Numerically modeling routes of sequential magma pulses in the upper crust

2021 ◽  
Author(s):  
Mara Arts ◽  
Boris Kaus ◽  
Nicolas Berlie
Keyword(s):  
Magma Chamber ◽  
Host Rock ◽  
Large Scale ◽  
Specific Area ◽  
Granitic Magma ◽  
Incremental Growth ◽  
Multiple Pulses ◽  
Magma Pulses ◽  
Host Rocks ◽  
Torres Del Paine

<p>Understanding the evolution and generation of large scale igneous bodies is important to understand the evolution of the crust. The way igneous bodies are constructed and the timescale of construction control the location, volume and composition of melt (Annen, 2015). Despite many previous studies that address the construction of igneous bodies, it remains unclear why melt focusses within a specific area. Igneous bodies are usually the result of multiple magmatic pulses that solidify in the same location. In many cases the time between subsequent pulses is sufficiently long for the magma of one pulse to completely solidified before the next pulse arrives.</p><p>Magma will rise when the buoyancy of the magma is greater than the resisting forces in the host rock. The rising magma will however not always follow a vertical path to the surface. Variables like the direction of the least compressive stress, the presence of folding or faulting and weak contacts between layers are all factors that can cause melt to follow a different pathway. In the case of multiple pulses, the effects of earlier pulses can alter these factors. Thermal and chemical alteration is thought to lead to new preferred paths for the melt.</p><p>The granitic laccolith in Torres del Paine natural park in the south of Chile is a particularly well-studied example where magma seems to have followed the same path from the lower magma chamber to the present location of the laccolith over multiple pulses. This laccolith consists of three pulses of granitic magma that intruded into folded sedimentary materials over a timespan of approximately 90ka (Michel et al., 2008), all through the same same deeder channel. The time between pulses was sufficiently long for the magma to completely solidify. Therefore, thermal weakening can possibly be excluded as a reason why the magma followed the same path multiple times. Yer, why the feeder zone stayed in the same location for all pulses remains poorly understood.</p><p>Here, we therefore present numerical simulations in which we model multiple magma pulses and track whether multiple pulses follow the same path. The pulses start in a mid-crustal magma chamber and rise upwards through a folded host rock. We will employ a newly developed, thermomechanical parallel staggered finite difference code for that takes visco-elasto plastic rheologies into account. Systematic simulations are presented in which we test the effect of pulse-intervals, fold wavelengths of the host rocks, intrusion temperature and viscosities as well as the effect of preexisting weaknesses on the subsequent pathways of the magma.</p><p> </p><p>[1] Annen, C., Blundy, J. D., Leuthold, J., & Sparks, R. S. J. (2015). Construction and evolution of igneous bodies: Towards an integrated perspective of crustal magmatism. <span><em>Lithos</em></span><span>, </span><span><em>230</em></span><span>, 206-221.</span></p><p><span>[2] Michel, J., Baumgartner, L., Putlitz, B., Schaltegger, U., & Ovtcharova, M. (2008). </span>Incremental growth of the Patagonian Torres del Paine laccolith over 90 ky. <em>Geology</em>, <em>36</em>(6), 459-462.</p>

2D thermo-mechanical-chemical coupled numerical models of interactions between a cooling magma chamber and a visco-elastic host rock

2020 ◽  
Author(s):  
Dániel Kiss ◽  
Evangelos Moulas ◽  
Lisa Rummel ◽  
Boris Kaus
Keyword(s):  
Magma Chamber ◽  
Host Rock ◽  
Numerical Models ◽  
Bulk Composition ◽  
Inertial Forces ◽  
Volume Changes ◽  
Consistent System ◽  
Host Rocks ◽  
2D Numerical Model ◽  
Crustal Magma

<p>A recent focus of studies in geodynamic modeling and magmatic petrology is to understand the coupled behavior between deformation and magmatic processes. Here, we present a 2D numerical model of an upper crustal magma (or mush) chamber in a visco-elastic host rock, with coupled thermal, mechanical and chemical (TMC) processes. The magma chamber is isolated from deeper sources of magma and it is cooling, and thus shrinking. We quantify the mechanical interaction between the shrinking magma chamber and the surrounding host rock, using a compressible visco-elastic formulation, considering several geometries of the magma chamber.</p><p>We present a self-consistent system of the conservation equations for coupled TMC processes, under the assumptions of slow (negligible inertial forces), visco-elastic deformation and constant chemical bulk composition. The thermodynamic melting/crystallization model is based on a pelitic melting model calculated with Perple_X, assuming a granitic composition and is incorporated as a look-up table. We will discuss the numerical implementation, show the results of systematic numerical simulations, and illustrate the effect of volume changes due to crystallization on stresses in the host rocks.</p>

