Subsurface reactivity dominates regional patterns of riverine nitrate concentration variability

2020 ◽  
Author(s):  
Andreas Musolff ◽  
Pia Ebeling ◽  
Jan H. Fleckenstein ◽  
Rohini Kumar ◽  
Rémi Dupas
Keyword(s):  
Large Scale ◽  
Nitrate Concentration ◽  
Low Flow ◽  
Flow Conditions ◽  
Regional Patterns ◽  
Low Concentration ◽  
Concentration Variance ◽  
Wide Range ◽  
Nitrate Concentrations ◽  
The Mean

<p>The mean surface water concentration and the concentration variance of nutrients are major water quality characteristics of catchments that directly relates to exported nutrient loads and ecosystems functioning. The mean concentration reflects nutrient input, discharge (Q) and retention within different compartments of the catchment. The concentration variability defines the export regime of a certain solute and can be characterized by the ratio of CV<sub>C</sub> and CV<sub>Q</sub> and the slope <em>b </em>of the logC-logQ relationship. Recent explorative modelling studies argue that the export regime is shaped by spatial variance of the solute source in the catchment and by the subsurface reactivity (Musolff et al. 2017, Zhi et al. 2019). Here, we seek large scale evidence of this hypothesis by analyzing nitrate concentration and discharge (C-Q) time series in more than 1400 catchments across France and Germany. We found a consistent relationship between mean nitrate concentrations and the fraction of cultivated area within the catchments pointing to agriculture as the dominant nitrate source. The upper boundary of this relationship follows an exponential function with catchments showing mean nitrate concentrations around this envelope function being characterized by chemostatic export regimes with low concentration variance and slope <em>b</em> near zero. In contrast, catchments deviating from this relationship i.e. with lower than expected mean nitrate concentrations are characterized by higher concentration variance and steep, positive logC-logQ slopes. We argue, that subsurface retention is the major control of this behavior: i.e., effective denitrification decreases groundwater nitrate concentration. This was mainly observed in catchments with sedimentary aquifers and low topographic slopes. Here, old water components in the catchment storage that dominate discharge under low flow conditions are low in nitrate. Under high flow conditions, young water components high in nitrate concentrations are activated. Catchments without effective nitrate retention are characterized by a low concentration gradient between younger and older water components. The observed relationship between the fraction of cultivated areas, mean nitrate concentration and export regime was found to be surprisingly consistent across the wide range of hydroclimatic conditions, geology and topography. In consequence, steeply positive logC-logQ slopes can be used as indicators of effective subsurface reactivity. Future work will further elucidate the catchment characteristics that favor effective denitrification.</p><p>References</p><p>Musolff, A., Fleckenstein, J.H., Rao, P.S.C., Jawitz, J.W., 2017. Emergent archetype patterns of coupled hydrologic and biogeochemical responses in catchments. Geophys Res Lett, 44(9): 4143-4151. DOI:10.1002/2017GL072630</p><p>Zhi, W., Li, L. Dong, W.M., Brown, W., Kaye, J., Steefel, C., Williams, K.H., 2019. Distinct Source Water Chemistry Shapes Contrasting Concentration-Discharge Patterns. Water Resour Res, 55(5): 4233-4251. DOI:10.1029/2018wr024257</p>

scholarly journals The nitrate concentration of domestic vegetables on Helsinki market in summer and autumn 1984

1987 ◽  
Vol 59 (5) ◽  
pp. 425-430
Author(s):  
Seija Ahonen ◽  
Iris Kuokkanen ◽  
Pirjo-Liisa Penttilä
Keyword(s):  
Brassica Oleracea ◽  
Brassica Rapa ◽  
Chinese Cabbage ◽  
Nitrate Concentration ◽  
Fresh Weight ◽  
Wide Range ◽  
Nitrate Concentrations ◽  
The Mean ◽  
Brassica Pekinensis

