A Highly Efficient Activated Carbon by Chemical Activation Method for Adsorption of Paraquat (Toxin)

2013 ◽  
Vol 773-774 ◽  
pp. 471-477
Author(s):  
Md Mokhlesur Rahman ◽  
Mohamed Awang ◽  
Mohosina Bintey Shajahan ◽  
Tariq Abdul Razak ◽  
Kamaruzzaman Yunus
Keyword(s):  
Activated Carbon ◽  
Chemical Activation ◽  
Total Pore Volume ◽  
Activation Method ◽  
Nacl Solution ◽  
Adsorption Ability ◽  
Activation Temperature ◽  
Highly Efficient ◽  
Surface Areas

The optimum condition for preparing a highly efficient activated carbon has been investigated in this work. The effects of different activation temperatures on the pore structure and surface morphology of highly efficient activated carbon (AC) derived from waste palm shell by chemical activation method using phosphoric acid as activating agent were studied. For activation, different activation temperatures in the range of 550 °C-650 °C were carried out. Activated carbon with well developed pore size were produced at activation temperature of 600 °C for 2 hours. At this temperature the Brunauer , Emmett and Teller (BET) surface areas are 1287 m2g-1, the total pore volume for adsorption and desorption are 0.742 cm3 g-1. Scanning Electron Microscope also confirmed the porosity of the highly efficient activated carbon. Finally it was tested in vitro to determine its adsorbing capacity for paraquat as a toxin. For optimum adsorption ability of activated carbon for paraquat, 0.9% NaCl solution is the most suitable solvent. The paraquat preferentially adsorbed onto the activated carbon in NaCl solution. The adsorption ability of the activated carbon (the amount adsorbed) for paraquat observed to be 99.9 mg g-1.

Production of Activated Carbon from Ligin: Optimization Using Response Surface Methodology

2011 ◽  
Vol 213 ◽  
pp. 427-431 ◽  
Author(s):  
Li Jiang ◽  
Fei Ma ◽  
Ai Jun Gu ◽  
Li Jun Zhang
Keyword(s):  
Response Surface Methodology ◽  
Activated Carbon ◽  
Response Surface ◽  
Chemical Activation ◽  
Technological Parameters ◽  
Activation Temperature ◽  
Surface Areas ◽  
Optimum Response ◽  
Temperature Activation ◽  
Central Composite

Activated carbon（AC）were prepared from lignin by chemical activation with sodium hydroxide（NaOH）. The influence of activation temperature，activation time and impregnation ration on the BET surface areas were investigated. Based on the central composite design (CCD) and response surface methodology(RSM)，the optimized technological parameters were as follows: temperature 751°C， time 57min and impregnation ration 2.06, BET surface areas was up to 1437.20 m2/g.The adequacy of the model equation for predicting the optimum response values was verified effectively by the validation.

Preparation of activated carbons from wet activated sludge by direct chemical activation

2009 ◽  
Vol 59 (12) ◽  
pp. 2387-2394 ◽  
Author(s):  
X. Wang ◽  
N. Zhu ◽  
J. Xu ◽  
B. Yin
Keyword(s):  
Activated Carbon ◽  
Activated Sludge ◽  
Water Content ◽  
Iodine Value ◽  
Activated Carbons ◽  
Chemical Activation ◽  
Total Pore Volume ◽  
Processing Parameters ◽  
Experimental Conditions ◽  
Activation Temperature

An improved method for preparing activated carbons from wet waste activated sludge (WAS) by direct chemical activation was studied in this paper. The effects of processing parameters on iodine adsorption capacity of the product were investigated. Results show that sludge-based activated carbon prepared with KOH had a larger iodine value than those activated with ZnCl2 and KCl. The maximum iodine value was observed at the KOH concentration of 0.50 M. Increasing the impregnation time from 10 to 20 h resulted in a 20% increase in the iodine value. The highest iodine value was obtained at the activation temperature of 600°C and holding time of 1 h. Sludge water content had insignificant effects on the iodine value of products. Raw WAS with a water content of 93.2% can be converted into an activated carbon with a high specific surface area of 737.6 m2 g−1 and iodine value of 864.8 mgg−1 under optimum experimental conditions. Other physical properties such as total pore volume, micropore volume and mean pore diameter of the product were also reported and compared with those of commercial activated carbon.