Petrogenesis of the St David's Head Layered Intrusion, Wales: a complex history of multiple magma injection and in situ crystallisation

1994 ◽  
Vol 85 (2) ◽  
pp. 91-121 ◽  
Author(s):  
R. E. Bevins ◽  
G. J. Lees ◽  
R. A. Roach ◽  
G. Rowbotham ◽  
P. A. Floyd
Keyword(s):  
Magma Chamber ◽  
Large Scale ◽  
Layered Intrusion ◽  
Geochemical Data ◽  
Residual Liquid ◽  
Magma Pulses ◽  
Modal Layering ◽  
Crystal Accumulation ◽  
High Level

AbstractThe St David's Head Intrusion, exposed in North Pembrokeshire, is a tholeiitic sill up to 570 m thick, comprising principally mafic gabbros, which are in part layered. Layering varies from the centimetre to the metre scale. A range of gabbroic compositions is present, defining seven major petrological types, which are cut by thin silicic (aplitic) veins.Log–log plots of incompatible elements from the various lithological units indicate that all of the rocks in the intrusion are petrogenetically linked, although a variety of processes has been operative. Roach (1969) considered the quartz gabbros and dolerites, which form an envelope around the other units, to relate most closely to the parental composition. However, the least evolved compositions in the intrusion are from the xenolithic laminated olivine gabbros, although these mafic compositions are due primarily to the presence of abundant, mafic, cognate xenoliths. These xenoliths are thought to relate to an earlier episode of crystal accumulation in a high-level magma chamber. The various laminated gabbros reflect crystal accumulation in situ after magma emplacement, leading in certain layers to extreme enrichments in Fe, Ti, and V, related to high modal proportions of cumulus ilmenite. Further in situ crystallisation led to differentiation of the residual liquid, producing more silicic gabbros with well-developed granophyric textures, the granophyre reflecting the silicic residuum. Extreme differentiation, possibly combined with expulsion of silicic residual liquid during crystal accumulation and compaction, resulted in the cross-cutting aplite veins.Three different types of layering are present in the intrusion. Firstly, preferred orientation of tabular minerals in the laminated gabbro units is thought to result from discrete sedimentation episodes from a convecting magma chamber. Secondly, macrorhythmic modal layering up to 1 m thick consists of an alternation of relatively ilmenite-rich and ilmenite-poor layers in the laminated gabbro units, although the reason for the modal variation is not certain. Thirdly, a centimetre-scale felsic–mafic microrhythmic layering is present in the envelope quartz gabbros and dolerites, which is similar to the inch-scale layering in the Stillwater Igneous Complex. This layering is thought to relate to metasomatic reaction in the gabbro in the presence of water at a late magmatic stage. Overall, these various lithological units themselves define a large-scale layering in the intrusion.Combined, the petrological and geochemical data suggest that the St David's Head Intrusion was not emplaced in a single event. Rather, a series of magma pulses, of contrasting compositions but petrogenetically linked, was intruded. Some of the chemical variations now seen existed prior to emplacement, indicating the former presence of high-level crustal magma chambers, while other variations developed as a result of in situ crystallisation processes and related chemical differentiation.

scholarly journals Magma Mixing Genesis of the Mafic Enclaves in the Qingshanbao Complex of Longshou Mountain, China: Evidence from Petrology, Geochemistry, and Zircon Chronology

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 195 ◽  
Author(s):  
Wenheng Liu ◽  
Xiaodong Liu ◽  
Jiayong Pan ◽  
Kaixing Wang ◽  
Gang Wang ◽  
...  
Keyword(s):  
Host Rock ◽  
Inductively Coupled Plasma ◽  
Magma Mixing ◽  
Coarse Grained ◽  
Calc Alkaline ◽  
Quartz Crystals ◽  
Alkaline Rocks ◽  
Mafic Enclaves ◽  
Normal Zoning ◽  
Host Rocks

