High Thermal Stability of SiC Packaging with Sintered Ag Paste Die-attach combined with Imide-based Molding

2015 ◽  
Vol 2015 (1) ◽  
pp. 000349-000352 ◽  
Author(s):  
Shijo Nagao ◽  
Takuo Sugioka ◽  
Satoshi Ogawa ◽  
Teruhisa Fujibayashi ◽  
Zhang Hao ◽  
...  

We report that ultra-high thermal reliability can be achieved by combining Ag paste sintering die-attach and injection transfer molding with imide-based mold composite. Test specimens of SiC SBD in TO247 discrete-package are prepared; SiC dies bonded on Cu lead frame, Al ribbon wiring from electrode of SiC Schottky barrier diode (SBD) chip to the Cu leads, and injection transfer molding process. The hybrid nano+micro flake Ag paste realizes a low temperature bond process of 250°C in air, die-shear stress recorded 23 MPa without intensive pressure. The thermo-mechanical parameters like glass transition temperature, Young's modulus and CTE of the thermosetting composite are carefully tuned for both the manufacturing process targeting the device operating temperature of 250°C. The test pieces are tested by harsh thermal cycling between −50°C to 250°C, and compared with the other specimens made with usual Pb-5Sn soldering die-attach with the same molding composite. Interface failures are investigated by scanning acoustic tomography (SAT), and the electric properties of SBD are checked by I-V measurements. The sintered Ag die-attach survived over 500 cycles without any failures around the interfaces of SiC die, Cu lead-frame, and mold materials, and no obvious change is found in electronic properties. However, Pb-Sn die-attach joints are gradually damaged with increasing thermal cycles causing degraded I-V property. The SEM images indicate the microstucture of sintered Ag layer is unchanged after the thermal cycles, because of the impregnated imid-matrix into the porous Ag. Our results demonstrate that the combination of Ag sinter paste die-attach and imide-based thermosetting composite can be a massproduction-ready packaging technology to realize the high operation temperature of post-silicon power devices.

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2531 ◽  
Author(s):  
Seungjun Noh ◽  
Hao Zhang ◽  
Katsuaki Suganuma

In this work, efforts were made to prepare a thermostable die-attach structure which includes stable sintered microporous Ag and multi-layer surface metallization. Silicon carbide particles (SiCp) were added into the Ag sinter joining paste to improve the high-temperature reliability of the sintered Ag joints. The use of SiCp in the bonding structures prevented the morphological evolution of the microporous structure and maintained a stable structure after high temperature storage (HTS) tests, which reduces the risk of void formation and metallization dewetting. In addition to the Ag paste, on the side of direct bonded copper (DBC) substrates, the thermal reliability of various surface metallizations such as Ni, Ti, and Pt were also evaluated by cross-section morphology and on-resistance tests. The results indicated that Ti and Pt diffusion barrier layers played a key role in preventing interfacial degradations between sintered Ag and Cu at high temperatures. At the same time, a Ni barrier layer showed a relatively weak barrier effect due to the generation of a thin Ni oxide layer at the interface with a Ag plating layer. The changes of on-resistance indicated that Pt metallization has relatively better electrical properties compared to that of Ti and Ni. Ag metallization, which lacks barrier capability, showed severe growth in an oxide layer between Ag and Cu, however, the on-resistance showed fewer changes.


Author(s):  
Ryo Kato ◽  
Masatoshi Okuda ◽  
Suguru Hashidate ◽  
Takamichi Mori ◽  
Junichiro Minami ◽  
...  

Aerospace ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 5
Author(s):  
Sicong Yu ◽  
Xufeng Zhang ◽  
Xiaoling Liu ◽  
Chris Rudd ◽  
Xiaosu Yi

In this concept-proof study, a preform-based RTM (Resin Transfer Molding) process is presented that is characterized by first pre-loading the solid curing agent onto the preform, and then injecting the liquid nonreactive resin with an intrinsically low viscosity into the mold to infiltrate and wet the pre-loaded preform. The separation of resin and hardener helped to process inherently high viscosity resins in a convenient way. Rosin-sourced, anhydrite-cured epoxies that would normally be regarded as unsuited to liquid composite molding, were thus processed. Rheological tests revealed that by separating the anhydrite curing agent from a formulated RTM resin system, the remaining epoxy liquid had its flowtime extended. C-scan and glass transition temperature tests showed that the preform pre-loaded with anhydrite was fully infiltrated and wetted by the liquid epoxy, and the two components were diffused and dissolved with each other, and finally, well reacted and cured. Composite laminates made via this approach exhibited roughly comparable quality and mechanical properties with prepreg controls via autoclave or compression molding, respectively. These findings were verified for both carbon and ramie fiber composites.