Preparation and TG/DTG, FT-IR, SEM, BET Surface Area, Iodine Number and Methylene Blue Number Analysis of Activated Carbon from Pistachio Shells by Chemical Activation

2017 ◽  
Vol 16 (2) ◽  
Author(s):  
Mustafa Kaya ◽  
Ömer Şahin ◽  
Cafer Saka
Keyword(s):  
Methylene Blue ◽  
Activated Carbon ◽  
Iodine Number ◽  
Surface Area ◽  
Chemical Activation ◽  
Total Pore Volume ◽  
Bet Surface Area ◽  
Optimum Conditions ◽  
Activation Temperature ◽  
Pistachio Shell

AbstractIn this study, low cost activated carbon was prepared from the pistachio shell by chemical activation with zinc chloride (ZnCl2). The prepared activated carbon was characterized by thermogravimetry (TG) and differential thermal gravimetry (DTG), infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and Brunauer, Emmett and Teller (BET) surface area analyses. Results showed that the activation temperature and impregnation ratio have significant effect on the iodine number of the prepared activated carbon. The optimum conditions for preparing the activated carbon having the highest surface area were found to be an activation temperature of 700 °C, soaking time of 24 h and ZnCl2/ pistachio shell ratio of 50 %. The results showed that the BET surface area, total pore volume, iodine number and methylene blue (MB) number of activated carbon prepared under the optimum conditions were 1108 m2/g, 0.39 cm3/g, 1051 mg/g, 98.48 mg/g, respectively.

scholarly journals A New Approach for Controlling Mesoporosity in Activated Carbon by the Consecutive Process of Air Oxidation, Thermal Destruction of Surface Functional Groups and Carbon Activation (the OTA Method)

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2758
Author(s):  
Panuwat Lawtae ◽  
Chaiyot Tangsathitkulchai
Keyword(s):  
Activated Carbon ◽  
Surface Area ◽  
Functional Groups ◽  
Thermal Destruction ◽  
Total Pore Volume ◽  
Activation Method ◽  
Air Oxidation ◽  
Mesopore Volume ◽  
Activation Time ◽  
Activation Temperature

A new and simple method, based entirely on a physical approach, was proposed to produce activated carbon from longan fruit seed with controlled mesoporosity. This method, referred to as the OTA, consisted of three consecutive steps of (1) air oxidation of initial microporous activated carbon of about 30% char burn-off to introduce oxygen surface functional groups, (2) the thermal destruction of the functional groups by heating the oxidized carbon in a nitrogen atmosphere at a high temperature to increase the surface reactivity due to increased surface defects by bond disruption, and (3) the final reactivation of the resulting carbon in carbon dioxide. The formation of mesopores was achieved through the enlargement of the original micropores after heat treatment via the CO2 gasification, and at the same time new micropores were also produced, resulting in a larger increase in the percentage of mesopore volume and the total specific surface area, in comparison with the production of activated carbon by the conventional two-step activation method using the same activation time and temperature. For the activation temperatures of 850 and 900 °C and the activation time of up to 240 min, it was found that the porous properties of activated carbon increased with the increase in activation time and temperature for both preparation methods. A maximum volume of mesopores of 0.474 cm3/g, which accounts for 44.1% of the total pore volume, and a maximum BET surface area of 1773 m2/g was achieved using three cycles of the OTA method at the activation temperature of 850 °C and 60 min activation time for each preparation cycle. The two-step activation method yielded activated carbon with a maximum mesopore volume of 0.270 cm3/g (33.0% of total pore volume) and surface area of 1499 m2/g when the activation temperature of 900 °C and a comparable activation time of 240 min were employed. Production of activated carbon by the OTA method is superior to the two-step activation method for better and more precise control of mesopore development.