The Qingshanbao complex, part of the uranium metallogenic belt of the Longshou-Qilian mountains, is located in the center of the Longshou Mountain next to the Jiling complex that hosts a number of U deposits. However, little research has been conducted in this area. In order to investigate the origin and formation of mafic enclaves observed in the Qingshanbao body and the implications for magmatic-tectonic dynamics, we systematically studied the mineralogy, petrography, and geochemistry of these enclaves. Our results showed that the enclaves contain plagioclase enwrapped by early dark minerals. These enclaves also showed round quartz crystals and acicular apatite in association with the plagioclase. Electron probe analyses showed that the plagioclase in the host rocks (such as K-feldspar granite, adamellite, granodiorite, etc.) show normal zoning, while the plagioclase in the mafic enclaves has a discontinuous rim composition and shows instances of reverse zoning. Major elemental geochemistry revealed that the mafic enclaves belong to the calc-alkaline rocks that are rich in titanium, iron, aluminum, and depleted in silica, while the host rocks are calc-alkaline to alkaline rocks with enrichment in silica. On Harker diagrams, SiO2 contents are negatively correlated with all major oxides but K2O. Both the mafic enclaves and host rock are rich in large ion lithophile elements such as Rb and K, as well as elements such as La, Nd, and Sm, and relatively poor in high field strength elements such as Nb, Ta, P, Ti, and U. Element ratios of Nb/La, Rb/Sr, and Nb/Ta indicate that the mafic enclaves were formed by the mixing of mafic and felsic magma. In terms of rare earth elements, both the mafic enclaves and the host rock show right-inclined trends with similar weak to medium degrees of negative Eu anomaly and with no obvious Ce anomaly. Zircon LA-ICP-MS (Laser ablation inductively coupled plasma mass spectrometry) U-Pb concordant ages of the mafic enclaves and host rock were determined to be 431.8 5.2 Ma (MSWD (mean standard weighted deviation)= 1.5, n = 14) and 432.8 4.2 Ma (MSWD = 1.7, n = 16), respectively, consistent with that for the zircon U-Pb ages of the granite and medium-coarse grained K-feldspar granites of the Qingshanbao complex. The estimated ages coincide with the timing of the late Caledonian collision of the Alashan Block. This comprehensive analysis allowed us to conclude that the mafic enclaves in the Qingshanbao complex were formed by the mixing of crust-mantle magma with mantle-derived magma due to underplating, which caused partial melting of the ancient basement crust during the collisional orogenesis between the Alashan Block and Qilian rock mass in the early Silurian Period.

EBS Behaviour Immediately After Repository Closure in a Clay Host Rock: The HE-E Experiment (Mont Terri URL)

2011 ◽  
Author(s):  
Irina Gaus ◽  
Klaus Wieczorek ◽  
Juan Carlos Mayor ◽  
Thomas Trick ◽  
Jose´-Luis Garcia` Sin˜eriz ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Host Rock ◽  
Large Scale ◽  
Process Models ◽  
Research Activities ◽  
Hydraulic Behaviour ◽  
Validation Experiment ◽  
Engineered Barrier ◽  
Mont Terri

The evolution of the engineered barrier system (EBS) of geological repositories for radioactive waste has been the subject of many research programmes during the last decade. The emphasis of the research activities was on the elaboration of a detailed understanding of the complex thermo-hydro-mechanical-chemical processes, which are expected to evolve in the early post closure period in the near field. It is important to understand the coupled THM-C processes and their evolution occurring in the EBS during the early post-closure phase so it can be confirmed that the safety functions will be fulfilled. Especially, it needs to be ensured that interactions during the resaturation phase (heat pulse, gas generation, non-uniform water uptake from the host rock) do not affect the performance of the EBS in terms of its safety-relevant parameters (e.g. swelling pressure, hydraulic conductivity, diffusivity). The 7th Framework PEBS project (Long Term Performance of Engineered Barrier Systems) aims at providing in depth process understanding for constraining the conceptual and parametric uncertainties in the context of long-term safety assessment. As part of the PEBS project a series of laboratory and URL experiments are envisaged to describe the EBS behaviour after repository closure when resaturation is taking place. In this paper the very early post-closure period is targeted when the EBS is subjected to high temperatures and unsaturated conditions with a low but increasing moisture content. So far the detailed thermo-hydraulic behaviour of a bentonite EBS in a clay host rock has not been evaluated at a large scale in response to temperatures of up to 140°C at the canister surface, produced by HLW (and spent fuel), as anticipated in some of the designs considered. Furthermore, earlier THM experiments have shown that upscaling of thermal conductivity and its dependency on water content and/or humidity from the laboratory scale to a field scale needs further attention. This early post-closure thermal behaviour will be elucidated by the HE-E experiment, a 1:2 scale heating experiment setup at the Mont Terri rock laboratory, that started in June 2011. It will characterise in detail the thermal conductivity at a large scale in both pure bentonite as well as a bentonite-sand mixture, and in the Opalinus Clay host rock. The HE-E experiment is especially designed as a model validation experiment at the large scale and a modelling programme was launched in parallel to the different experimental steps. Scoping calculations were run to help the experimental design and prediction exercises taking the final design into account are foreseen. Calibration and prediction/validation will follow making use of the obtained THM dataset. This benchmarking of THM process models and codes should enhance confidence in the predictive capability of the recently developed numerical tools. It is the ultimate aim to be able to extrapolate the key parameters that might influence the fulfilment of the safety functions defined for the long term steady state.