Nitrate concentration of some domestic vegetables at Helsinki district market was studied during the summer and autumn months of the year 1984.The species were cabbage (Brassica oleracea var capitata), Chinese cabbage (Brassica pekinensis), kohlrabi (Brassica oleracea var gongylodes), turnip (Brassica rapa), carrot (Daucus Carola subsp. sativas) and crisphead and butter head lettuce (Lactuca saliva var. capitata). The 395 samples were analysed with an ion specific electrode. There was a wide range of nitrate concentrations within each species. The mean concentrations mg nitrates/kg of fresh weight were the following: butter head lettuce 1835, Chinese cabbage 1057, kohlrabi 1008, crisphead lettuce 964, turnip 908, cabbage 607 and carrot 264. The nitrate concentration of butter head lettuce in the autumn was more than twice as high as that in the summer, and vice versa as to cabbage samples. The nitrate concentration of carrot samples in the summer was about 40 % higher than in the autumn.

scholarly journals Antecedent flow conditions and nitrate concentrations in the Mississippi River basin

2014 ◽  
Vol 18 (3) ◽  
pp. 967-979 ◽  
Author(s):  
J. C. Murphy ◽  
R. M. Hirsch ◽  
L. A. Sprague
Keyword(s):  
River Basin ◽  
Mississippi River ◽  
Nitrate Concentration ◽  
Regional Scale ◽  
Mississippi River Basin ◽  
Flow Conditions ◽  
Daily Streamflow ◽  
Nitrate Concentrations ◽  
High Flows ◽  
The Mean

Abstract. The relationship between antecedent flow conditions and nitrate concentrations was explored at eight sites in the 2.9 million square kilometers (km2) Mississippi River basin, USA. Antecedent flow conditions were quantified as the ratio between the mean daily flow of the previous year and the mean daily flow from the period of record (Qratio), and the Qratio was statistically related to nitrate anomalies (the unexplained variability in nitrate concentration after filtering out season, long-term trend, and contemporaneous flow effects) at each site. Nitrate anomaly and Qratio were negatively related at three of the four major tributary sites and upstream in the Mississippi River, indicating that when mean daily streamflow during the previous year was lower than average, nitrate concentrations were higher than expected. The strength of these relationships increased when data were subdivided by contemporaneous flow conditions. Five of the eight sites had significant negative relationships (p ≤ 0.05) at high or moderately high contemporaneous flows, suggesting nitrate that accumulates in these basins during a drought is flushed during subsequent high flows. At half of the sites, when mean daily flow during the previous year was 50 percent lower than average, nitrate concentration can be from 9 to 27 percent higher than nitrate concentrations that follow a year with average mean daily flow. Conversely, nitrate concentration can be from 8 to 21 percent lower than expected when flow during the previous year was 50 percent higher than average. Previously documented for small, relatively homogenous basins, our results suggest that relationships between antecedent flows and nitrate concentrations are also observable at a regional scale. Relationships were not observed (using all contemporaneous flow data together) for basins larger than 1 million km2, suggesting that above this limit the overall size and diversity within these basins may necessitate the use of more complicated statistical approaches or that there may be no discernible basin-wide relationship with antecedent flow. The relationships between nitrate concentration and Qratio identified in this study serve as the basis for future studies that can better define specific hydrologic processes occurring during and after a drought (or high flow period) which influence nitrate concentration, such as the duration or magnitude of low flows, and the timing of low and high flows.

scholarly journals Antecedent flow conditions and nitrate concentrations in the Mississippi River Basin

2013 ◽  
Vol 10 (9) ◽  
pp. 11451-11484 ◽  
Author(s):  
J. C. Murphy ◽  
R. M. Hirsch ◽  
L. A. Sprague
Keyword(s):  
River Basin ◽  
Mississippi River ◽  
Nitrate Concentration ◽  
Mississippi River Basin ◽  
Storm Events ◽  
Flow Conditions ◽  
Continental Scale ◽  
Antecedent Moisture ◽  
Nitrate Concentrations ◽  
The Mean

