Densification and Microstructure Development in Zirconia Toughened Hardmetals

2012 ◽  
Vol 527 ◽  
pp. 50-55 ◽  
Author(s):  
Nikolai Voltsihhin ◽  
Irina Hussainova ◽  
M. Erkin Cura ◽  
Simo Pekka Hannula ◽  
Rainer Traksmaa

Different process methods and parameters together with different amount of additives were used to fabricate WC-Ni-ZrO2 hardmetals with mechanical properties aiming at improved performance under erosive wear. XRD observation showed the presence of tetragonal zirconia in the cermet matrix after processing. The best erosion resistance with erosion rate of about 0.7 mm3/kg was demonstrated by the specimen produced either by vacuum sintering or SPS and added by 0.2 wt% of free carbon. This cermet has also demonstrated the highest hardness of 17.7 GPa.

Coatings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 992
Author(s):  
Kenji Yamamoto ◽  
Yuuya Tatsuhira ◽  
Yoshiro Iwai

TiAlN coatings with different Al ratios were deposited by the cathodic arc ion plating (AIP) method, and the relationship between solid particle erosion resistance and structural, mechanical properties was investigated by a micro slurry-jet erosion (MSE) test. The crystal structure of TiAlN coating changes depending on the Al ratio. The coating shows a B1 single cubic phase between the Al ratio of 0 and 0.58; above this ratio, formation of a B4 hexagonal phase is observed. The mechanical properties such as hardness and Young’s modulus of the TiAlN coating also depend on the Al ratio and the crystal structure. The erosion rate decreases by increasing the Al ratio up to 0.58, as the coating is a cubic single phase. The TiAlN coating shows the lowest erosion rate at an Al ratio of 0.58. The erosion rate increases drastically as the crystalline phase changes from the B1 cubic to B4 hexagonal phase at the Al ratio of more than 0.58. The change in erosion rate is also discussed in connection with mechanical properties such as erodent particle hardness to coating hardness ratio and coating hardness to Young’s modulus ratio.


2018 ◽  
Vol 925 ◽  
pp. 400-407 ◽  
Author(s):  
Kazumichi Shimizu ◽  
Kenta Kusumoto ◽  
Kimitoshi Nakamura ◽  
Shoji Kiguchi ◽  
Masato Shirai ◽  
...  

Hot hardness and oxidation property of target material influences greatly on the erosion behavior at elevated temperature. The correlation between hot hardness and oxidation property of multi component white cast irons and its erosion resistance were investigated, and try to estimate the high temperature erosion behavior in the study. Nine kinds of multi component white cast iron and cast steel were used in this study. Specimen were machined into a flat plate with dimension of 50×50×10 mm. High temperature erosion test machine was used to investigate the erosive wear property of experimental materials at 1173K. Alumina grits (average diameter: 1.16 mm, hardness: 1250 HV1) which were used as impact particles were heated to 1073K and shoot on the heated specimen by hot air at the velocity of 100 m/s. The total particle loading was 2 kg. In order to clarify the correlation of hot hardness, oxidation property and the erosion resistance of specimens, hot hardness test was carried out specimens, to estimate erosion damage caused by solid particle. Hot hardness of specimens showed a value comparable to 200~250HV1. Result of erosion and oxidation tests, erosion rate and amount of oxidation of the specimen were suppressed by Ni addition. It suggested that the more amount of Ni contents, the lower the erosion rate and the less the amount of oxidation.


2019 ◽  
Vol 13 (2) ◽  
pp. 4794-4815
Author(s):  
Z. Shanti Kiran ◽  
V. Suresh Babu ◽  
K. V. L. Soma Shekar

This research concentrates on examination and optimization of microhardness and erosion resistance of epoxy-glass-nanoclay composites (EGCN’s). The parameters considered were the weight content of Cloisite 15A (A), the volume of glass fiber (B), and the direction of glass fibers (C). Hand lay-up technique was used to make the composites and tested for microhardness and erosive wear as per ASTM standards. The L9 orthogonal array was utilized to design the microhardness tests and erosive wear test, and it was noted that the composite with high clay content, low fiber volume, and 45° orientation had shown low erosion rate (Er) even though its hardness was lesser than the optimized value. At the optimum composition corresponding to the lowest Er, further erosion studies were conducted with the L18 orthogonal array for optimizing machine testing parameters. Scanning electron microscopy (SEM) was used to explain the effect of each parameter on the output. This research gives a thought regarding the consolidated effect of A, B, and C on the erosion resistance of the EGCN’s and the effect of testing parameters.


2021 ◽  
pp. 002199832110370
Author(s):  
Tihomir Kovačević ◽  
Saša Brzić ◽  
Melina Kalagasidis Krušić ◽  
Jovica Nešić ◽  
Ljubica Radović ◽  
...  