Synthesis of Activated Carbon from Cocos Nucifera Leaves Agrowaste by Chemical Activation Method

2016 ◽  
Vol 10 (2) ◽  
pp. 201-208
Author(s):  
Abhijit Jadhav ◽  
◽  
Govindraj Mohanraj ◽  
Keyword(s):  
Activated Carbon ◽  
Cocos Nucifera ◽  
Chemical Activation ◽  
Nitrogen Adsorption ◽  
Activation Method ◽  
Carbon Surface ◽  
Systematic Change ◽  
Sem Images ◽  
Activation Temperature ◽  
Impregnation Ratio

Activated carbon from Cocos nucifera leaves agrowaste was derived. The effect of impregnation ratio was studied by chemical activation method using phosphoric acid as an activating agent. Activated carbon was produced at the activation temperature of 673 K by slow pyrolysis. Nitrogen adsorption isotherms study was performed. Effect of impregnation ratio on the yield, methylene blue number, iodine number, and acid adsorption was studied. The FT-IR spectra show the presence of activated carbon. The TGA investigation reveals that activated carbon is thermally stable at 723 K. The SEM images show the incorporation of activated carbon particles which lead to the systematic change in the morphology of activated carbon. Surface chemistry study predicts the acidic and basic functional groups of Cocos nucifera leaves activated carbon.

Analisis Variasi Temperatur Aktivasi Terhadap Daya Serap Arang Aktif Tandan Aren (Arenga Pinnata Merr) Dengan Agen Aktivasi Potassium Silicate(K2SiO3)

2020 ◽  
Vol 5 (3) ◽  
pp. 221
Author(s):  
Muhammad Azam ◽  
Muhammad Anas ◽  
Erniwati Erniwati
Keyword(s):  
Methylene Blue ◽  
Activated Carbon ◽  
Adsorption Capacity ◽  
Temperature Variation ◽  
Chemical Activation ◽  
Weight Ratio ◽  
Potassium Silicate ◽  
Physical Activation ◽  
Activation Temperature ◽  
Pyrolysis Reactor

This study aims to determine the effect of variation of activation temperature of activated carbon from sugar palm bunches of chemically activatied with the activation agent of potassium silicate (K2SiO3) on the adsorption capacity of iodine and methylene blue. Activated carbon from bunches of sugar palmacquired in four steps: preparationsteps, carbonizationstepsusing the pyrolysis reactor with temperature of 300 oC - 400 oC for 8 hours and chemical activation using of potassium silicate (K2SiO3) activator in weight ratio of 2: 1 and physical activation using the electric furnace for 30 minutes with temperature variation of600 oC, 650 oC, 700 oC, 750 oC and 800 oC. The iodine and methyleneblue adsorption testedby Titrimetric method and Spectrophotometry methodrespectively. The results of the adsorption of iodine and methylene blue activated carbon from sugar palm bunches increased from 240.55 mg/g and 63.14 mg/g at a temperature of 600 oC to achieve the highest adsorption capacity of 325.80 mg/g and 73.59 mg/g at temperature of 700 oC and decreased by 257.54 mg/g and 52.03 mg/g at a temperature of 800 oCrespectively.However, it does not meet to Indonesia standard (Standard Nasional Indonesia/SNI), which is 750 mg/g and 120 mg/g respectively.

scholarly journals Computer Analysis of the Effect of Activation Temperature on the Microporous Structure Development of Activated Carbon Derived from Common Polypody

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2951
Author(s):  
Mirosław Kwiatkowski ◽  
Jarosław Serafin ◽  
Andy M. Booth ◽  
Beata Michalkiewicz
Keyword(s):  
Activated Carbon ◽  
Porous Structure ◽  
Computer Analysis ◽  
Density Functional ◽  
Activated Carbons ◽  
Chemical Activation ◽  
Geometrical Parameters ◽  
Activation Process ◽  
Microporous Structure ◽  
Activation Temperature

