Flammability of the Disperse-Filled Polymer Composites

2016 ◽  
Vol 871 ◽  
pp. 40-46 ◽  
Author(s):  
Andrey Askadsky ◽  
Valentin Ushkov ◽  
Vladimir Smirnov ◽  
Viktor Voronin
Keyword(s):  
Experimental Data ◽  
Chemical Composition ◽  
Specific Heat ◽  
Main Parameter ◽  
Building Materials ◽  
Oxygen Index ◽  
Limiting Oxygen Index ◽  
Polymer Binders ◽  
Mineral Fillers ◽  
Epoxy Matrices

For the purpose of fire safe construction it is necessary to develop and investigate effects of fillers to flammability of building materials, including composite materials with polymer matrix. In present work we demonstrate the results of such investigation. We have examined influence of chemical composition, amount of mineral fillers to flammability, smoke-forming ability and limiting oxygen index of building materials based on different polymer binders. The experimental data indicate that the main parameter which determines the influence of mineral fillers on the flammability of composites is a specific heat absorbed by the filler. The dependence between limiting oxygen index and specific heat of mineral fillers is revealed for composites with epoxy matrices. This dependence is simple and beneficial for practical use.

scholarly journals Fire-Resiting Composites Based on Polymer Matrix

2018 ◽  
Vol 14 ◽  
pp. 1-13
Author(s):  
V.A. Ushkov ◽  
O.L. Figovsky
Keyword(s):  
Thermal Stability ◽  
Chemical Composition ◽  
High Efficiency ◽  
Oxygen Index ◽  
Epoxy Composites ◽  
Matrix Composites ◽  
Fire Retardants ◽  
Different Types ◽  
Mineral Fillers ◽  
Degree Of Filling

In the present work we have studied the thermal stability, flammability, fume evolution of epoxy matrix composites with different types and amounts of hardeners, fillers, plasticizers and fire retardants. It is shown that chemical composition of fillers has little effect on the flammability of epoxy composites when the content of mineral fillers is less than 45% by mass. Smoke formation decreases linearly with increasing the degree of filling. It is shown that to obtain low-combustible materials the oxygen index should exceed 31%. It was found that the optimal concentration of industrial brominated fire retardants is 8-10% by mass. To reduce the flammability of epoxy composites, additive brominated fire retardants in the form of a solution in N,N-dimethyl-2,4,6-tribromoaniline have been proposed. The high efficiency of acetyl-and α-hydroxyethyl ferrocene as a smoke suppressor of epoxy composites is shown.

An investigation into waterborne intumescent coating with different fillers for steel application

2018 ◽  
Vol 47 (2) ◽  
pp. 142-153 ◽  
Author(s):  
K. Md Nasir ◽  
N.H. Ramli Sulong ◽  
M.R. Johan ◽  
A.M. Afifi
Keyword(s):  
Fire Protection ◽  
Oxygen Index ◽  
Human Life ◽  
Equilibrium Temperature ◽  
Limiting Oxygen Index ◽  
Intumescent Coating ◽  
Content Type ◽  
Char Layer ◽  
Mineral Fillers ◽  
Practical Implications

Purpose This study aims to discuss the modification and/or improvement of intumescent coating system by incorporating waterborne resin with an appropriate combination of flame-retardant additives and four different fillers, namely, TiO2, Al(OH)3, Mg(OH)2 and CaCO3. Design/methodology/approach Coating mixtures are characterized using the Bunsen burner, thermogravimetric analysis, limiting oxygen index, scanning electron microscope, static immersion bath, Fourier transform infrared and adhesion tester. Findings Results show that the combination of coating with CaCO3 filler significantly improved fire protection performance because of its thick char layer and the equilibrium temperature being 264°C. Char layer showed a uniform dense foam structure on micrograph and this formulation had adhesion strength of 2.13 MPa, which indicates effectiveness of the interface adhesion on substrate. Conversely, the combination of coating with Al(OH)3 exhibited highest oxygen index of 35 per cent, which resulted in excellent flammability resistance. Research limitations/implications This paper discusses only the effect of mineral fillers on properties of intumescent coatings. Practical implications In the modern design of building infrastructure, fire safety is significant for the protection of human life and assets. The application of intumescent coating in buildings is currently practiced because of its effect on material flammability during a fire. Originality/value The analysis method to evaluate the performance of water-borne resin with different fillers is formulated, and it could be applied in all kinds of coatings and mixtures to be used as an effective fire protection system for steel constructions.

scholarly journals The Preparation, Thermal Properties, and Fire Property of a Phosphorus-Containing Flame-Retardant Styrene Copolymer

