Influence of Calcium on the Structure and Mechanical Properties of Biodegradable Zinc Alloys

2017 ◽  
Vol 891 ◽  
pp. 400-403 ◽  
Author(s):  
Iva Pospíšilová ◽  
Věra Soukupová ◽  
Dalibor Vojtěch
Keyword(s):  
Mechanical Properties ◽  
Alloy Composition ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Small Addition ◽  
Secondary Phases ◽  
Zinc Alloys ◽  
Suitable Material ◽  
Human Bones ◽  
Alloy Microstructure

In this work, Zn-1.5Mg-0.5Ca alloy was studied. The alloy composition was chosen according to the results of our previous work that was focused on the research of biodegradable materials. The mechanical properties of such cast alloy are similar to the characteristics of human bones. Moreover, Zn-1.5Mg alloy itself satisfies biocompatibility requirements. The main goal of this work was to improve the mechanical properties of this alloy. A small addition of calcium affected both the alloy microstructure and mechanical properties. Light microscope and scanning electron microscope were used for the analysis of microstructure. After calcium addition, secondary phases were visible in observed micrographs; their composition was verified by XRD. Mechanical properties (Vickers hardness, compressive and tensile tests) were studied and compared with the Zn-1.5Mg alloy prepared in our previous work. Based on presented results, Zn-1.5Mg-0.5Ca alloy is intended for use in medicine as a suitable material for temporary implants.

scholarly journals Corrosion Behavior, Microstructure and Mechanical Properties of Novel Mg-Zn-Ca-Er Alloy for Bio-Medical Applications

Metals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 519
Author(s):  
Devadas Bhat Panemangalore ◽  
Rajashekhara Shabadi ◽  
Manoj Gupta
Keyword(s):  
Mechanical Properties ◽  
Corrosion Behavior ◽  
Base Material ◽  
Hot Extrusion ◽  
Secondary Phases ◽  
Zinc Alloys ◽  
Alloying Additions ◽  
Degradation Rates ◽  
Master Alloys ◽  
Melt Deposition

In this study, the effect of calcium (Ca) and erbium (Er) on the microstructure, mechanical properties, and corrosion behavior of magnesium-zinc alloys is reported. The alloys were prepared using disintegrated melt deposition (DMD) technique using the alloying additions as Zn, Ca, and Mg-Er master alloys and followed by hot extrusion. Results show that alloying addition of Er has significantly reduced the grain sizes of Mg-Zn alloys and also when compared to pure magnesium base material. It also has substantially enhanced both the tensile and the compressive properties by favoring the formation of MgZn2 type secondary phases that are uniformly distributed during hot-extrusion. The quaternary Mg-Zn-Ca-Er alloy exhibited the highest strength due to lower grain size and particle strengthening due to the influence of the rare earth addition Er. The observed elongation was a result of extensive twinning observed in the alloys. Also, the degradation rates have been substantially reduced as a result of alloying additions and it is attributed to the barrier effect caused by the secondary phases.

scholarly journals The Mechanical Properties of AlSi17Cu5 Cast Alloy after Overheating and Modification of CuP Master Alloy

2013 ◽  
Vol 13 (3) ◽  
pp. 68-71
Author(s):  
J. Piątkowski ◽  
M. Jabłońska
Keyword(s):  
Mechanical Properties ◽  
Elevated Temperature ◽  
Master Alloy ◽  
Liquid State ◽  
Alloy Composition ◽  
Cast Alloy ◽  
Primary Silicon ◽  
Grain Structure ◽  
Silicon Crystals ◽  
Fine Grain

Abstract The paper presents the results of studies on the effect of the AlSi17Cu5 alloy overheating to atemperature of 920°C and modification with phosphorus (CuP10) on the resultingmechanical (HB, Rm, R0.2) and plastic (A5 and Z) properties. It has been shown that, so-called, "timethermal treatment" (TTT) of an alloy in the liquid state, consisting inoverheating the metal to about 250°C above Tliq,holding at this temperature by 30 minutes improvesthe mechanical properties. It has also been found that overheating of alloy above Tliq.enhances the process of modification, resulting in the formation of fine-grain structure. The primary silicon crystals uniformly distributed in the eutectic and characteristics ofthe α(Al) solution supersaturated with alloying elements present in the starting alloy composition (Cu, Fe) provide not only an increase of strength at ambient temperature but also at elevated temperature (250°C).

