Research of Pyrophoric Compounds in Order to Reduce their Hazard

2021 ◽  
Vol 1038 ◽  
pp. 454-459
Author(s):  
Natalia Korovnikova ◽  
Volodymyr Oliinik ◽  
Oleksandr Dubyna
Keyword(s):  
Diesel Fuel ◽  
Spontaneous Combustion ◽  
Experimental Studies ◽  
Material Balance ◽  
Corrosion Damage ◽  
Petroleum Products ◽  
Practical Significance ◽  
Oil Refineries ◽  
Oil Storage ◽  
Organic Impurities

The constantly growing content of sulfur compounds and the increased water content in the extracted oil enhances the aggressiveness of the environments in which the technological equipment of oil depots and pipelines operates, resulting in a higher number of emergencies in the equipment of oil refineries. Thus, one of the most urgent problems is the corrosion damage to oil storage equipment and the associated consequences of flammable pyrophoric compounds formation. Finely dispersed flammable sulfides with organic impurities are formed in the equipment of the diesel fuel distillate hydrotreating unit thus accumulating on the bottoms and walls of tanks and reservoirs. This negatively affects the material balance of the hydrotreating process and increases fire and explosion hazards of the whole hydrotreating process at the refinery. For the first time, the elemental composition of pyrophoric deposits formed while storing petroleum products in the LCh-24-2000 unit was experimentally investigated. These sulfides are a flammable component of the equipment in the hydrotreating process, where diesel fuel distillates rotate. The obtained results of the test study as for the prevention of pyrophores spontaneous combustion indicate that hydrogen peroxide solutions have the highest efficiency. The practical significance of the results is in the use of experimental studies on the spontaneous combustion of pyrophoric samples in the development of the equipment cleaning terms during the hydrotreating process from pyrophoric deposits at the refinery. The experimental results of testing the ability of chemicals to prevent pyrophores spontaneous combustion can be used to reduce the risk of spontaneous combustion of pyrophoric compounds.

Energetic properties of peat saturated with petroleum products

2020 ◽  
Vol 13 (2) ◽  
pp. 105-109
Author(s):  
E. S. Dremicheva
Keyword(s):  
Crude Oil ◽  
Diesel Fuel ◽  
Energy Use ◽  
Experimental Studies ◽  
Calorific Value ◽  
Petroleum Products ◽  
Ash Content ◽  
Motor Oil ◽  
Initial Sample

This paper presents a method of sorption using peat for elimination of emergency spills of crude oil and petroleum products and the possibility of energy use of oil-saturated peat. The results of assessment of the sorbent capacity of peat are presented, with waste motor oil and diesel fuel chosen as petroleum products. Natural peat has been found to possess sorption properties in relation to petroleum products. The sorbent capacity of peat can be observed from the first minutes of contact with motor oil and diesel fuel, and significantly depends on their viscosity. For the evaluation of thermal properties of peat saturated with petroleum products, experimental studies have been conducted on determination of moisture and ash content of as-fired fuel. It is shown that adsorbed oil increases the moisture and ash content of peat in comparison with the initial sample. Therefore, when intended for energy use, peat saturated with petroleum products is to be subjected to additional drying. Simulation of net calorific value has been performed based on the calorific values of peat and petroleum products with different ratios of petroleum product content in peat and for a saturated peat sample. The obtained results are compared with those of experiments conducted in a calorimetric bomb and recalculated for net calorific value. A satisfactory discrepancy is obtained, which amounts to about 12%. Options have been considered providing for combustion of saturated peat as fuel (burnt per se and combined with a solid fuel) and processing it to produce liquid, gaseous and solid fuels. Peat can be used to solve environmental problems of elimination of emergency spills of crude oil and petroleum products and as an additional resource in solving the problem of finding affordable energy.

Inhibited compound for internal preservation

2019 ◽  
Vol 60 (12) ◽  
pp. 81-86
Author(s):  
Renata S. Krymskaya ◽  
Keyword(s):  
Corrosion Inhibitor ◽  
Corrosion Protection ◽  
Diesel Fuel ◽  
Petroleum Products ◽  
Accelerated Corrosion ◽  
Oil Storage ◽  
Accelerated Corrosion Tests ◽  
New Type ◽  
Metal Products ◽  
Derivatives Of