Abstract. The influence of antecedent flow conditions on nitrate concentrations was explored at eight sites in the Mississippi River Basin, USA. Antecedent moisture conditions have been shown to influence nutrient export from small, relatively homogenous basins, but this influence has not been observed at a regional or continental scale. Antecedent flow conditions were quantified as the ratio between the mean daily flow of the previous year and the mean daily flow from the period of record (Q ratio), and the Q ratio was statistically related to nitrate anomalies (the unexplained variability in nitrate concentration after filtering out season, long-term trend, and contemporaneous flow effects) at each site. Nitrate anomaly and Q ratio were negatively related at three of the four major tributary sites and upstream in the Mississippi River, indicating that when the previous year was drier than average, at these sites, nitrate concentrations were higher than expected. The strength of these relationships increased when data were subdivided by contemporaneous flow conditions. Five of the eight sites had significant negative relationships (p ≤ 0.05) at high or moderately high contemporaneous flows, suggesting nitrate that accumulates in these basins during a drought is flushed during subsequent storm events. At half of the sites, when flow during the previous year was 50% drier than average, nitrate concentration can be from 9 and 27% higher than nitrate concentrations that follow a year with average daily flow. Conversely, nitrate concentration can be from 8 and 21% lower than expected when the previous year was 50% wetter than average. These relationships between nitrate concentration and Q ratio serve as the basis for future studies that can better define specific hydrologic processes occurring during and after a drought, which influence nitrate concentration, such as the duration or magnitude of low flows, and the timing of low and high flows.

scholarly journals Large-Scale Particle Image Velocimetry to Measure Streamflow from Videos Recorded from Unmanned Aerial Vehicle and Fixed Imaging System

2021 ◽  
Vol 13 (14) ◽  
pp. 2661
Author(s):  
Wen-Cheng Liu ◽  
Chien-Hsing Lu ◽  
Wei-Che Huang
Keyword(s):  
Large Scale ◽  
Particle Image ◽  
Surface Velocity ◽  
Low Flow ◽  
Flow Conditions ◽  
Image Velocimetry ◽  
Flight Height ◽  
Aerial Vehicle ◽  
The Mean ◽  
Scale Particle

The accuracy of river velocity measurements plays an important role in the effective management of water resources. Various methods have been developed to measure river velocity. Currently, image-based techniques provide a promising approach to avoid physical contact with targeted water bodies by researchers. In this study, measured surface velocities collected under low flow and high flow conditions in the Houlong River, Taiwan, using large-scale particle image velocimetry (LSPIV) captured by an unmanned aerial vehicle (UAV) and a terrestrial fixed station were analyzed and compared. Under low flow conditions, the mean absolute errors of the measured surface velocities using LSPIV from a UAV with shooting heights of 9, 12, and 15 m fell within 0.055 ± 0.015 m/s, which was lower than that obtained using LSPIV on video recorded from a terrestrial fixed station (i.e., 0.34 m/s). The mean absolute errors obtained using LSPIV derived from UAV aerial photography at a flight height of 12 m without seeding particles and with different seeding particle densities were slightly different, and fell within the range of 0.095 ± 0.025 m/s. Under high flow conditions, the mean absolute errors associated with using LSPIV derived from terrestrial fixed photography and LSPIV derived from a UAV with flight heights of 32, 62, and 112 m were 0.46 m/s and 0.49 m/s, 0.27 m, and 0.97 m/s, respectively. A UAV flight height of 62 m yielded the best measured surface velocity result. Moreover, we also demonstrated that the optimal appropriate interrogation area and image acquisition time interval using LSPIV with a UAV were 16 × 16 pixels and 1/8 s, respectively. These two parameters should be carefully adopted to accurately measure the surface velocity of rivers.

scholarly journals Forensic Investigation of Four Monitored Green Infrastructure Inlets

Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1787
Author(s):  
Leena J. Shevade ◽  
Franco A. Montalto
Keyword(s):  
Measurement Uncertainty ◽  
Green Infrastructure ◽  
Stormwater Management ◽  
Catchment Area ◽  
Low Flow ◽  
Inflow Rate ◽  
Forensic Investigation ◽  
Flow Conditions ◽  
The Mean

