Synthesis and Evaluation of a New Kind of Kinetic Hydrate Inhibitor

2017 ◽  
Vol 727 ◽  
pp. 781-790
Author(s):  
Ke Le Yan ◽  
Hong Xing Zhang ◽  
Ying Li ◽  
Bing Zou ◽  
An Shan Xiao ◽  
...  

A new kind of kinetic hydrate inhibitor (KHI) named KL-1 as the ramification of poly (N-vinyl caprolactam) (PVCap), was synthesized successfully by use of precipitation polymerization. The hydrate inhibition performance of KL-1 was assessed in a high pressure sapphire cell, and the onset time of hydrate formation and maximum subcooling were determined by the visual observation method and compared with the commercial KHIs, including Inhibex 501 and VC-713. Meanwhile, the synergic effect between ethanol and KL-1 developed was also studied in this work. The experimental results show that the onset time of KL-1 measured increases with the increase of the dosage and decrease of subcooling. Compared with the system without kinetic hydrate inhibitor, the morphological behavior of hydrate crystals in the systems containing KL-1 is different, and the hydrate crystals only grow to the gas phase with the hydrate formation. Additionally, based on the measurement of inhibition time, the inhibition performance of KL-1 is superior to Inhibex 501 and VC-713, and shows higher maximum subcooling at the similar conditions. Finally, we also demonstrated that ethanol can be used as synergist to improve the performance of KL-1 remarkably at suitable dosage.

2019 ◽  
Vol 965 ◽  
pp. 97-105
Author(s):  
Alexandre Mendonça Teixeira ◽  
Lara de Oliveira Arinelli ◽  
José Luiz de Medeiros ◽  
Ofélia de Queiroz Fernandes Araújo

The oil and gas industry represents an important contributor to CO2 emissions as offshore platforms are power intensive for producing, processing and transporting hydrocarbons. In offshore rigs CO2 emissions mainly come from on-site gas-fired power generation for heat and electricity production. The accumulation of atmospheric CO2 is one of the main causes of the planetary greenhouse effect, thus CO2 emissions should be minimized. To achieve that, more energy efficient processes for natural gas (NG) conditioning are needed in order to minimize platform power consumption and thus lowering the associated generation of CO2. In addition, in offshore scenarios gas-hydrate obstructions are a major concern in flow assurance strategies, since thermodynamic conditions favoring hydrate formation are present, such as high pressure, low external temperature and gas contact with free water. To avoid hydrate issues, hydrate inhibition is carried out by the injection of a thermodynamic hydrate inhibitor (THI) in well-heads such that it flows along with production fluids, thus removing the thermodynamic conditions for hydrate formation and ensuring unimpeded flow. Therefore, the three-phase high-pressure separator (HPS) is fed with production fluids, where the HPS splits the feed into: (i) an upper gas phase, (ii) hydrocarbon condensate, and (iii) a bottom aqueous phase. The gas phase goes to NG conditioning for hydrocarbon dew point adjustment (HCDPA) and water dew point adjustment (WDPA) so as to make NG exportable. The hydrocarbon condensate (if present) is collected for stabilization and the bottom aqueous phase consisting of water, salts and THI is sent to a THI recovery unit (THI-RU) for THI re-concentration and reinjection. In conventional plants, WDPA and HCDPA are done by glycol absorption and Joule-Thomson expansion respectively. Moreover, the HPS gas carries some THI such as methanol that is lost in the processing. This work analyses a new process – SS-THI-Recovery – where HPS gas feeds a supersonic separator (SS) with injected water and compares it to the conventional processing. As a result, SS ejects a cold two-phase condensate with almost all water, THI and C3+ hydrocarbons, discharging exportable NG with enough HCDPA and WDPA grades, while the condensate gives aqueous THI returned to the THI-RU and LPG with high commercial value. Thus, SS-THI-Recovery not only avoids THI losses as well as exports NG and LPG. Both conventional gas plant and SS-THI-Recovery alternative coupled to THI-RU were simulated in HYSYS 8.8 for a given NG field and targeting the same product specifications. SS-THI-Recovery presented lower power consumption and thus less associated CO2 emissions, while potentially increasing the gas plant profitability, as THI losses are significantly reduced and higher flow rate of LPG with higher commercial value is produced in comparison with the conventional alternative. Hence, the higher efficiency of SS-THI-recovery makes it not only more environmentally friendly with lower CO2 emissions, but also a potential alternative for improving process economics and thus providing an economic leverage that could justify investments in carbon capture technologies, contributing to avoid CO2 emissions even more with cleaner NG and LPG production.


2021 ◽  
Vol 5 (3) ◽  
pp. 32
Author(s):  
Benedikt Mutsch ◽  
Peter Walzel ◽  
Christian J. Kähler

The droplet deformation in dispersing units of high-pressure homogenizers (HPH) is examined experimentally and numerically. Due to the small size of common homogenizer nozzles, the visual analysis of the transient droplet generation is usually not possible. Therefore, a scaled setup was used. The droplet deformation was determined quantitatively by using a shadow imaging technique. It is shown that the influence of transient stresses on the droplets caused by laminar extensional flow upstream the orifice is highly relevant for the droplet breakup behind the nozzle. Classical approaches based on an equilibrium assumption on the other side are not adequate to explain the observed droplet distributions. Based on the experimental results, a relationship from the literature with numerical simulations adopting different models are used to determine the transient droplet deformation during transition through orifices. It is shown that numerical and experimental results are in fairly good agreement at limited settings. It can be concluded that a scaled apparatus is well suited to estimate the transient droplet formation up to the outlet of the orifice.


