scholarly journals Estimation of oak stand pollution with heavy metals on the Krotoszyn Plateau

2014 ◽  
Vol 63 (1) ◽  
pp. 83-86 ◽  
Author(s):  
Jadwiga Opydo

The content of heavy metals - Zn, Cd, Pb and Cu - in oak wood of <i>Quercus robur</i> L. and in the soil was investigated. The studies were carried out in five areas: on the Krotoszyn Plateau, in two areas of the Copper Basin, in the area of Zawiercie and in the control area in Kórnik. The results showed an elevated content of copper in the wood of oaks from the Krotoszyn Plateau as compared with oaks from the other investigated areas. The copper content in the examined oaks was 0.6 µg/g in Kórnik, 1.1 µg/g in Zawiercie, 3.9-15.8 µg/g in the Copper Basin, whereas in the oaks of the Krotoszyn Plateau it amounted to 7.0-26.5 µg/g. It was also noticed that there is a correlation between the copper content in the wood and sanitary condition of the trees. The content of other toxic metals in the oak stands of the Krotoszyn Plateau was on the level of non-polluted areas ranging between 0.08-0.21 µg/g for Cd, 0.12-0.45 µg/g for Pb and 9.1-14.7 µg/g for Zn.

2020 ◽  
Vol 109 ◽  
pp. 76-80
Author(s):  
Adrianna Balicka ◽  
Dominika Szadkowska

XRF analysis of heavy metals contents in oak wood (Quercur robur L.). The aim of this study was to determine an amount of adsorbed metals ions from water solutions by oak ( Quercus robur L.) shavings. This paper focuses on XRF analysis of metal contents in examined samples. Necessary material was obtained from damaged flooring strips. Samples were soaked with standard water solutions of lead (II) nitrate, cadmium nitrate and mercury (II) chloride. After 7 days wood shavings were dried and reduced to ashes in muffle furnace. Content of adsorbed metal was marked (XRF) and classified depending on percentage concentration of metal ions in solutions.


Author(s):  
Maroš Sirotiak ◽  
Marek Lipovský ◽  
Alica Bartošová

Abstract In the research described in this paper, studied was sorption capacity of natural and ferric modification of zeolite tuff containing mineral clinoptilolite from the Nižný Hrabovec deposit to remove potentially toxic metals (ionic forms of chromium, nickel, copper and aluminium) from their water solutions. We reported that the Fe (III) zeolite has an enhanced ability to sorption of Cu (II), and a slight improvement occurs in the case of Cr (VI) and Ni (II). On the other hand, the deterioration was observed in the case of Al (III) adsorption.


2019 ◽  
Vol 6 (2) ◽  
pp. 113-118
Author(s):  
Hossein Alidadi ◽  
Sima Zamand ◽  
Aliasghar Najafpoor ◽  
Hamid Heidarian ◽  
Aliakbar Dehghan ◽  
...  

This study aimed to investigate the levels of heavy metals in the lipstick products. In general, 30 samples were randomly selected from Mashhad markets. Analysis of variance (ANOVA) and t test were used to compare color and price variables. Based on the results, the mean concentrations of studied elements were as follows: Cd (ND-0.52 µg/g), Cr (0.25-76.35 µg/g), Ni (ND-20.12 µg/g), Zn (ND-224.22 µg/g), Pb (ND-44.77 µg/g), and Hg (ND-0.32 µg/g). The presence of toxic metals in the samples, and on the other hand, continuous use and unintended ingestion of these metals can lead to their biological accumulation in the human body, thereby causing the development of different diseases. Hence, it deems necessary to apply suitable actions for the improvement of quality control over these products.