Green infrastructure (GI) is viewed as a sustainable approach to stormwater management that is being rapidly implemented, outpacing the ability of researchers to compare the effectiveness of alternate design configurations. This paper investigated inflow data collected at four GI inlets. The performance of these four GI inlets, all of which were engineered with the same inlet lengths and shapes, was evaluated through field monitoring. A forensic interpretation of the observed inlet performance was conducted using conclusions regarding the role of inlet clogging and inflow rate as described in the previously published work. The mean inlet efficiency (meanPE), which represents the percentage of tributary area runoff that enters the inlet was 65% for the Nashville inlet, while at Happyland the NW inlet averaged 30%, the SW inlet 25%, and the SE inlet 10%, considering all recorded events during the monitoring periods. The analysis suggests that inlet clogging was the main reason for lower inlet efficiency at the SW and NW inlets, while for the SE inlet, performance was compromised by a reverse cross slope of the street. Spatial variability of rainfall, measurement uncertainty, uncertain tributary catchment area, and inlet depression characteristics are also correlated with inlet PE. The research suggests that placement of monitoring sensors should consider low flow conditions and a strategy to measure them. Additional research on the role of various maintenance protocols in inlet hydraulics is recommended.

scholarly journals Exploring the physical controls of regional patterns of flow duration curves – Part 4: A synthesis of empirical analysis, process modeling and catchment classification

2012 ◽  
Vol 16 (11) ◽  
pp. 4483-4498 ◽  
Author(s):  
M. Yaeger ◽  
E. Coopersmith ◽  
S. Ye ◽  
L. Cheng ◽  
A. Viglione ◽  
...  
Keyword(s):  
Low Flow ◽  
Middle Portion ◽  
Qualitative Synthesis ◽  
Statistical Parameters ◽  
Regional Patterns ◽  
Flow Duration ◽  
Analysis Process ◽  
Wide Range ◽  
Physical Controls ◽  
Flow Duration Curves

Abstract. The paper reports on a four-pronged study of the physical controls on regional patterns of the flow duration curve (FDC). This involved a comparative analysis of long-term continuous data from nearly 200 catchments around the US, encompassing a wide range of climates, geology, and ecology. The analysis was done from three different perspectives – statistical analysis, process-based modeling, and data-based classification – followed by a synthesis, which is the focus of this paper. Streamflow data were separated into fast and slow flow responses, and associated signatures, and both total flow and its components were analyzed to generate patterns. Regional patterns emerged in all aspects of the study. The mixed gamma distribution described well the shape of the FDC; regression analysis indicated that certain climate and catchment properties were first-order controls on the shape of the FDC. In order to understand the spatial patterns revealed by the statistical study, and guided by the hypothesis that the middle portion of the FDC is a function of the regime curve (RC, mean within-year variation of flow), we set out to classify these catchments, both empirically and through process-based modeling, in terms of their regime behavior. The classification analysis showed that climate seasonality and aridity, either directly (empirical classes) or through phenology (vegetation processes), were the dominant controls on the RC. Quantitative synthesis of these results determined that these classes were indeed related to the FDC through its slope and related statistical parameters. Qualitative synthesis revealed much diversity in the shapes of the FDCs even within each climate-based homogeneous class, especially in the low-flow tails, suggesting that catchment properties may have become the dominant controls. Thus, while the middle portion of the FDC contains the average response of the catchment, and is mainly controlled by climate, the tails of the FDC, notably the low-flow tails, are mainly controlled by catchment properties such as geology and soils. The regime behavior explains only part of the FDC; to gain a deeper understanding of the physical controls on the FDC, these extremes must be analyzed as well. Thus, to completely separate the climate controls from the catchment controls, the roles of catchment properties such as soils, geology, topography etc. must be explored in detail.

scholarly journals Effect on nitrate concentration in stream water of agricultural practices in small catchments in Brittany: I. Annual nitrogen budgets

2002 ◽  
Vol 6 (3) ◽  
pp. 497-506 ◽  
Author(s):  
L. Ruiz ◽  
S. Abiven ◽  
P. Durand ◽  
C. Martin ◽  
F. Vertès ◽  
...  
Keyword(s):  
Land Use ◽  
Nitrate Concentration ◽  
Stream Water ◽  
Agricultural Practices ◽  
Climatic Conditions ◽  
Nitrogen Budgets ◽  
Annual Variations ◽  
Nitrate Concentrations ◽  
The Mean ◽  
Small Catchments