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao
Keyword(s):  
Thermal Properties ◽  
Thermogravimetric Analysis ◽  
Flame Retardant ◽  
Oxygen Index ◽  
Limiting Oxygen Index ◽  
Chemical Structures ◽  
1H Nuclear Magnetic Resonance ◽  
Phosphorus Containing ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.

scholarly journals Effects of Various Types of Expandable Graphite and Blackcurrant Pomace on the Properties of Viscoelastic Polyurethane Foams

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1801
Author(s):  
Rafał Oliwa ◽  
Joanna Ryszkowska ◽  
Mariusz Oleksy ◽  
Monika Auguścik-Królikowska ◽  
Małgorzata Gzik ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Chemical Structure ◽  
Oxygen Index ◽  
Polyurethane Foams ◽  
Expandable Graphite ◽  
Ftir Analysis ◽  
Limiting Oxygen Index ◽  
Peak Heat Release Rate ◽  
Physical And Chemical ◽  
Scanning Electron

We investigated the effect of the type and amount of expandable graphite (EG) and blackcurrant pomace (BCP) on the flammability, thermal stability, mechanical properties, physical, and chemical structure of viscoelastic polyurethane foams (VEF). For this purpose, the polyurethane foams containing EG, BCP, and EG with BCP were obtained. The content of EG varied in the range of 3–15 per hundred polyols (php), while the BCP content was 30 php. Based on the obtained results, it was found that the additional introduction of BCPs into EG-containing composites allows for an additive effect in improving the functional properties of viscoelastic polyurethane foams. As a result, the composite containing 30 php of BCP and 15 php of EG with the largest particle size and expanded volume shows the largest change in the studied parameters (hardness (H) = 2.65 kPa (+16.2%), limiting oxygen index (LOI) = 26% (+44.4%), and peak heat release rate (pHRR) = 15.5 kW/m2 (−87.4%)). In addition, this composite was characterized by the highest char yield (m600 = 17.9% (+44.1%)). In turn, the change in mechanical properties is related to a change in the physical and chemical structure of the foams as indicated by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) analysis.

scholarly journals An Effective Method for Preparation of Liquid Phosphoric Anhydride and Its Application in Flame Retardant Epoxy Resin

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2205
Author(s):  
Qian Li ◽  
Yujie Li ◽  
Yifan Chen ◽  
Qiang Wu ◽  
Siqun Wang
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Epoxy Resins ◽  
Oxygen Index ◽  
Decomposition Temperature ◽  
Ease Of Use ◽  
Limiting Oxygen Index ◽  
Good Thermal Stability ◽  
Low Viscosity ◽  
The Impact

A novel liquid phosphorous-containing flame retardant anhydride (LPFA) with low viscosity was synthesized from 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and methyl tetrahydrophthalic anhydride (MeTHPA) and further cured with bisphenol-A epoxy resin E-51 for the preparation of the flame retardant epoxy resins. Both Fourier transform infrared spectroscopy (FT-IR), mass spectrometry (MS) and nuclear magnetic resonance (NMR) measurements revealed the successful incorporation of DOPO on the molecular chains of MeTHPA through chemical reaction. The oxygen index analysis showed that the LPFA-cured epoxy resin exhibited excellent flame retardant performance, and the corresponding limiting oxygen index (LOI) value could reach 31.2%. The UL-94V-0 rating was achieved for the flame retardant epoxy resin with the phosphorus content of 2.7%. With the addition of LPFA, the impact strength of the cured epoxy resins remained almost unchanged, but the flexural strength gradually increased. Meanwhile, all the epoxy resins showed good thermal stability. The glass transition temperature (Tg) and thermal decomposition temperature (Td) of epoxy resin cured by LPFA decreased slightly compared with that of MeTHPA-cured epoxy resin. Based on such excellent flame retardancy, low viscosity at room temperature and ease of use, LPFA showed potential as an appropriate curing agent in the field of electrical insulation materials.

Research on Properties of Flame Retardant Silk Georgette

2012 ◽  
Vol 441 ◽  
pp. 284-288
Author(s):  
Hong Lu ◽  
Yan Chen ◽  
Jin Ping Guan
Keyword(s):  
Flame Retardant ◽  
Graft Copolymerization ◽  
Oxygen Index ◽  
Color Fastness ◽  
Limiting Oxygen Index ◽  
Wrinkle Resistance ◽  
Garment Design

In this paper, four kinds of silk georgettes with different density were chosen as samples. The flame retardant formaldehyde-free vinyl phosphate dimethyl-2-(methacryloyloxyethyl) phosphate (DMMEP) was grafted onto them by graft copolymerization technique. Some tests such as Limiting Oxygen Index (LOI), vertical flammability, wrinkle resistance and color fastness were examined. Through the discussion and analysis of the experiment results, the properties of original and treated fabrics were compared and suggestions were given for the flame retardant process and garment design.

