scholarly journals Dynamical geochemistry of the mantle

Solid Earth ◽  
2011 ◽  
Vol 2 (2) ◽  
pp. 159-189 ◽  
Author(s):  
G. F. Davies
Keyword(s):  
Trace Elements ◽  
Oceanic Crust ◽  
Primitive Mantle ◽  
Mantle Heterogeneity ◽  
The Past ◽  
Incompatible Elements ◽  
The Earth ◽  
Depleted Mantle ◽  
Morb Source ◽  
Dynamical Modelling

Abstract. The reconciliation of mantle chemistry with the structure of the mantle inferred from geophysics and dynamical modelling has been a long-standing problem. This paper reviews three main aspects. First, extensions and refinements of dynamical modelling and theory of mantle processing over the past decade. Second, a recent reconsideration of the implications of mantle heterogeneity for melting, melt migration, mantle differentiation and mantle segregation. Third, a recent proposed shift in the primitive chemical baseline of the mantle inferred from observations of non-chondritic 142Nd in the Earth. It seems most issues can now be resolved, except the level of heating required to maintain the mantle's thermal evolution. A reconciliation of refractory trace elements and their isotopes with the dynamical mantle, proposed and given preliminary quantification by Hofmann, White and Christensen, has been strengthened by work over the past decade. The apparent age of lead isotopes and the broad refractory-element differences among and between ocean island basalts (OIBs) and mid-ocean ridge basalts (MORBs) can now be quantitatively accounted for with some assurance. The association of the least radiogenic helium with relatively depleted sources and their location in the mantle have been enigmatic. The least radiogenic helium samples have recently been recognised as matching the proposed non-chondritic primitive mantle. It has also been proposed recently that noble gases reside in a so-called hybrid pyroxenite assemblage that is the result of melt from fusible pods reacting with surrounding refractory peridotite and refreezing. Hybrid pyroxenite that is off-axis may not remelt and erupt at MORs, so its volatile constituents would recirculate within the mantle. Hybrid pyroxenite is likely to be denser than average mantle, and thus some would tend to settle in the D" zone at the base of the mantle, along with some old subducted oceanic crust. Residence times in D" are longer, so the hybrid pyroxenite there would be less degassed. Plumes would sample both the degassed, enriched old oceanic crust and the gassy, less enriched hybrid pyroxenite and deliver them to OIBs. These findings can account quantitatively for the main He, Ne and Ar isotopic observations. It has been commonly inferred that the MORB source is strongly depleted of incompatible elements. However it has recently been argued that conventional estimates of the MORB source composition fail to take full account of mantle heterogeneity, and in particular focus on an ill-defined "depleted" mantle component while neglecting less common enriched components. Previous estimates have also been tied to the composition of peridotites, but these probably do not reflect the full complement of incompatible elements in the heterogeneous mantle. New estimates that account for enriched mantle components suggest the MORB source complement of incompatibles could be as much as 50–100 % larger than previous estimates. A major difficulty has been the inference that mass balances of incompatible trace elements could only be satisfied if there is a deep enriched layer in the mantle, but the Earth's topography precludes such a layer. The difficulty might be resolved if either the Earth is depleted relative to chondritic or the MORB source is less depleted than previous estimates. Together these factors can certainly resolve the mass balance difficulties.

scholarly journals Dynamical geochemistry of the mantle

2011 ◽  
Vol 3 (1) ◽  
pp. 249-333 ◽  
Author(s):  
G. F. Davies
Keyword(s):  
Trace Elements ◽  
Oceanic Crust ◽  
Noble Gases ◽  
Poor Correlation ◽  
Refractory Element ◽  
Mass Balances ◽  
Primitive Earth ◽  
Incompatible Elements ◽  
Depleted Mantle ◽  
Morb Source