Corrosion of metal products during storage, transportation, or other inter-operational periods keeps researchers concerned, and as a result, encourages study of anti-corrosion protection agents in current unstable economic situation, for example, possibility of their recycling. It is not surprising that nowadays scientists are searching for anti-corrosion protection agents. Accordingly, important requirements for corrosion protection agents are affordability and adaptability. The term “adaptability” means that anti-corrosion protection agents can be used in hard-to-reach structures. Under such conditions, the best anti-corrosion protection agents are preservation compounds, as they are relatively inexpensive, often organic-based, with an effective corrosion inhibitor in. The author tested anti-corrosion effectiveness of FMT corrosion inhibitor solution in diesel fuel. FMT is a nitrogen-containing inhibitor consisting of tallow oil fatty acids and added copper derivatives of chlorophyll (where central magnesium atom of chlorophyll is replaced by copper). Copper derivatives of chlorophyll were obtained from kelp algae extract. We synthesized a new solution of FMT inhibitor in diesel fuel; this solution has a natural coniferous complex instead of copper derivatives of chlorophyll from algae. FMT efficiency was proved experimentally in accelerated corrosion tests. The paper explains necessity of synthesizing a new type of FMT inhibitor after experimental stability assessment of various solutions. The article also gives an example of how this compound can be used for storing petroleum products in the space between the first and second bottom of underground tanks (oil storage tanks with double walls and double bottom).

DIESEL ENGINE OPERATION IN USE OF FUEL WITH ADDITIVES

2018 ◽  
pp. 18-24
Author(s):  
Petar Kazakov ◽  
Atanas Iliev ◽  
Emil Marinov
Keyword(s):  
Diesel Engine ◽  
Fuel Consumption ◽  
Diesel Fuel ◽  
Internal Combustion Engines ◽  
Experimental Studies ◽  
Combustion Engines ◽  
Engine Operation ◽  
Factors Affecting ◽  
Operating Modes ◽  
Positive Effects

Over the decades, more attention has been paid to emissions from the means of transport and the use of different fuels and combustion fuels for the operation of internal combustion engines than on fuel consumption. This, in turn, enables research into products that are said to reduce fuel consumption. The report summarizes four studies of fuel-related innovation products. The studies covered by this report are conducted with diesel fuel and usually contain diesel fuel and three additives for it. Manufacturers of additives are based on already existing studies showing a 10-30% reduction in fuel consumption. Comparative experimental studies related to the use of commercially available diesel fuel with and without the use of additives have been performed in laboratory conditions. The studies were carried out on a stationary diesel engine СМД-17КН equipped with brake КИ1368В. Repeated results were recorded, but they did not confirm the significant positive effect of additives on specific fuel consumption. In some cases, the factors affecting errors in this type of research on the effectiveness of fuel additives for commercial purposes are considered. The reasons for the positive effects of such use of additives in certain engine operating modes are also clarified.

USE OF NORTHERN ECOTYPE SOYBEANS FOR BIOFUEL PRODUCTION

2020 ◽  
pp. 22-30
Author(s):  
SERGEY N. DEVYANIN ◽  
◽  
VLADIMIR A. MARKOV ◽  
ALEKSANDR G. LEVSHIN ◽  
TAMARA P. KOBOZEVA ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Soybean Oil ◽  
Diesel Fuel ◽  
Experimental Studies ◽  
Motor Fuel ◽  
Biodiesel Production ◽  
Biofuel Production ◽  
Exhaust Gases ◽  
Oil Productivity ◽  
Toxic Components

The paper presents the results of long-term research on the oil productivity and chemical composition of soybean oil of the Northern ecotype varieties in the Central Non-Black Earth Region. The authors consider its possible use for biodiesel production. Experiments on growing soybeans were carried out on the experimental fi eld of Russian State Agrarian University –Moscow Timiryazev Agricultural Academy (2008-2019) on recognized ultra-early ripening varieties of the Northern ecotype Mageva, Svetlaya, Okskaya (ripeness group 000). Tests were set and the research results were analyzed using standard approved methods. It has been shown that in conditions of high latitudes (57°N), limited thermal resources of the Non-Chernozem zone of Russia (the sum of active temperatures of the growing season not exceeding 2000°С), the yield and productivity of soybeans depend on the variety and moisture supply. Over the years, the average yield of soybeans amounted to 1.94 … 2.62 t/ha, oil productivity – 388 … 544 kg/ha, oil content – 19…20%, the content of oleic and linoleic fatty acids in oil – 60%, and their output from seeds harvested – 300 kg/ha. It has been established that as soybean oil and diesel fuel have similar properties,they can be mixed by conventional methods in any proportions and form stable blends that can be stored for a long time. Experimental studies on the use of soybean oil for biodiesel production were carried out on a D-245 diesel engine (4 ChN11/12.5). The concentrations of toxic components (CO, CHx, and NOx) in the diesel exhaust gases were determined using the SAE-7532 gas analyzer. The smoke content of the exhaust gases was measured with an MK-3 Hartridge opacimeter. It has been experimentally established that the transfer of a diesel engine from diesel fuel to a blend of 80% diesel fuel and 20% lubrication oil leads to a change in the integral emissions per test cycle: nitrogen oxides in 0.81 times, carbon monoxide in 0.89 times and unburned hydrocarbons in 0.91 times, i.e. when biodiesel as used as a motor fuel in a serial diesel engine, emissions of all gaseous toxic components are reduced. The study has confi rmed the expediency of using soybeans of the Northern ecotype for biofuel production.