Abstract. The hydrological and biogeochemical monitoring of catchments has become a common approach for studying the effect of the evolution of agricultural practices on water resources. In numerous studies, the catchment is used as a "mega-lysimeter" to calculate annual input-output budgets. However, the literature reflects two opposite interpretations of the trends of nitrate concentration in streamwater. For some authors, essentially in applied studies, the mean residence time of leached nitrate in shallow groundwater systems is much less than one year and river loads reflect annual land use while for others, nitrate is essentially transport limited, independent of soil nitrate supply in the short term and annual variations reflect changes in climatic conditions. This study tests the effect of agricultural land-use changes on inter-annual nitrate trends on stream water of six small adjacent catchments from 0.10 to 0.57 km2 in area, on granite bedrock, at Kerbernez, in Western Brittany (France). Nitrate concentrations and loads in streamwater have been monitored for nine years (1992 to 2000) at the outlet of the catchments. An extensive survey of agricultural practices from 1993 to 1999 allowed assessment of the nitrogen available for leaching through nitrogen budgets. For such small catchments, year-to-year variations of nitrate leaching can be very important, even when considering the 'memory effect' of soil, while nitrate concentrations in streamwater appear relatively steady. No correlation was found between the calculated mean nitrate concentration of drainage water and the mean annual concentration in streams, which can even exhibit opposite trends in inter-annual variations. The climatic conditions do not affect the mean concentration in streamwater significantly. These results suggest that groundwater plays an important role in the control of streamwater nitrate concentration. Keywords: nitrate, diffuse pollution, agricultural catchment, nitrogen budget, leaching, Kerbernez catchments

Optimal energy growth in stably stratified turbulent Couette flow

2021 ◽  
Author(s):  
Grigory Zasko ◽  
Andrey Glazunov ◽  
Evgeny Mortikov ◽  
Yuri Nechepurenko ◽  
Pavel Perezhogin
Keyword(s):  
Boundary Layer ◽  
Turbulent Flow ◽  
Couette Flow ◽  
Large Scale ◽  
Thin Layers ◽  
Plane Couette Flow ◽  
Turbulent Layer ◽  
Wide Range ◽  
The Mean ◽  
Optimal Disturbances

<p>In this report, we will try to explain the emergence of large-scale organized structures in stably stratified turbulent flows using optimal disturbances of the mean turbulent flow. These structures have been recently obtained in numerical simulations of turbulent stably stratified flows [1] (Ekman layer, LES) and [2] (plane Couette flow, DNS and LES) and indirectly confirmed by field measurements in the stable boundary layer of the atmosphere [1, 2]. In instantaneous temperature fields they manifest themselves as irregular inclined thin layers with large gradients (fronts), spaced from each other by distances comparable to the height of the entire turbulent layer, and separated by regions with weak stratification.</p><p>Optimal disturbances of a stably stratified turbulent plane Couette flow are investigated in a wide range of Reynolds and Richardson numbers. These disturbances were computed based on a simplified linearized system of equations in which turbulent Reynolds stresses and heat fluxes were approximated by isotropic viscosity and diffusion with coefficients obtained from DNS results. It was shown [3] that the spatial scales and configurations of the inclined structures extracted from DNS data coincide with the ones obtained from optimal disturbances of the mean turbulent flow.</p><p>Critical value of the stability parameter is found starting from which the optimal disturbances resemble inclined structures. The physical mechanisms that determine the evolution, energetics and spatial configuration of these optimal disturbances are discussed. The effects due to the presence of stable stratification are highlighted.</p><p>Numerical experiments with optimal disturbances were supported by the RSF (grant No. 17-71-20149). Direct numerical simulation of stratified turbulent Couette flow was supported by the RFBR (grant No. 20-05-00776).</p><p>References:</p><p>[1] P.P. Sullivan, J.C. Weil, E.G. Patton, H.J. Jonker, D.V. Mironov. Turbulent winds and temperature fronts in large-eddy simulations of the stable atmospheric boundary layer // J. Atmos. Sci., 2016, V. 73, P. 1815-1840.</p><p>[2] A.V. Glazunov, E.V. Mortikov, K.V. Barskov, E.V. Kadantsev, S.S. Zilitinkevich. Layered structure of stably stratified turbulent shear flows // Izv. Atmos. Ocean. Phys., 2019, V. 55, P. 312–323.</p><p>[3] G.V. Zasko, A.V. Glazunov, E.V. Mortikov, Yu.M. Nechepurenko. Large-scale structures in stratified turbulent Couette flow and optimal disturbances // Russ. J. Num. Anal. Math. Model., 2010, V. 35, P. 35–53.</p>

scholarly journals Hierarchical Porous Polyamide 6 by Solution Foaming: Synthesis, Characterization and Properties

Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1310 ◽  
Author(s):  
Liang Wang ◽  
Yu-Ke Wu ◽  
Fang-Fang Ai ◽  
Jie Fan ◽  
Zhao-Peng Xia ◽  
...  
Keyword(s):  
Large Scale ◽  
Polyamide 6 ◽  
Solution Concentration ◽  
The Novel ◽  
Foaming Agent ◽  
Hierarchical Porous ◽  
Wide Range ◽  
The Mean ◽  
Novel Strategy

Porous polym er materials have received great interest in both academic and industrial fields due to their wide range of applications. In this work, a porous polyamide 6 (PA6) material was prepared by a facile solution foaming strategy. In this approach, a sodium carbonate (SC) aqueous solution acted as the foaming agent that reacted with formic acid (FA), generating CO2 and causing phase separation of polyamide (PA). The influence of the PA/FA solution concentration and Na2CO3 concentration on the microstructures and physical properties of prepared PA foams were investigated, respectively. PA foams showed a hierarchical porous structure along the foaming direction. The mean pore dimension ranged from hundreds of nanometers to several microns. Low amounts of sodium salt generated from a neutralization reaction played an important role of heterogeneous nucleation, which increased the crystalline degree of PA foams. The porous PA materials exhibited low thermal conductivity, high crystallinity and good mechanical properties. The novel strategy in this work could produce PA foams on a large scale for potential engineering applications.

scholarly journals Upland streamwater nitrate dynamics across decadal to sub-daily timescales: a case study of Plynlimon, Wales

2013 ◽  
Vol 10 (12) ◽  
pp. 8013-8038 ◽  
Author(s):  
S. J. Halliday ◽  
R. A. Skeffington ◽  
A. J. Wade ◽  
C. Neal ◽  
B. Reynolds ◽  
...  
Keyword(s):  
High Frequency ◽  
N Uptake ◽  
Low Flow ◽  
Downstream Site ◽  
Drought Period ◽  
Diurnal Dynamics ◽  
Early Afternoon ◽  
Wide Range ◽  
Nitrate Concentrations

Abstract. Streamwater nitrate dynamics in the River Hafren, Plynlimon, mid-Wales were investigated over decadal to sub-daily timescales using a range of statistical techniques. Long-term data were derived from weekly grab samples (1984–2010) and high-frequency data from 7-hourly samples (2007–2009) both measured at two sites: a headwater stream draining moorland and a downstream site below plantation forest. This study is one of the first to analyse upland streamwater nitrate dynamics across such a wide range of timescales and report on the principal mechanisms identified. The data analysis provided no clear evidence that the long-term decline in streamwater nitrate concentrations was related to a decline in atmospheric deposition alone, because nitrogen deposition first increased and then decreased during the study period. Increased streamwater temperature and denitrification may also have contributed to the decline in stream nitrate concentrations, the former through increased N uptake rates and the latter resultant from increased dissolved organic carbon concentrations. Strong seasonal cycles, with concentration minimums in the summer, were driven by seasonal flow minimums and seasonal biological activity enhancing nitrate uptake. Complex diurnal dynamics were observed, with seasonal changes in phase and amplitude of the cycling, and the diurnal dynamics were variable along the river. At the moorland site, a regular daily cycle, with minimum concentrations in the early afternoon, corresponding with peak air temperatures, indicated the importance of instream biological processing. At the downstream site, the diurnal dynamics were a composite signal, resultant from advection, dispersion and nitrate processing in the soils of the lower catchment. The diurnal streamwater nitrate dynamics were also affected by drought conditions. Enhanced diurnal cycling in Spring 2007 was attributed to increased nitrate availability in the post-drought period as well as low flow rates and high temperatures over this period. The combination of high-frequency short-term measurements and long-term monitoring provides a powerful tool for increasing understanding of the controls of element fluxes and concentrations in surface waters.

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