Abstract. Despite progress in reconciling refractory trace elements and isotopes with the structure and dynamics of the mantle inferred from geophysical constraints and dynamical modelling, mass balances of key elements and observations of noble gases in the mantle have remained enigmatic. This paper reviews arguments that most issues can be resolved if the full implications of the major-element heterogeneity of the mantle are taken into account. A reconciliation of refractory trace elements and their isotopes with the dynamical mantle, proposed and quantified by Hofmann, White and Christensen, has been strengthened by work over the past decade. The apparent age of lead isotopes and the broad refractory-element differences among and between ocean island basalts (OIBs) and mid-ocean ridge basalts (MORBs) can now be quantitatively accounted for with some assurance. It has been proposed recently that noble gases reside in a so-called hybrid pyroxenite assemblage that is the result of melt from fusible pods reacting with surrounding refractory peridotite and refreezing. Hybrid pyroxenite that is off-axis may not remelt and erupt at MORs, so its volatile constituents would recirculate within the mantle. Hybrid pyroxenite is likely to be denser than average mantle, and thus some would tend to settle in the D" zone at the base of the mantle, along with some old subducted oceanic crust. Residence times in D" are longer, so the hybrid pyroxenite there would be less degassed. Plumes would sample both the degassed, enriched old oceanic crust and the gassy, less enriched hybrid pyroxenite and deliver them to OIBs. This model can account quantitatively for the main He, Ne and Ar isotopic observations, and for the poor correlation of unradiogenic gases with refractory-element enrichment in OIBs. The difficulty with mass balances can be traced to the common inference that the MORB source is strongly depleted of incompatible elements, which leaves a deficit of key elements and seems to require a hidden reservoir that is enriched and undegassed. However it has recently been argued that conventional estimates of the MORB source composition fail to take full account of mantle heterogeneity, and in particular focus on an ill-defined "depleted" mantle component while neglecting less common enriched components. Recent estimates have also been tied to the composition of peridotites, but these probably do not reflect the full complement of incompatible elements in the heterogeneous mantle. New estimates that account for enriched mantle components are capable of satisfying mass balance requirements, although some additional uncertainties apply to argon. The result is that the MORB source is depleted by only about a factor of 2, relative to the primitive Earth.

Were Karoo flood basalts derived from a LLSVP-related plume source?

2020 ◽  
Author(s):  
Arto Luttinen ◽  
Jussi Heinonen ◽  
Sanni Turunen ◽  
Richard Carlson ◽  
Mary Horan
Keyword(s):  
Oceanic Crust ◽  
Mantle Plume ◽  
Flood Basalt ◽  
Planetary Science ◽  
Large Igneous Province ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
Flood Basalts ◽  
Depleted Mantle ◽  
Mantle Reservoir