2017 ◽  
Vol 1 ◽  
pp. 264
Author(s):  
Md Didarul Islam ◽  
Ashiqur Rahaman ◽  
Fahmida Jannat

This study was based on to determine the concentration of macro and micro nutrients as well as toxic and nontoxic heavy metals present in the chicken feed available in Dhaka city of Bangladesh. All macro nutrients, if present in the feed at high concentration have some adverse effect, at the same time if this nutrient present in the feed at low concentration this have some adverse effect too. So that this nutrient level should be maintained at a marginal level. On the other side toxic heavy metals if present in the feed at very low concentration those can contaminate the total environment of the ecosystem. In this study six brand samples (starter, grower, finisher and layer) which was collected from different renowned chicken feed formulation industry in Bangladesh. Those samples were prepared for analysis by wet ashing and then metals were determined by Atomic Absorption Spectroscopy. It was found that 27.7 to 68.4, 57.3 to 121.9, 0.21 to 4.1, 0.32 to 2.1, 0.11 to 1.58, 0.28 to 2.11 and 0.28 to 1.78 for zinc, iron, copper, mercury, cadmium, nickel and cobalt respectively. It was found that essential macro and micro nutrients were present in the feed in low concentration on the other side mercury was present in high concentration in the feed samples.


2013 ◽  
Vol 12 (3) ◽  
pp. 239-247

The removal of heavy metals from wastewaters is a matter of paramount importance due to the fact that their high toxicity causes major environmental pollution problems. One of the most efficient, applicable and low cost methods for the removal of toxic metals from aqueous solutions is that of their adsorption on an inorganic adsorbent. In order to achieve high efficiency, it is important to understand the influence of the solution parameters on the extent of the adsorption, as well as the kinetics of the adsorption. In the present work, the adsorption of Cu(II) species onto TiO2 surface was studied. It was found that the adsorption is a rapid process and it is not affected by the value of ionic strength. In addition, it was found that by increasing the pH, the adsorbed amount of Cu2+ ions and the value of the adsorption constant increase, whereas the value of the lateral interaction energy decreases.


Foods ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 649
Author(s):  
Estefanía Noriega-Fernández ◽  
Izumi Sone ◽  
Leire Astráin-Redín ◽  
Leena Prabhu ◽  
Morten Sivertsvik ◽  
...  

The aim of this work was to evaluate the potential of ultrasound (US), alone or in combination with mild heating and/or EDTA towards reduction of As, Cd, I, and Hg content of Laminaria hyperborea. Concentrations of As, Cd, I, and Hg of 56.29, 0.596, 7340, and <0.01 mg kg−1 of dry weight, respectively, were found in L. hyperborea blades. Treatment with US at 50 °C increased approx. 2-fold the amount of As released, although did not affect significantly the content of Cd or I, as compared to control (no US) samples. Reducing the temperature to 8 °C significantly decreased the effect of US, but heating at 80 °C did not cause a significant effect as compared to treatments at 50 °C. On the other hand, treatment with 0.1 N EDTA at 50 °C enhanced the percentage of Cd released by approximately 7-fold, regardless of sonication. In the present work, the combination of US and EDTA at 50 °C for 5 min led to a significant reduction of the As (32%), Cd (52%) and I (31%) content in L. hyperborea, thus improving the product’s safety for consumers.


1992 ◽  
Vol 25 (10) ◽  
pp. 55-67 ◽  
Author(s):  
R. C. Squires

The performance of Exxflow, a patented form of crossflow microfiltration, treating industrial wastewaters containing mixed heavy metals discharged by two types of industry is quantified and compared with the traditional technologies used for such treatment. Pilot trial results using Exxflow are shown and compared to the performance of the full scale plants now operating on these effluents. The operating costs of the Exxflow process are estimated for the two plants. One of which has been operating for 18 months and the other about 4 months. The Exxflow process is described and improvements which are being developed to lower the operating costs are presented. It is shown that industrial effluents containing mixed heavy metals are very effectively treated by the Exxflow process and since the installation of the plants the treated effluent has been of a quality suitable for discharge to the River Thames in one case and to a sewage treatment plant in the other. Unlike other processes, Exxflow has shown that it can successfully treat effluent containing mixed metals and that removal of antimony from mixed metal waste waters is affected by the concentration of sodium sulphate in the wastewater.