EFFECT OF THIXOFORMING ON THE MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AL-6%SI-3%CU ALLOY

2017 ◽  
Vol 79 (5-2) ◽  
Author(s):  
Mohd Shukor Salleh ◽  
Mohd Azizul Hikmi Safian ◽  
Mohamad Ridzuan Mohamad Kamal ◽  
Zolkarnain Marjom ◽  
Saifudin Hafiz Yahaya ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Hydraulic Press ◽  
Permanent Mold ◽  
Cast Sample ◽  
X Ray ◽  
Cu Alloy ◽  
Microstructure And Mechanical Properties ◽  
Mold Casting

Thixoforming is a type of semisolid metal (SSM) processing for forming alloys in the semisolid state to near net-shaped products. In the present study, the effect of a thixoforming process on the microstructure and mechanical properties of Al-6Si-3Cu aluminium alloy was investigated. Melt was poured on a cooling slope at 630oC and the samples were obtained through permanent mold casting. They were thixoformed using a hydraulic press after holding at 571oC for 5min to yield a microstructure predominantly composed of α-Al globules and inter-globular Si particles. As-cast and thixoformed samples were characterized using optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and X-ray diffraction (XRD) as well as hardness measurements and tensile tests. The results indicate that the mechanical properties of thixoformed alloy have improved as compared to permanent mold cast alloy. The ultimate tensile strength of as-cast sample was 210 ± 3.5 MPa and increased to 241 ±3.1 MPa in the thixoformed sample while the yield strength of as-cast alloy was 140 ±4.5 MPa and increased to 176±3.3 MPa in the thixoformed sample. The thixoformed alloy also showed an improvement in elongation to fracture as it increased from 2% in as-cast sample to 3.2% in thixoformed alloy. The fracture of as-cast sample showed a cleavage fracture, whereas in the thixoformed alloy, a combination of dimple and cleavage was observed.

Investigation on the Microstructure and Mechanical Properties of Hot Forged Mg−8Gd−2Y−1Nd−0.3Zn−0.6Zr Alloy

2011 ◽  
Vol 284-286 ◽  
pp. 1598-1602 ◽  
Author(s):  
Xiu Li Hou ◽  
Zhan Yi Cao ◽  
Li Dong Wang ◽  
Li Min Wang
Keyword(s):  
Mechanical Properties ◽  
Large Strain ◽  
Hot Forging ◽  
Tensile Tests ◽  
Age Hardening ◽  
Secondary Phases ◽  
Ageing Treatment ◽  
Size Refinement ◽  
Microstructure And Mechanical Properties ◽  
Peak Aged

The influences of hot forging and ageing treatment on the microstructure and mechanical properties of Mg−8Gd−2Y−1Nd−0.3Zn−0.6Zr (wt.%) alloy have been investigated. The results showed that the grains were significantly refined after hot forging. And the secondary phases in this alloy i.e. Mg5(Gd1-x-yNdxYy) and Mg24(Y1-x-yGdxNdy)5phases were fragmented to small particles due to the large strain during hot forging. Tensile tests revealed that mechanical properties were improved due to grain size refinement. Moreover, the as-forged alloy exhibited remarkable age-hardening response and mechanical properties were further improved by ageing treatment. The ultimate tensile strength, yield strength and elongation of the peak-aged (T5) alloy are 286 MPa, 245 MPa and 5.6 % at room temperature, and 211 MPa, 103 MPa and 19.4 % at 300°C, respectively.

The Effect of Remelting on the Microstructure and Mechanical Properties of a Nickel Superalloy

2016 ◽  
Vol 849 ◽  
pp. 492-496
Author(s):  
Zhi Wei Zhang ◽  
Yong Ji Niu ◽  
Jian Jun Tian ◽  
Ning An ◽  
Yang Gao ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Nickel Superalloy ◽  
Temperature Changes ◽  
X Ray ◽  
Optical Micrograph ◽  
Microstructure And Mechanical Properties ◽  
Shell Temperature ◽  
Average Grain Size

Effect of remelting processes on the microstructure and mechanical properties of as-cast Nimonic 90 superalloy was investigated by OM (optical micrograph), SEM (scanning electron microscopy), EDS (energy-dispersive X-ray) and tensile tests. The results indicated that the microstructure of the as-cast alloy was mainly composed of γ, γ' and carbides which contain Ti and Cr elements. The average grain size of the alloy tends to increase with mould shell temperature ranging from 350°C to 950°C. The strength of the as-cast alloy decreased with the increasing of mold shell temperature, with constant elongation as the mold shell temperature changes.

Synthesis, Microstructure, and Mechanical Properties of FeCo-VC Composites

2006 ◽  
Vol 980 ◽  
Author(s):  
Hongbin Bei ◽  
E. P. George
Keyword(s):  
Mechanical Properties ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Eutectic Structure ◽  
Directionally Solidified ◽  
Quaternary Alloys ◽  
The Matrix ◽  
Solid Solution Matrix ◽  
Solution Matrix

AbstractFe-Co-V-C quaternary alloys were drop cast and directionally solidified to obtain an in situ composite. It is found that the fully eutectic structure occurs at a composition of Fe - 40.5Co -10.4V- 8.6C (at. %) in a drop-cast alloy. Directional solidification of this composition in a high-temperature optical floating zone furnace produces a well-aligned microstructure, consisting of sub-micron VC fibers (~19% by volume) embedded in a FeCo-5V solid solution matrix containing ~ 1% C. The temperature dependencies of mechanical properties of this composite were examined by tensile tests and the composite was found to have higher yield strength and lower ductility than the matrix.

scholarly journals Solidification, Microstructure and Mechanical Properties of Mg-2.8Nd-1.5Gd-0.5Zn-0.5Zr Cast Alloy with Erbium Addition