<p>Examination of the least-contaminated rocks of the Jurassic Karoo flood basalt province indicates considerable compositional variability in the mantle source. New and previously published Sr, Nd, and Pb isotopic data are suggestive of two main categories of mantle reservoirs: one coincides with the field of depleted mantle (DM) -affinity oceanic crust and the other has low initial eNd (+3.3 to 0.3) and high <sup>87</sup>Sr/<sup>86</sup>Sr (0.7039 to 0.7057) and Δ8/4 (92 to 138) typical of enriched mantle 1 (EM1) -affinity oceanic crust. Previous studies have proposed the DM type reservoir included domains affected by subduction-related fluids and recycled oceanic components (e.g. Heinonen et al., 2014). The EM1 type reservoir probably also contained subducted crustal components, but the geochemical data are suggestive of an additional primitive mantle (PM) type component (Turunen et al., 2019).</p><p>Importantly, the two reservoirs can be geochemically linked to a recently identified bilateral compositional asymmetry in the volumious Karoo flood basalts (Luttinen, 2018): The DM type  reservoir is the most likely source of Nb-depleted flood basalts in the southeastern Karoo subprovince (Lebombo rifted margin and Antarctica), whereas the EM1-PM type reservoir has been identified as the principal source of the Nb-undepleted flood basalts in the northwestern subprovince (Karoo-Kalahari-Zambezi basins). The boundary between the flood basalt subprovinces and the occurrences of the DM-affinity and EM1-PM-affinity rocks overlie the Jurassic location of the margin of the Jurassic sub-African LLSVP. Magmas derived from the EM1-PM type reservoir were largely emplaced above the deep mantle anomaly, whereas those derived from the DM type reservoir were emplaced outside the footprint of the LLSVP.</p><p>Based on isotopic similarity, the EM1-PM type reservoir of the Karoo province may record the same overall LLSVP material as the Gough component in the zoned Tristan da Cunha plume (e.g. Hoernle et al., 2015). Furthermore, it is possible that the DM type reservoir of the Karoo province, which has been interpreted to represent depleted upper mantle heated by mantle plume, could also represent a plume component and that the bilateral Karoo flood basalt province as a whole could thus register melting of a large zoned plume source associated with the margin of the sub-African LLSVP.</p><p>References</p><p>Heinonen, J.S., Carlson, R.W., Riley, T.R., Luttinen, A.V., Horan, M.F. (2014). Subduction-modified oceanic crust mixed with a depleted mantle reservoir in the sources of the Karoo continental flood basalt province. Earth and Planetary Science Letters 394, 229–241. http://dx.doi.org/10.1016/j.epsl.2014.03.012</p><p>Hoernl, K., Ronde, J., Hauff, F., Garbe-Schönberg, D., Homrighausen, S., Werner, W., Morgan, J.P. (2015).  How and when plume zonation appeared during the 132 Myr evolution of the Tristan Hotspot. Nature Communications 6:7799. doi: 10.1038/ncomms8799</p><p>Luttinen, A.V. (2018). Bilateral geochemical asymmetry in the Karoo large igneous province. Scientific Reports 8:5223. doi:10.1038/s41598-018-23661-3</p><p>Turunen, S.T., Luttinen, A.V., Heinonen, J.S., Jamal, D.L. (2019). Luenha picrites, Central Mozambique – Messengers from a mantle plume source of Karoo continental flood basalts? Lithos 346–347. https://doi.org/10.1016/j.lithos.2019.105152</p>

Geochemistry and models of mantle circulation

1989 ◽  
Vol 328 (1599) ◽  
pp. 425-439 ◽  
Keyword(s):  
Mass Balance ◽  
Continental Crust ◽  
Oceanic Crust ◽  
Large Scale ◽  
Oceanic Islands ◽  
Primitive Mantle ◽  
Geochemical Data ◽  
Depleted Mantle ◽  
Subducted Oceanic Crust ◽  
Subcontinental Lithosphere