Paragenesis of veins of the Duck Pond tin prospect, Meguma Group, East Kemptville, Nova Scotia

1989 ◽  
Vol 26 (10) ◽  
pp. 2032-2043 ◽  
Author(s):  
Christian V. Pitre ◽  
Jean M. Richardson
Keyword(s):  
Nova Scotia ◽  
Manganese Oxides ◽  
Open Pit ◽  
Granitic Magma ◽  
Sulphide Minerals ◽  
Main Indicator ◽  
Argillic Alteration ◽  
Mineral Assemblages ◽  
Indicator Mineral ◽  
Host Rocks

The Duck Pond tin prospect is a vein- and strata-bound cassiterite prospect that is located 2 km west of the East Kemptville open-pit tin mine in southwestern Nova Scotia. The host rocks of the Duck Pond prospect are interbedded metawacke and meta-argillite that belong to the transition unit of the Meguma Group. These rocks contain quartz, sericite, chlorite, hematite, rutile, manganese oxides, feldspar, and porphyroblastic garnet, but not detrital cassiterite. The prospect is structurally controlled and contains several cross-cutting vein sets that have alkalic, chloritic, or argillic alteration assemblages. Muscovite is the main indicator mineral for alkalic alteration and occurs in veins that contain anorthoclase or quartz. Cassiterite is associated with chloritic alteration and occurs as subhedral to euhedral grains, acicular needles, and colloform layers in veins in meta-argillite and as strata-bound disseminations in metawacke. Most cassiterite precipitated under externally buffered conditions with respect to oxygen. Fe, Cu, Zn, and As sulphide minerals and quartz were deposited during argillic alteration. Late-stage processes such as recrystallization, sulphidation, and oxidation also occurred. Chalcopyrite is replaced by bornite and covellite; pyrite is replaced by marcasite.Unlike the F-rich East Kemptville deposit, fluorine-rich and tin-sulphide minerals are not present in the Duck Pond prospect. Trace tourmaline, absent at East Kemptville, is found at Duck Pond. However, the source of tin-mineralizing fluids at Duck Pond and East Kemptville was likely the granitic magma of the Davis Lake complex, which also hosts the East Kemptville deposit. From the mineral assemblages and textural relationships, it appears that as the temperature dropped from 425–405 °C to less than 200 °C at Duck Pond, the pH dropped from 5.2 to no lower than 3. Log [Formula: see text] dropped from at least −19 to −43. Log [Formula: see text] rose from < −15 to > −10. Cassiterite precipitated at the higher ends of the temperature and pH ranges and the lower end of the log [Formula: see text] range.