Two types of polymer waste materials, poly(ethylene terephthalate) (PET) and polycarbonate based Colombian Resin (CR-39), were used for the designing of fully recycled composite materials. Waste PET was employed for the synthesis of thermoset unsaturated polyester resin (UPR), while CR-39 was used as reinforcement in the UPR matrix. Prior to mixing, CR-39 particles were subjected to oxidation and chemical activation using acids/base and ethanol amine, respectively. The effect of the modifier type and variable loading of the activated CR-39 particles on mechanical and dynamic-mechanical properties of the corresponding composites was investigated. The greatest improvement in the tensile and flexural strength of UPR resin was achieved with the composite containing 0.5 wt% of amine activated filler particles, 96.0% and 62.2%, respectively. The Arrhenius equation was used to calculate the activation energy for glass transition from dynamic mechanical properties measured at various frequencies. The activation energy of the main transition for UPR resin and composites were calculated to be 173 and 350 kJ·mol−1 indicating that reinforcement results in an increase in the energy barrier to macromolecules viscoelastic relaxation. In addition, erosion resistance was studied during exposure of samples to cavitation tests. According to the obtained results, these materials can be applied in construction and mining industry.


Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1041
Author(s):  
Eliseo Hernandez-Duran ◽  
Luca Corallo ◽  
Tanya Ros-Yanez ◽  
Felipe Castro-Cerda ◽  
Roumen H. Petrov

This study focuses on the effect of non-conventional annealing strategies on the microstructure and related mechanical properties of austempered steels. Multistep thermo-cycling (TC) and ultrafast heating (UFH) annealing were carried out and compared with the outcome obtained from a conventionally annealed (CA) 0.3C-2Mn-1.5Si steel. After the annealing path, steel samples were fast cooled and isothermally treated at 400 °C employing the same parameters. It was found that TC and UFH strategies produce an equivalent level of microstructural refinement. Nevertheless, the obtained microstructure via TC has not led to an improvement in the mechanical properties in comparison with the CA steel. On the other hand, the steel grade produced via a combination of ultrafast heating annealing and austempering exhibits enhanced ductility without decreasing the strength level with respect to TC and CA, giving the best strength–ductility balance among the studied steels. The outstanding mechanical response exhibited by the UFH steel is related to the formation of heterogeneous distribution of ferrite, bainite and retained austenite in proportions 0.09–0.78–0.14. The microstructural formation after UFH is discussed in terms of chemical heterogeneities in the parent austenite.


2021 ◽  
Vol 10 (1) ◽  
pp. 62-72
Author(s):  
Huanran Lin ◽  
Xiuhua Guo ◽  
Kexing Song ◽  
Jiang Feng ◽  
Shaolin Li ◽  
...  

Abstract Although Cu–Al2O3 composites have good comprehensive performance, higher mechanical properties and arc erosion resistance are still required to meet heavy-duty applications such as electromagnetic railguns. In this work, a novel hybrid SiCw/Cu–Al2O3 composite was successfully prepared by combining powder metallurgy and internal oxidation. The microstructure and mechanical behavior of the SiCw/Cu–Al2O3 composite were studied. The results show that nano-Al2O3 particles and micro-SiCw are introduced into the copper matrix simultaneously. Well-bonded interfaces between copper matrix and Al2O3 particles or SiCw are obtained with improved mechanical and arc erosion resistance of SiCw/Cu–Al2O3 composite. The ultimate tensile strength of the SiCw/Cu–Al2O3 composite is 508.9 MPa, which is 7.9 and 56.1% higher than that of the Cu–Al2O3 composite and SiCw/Cu composite, respectively. The strengthening mechanism calculation shows that Orowan strengthening is the main strengthening mechanism of the SiCw/Cu–Al2O3 composite. Compared with Cu–Al2O3 composite, the hybrid SiCw/Cu–Al2O3 composite has lower arc time and energy and better arc stability.


2010 ◽  
Vol 150-151 ◽  
pp. 51-55 ◽  
Author(s):  
Jun Du ◽  
Ping Zhang ◽  
Jun Jun Zhao ◽  
Zhi Hai Cai

Titanium alloys are susceptible to sand erosion, hard zirconium nitride coatings have been deposited onto titanium alloys by Physical vapor deposition (PVD) in order to improve erosion resistance. Al and Cu were added into ZrN coatings to strength and toughing the coating. The microstructure and mechanical properties of ZrAlCuN coating were studied. Erosion tests were conducted to evaluate anti-erosion ability. Erosion rates were measured and characteristic damage features were identified on the surface of eroded specimens. The mechanisms of erosion are discussed in order to explain the promising performance of materials in erosive conditions. It was found that there is an significant increase of erosion resistance because of the increase of hardness and toughness.


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