Geochemical data help to constrain the sizes of identifiable reservoirs within the framework of models of layered or whole-mantle circulation, and they identify the sources of the circulating heterogeneities as mainly crustal and/or lithospheric, but they do not decisively distinguish between different types of circulation. The mass balance between crust, depleted mantle and undepleted mantle based on 143 Nd/ 144 Nd, Nb/U and Ce/Pb, and the concentrations of very highly incompatible elements Ba, Rb, Th, U, and K, shows that ca. 25- 70% (by mass) of depleted mantle balances the trace element and isotopic abundances of the continental crust. This mass balance reflects the actual proportions of mantle reservoirs only if there are no additional unidentified reservoirs. Evidence on the nature and ages of different source reservoirs comes from the geochemical fingerprints of basalts extruded at mid-ocean ridges and oceanic islands. Consideration of Nd and He isotopes alone indicates that ocean island basalts (oibs) may be derived from a relatively undepleted portion of the mantle. This has in the past provided a geochemical rationale for a two-layer model consisting of an upper depleted and a lower undepleted (‘primitive’) mantle layer. However, Pb-isotopic ratios, and Nb/U and Ce/Pb concentration ratios demonstrate that most or all oib source reservoirs are definitely not primitive. Models consistent with this evidence postulate recycling of oceanic crust and lithosphere or subcontinental lithosphere. Recycling is a natural consequence of mantle convection. This cannot be said for some other models such as those requiring large-scale vertical metasomatism beneath oib source regions. Unlike other trace elements, Nb, Ta, and Pb discriminate sharply between continental and oceanic crust-forming processes. Because of this, the primitive mantle value of Nb/U = 30 (Ce/Pb = 9) has been fractionated into a continental crustal Nb/U = 12 (Ce/Pb = 4) and a residual-mantle (morb (mid-ocean ridge basalt) plus oib source) Nb/U = 47 (Ce/Pb = 25). These residual mantle values are uniform within about 20% and are not fractionated during formation of oceanic crust. By using these concentrations ratios as tracers, it can be shown that the possible contribution of recycled continental crust to oib sources is limited to a few percent. Therefore, recycling must be dominated by oceanic crust and lithosphere, or by subcontinental lithosphere. Oceanic crust normally bears a thin layer of pelagic sediment at the time of subduction, and this is consistent with oib sources that are dominated by subducted oceanic crust with variable but always small additions of continental material. Primordial 3 He, 36 Ar, and excess 129 Xe, in oceanic basalts demonstrate that the mantle has been neither completely outgassed nor homogenized, but they do not constrain the degree of mixing or the size of reservoirs. Also, helium does not correlate well with other isotopic data and may have migrated into the basalt source from other regions. The high 3 He/ 4 He ratios found in some oibs suggest that, even though the basalts are not derived from primordial mantle, their sources may be located close to a reservoir rich in primordial gases. This leads to models in which the oib sources are in a boundary layer within the mantle. The primordial helium migrates into this layer from below. The interpretation of the rare-gas data is still quite controversial. It is often argued that the upper mantle is a well-homogenized reservoir, but the data indicate heterogeneities on scales ranging from 10° to 10 6 m. The 206 Pb/ 204 Pb ratios in the oceanic m antle range from 17 to 21, which is similar to the range in most continental rocks. The degree of mixing cannot be directly inferred from these data unless the size and composition of the heterogeneities and the time of their introduction into the system are known. The relative uniformity of Nb/U and Ce/Pb ratios in the otherwise heterogeneous morb and oib sources indicates that this reservoir was indeed homogenized after the separation of the continental crust, and that the observed isotopic and chem ical heterogeneities were introduced subsequently. Overall, the results are consistent with, but do not prove, a layered mantle where the upper layer contains both morb and oib sources, and the lower, primitive mantle is not sampled by present-day volcanism. Alternative models such as those involving a chemically graded mantle have not been sufficiently explored.

scholarly journals Long-lasting influence of the Discovery plume on tholeiitic magmatism in the South Atlantic: data on basalts recovered by hole 513a, dsdp leg 71

2019 ◽  
Vol 64 (2) ◽  
pp. 107-127
Author(s):  
N. M. Sushchevskaya ◽  
T. A. Shishkina ◽  
M. V. Portnyagin ◽  
V. G. Batanova ◽  
B. V. Belyatsky
Keyword(s):  
Trace Elements ◽  
Mantle Peridotite ◽  
Major And Trace Elements ◽  
South Atlantic ◽  
The South ◽  
Incompatible Elements ◽  
Depleted Mantle ◽  
A Minor ◽  
Lasting Influence ◽  
Tholeiitic Magmatism