2013 ◽  
Vol 35 (9) ◽  
pp. 1683-1689 ◽  
Author(s):  
Raghu Raja Pandiyan Kuppusamy ◽  
Swati Neogi

2013 ◽  
Vol 7 (2) ◽  
pp. 125-136 ◽  
Author(s):  
Iran de Oliveira ◽  
Sandro Amico ◽  
Jeferson Souza ◽  
Antonio de Lima

Author(s):  
Fei Qin ◽  
Shuai Zhao ◽  
Yanwei Dai ◽  
Lingyun Liu ◽  
Tong An ◽  
...  

Abstract Thermo-mechanical reliability assessment for sintered silver is a crucial issue as sintered silver is a promising candidate of die-attachment materials for power devices. In this paper, the nano-indentation tests are performed for sintered silver in typical die-attach interconnection under different thermal cycles. Based on thermal cycling test, the Young's modulus and hardness of sintered silver layer have been presented. It is found that the Young's modulus and hardness of sintered silver layer changes slightly although the microstructure of sintered silver also presents some variations. The stress and strain curves for different thermal cycling tests for sintered silver based on reverse analysis of nano-indentation are also given. The results show that the elastoplastic constitutive equations change significantly after thermal cycling tests, and the yielding stress decreases remarkably after 70 thermal cycles. The experimental investigation also show that the cracking behaviors of sintered silver depends on its geometry characteristics, which implies that the possible optimization of sintered silver layer could enhance its thermo-mechanical performance.


1999 ◽  
Vol 122 (3) ◽  
pp. 463-475 ◽  
Author(s):  
K-T. Hsiao ◽  
R. Mathur ◽  
S. G. Advani ◽  
J. W. Gillespie, ◽  
B. K. Fink

A closed form solution to the flow of resin in vacuum assisted resin transfer molding process (VARTM) has been derived. VARTM is used extensively for affordable manufacturing of large composite structures. During the VARTM process, a highly permeable distribution medium is incorporated into the preform as a surface layer. During infusion, the resin flows preferentially across the surface and simultaneously through the preform giving rise to a complex flow front. The analytical solution presented here provides insight into the scaling laws governing fill times and resin inlet placement as a function of the properties of the preform, distribution media and resin. The formulation assumes that the flow is fully developed and is divided into two regimes: a saturated region with no crossflow and a flow front region where the resin is infiltrating into the preform from the distribution medium. The flow front region moves with a uniform velocity. The law of conservation of mass and Darcy’s Law for flow through porous media are applied in each region. The resulting equations are nondimensionalized and are solved to yield the flow front shape and the development of the saturated region. It is found that the flow front is parabolic in shape and the length of the saturated region is proportional to the square root of the time elapsed. The results thus obtained are compared to data from full scale simulations and an error analysis of the solution was carried out. It was found that the time to fill is determined with a high degree of accuracy while the error in estimating the flow front length, d, increases with a dimensionless parameter ε=K2xxh22/K2yyd2. The solution allows greater insight into the process physics, enables parametric and optimization studies and can reduce the computational cost of full-scale 3-dimensional simulations. A parametric study is conducted to establish the sensitivity of flow front velocity to the distribution media/preform thickness ratio and permeabilities and preform porosity. The results provide insight into the scaling laws for manufacturing of large scale structures by VARTM. [S1087-1357(00)02002-5]


1993 ◽  
Vol 217 ◽  
pp. 251-262 ◽  
Author(s):  
D.J. Melotik ◽  
M. Czaplicki ◽  
T.J. Whalen ◽  
D.R. Day

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