This paper presents the results of a computer analysis of the effect of activation process temperature on the development of the microporous structure of activated carbon derived from the leaves of common polypody (Polypodium vulgare) via chemical activation with phosphoric acid (H3PO4) at activation temperatures of 700, 800, and 900 °C. An unconventional approach to porous structure analysis, using the new numerical clustering-based adsorption analysis (LBET) method together with the implemented unique gas state equation, was used in this study. The LBET method is based on unique mathematical models that take into account, in addition to surface heterogeneity, the possibility of molecule clusters branching and the geometric and energy limitations of adsorbate cluster formation. It enabled us to determine a set of parameters comprehensively and reliably describing the porous structure of carbon material on the basis of the determined adsorption isotherm. Porous structure analyses using the LBET method were based on nitrogen (N2), carbon dioxide (CO2), and methane (CH4) adsorption isotherms determined for individual activated carbon. The analyses carried out showed the highest CO2 adsorption capacity for activated carbon obtained was at an activation temperature of 900 °C, a value only slightly higher than that obtained for activated carbon prepared at 700 °C, but the values of geometrical parameters determined for these activated carbons showed significant differences. The results of the analyses obtained with the LBET method were also compared with the results of iodine number analysis and the results obtained with the Brunauer–Emmett–Teller (BET), Dubinin–Radushkevich (DR), and quenched solid density functional theory (QSDFT) methods, demonstrating their complementarity.

scholarly journals Preparation of High-Performance Activated Carbon from Coffee Grounds after Extraction of Bio-Oil

Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 257
Author(s):  
Jie Ren ◽  
Nanwei Chen ◽  
Li Wan ◽  
Guojian Li ◽  
Tao Chen ◽  
...  
Keyword(s):  
Activated Carbon ◽  
High Performance ◽  
Average Pore Size ◽  
Total Pore Volume ◽  
Micropore Volume ◽  
Bet Surface Area ◽  
Average Pore ◽  
Activation Temperature ◽  
Coffee Grounds ◽  
Bio Oil

In this study, a new method for economical utilization of coffee grounds was developed and tested. The resulting materials were characterized by proximate and elemental analyses, thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and N2 adsorption–desorption at 77 K. The experimental data show bio-oil yields reaching 42.3%. The optimal activated carbon was obtained under vacuum pyrolysis self-activation at an operating temperature of 450 °C, an activation temperature of 600 °C, an activation time of 30 min, and an impregnation ratio with phosphoric acid of 150 wt.%. Under these conditions, the yield of activated carbon reached 27.4% with a BET surface area of 1420 m2·g−1, an average pore size of 2.1 nm, a total pore volume of 0.747 cm3·g−1, and a t-Plot micropore volume of 0.428 cm3·g−1. In addition, the surface of activated carbon looked relatively rough, containing mesopores and micropores with large amounts of corrosion pits.

Treatment of Dyeing and Printing Wastewater by Copper Oxide Loaded on Coconut Shell Activated Carbon

2011 ◽  
Vol 366 ◽  
pp. 412-415
Author(s):  
Yu De Liu ◽  
Bo Quan Jiang ◽  
Zheng Qiang Xiao
Keyword(s):  
Activated Carbon ◽  
Copper Oxide ◽  
Orthogonal Experiment ◽  
Chemical Activation ◽  
Copper Nitrate ◽  
Color Removal ◽  
Removal Rates ◽  
Activation Temperature ◽  
Coconut Shells ◽  
Coconut Shell Activated Carbon

The activated carbon loaded copper oxide catalyst was prepared from Hainan abandoned coconut shells using chemical activation method and applied in treatment of acid bright red GR simulation dyeing wastewater. The effects of phosphoric acid concentration, ratio of liquid to solid, activation time and activation temperature on the COD and color removal rates were investigated by orthogonal experiment. The results showed that the optimal values of the parameters above were 65% (in mass), 3:1, 2.5h and 500°C under the designed copper oxide loading conditions of calcining temperature 300°C,calcining time 3.0 h and use level of copper nitrate 15 mL. Using the prepared sample for the treatment of the wastewater, the COD and color removal rates reached 94.384% and 99.840%, respectively.

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