The paper presents the very first data on concentrations of major and trace elements; Sr, Nd, and Pb isotopic ratios of rocks; and the composition of olivine phenocrysts of 38-Ma basalts recovered by Hole 513a (DSDP Leg 71) in the South Atlantic. The bulk-rock samples and the chilled glasses are mildly magnesian (7–8 wt % MgO) and bear elevated FeO and low Na2O concentrations, as is typical of MORB of the TOR-1 type. Olivine phenocrysts (Fo84.5–88) in these rocks contain concentrations of trace elements (Ni, Mn, Cr, and Zn) that are typical of classic MORB, which are produced by partial melting mantle peridotite. The rocks are strongly depleted in incompatible elements [(La/Sm)n ~ 0.6] but have elevated Ba/Nb, K/Nb, and Pb/Ce ratios and Cu, Ag, and Au concentrations that are 1.5–4 times higher than in typical depleted MORB (N-MORB) and in most rift basalts in the South Atlantic. Isotope compositions of the basalts (average ratios 206Pb/204Pb ~ 18.0; 207Pb/204Pb ~ 15.6, 208Pb/204Pb ~ 38.0, 143Nd/144 Nd ~ 0.5130, and 87Sr/86Sr ~ 0.7040) are close to those in modern tholeiites from the southern MAR segment (SMAR) north of the Agulhas Fracture Zone. The data indicate that the magmas were derived from a strongly depleted mantle source that contained a minor (~3%) admixture of an enriched component, which is discernible in the magmas of the Discovery hotspot. The composition of the source, which is more depleted than DM, and the high degrees of melting of this source explain why the basalts from DSDP Hole 513a are enriched in chalcophile elements. It is believed that spreading magmatism at 45°–48° S in SMAR as far back as 40 Ma was already affected by the Discovery hotspot. This hotspot might be related to the Tristan plume system, and its origin and long-lasting influence on spreading magmatism in the South Atlantic are regarded as evidence of the extensive effect of the Tristan plume.

The Origin of the Moon and its Relationship to the Origin of the Solar System

1962 ◽  
Vol 14 ◽  
pp. 133-148 ◽  
Author(s):  
Harold C. Urey
Keyword(s):  
Solar System ◽  
The Moon ◽  
The Past ◽  
The Earth ◽  
Short Period ◽  
Origin Of The Moon

During the last 10 years, the writer has presented evidence indicating that the Moon was captured by the Earth and that the large collisions with its surface occurred within a surprisingly short period of time. These observations have been a continuous preoccupation during the past years and some explanation that seemed physically possible and reasonably probable has been sought.

scholarly journals Calibration of Radiocarbon Dates for the Late Pleistocene Using U/Th Dates on Stalagmites

Radiocarbon ◽  
1997 ◽  
Vol 39 (1) ◽  
pp. 27-32 ◽  
Author(s):  
John C. Vogel ◽  
Joel Kronfeld
Keyword(s):  
South Africa ◽  
Magnetic Dipole ◽  
Satisfactory Agreement ◽  
Late Pleistocene ◽  
Calibration Curve ◽  
Dipole Field ◽  
Radiocarbon Dates ◽  
The Past ◽  
The Earth ◽  
Magnetic Dipole Field

Twenty paired 14C and U/Th dates covering most of the past 50,000 yr have been obtained on a stalagmite from the Cango Caves in South Africa as well as some additional age-pairs on two stalagmites from Tasmania that partially fill a gap between 7 ka and 17 ka ago. After allowance is made for the initial apparent 14C ages, the age-pairs between 7 ka and 20 ka show satisfactory agreement with the coral data of Bard et al. (1990, 1993). The results for the Cango stalagmite between 25 ka and 50 ka show the 14C dates to be substantially younger than the U/Th dates except at 49 ka and 29 ka, where near correspondence occurs. The discrepancies may be explained by variations in 14C production caused by changes in the magnetic dipole field of the Earth. A tentative calibration curve for this period is offered.

Plant leaf recognition with shallow and deep learning: A comprehensive study

2020 ◽  
Vol 24 (6) ◽  
pp. 1311-1328
Author(s):  
Jozsef Suto
Keyword(s):  
Machine Learning ◽  
Plant Species ◽  
Research Area ◽  
Research Papers ◽  
Plant Leaf ◽  
Leaf Characteristics ◽  
The Past ◽  
The Earth ◽  
Test Sets ◽  
Comprehensive Study

Nowadays there are hundreds of thousands known plant species on the Earth and many are still unknown yet. The process of plant classification can be performed using different ways but the most popular approach is based on plant leaf characteristics. Most types of plants have unique leaf characteristics such as shape, color, and texture. Since machine learning and vision considerably developed in the past decade, automatic plant species (or leaf) recognition has become possible. Recently, the automated leaf classification is a standalone research area inside machine learning and several shallow and deep methods were proposed to recognize leaf types. From 2007 to present days several research papers have been published in this topic. In older studies the classifier was a shallow method while in current works many researchers applied deep networks for classification. During the overview of plant leaf classification literature, we found an interesting deficiency (lack of hyper-parameter search) and a key difference between studies (different test sets). This work gives an overall review about the efficiency of shallow and deep methods under different test conditions. It can be a basis to further research.