Flame Retardation of Plain Weave Fabrics Made of Polyacrylonitrile Pre-Oxidized Yarns

2011 ◽  
Vol 175-176 ◽  
pp. 465-468 ◽  
Author(s):  
Lei Shi ◽  
Hua Wu Liu ◽  
Ping Xu ◽  
Dang Feng Zhao
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Oxygen Index ◽  
Limiting Oxygen Index ◽  
Plain Weave ◽  
Weave Fabric ◽  
Short Period ◽  
Flame Retardation ◽  
Fabric Structures

Plain weave fabrics of polyacrylonitrile pre-oxidation yarns (PANOF) were prepared by small rapier loom. The flame retardation properties, mechanical properties and wear behaviors of PANOF plain weave fabrics were tested. The limiting oxygen index (LOI) of these PANOF plain weave fabric samples was 31%, which meets the criterion of flame-retardant fabrics. These fabrics neither melt nor shrunk when left in flame for a short period of time and the fabric structures were well maintained. Compared with flammable polyacrylonitrile fabrics, the polyacrylonitrile pre-oxidation fabrics exhibited excellent flame retardation properties, with satisfactory mechanical properties and comfortable handle.

The Research of Iron Containing Wastes Modification Process of Leninabad Rare Metals Plant

2021 ◽  
Vol 410 ◽  
pp. 778-783
Author(s):  
Pavel V. Matyukhin ◽  
Daler I. Mirzoev
Keyword(s):  
Chemical Composition ◽  
Building Materials ◽  
Raw Material ◽  
Filling Material ◽  
Rare Metals ◽  
X Ray ◽  
Modification Process ◽  
Before And After ◽  
The Republic ◽  
Enrichment Process

The paper presents the results of ferriferous wastes modification process research carried on the basis of JCS “Leninobad rare metals Plant” located in the Republic of Tajikistan. The wastes for the study were taken from the western tailing. The article presents the justification of the chosen wastes as a filling material in the development of new radiation protective composite building materials. The data on the initial ferriferous chemical composition of the tailing wastes and the chemical composition of the material that passed the enrichment process is presented. The study contains microphotos of ferriferous haematite raw material particles surface before and after completing the modifying process. The paper presents and describes the study of X-ray phase analysis diffractograms of enriched iron-containing wastes before and after the modification process. The current research proves that the enrichment ferriferous wastes particles modification process is possible and as a result it can be used as a filling for the development of new kinds of radioprotective composite materials.

Interfacial interactions between urea formaldehyde and cellulose nanofibrils (CNFs) of varying chemical composition and their impact on particle boards manufacture (PBs)

2021 ◽  
Author(s):  
Maria C. Iglesias ◽  
Philip S. McMichael ◽  
Osei A. Asafu-Adjaye ◽  
Brian K. Via ◽  
Maria S. Peresin
Keyword(s):  
Chemical Composition ◽  
Building Materials ◽  
Colloidal Stability ◽  
Low Cost ◽  
Urea Formaldehyde ◽  
Cellulose Nanofibrils ◽  
Global Market ◽  
Modulus Of Rupture ◽  
Superior Performance ◽  
Interfacial Interactions

Abstract Wood-based panels are commonly used as building materials for interior and exterior purposes. Their production and utilization have increased over the past decades due to the useful properties they present. Adhesive-bonded products make up to 80% of the wood alternatives on the global market, and of that, urea-formaldehyde (UF) makes up approximately 81% of the resins used. Formaldehyde-based resins are used due to their effectiveness and low cost, as well as their ease of application and lack of color. Nevertheless, their main disadvantages are the lack of tackiness and the emission of formaldehyde over time. To improve UF performance, the utilization of microfibrillated cellulose, has been demonstrated to be effective. However, more understanding on the mechanisms of the interactions is of relevant importance. In this work, we studied interfacial interactions between UF with bleached (BCNF) and unbleached (LCNF) cellulose nanofibrils using Quartz Crystal Microbalance with dissipation monitoring (QCM-D) technique observing the superior performance of lignin-containing CNF. Additionally, the surface free energies were investigated using Contact Angle Measurements (CA) showing a decrease of the values mainly when utilizing LCNF, which was later correlated with the wettability properties of the particle boards (PBs). PBs with different adhesive/CNF formulations were produced showing larger improvements when adding LCNF in terms of modulus of elasticity (MOE), modulus of rupture (MOR), and internal bonding (IB). To gain a better understanding on the interactions between CNF and UF, CNF was fully characterized in terms of morphology, chemical composition, charge density, as well as thermal and colloidal stability.

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