Cosmogenic <sup>10</sup>Be in river sediment: where grain size matters and
why
Abstract. Concentrations of in situ-produced cosmogenic 10Be in river sediment are widely used to estimate catchment-average denudation rates. Typically, the 10Be concentrations are measured in the sand fraction of river sediment. However, the grain size of bedload sediment in most bedrock rivers cover a much wider range. Where 10Be concentrations depend on grain size, denudation rate estimates based on the sand fraction alone could potentially be biased. To date, knowledge about catchment attributes that may induce grain size-dependent 10Be concentrations is incomplete or has only been investigated in modelling studies. Here we present an empirical study on the occurrence of grain size-dependent 10Be concentrations and the potential controls of hillslope angle, precipitation, lithology and abrasion. We first conducted a study focusing on the sole effect of precipitation in four granitic catchments located on a climate-gradient in the Chilean Coastal Cordillera. We found that observed grain size dependencies of 10Be concentrations in the most-arid and most-humid catchments could be explained by the effect of precipitation on both the scouring depth of erosion processes and the depth of the mixed soil layer. Analysis of a global dataset of published 10Be concentrations in different grain sizes (n=62 catchments), comprising catchments with contrasting hillslope angles, climate, lithology and catchment size revealed a similar pattern. Lower 10Be concentrations in coarse grains (defined as negative grain size dependency) emerge frequently in catchments which likely have thin soil and where deep-seated erosion processes (e.g. landslides) excavate grains over a larger depth-interval. These catchments include steep (>25°), arid (<100 mm yr−1) and humid catchments (>2000 mm yr−1). Furthermore, we found that an additional cause of negative grain size dependencies may emerge in large catchments with long sediment travel distances (>2300–7000 m, depending on lithology) where abrasion and sediment provenance may lead to a grain size distribution that is not representative for the entire catchment. The results of this study can be used to evaluate whether catchment-average denudation rates are likely to be biased in particular catchments.