scholarly journals Trajectories of the Earth System in the Anthropocene

2018 ◽  
Vol 115 (33) ◽  
pp. 8252-8259 ◽  
Author(s):  
Will Steffen ◽  
Johan Rockström ◽  
Katherine Richardson ◽  
Timothy M. Lenton ◽  
Carl Folke ◽  
...  
Keyword(s):  
Global Economy ◽  
Human Action ◽  
Behavioral Changes ◽  
Earth System ◽  
New Governance ◽  
Sea Levels ◽  
Average Temperature ◽  
The Past ◽  
The Earth ◽  
Potential Threshold

We explore the risk that self-reinforcing feedbacks could push the Earth System toward a planetary threshold that, if crossed, could prevent stabilization of the climate at intermediate temperature rises and cause continued warming on a “Hothouse Earth” pathway even as human emissions are reduced. Crossing the threshold would lead to a much higher global average temperature than any interglacial in the past 1.2 million years and to sea levels significantly higher than at any time in the Holocene. We examine the evidence that such a threshold might exist and where it might be. If the threshold is crossed, the resulting trajectory would likely cause serious disruptions to ecosystems, society, and economies. Collective human action is required to steer the Earth System away from a potential threshold and stabilize it in a habitable interglacial-like state. Such action entails stewardship of the entire Earth System—biosphere, climate, and societies—and could include decarbonization of the global economy, enhancement of biosphere carbon sinks, behavioral changes, technological innovations, new governance arrangements, and transformed social values.

Le terrane de Slide Mountain (Cordillères canadiennes) : une lithosphère océanique marquée par des points chauds

2003 ◽  
Vol 40 (6) ◽  
pp. 833-852 ◽  
Author(s):  
M Tardy ◽  
H Lapierre ◽  
D Bosch ◽  
A Cadoux ◽  
A Narros ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Oceanic Island ◽  
Light Rare Earth ◽  
Isotopic Compositions ◽  
Incompatible Elements ◽  
Depleted Mantle ◽  
Mantle Sources ◽  
British Colombia ◽  
Ultramafic Cumulates ◽  
Back Arc

The Slide Mountain Terrane consists of Devonian to Permian siliceous and detrital sediments in which are interbedded basalts and dolerites. Locally, ultramafic cumulates intrude these sediments. The Slide Mountain Terrane is considered to represent a back-arc basin related to the Quesnellia Paleozoic arc-terrane. However, the Slide Mountain mafic volcanic rocks exposed in central British Colombia do not exhibit features of back-arc basin basalts (BABB) but those of mid-oceanic ridge (MORB) and oceanic island (OIB) basalts. The N-MORB-type volcanic rocks are characterized by light rare-earth element (LREE)-depleted patterns, La/Nb ratios ranging between 1 and 2. Moreover, their Nd and Pb isotopic compositions suggest that they derived from a depleted mantle source. The within-plate basalts differ from those of MORB affinity by LREE-enriched patterns; higher TiO2, Nb, Ta, and Th abundances; lower εNd values; and correlatively higher isotopic Pb ratios. The Nd and Pb isotopic compositions of the ultramafic cumulates are similar to those of MORB-type volcanic rocks. The correlations between εNd and incompatible elements suggest that part of the Slide Mountain volcanic rocks derive from the mixing of two mantle sources: a depleted N-MORB type and an enriched OIB type. This indicates that some volcanic rocks of the Slide Mountain basin likely developed from a ridge-centered or near-ridge hotspot. The activity of this hotspot is probably related to the worldwide important mantle plume activity that occurred at the end of Permian times, notably in Siberia.

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