JUSTIFICATION OF THE USE OF METALLURGICAL SLAGS AS A BACKFILL MATERIAL FOR QUARRY CAVITIES

2021 ◽  
pp. 15-25
Author(s):  
Volodymyr Bondarenko ◽  
◽  
Oleksandr Filonenko ◽  
Mykhailo Petlovanyi ◽  
Vladyslav Ruskykh ◽  
...  
Keyword(s):  
Blast Furnace ◽  
Large Scale ◽  
Experimental Studies ◽  
Metallurgical Slag ◽  
Open Pit ◽  
Practical Significance ◽  
Steel Smelting ◽  
Backfill Material ◽  
Steel Making ◽  
Metallurgical Slags

Purpose. Experimental studies of the interaction of blast-furnace and steel-making slags with open pit waters during their direct contact and assessment of the volume of filling of the formed man-made cavities during mining of mineral deposits. Methods. Based on the analysis, the current low level of metallurgical slag and the lack of real and effective directions of their large-scale utilization were determined. The laboratory studies of the interaction of metallurgical slags with open pit water at a certain time of interaction, generally accepted methods for studying the chemical composition and concentration of substances in water, computer-aided design software packages and drawings to determine the volumes of the open pit mined-out area were used. Results. The dynamics of changes in the products of interactions of steel-smelting slags with open-pit waters at a certain ratio and period of interaction was investigated. It was found that the concentration of pollutants upon contact of water with steel-making slag changes according to polynomial dependences on the time of their interaction, decreasing by the 30th day, which eliminates the danger for the aquifer. The safest type of metallurgical slag was recommended for the formation of the bottom layer of the backfill massif. The volumes of the mined-out area of the open pit were determined in detail to assess the volumes of placement of the backfill material based on metallurgical slags. Scientific novelty. The safety of the contact of backfill materials based on steelmaking slags with open pit water was scientifically proven, which is confirmed by the established polynomial patterns of changes in concentrations and pollutants from the ratio and time of interaction. Practical significance. The formation of the backfill massif on the basis of blast-furnace dump and steel-smelting slags will allow achieving an environmental effect, such as their safe disposal as a reclamation of technologically disturbed lands by mining and restoration of the economic value of the land plot, as well as preventing the formation of new dumps.

Characteristics of injection of diesel fuel, rapeseed oil and their mixtures in diesel engines of various types

2021 ◽  
pp. 167-178
Author(s):  
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Diesel Engines ◽  
Rapeseed Oil ◽  
High Speed ◽  
Fuel Injection ◽  
Experimental Studies ◽  
Fuel Injector ◽  
High Speed Diesel ◽  
Engine Type

The necessity of adapting diesel engines to work on vegetable oils is justified. The possibility of using rapeseed oil and its mixtures with petroleum diesel fuel as motor fuels is considered. Experimental studies of fuel injection of small high-speed diesel engine type MD-6 (1 Ch 8,0/7,5)when using diesel oil and rapeseed oil and computational studies of auto-tractor diesel engine type D-245.12 (1 ChN 11/12,5), working on blends of petroleum diesel fuel and rapeseed oil. When switching autotractor diesel engine from diesel fuel to rapeseed oil in the full-fuel mode, the mass cycle fuel supply increased by 12 %, and in the small-size high-speed diesel engine – by about 27 %. From the point of view of the flow of the working process of these diesel engines, changes in other parameters of the fuel injection process are less significant. Keywords diesel engine; petroleum diesel fuel; vegetable oil; rapeseed oil; high pressure fuel pump; fuel injector; sprayer

scholarly journals OIL SPILL INCIDENTS AND DISPERSANT APPLICATIONS IN KUWAIT

1987 ◽  
Vol 1987 (1) ◽  
pp. 247-253
Author(s):  
Salah M. Al-Mazidi ◽  
Omar Samhan
Keyword(s):  
Oil Spill ◽  
Marine Environment ◽  
Petroleum Hydrocarbons ◽  
Petroleum Hydrocarbon ◽  
Oil Spills ◽  
Petroleum Products ◽  
Coastal Environment ◽  
Industrial Activities ◽  
Oil Refineries ◽  
North And South