Compositional variation in the chevkinite group: new data from igneous and metamorphic rocks

2009 ◽  
Vol 73 (5) ◽  
pp. 777-796 ◽  
Author(s):  
R. Macdonald ◽  
H. E. Belkin ◽  
F. Wall ◽  
B. Baginski
Keyword(s):  
Electron Microprobe ◽  
Host Rock ◽  
Metamorphic Rocks ◽  
Compositional Variation ◽  
Temperature Range ◽  
Wide Range ◽  
Host Rocks ◽  
Cation Sites ◽  
Dominant Cation

AbstractElectron microprobe analyses are presented of chevkinite-group minerals from Canada, USA, Guatemala, Norway, Scotland, Italy and India. The host rocks are metacarbonates, alkaline and subalkaline granitoids, quartz-bearing pegmatites, carbonatite and an inferred K-rich tuff. The analyses extend slightly the range of compositions in the chevkinite group, e.g. the most MgO-rich phases yet recorded, and we report two further examples where La is the dominant cation in the A site. Patchily- zoned crystals from Virginia and Guatemala contain both perrierite and chevkinite compositions. The new and published analyses are used to review compositional variation in minerals of the perrierite subgroup, which can form in a wide range of host rock compositions and over a substantial pressure- temperature range. The dominant substitutions in the various cation sites and a generalized substitution scheme are described.

Competence and lithostratigraphy of host rocks govern kimberlite pipe morphology

2018 ◽  
Vol 55 (2) ◽  
pp. 130-137
Author(s):  
David E. Newton ◽  
Amy G. Ryan ◽  
Luke J. Hilchie
Keyword(s):  
Host Rock ◽  
Sedimentary Rock ◽  
Kimberlite Pipe ◽  
Crystalline Rock ◽  
Experimental Results ◽  
Compressed Air ◽  
Unconsolidated Sediments ◽  
Final Shape ◽  
Class 1 ◽  
Host Rocks

We use analogue experimentation to test the hypothesis that host rock competence primarily determines the morphology of kimberlite pipes. Natural occurrences of kimberlite pipes are subdivided into three classes: class 1 pipes are steep-sided diatremes emplaced into crystalline rock; class 2 pipes have a wide, shallow crater emplaced into sedimentary rock overlain by unconsolidated sediments; class 3 pipes comprise a steep-sided diatreme with a shallow-angled crater emplaced into competent crystalline rock overlain by unconsolidated sediments. We use different configurations of three analogue materials with varying cohesions to model the contrasting geological settings observed in nature. Pulses of compressed air, representing the energy of the gas-rich head of a kimberlitic magma, are used to disrupt the experimental substrate. In our experiments, the competence and configuration of the analogue materials control the excavation processes as well as the final shape of the analogue pipes: eruption through competent analogue strata results in steep-sided analogue pipes; eruption through weak analogue strata results in wide, shallow analogue pipes; eruption through intermediate strength analogue strata results in analogue pipes with a shallow crater and a steep-sided diatreme. These experimental results correspond with the shapes of natural kimberlite pipes, and demonstrate that variations in the lithology of the host rock are sufficient to generate classic kimberlite pipe shapes. These findings are consistent with models that ascribe the pipe morphologies of natural kimberlites to the competence of the host rocks in which they are emplaced.

A numerical study of the nucleation, growth and settling of crystals from a turbulent convecting fluid

2021 ◽  
Author(s):  
Vojtech Patocka ◽  
Nicola Tosi ◽  
Enrico Calzavarini
Keyword(s):  
Magma Chamber ◽  
Solid Fraction ◽  
Large Scale ◽  
Solid Phase ◽  
Numerical Study ◽  
Equilibrium Concentration ◽  
Solid Particles ◽  
Settling Rate ◽  
Carrier Fluid ◽  
Nucleation Growth