2018 ◽  
Vol 202 ◽  
pp. 01001
Author(s):  
R. Ahmad ◽  
A.M.M. Elaswad ◽  
M. Z. Hamzah ◽  
N. R. Shahizan
Keyword(s):  
Electron Microscopy ◽  
Mechanical Properties ◽  
Scanning Electron Microscopy ◽  
Grain Size ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Optical Microscope ◽  
Microstructure Analysis ◽  
Cooling Curve ◽  
Scanning Electron

The thermal parameters of Mg-2.8Nd-1.5Gd-0.5Zn-0.5Zr cast alloy with 0.25 wt.% of erbium (Er) were evaluated by the computer-aided cooling curve thermal analysis(CA CCTA), whereas the microstructure analysis was investigated by the optical microscope and scanning electron microscopy. Results from the cooling curve and microstructure analysis showed that Er altered the grain size of the alloys. In addition, the grain size was reduced by approximately 19.6% with the addition of Er. Scanning electron microscopy results showed that Er formed an Mg-Zn-Nd-Er phase which distributed along the grain boundaries. Furthermore, the mechanical properties were investigated by hardness and tensile tests with Er addition. The addition of 0.25 wt.% of Er significantly improved the ultimate tensile strength and yield strength. In addition, the hardness value of Mg-2.8Nd-1.5Gd-0.5Zn-0.5Zr increased by 13.9% with Er addition.

Research on the Microstructure and Mechanical Properties of Spray-Deposited 8009 Heat Resistant Aluminum Alloy

2014 ◽  
Vol 543-547 ◽  
pp. 3733-3736
Author(s):  
Rong Hua Zhang ◽  
Biao Wu ◽  
Xiao Ping Zheng
Keyword(s):  
Mechanical Properties ◽  
Aluminum Alloy ◽  
Tensile Tests ◽  
Test Results ◽  
Secondary Phases ◽  
X Ray Diffraction ◽  
X Ray ◽  
Heat Resistant ◽  
Microstructure And Mechanical Properties ◽  
Transmission Electron

In this study, 8009 heat resistant aluminum alloy was synthesized by the spray atomization and deposition technique. The microstructure and mechanical properties of the alloy were studied using transmission electron microscopy, X-ray diffraction, and tensile tests. The secondary phases in the microstructure of the spray-deposited alloy were examined. The tensile test results indicate that the spray-deposited 8009 alloy both at room and elevated temperature displays superior tensile strength due to the presence of the thermally stable Al12(Fe,V)3Si particles.

Microstructure and Mechanical Properties of an Al-Cu-Mg-Fe-Ni Alloy

2014 ◽  
Vol 988 ◽  
pp. 156-160
Author(s):  
Hong Wei Liu ◽  
Feng Wang ◽  
Bai Qing Xiong ◽  
Yong An Zhang ◽  
Zhi Hui Li ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cast Alloy ◽  
Tensile Tests ◽  
Eutectic Structure ◽  
Test Results ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microstructure And Mechanical Properties ◽  
Ni Alloy ◽  
Scanning Electron

The microstructure and mechanical properties of the Al-2.24Cu-1.42Mg-0.9Fe-0.9Ni alloy were studied using optical microscopy (OM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and tensile tests. The results indicate that the microstructures of the as cast alloy involve α-Al matrix, Al/Al2CuMg eutectic structure, Al7Cu2Fe, Al7Cu4Ni and Al9FeNi compounds. The tensile test results indicate that the alloy at elevated temperature (200°C) displays superior tensile strength due to the presence of the thermally stable Al7Cu2Fe, Al7Cu4Ni and Al9FeNi compounds.

Effect of Overheating on the Mechanical and Plastic Properties of A390.0 Cast Alloy

2013 ◽  
Vol 211 ◽  
pp. 9-14
Author(s):  
Jaroslaw Piątkowski
Keyword(s):  
Mechanical Properties ◽  
Elevated Temperature ◽  
Alloy Composition ◽  
Cast Alloy ◽  
Primary Silicon ◽  
Grain Structure ◽  
Automotive Applications ◽  
Plastic Properties ◽  
Silicon Crystals ◽  
Fine Grain

The paper presents the results of studies on the effect of the A390.0 (AlSi17Cu5) alloy overheating to a temperature of 920°C and modification with phosphorus (CuP10) on the resulting mechanical (HB, Rm, R0.2) and plastic (A5and Z) properties. It has been shown that, so-called, "time-thermal treatment" (TTT) of an alloy in the liquid state, consisting in overheating the metal to about 250÷300°C above Tliq, holding at this temperature and rapid cooling, refines the structure and improves the mechanical properties. It has also been found that strong overheating of alloy above Tliq"enhances" the process of modification, resulting in the formation of fine-grain structure. The primary silicon crystals uniformly distributed in the eutectic and characteristics of the α (Al) solution supersaturated with alloying elements present in the starting alloy composition (Cu, Fe) provide not only an increase of strength at ambient temperature but also at elevated temperature (250°C), which is of particular importance for the automotive applications, especially as regards cast pistons operating in IC.

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