ABSTRACT Since the discovery of oil in Kuwait, most oil-related activities have been located along the coastline 50 km south of Kuwait City. Other related industrial activities have been developed in this area apart from oil and petroleum products export in order to diversify the national sources of income. For these reasons, the potential for large oil spills in Kuwait's marine environment is highest along the south coast, where oil refineries and exporting facilities are located. An average of 219 barrels of oil were spilled annually between 1979 and 1985, and 2,100 gallons of dispersants were used in cleanup operations. The majority of incidents involved less than 5 barrels of oil and 500 gallons of dispersants. Incidents involving more than 100 barrels of oil and 5,000 gallons of dispersants were confined to the Sea Island and Mina Al-Ahmadi North and South Piers. This distribution undoubtedly affects the concentration of petroleum residues in various components of the marine environment, resulting in an increase in tar ball density along this coast, reaching a maximum at Ras Az-Zor, and significantly higher levels of vanadium and petroleum hydrocarbons in sediments and oysters collected south of Mina Al-Ahmadi. The objective of this paper is to report on the number, volume, and frequency distribution of oil spill incidents in Kuwait and the usage of dispersants in cleanup operations. Vanadium and petroleum hydrocarbon concentrations also are described as is the sensitivity of the southern coastal environment to oil spills. Recommendations have been made on how to conduct cleanup operations for any future oil spill incidents along the southern shoreline of Kuwait.

scholarly journals Performance Evaluation of Single Cylinder Diesel Engine Using Tyre Pyrolysis Oil (TPO) Blends

2019 ◽  
Vol 7 (2) ◽  
pp. 46-51
Author(s):  
P M Bhatt
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Internal Combustion Engines ◽  
Petroleum Products ◽  
Permissible Limit ◽  
Pyrolysis Oil ◽  
Single Cylinder ◽  
Performance And Emission ◽  
Partial Load ◽  
Alternate Fuels

Increasing industrialization and motorization led to a significant rise in demand of petroleum products. As these are the non-renewable resources, it will be troublesome to predict the availability of these resources in the future, resulting in uncertainty in its supply and price and is impacting growing economies like India importing 80% of the total demand of the petroleum products. Many attempts have been made by different researchers to find out alternate fuels for Internal Combustion engines. Many alternate fuels like Biodiesel, LPG (Liquefied Petroleum Gas), CNG (Compressed Natural Gas) and Alcohol are being used nowadays by different vehicles. In this context pyrolysis of scrap tyres can be used effectively to produce oil, thereby solving the problem of waste tyre disposal. In the present study, Experimental investigations were carried out to evaluate the performance and emission characteristics of a single cylinder diesel engine fueled by TPO10, TPO15, and TPO20 at a crank angle 280 before TDC (Top Dead Centre) and injection pressure of 180 bar keeping the blend quality by controlling the density and viscosity of tyre pyrolysis oil within permissible limit of euro IV diesel requirement. The performance and emission results were analyzed and compared with that of diesel fuel operation. The results of investigations indicate that the brake thermal efficiency of the TPO - DF blend decreases by 4 to 8%. CO emissions are slightly higher but within permissible limit of euro IV emission standards. HC emissions are higher by about 40 to 60% at partial load whereas smoke opacity is lower by about 14% to 22% as compared to diesel fuel.

Diesel engine performance at the intake of the hydrogen&air mixture

2021 ◽  
pp. 119-126
Author(s):  
Keyword(s):  
Diesel Engine ◽  
Diesel Fuel ◽  
Internal Combustion Engines ◽  
Fuel Efficiency ◽  
Experimental Studies ◽  
Motor Fuel ◽  
Engine Performance ◽  
Calorific Value ◽  
Hydrocarbon Emissions ◽  
The Difference

The prospects of using hydrogen as a motor fuel are noted. The problems that arise when converting a diesel engine to run on hydrogen are considered. The features of the organization of the working process of enginesrunning on hydrogen are analyzed. A method of supplying a hydrogenair mixture to a diesel engine is investigated. To supply hydrogen to the engine cylinders, it is proposed to use the Leader4M installation developed by TechnoHill Club LLC (Moscow). Experimental studies of a stationary diesel engine of the D245.12 S type with the supply of hydrogen at the inlet obtained at this installation are carried out. At the maximum power mode, the supply of hydrogen from this installation to the inlet of the diesel engine under study was 0.9 % by weight (taking into account the difference in the calorific value of oil diesel fuel and hydrogen). Such a supply of hydrogen in the specified mode made it possible to increase the fuel efficiency of the diesel engine and reduce the smoke content of exhaust gases, carbon monoxide and unburned hydrocarbon emissions. Keywords internal combustion engines; diesel engine; diesel fuel; hydrogen; hydrogenair mixture; fuel efficiency; exhaust gas toxicity indicators

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