads (90-106 µm, Fuji Manufacturing Industries, Japan) with 5% talc (Sigma Aldrich) in 4 different moisture and 4 different salinity values were examined. The results obtained from the IA and the VNA were combined and modeled with complex conductivity and dielectric permittivity model. The influence of water content and electrical conductivity on broadband complex dielectric spectra and the fitted model parameters was examined.</p><p> </p><p>The work has been supported by the National Centre for Research and Development, Poland, BIOSTRATEG3/343547/8/NCBR/2017.</p>


Author(s):  
Sema Türkay ◽  
Adem Tataroğlu

AbstractRF magnetron sputtering was used to grow silicon nitride (Si3N4) thin film on GaAs substrate to form metal–oxide–semiconductor (MOS) capacitor. Complex dielectric permittivity (ε*), complex electric modulus (M*) and complex electrical conductivity (σ*) of the prepared Au/Si3N4/p-GaAs (MOS) capacitor were studied in detail. These parameters were calculated using admittance measurements performed in the range of 150 K-350 K and 50 kHz-1 MHz. It is found that the dielectric constant (ε′) and dielectric loss (ε″) value decrease with increasing frequency. However, as the temperature increases, the ε′ and ε″ increased. Ac conductivity (σac) was increased with increasing both temperature and frequency. The activation energy (Ea) was determined by Arrhenius equation. Besides, the frequency dependence of σac was analyzed by Jonscher’s universal power law (σac = Aωs). Thus, the value of the frequency exponent (s) were determined.


Author(s):  
Peter Schlicht ◽  
◽  
Tianhua Zhang ◽  
Martin G. Lüling ◽  
Brita Renee Graham ◽  
...  

Natural fractures maintain a significant role in many hydrocarbon plays, in both conventional and unconventional reservoirs. In exploration and development scenarios, specific fracture properties, such as orientation and density, are important. However, more critical is their internal architecture: are the fractures open to fluid flow or filled with minerals? Borehole microresistivity imaging tools are widely used to determine these fracture characteristics. In wells drilled with water-based muds, open fractures are filled with conductive borehole fluid that enables distinguishing open, water-filled fractures from resistive, mineral-filled fractures and the surrounding rock. However, many wells today are drilled with oil-based muds. In this case, mineral-filled fractures and oil-based-mud-filled fractures are equally highly resistive and cannot be directly distinguished using resistivity images only. The latest-generation wireline oil-based-mud microresistivity imagers operate in the megahertz frequency range, radiating the electrical current capacitively through the nonconductive mud column and delivering photorealistic borehole images. Both electrical conductivity and dielectric permittivity components constitute the measured signal, from which button standoff, formation resistivity, and dielectric permittivity are inverted. Our example case shows highly resistive, high-angle fractures from the resistivity images with their orientation and density. The standoff image determines if the mud column penetrates the fracture plane, showing an apparently high standoff compared with the surrounding rock. If the standoff appears high in the fracture plane, the fracture is classified as open to fluid flow. However, are these fractures indeed fully dilated and open, or are they filled with different materials—are they partially mineralized with calcite and partially open, filled with mud? To further determine the fracture fill and susceptibility to fluid flow, a new workflow employs the material dependency of the relative dielectric permittivity. The relative permittivity is estimated as a function of resistivity and frequency pixel by pixel on the resistivity image. The estimate formula is based on several hundred laboratory measurements on core plugs with different fluid saturations and salinities. The resulting borehole image enables distinguishing materials in the volume of investigation, where low values correspond to mud-dominated oil in open fracture planes, medium values correspond to rock-forming minerals, and high values are attributed to shales and other clay-rich rocks. Fracture planes filled with patches of both low- and medium-permittivity values are classified as partially open.


2016 ◽  
Vol 52 ◽  
pp. 161-167 ◽  
Author(s):  
Igor V. Kotelnikov ◽  
Andrey G. Altynnikov ◽  
Anatoly Konstantinovich Mikhailov ◽  
Valentina V. Medvedeva ◽  
Andrey Kozyrev

Author(s):  
Pavels Narica ◽  
Svetlana Pan’kova ◽  
Vladimir Solovyev ◽  
Alexander Vanin ◽  
Mikhail Yanikov

Laser colour-marking method often displace conventional marking techniques. Complicated technology of laser-induced periodic surface structure creation on stainless steel samples allows changing their surface morphology and optical properties, which were studied in this work by atomic force microscopy (AFM), laser scanning microscopy, reflectance spectroscopy and ellipsometry. Reflectance spectra of the samples demonstrate reflectance maxima correlate with the visible colours of the samples and with the extrema in the non-monotonic spectral dependences of the derivative of real part of complex dielectric permittivity extracted from the ellipsometric data. Thus, the most intensive light scattering takes place when the real part of complex dielectric permittivity falls down quickly with changing wavelength. We did not observe any “azimuth anisotropy” in our optical measurements at constant incidence angle: the spectra were the same independently of the light incidence plane orientation (parallel or perpendicular to the previous laser light spot scanning direction). We suppose that this selective resonance-like light scattering is due to the sample surface inhomogeneity, which is the result of previous laser treatment. This assumption agrees with estimations based on laser microscope and AFM images as well as with predictions of Mie theory. Thus, the colours of the samples under study are due to the light scattering by randomly distributed surface species with different sizes. 


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