1981 ◽  
Vol 59 (15) ◽  
pp. 2412-2416 ◽  
Author(s):  
John A. Stone ◽  
Margaret S. Lin ◽  
Jeffrey Varah

The reactivity of the dimethylchloronium ion with a series of aromatic hydrocarbons has been studied in a high pressure mass spectrometer ion source using the technique of reactant ion monitoring. Benzene is unreactive but all others, from toluene to mesitylene, react by CH3+ transfer to yield σ-bonded complexes. The relative rate of reaction increases with increasing exothermicity in line with current theories of nucleophilic displacement reactions.


Author(s):  
J. Stengele ◽  
H.-J. Bauer ◽  
S. Wittig

The understanding of multicomponent droplet evaporation in a high pressure and high temperature gas is of great importance for the design of modern gas turbine combustors, since the different volatilities of the droplet components affect strongly the vapor concentration and, therefore, the ignition and combustion process in the gas phase. Plenty of experimental and numerical research is already done to understand the droplet evaporation process. Until now, most numerical studies were carried out for single component droplets, but there is still lack of knowledge concerning evaporation of multicomponent droplets under supercritical pressures. In the study presented, the Diffusion Limit Model is applied to predict bicomponent droplet vaporization. The calculations are carried out for a stagnant droplet consisting of heptane and dodecane evaporating in a stagnant high pressure and high temperature nitrogen environment. Different temperature and pressure levels are analyzed in order to characterize their influence on the vaporization behavior. The model employed is fully transient in the liquid and the gas phase. It accounts for real gas effects, ambient gas solubility in the liquid phase, high pressure phase equilibrium and variable properties in the droplet and surrounding gas. It is found that for high gas temperatures (T = 2000 K) the evaporation time of the bicomponent droplet decreases with higher pressures, whereas for moderate gas temperatures (T = 800 K) the lifetime of the droplet first increases and then decreases when elevating the pressure. This is comparable to numerical results conducted with single component droplets. Generally, the droplet temperature increases with higher pressures reaching finally the critical mixture temperature of the fuel components. The numerical study shows also that the same tendencies of vapor concentration at the droplet surface and vapor mass flow are observed for different pressures. Additionally, there is almost no influence of the ambient pressure on fuel composition inside the droplet during the evaporation process.


2015 ◽  
Vol 93 (9) ◽  
pp. 1025-1030 ◽  
Author(s):  
Nagu Daraboina ◽  
Christine Malmos Perfeldt ◽  
Nicolas von Solms

Low dosage kinetic hydrate inhibitors are employed as alternatives to expensive thermodynamic inhibitors to manage the risk of hydrate formation inside oil and gas pipelines. These chemicals need to be tested at appropriate conditions in the laboratory before deployment in the field. A high pressure micro differential scanning calorimeter HP-μDSC VII (Setaram Inc.) containing two 50 cc high pressure cells (maximum operating pressure 40 MPa; temperature range –40 to 120 °C) was employed to observe methane hydrate formation and decomposition in the presence of hyperactive antifreeze protein from Rhagium mordax (RmAFP) and biodegradable synthetic kinetic inhibitor Luvicap Bio. A systematic capillary dispersion method was used, and this method enhanced the ability to detect the effect of various inhibitors on hydrate formation with small quantities. The presence of RmAFP and Luvicap Bio influence (inhibit) the hydrate formation phenomena significantly. Luvicap Bio (relative strength compared to buffer: 13.3 °C) is stronger than RmAFP (9.8 °C) as a nucleation inhibitor. However, the presence RmAFP not only delays hydrate nucleation but also reduces the amount of hydrate formed (20%–30%) after nucleation significantly. Unlike RmAFP, Luvicap Bio promoted the amount of hydrate formed after nucleation. The superior hydrate growth inhibition capability and predictable hydrate melting behavior compared to complex, heterogeneous hydrate melting with Luvicap Bio shows that RmAFP can be a potential natural green kinetic inhibitor for hydrate formation in pipelines.


1999 ◽  
Vol 13 (29n31) ◽  
pp. 3623-3625 ◽  
Author(s):  
K. Amaya ◽  
K. Shimizu ◽  
M. I. Eremets

Techniques of producing ultra-high pressure at very low temperature and measuring method of electrical resistance and magnetization of samples confirmed in the used diamond anvil ceil (DAC) are shortly described. Experimental results on simple molecular systems such as iodine, sulfur, oxygen and organic iodanil are reviewed as typical example of pressure induced superconductivity.


2013 ◽  
Vol 111 (3) ◽  
pp. 469-481 ◽  
Author(s):  
J. P. J. van Lipzig ◽  
M. Yu ◽  
N. J. Dam ◽  
C. C. M. Luijten ◽  
L. P. H. de Goey

1977 ◽  
Vol 32 (1) ◽  
pp. 47-52 ◽  
Author(s):  
Marlis F. Mirbach ◽  
Manfred J. Mirbach ◽  
Alfons Saus

The photochemical cycloaddition of 1,3-cyclohexadiene (CHD) to ethylene and acetylene at pressures above 10 bar is described. Upon sensitized irradiation (2-acetylnaphthaline) CHD adds to ethylene at room temperature in dichloromethane to give cis-bicyclo[4,2,0]-oct-2-ene (1) along with dimers of cyclohexadiene. The yield of cross adduct increases with ethylene pressure (10-50 bar) whereas dimerisation decreases. Quantum yields of cross addition and dimerisation at 12 M ethylene were determined to be 0.31 and 0.35 respectively. At a pressure of 15 bar acetylene CHD reacts with acetylene to give bicyclo-[4,2,0]octa-2,7-diene (2) and bicyclo[2,2,2]octa-2,5-diene (3) as the major and minor products respectively. In a solvent mixture containing 60 vol-% CH2Cl2 and 40 vol-% acetone (2) is formed with a quantum yield of φ = 0.2. The experimental results are explained by a formal kinetic scheme.


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