&lt;p&gt;We evaluate the equilibrium concentration of a thermally convecting suspension that is cooled from above and in which&lt;br&gt;solid crystals are self-consistently generated in the thermal boundary layer near the top. In a previous study (Patoc&amp;#780;ka et&lt;br&gt;al., 2020), we investigated the settling rate of solid particles suspended in a highly vigorous (Ra = 10&lt;sup&gt;8&lt;/sup&gt; , 10&lt;sup&gt;10&lt;/sup&gt;, and 10&lt;sup&gt;12&lt;/sup&gt; ),&lt;br&gt;finite Prandtl number (Pr = 10, 50) convection. In this follow-up study we additionally employ the model of crystal&lt;br&gt;generation and growth of Jarvis and Woods (1994), instead of using particles with a predefined size and density that are&lt;br&gt;uniformly injected into the carrier fluid.&lt;/p&gt;&lt;p&gt;We perform a series of numerical experiments of particle-laden thermal convection in 2D and 3D Cartesian geometry&lt;br&gt;using the freely available code CH4 (Calzavarini, 2019). Starting from a purely liquid phase, the solid fraction gradually&lt;br&gt;grows until an equilibrium is reached in which the generation of the solid phase balances the loss of crystals due to&lt;br&gt;sedimentation at the bottom of the fluid. For a range of predefined density contrasts of the solid phase with respect to&lt;br&gt;the density of the fluid (&amp;#961;&lt;sub&gt;p&lt;/sub&gt; /&amp;#961;&lt;sub&gt;f&lt;/sub&gt; = [0, 2]), we measure the time it takes to reach such equilibrium. Both this time and&lt;br&gt;the equilibrium concentration depend on the average settling rate of the particles and are thus non-trival to compute for&lt;br&gt;particle types that interact with the large-scale circulation of the fluid (see Patoc&amp;#780;ka et al., 2020).&lt;/p&gt;&lt;p&gt;We apply our results to the cooling of a large volume of magma, spanning from a large magma chamber up to a&lt;br&gt;global magma ocean. Preliminary results indicate that, as long as particle re-entrainment is not a dominant process, the&lt;br&gt;separation of crystals from the fluid is an efficient process. Fractional crystallization is thus expected and the suspended&lt;br&gt;solid fraction is typically small, prohibiting phenomena in which the feedback of crystals on the fluid begins to govern the&lt;br&gt;physics of the system (e.g. Sparks et al, 1993).&lt;/p&gt;&lt;p&gt;References&lt;br&gt;Patoc&amp;#780;ka V., Calzavarini E., and Tosi N.(2020). Settling of inertial particles in turbulent Rayleigh-Be&amp;#769;nard convection.&lt;br&gt;Physical Review Fluids, 26(4) 883-889.&lt;/p&gt;&lt;p&gt;Jarvis, R. A. and Woods, A. W.(1994). The nucleation, growth and settling of crystals from a turbulently convecting&lt;br&gt;fluid. J. Fluid. Mech, 273 83-107.&lt;/p&gt;&lt;p&gt;Sparks, R., Huppert, H., Koyaguchi, T. et al (1993). Origin of modal and rhythmic igneous layering by sedimentation in&lt;br&gt;a convecting magma chamber. Nature, 361, 246-249.&lt;/p&gt;&lt;p&gt;Calzavarini, E (2019). Eulerian&amp;#8211;Lagrangian fluid dynamics platform: The ch4-project. Software Impacts, 1, 100002.&lt;/p&gt;

scholarly journals Superior Pseudocapacitive Storage of a Novel Ni3Si2/NiOOH/Graphene Nanostructure for an All-Solid-State Supercapacitor

2020 ◽  
Vol 13 (1) ◽  
Author(s):  
Jing Ning ◽  
Maoyang Xia ◽  
Dong Wang ◽  
Xin Feng ◽  
Hong Zhou ◽  
...  
Keyword(s):  
Solid State ◽  
High Performance ◽  
Large Scale ◽  
Specific Capacity ◽  
Three Dimensional ◽  
Chemical Vapor ◽  
Specific Area ◽  
High Energy ◽  
Scale Production ◽  
Free Standing

Abstract Recent developments in the synthesis of graphene-based structures focus on continuous improvement of porous nanostructures, doping of thin films, and mechanisms for the construction of three-dimensional architectures. Herein, we synthesize creeper-like Ni3Si2/NiOOH/graphene nanostructures via low-pressure all-solid melting-reconstruction chemical vapor deposition. In a carbon-rich atmosphere, high-energy atoms bombard the Ni and Si surface, and reduce the free energy in the thermodynamic equilibrium of solid Ni–Si particles, considerably catalyzing the growth of Ni–Si nanocrystals. By controlling the carbon source content, a Ni3Si2 single crystal with high crystallinity and good homogeneity is stably synthesized. Electrochemical measurements indicate that the nanostructures exhibit an ultrahigh specific capacity of 835.3 C g−1 (1193.28 F g−1) at 1 A g−1; when integrated as an all-solid-state supercapacitor, it provides a remarkable energy density as high as 25.9 Wh kg−1 at 750 W kg−1, which can be attributed to the free-standing Ni3Si2/graphene skeleton providing a large specific area and NiOOH inhibits insulation on the electrode surface in an alkaline solution, thereby accelerating the electron exchange rate. The growth of the high-performance composite nanostructure is simple and controllable, enabling the large-scale production and application of microenergy storage devices.

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