1926 ◽  
Vol 10 (1) ◽  
pp. 9-21 ◽  
Author(s):  
Paul Reznikoff

I. Plasmalemma. 1. The order of toxicity of the salts used in these experiments on the surface membrane of a cell, taking as a criterion viability of amebæ immersed in solutions for 1 day, is HgCl2, FeCl3&gt; AlCl3&gt; CuCl2&gt; PbCl2&gt; FeCl2. Using viability for 5 days as a criterion, the order of toxicity is PbCl2&gt; CuCl2&gt; HgCl2&gt; AlCl3&gt; FeCl3&gt; FeCl2. 2. The rate of toxicity is in the order FeCl3&gt; HgCl2&gt; AlCl3&gt; FeCl2&gt; CuCl2&gt; PbCl2. 3. The ability of amebæ to recover from a marked tear of the plasmalemma in the solutions of the salts occurred in the following order: AlCl3&gt; PbCl2&gt; FeCl2&gt; CuCl2&gt; FeCl3&gt; HgCl2. II. Internal Protoplasm. 4. The relative toxicity of the salts on the internal protoplasm, judged by the recovery of the amebæ from large injections and the range over which these salts can cause coagulation of the internal protoplasm, is in the following order: PbCl2&gt; CuCl2&gt; FeCl3&gt; HgCl2&gt; FeCl2&gt; AlCl3. 5. AlCl3 in concentrations between M/32 and M/250 causes a marked temporary enlargement of the contractile vacuole. FeCl2, FeCl3, and CuCl3 produce a slight enlargement of the vacuole. 6. PbCl2, in concentrations used in these experiments, appears to form a different type of combination with the internal protoplasm than do the other salts. III. Permeability. 7. Using the similarity in appearance of the internal protoplasm after injection and after immersion to indicate that the surface is permeable to a substance in which the ameba is immersed, it is concluded that AlCl3 can easily penetrate the intact plasmalemma. CuCl2 also seems to have some penetrating power. None of the other salts studied give visible internal evidence of penetrability into the ameba. IV. Toxicity. 8. The toxic action of the chlorides of the heavy metals used in these experiments, and of aluminum, is exerted principally upon the surface of the cell and is due not only to the action of the metal cation but also to acid which is produced by hydrolysis.


2021 ◽  
Author(s):  
Abdulkareem AS ◽  
Hamzat WA ◽  
Tijani JO ◽  
Bankole MT ◽  
Titus Egbosiuba ◽  
...  

Abstract Comparative adsorption study of some toxic metals (Ni, Fe, Cu, Cd, and Pb) from battery industrial effluent by purified and polyethylene glycol-modified carbon nanotubes (CNTs) is reported. The as-prepared CNTs via chemical vapour deposition method (A-CNTs), its acid purified form (P-CNTs), and polyethylene glycol functionalized form (PEG-CNTs) were characterized by HRTEM, BET, HRSEM, FTIR and XRD. The HRSEM and HRTEM micrograph revealed the formation of multi-walled tubular network structures of different inner and outer diameter. The BET study of PEG-CNTs and purified CNTs showed surface areas of 970.81 m2/g and 781.88 m2/g, respectively. The nanomaterials batch adsorption effect of various parameters such as contact time, nano-adsorbent dosage and temperature was conducted. The optimum equilibrium to achieve maximum removal of Cd (83.41 %), Ni (92.79 %), Fe (95.93%), Pb (97.16 %) Cu (99.9 9%) using PEG-CNTs was 90 min of contact time, 0.3 g of nano-adsorbent dosage and 60 oC temperature. While the maximum percentage removal efficiencies accomplished using P-CNTs under the same applied conditions were Cd (78.64 %), Ni (76.12 %), Fe (92.87 %), Pb (90.7 2%) Cu (99.09 %). PEG-CNTs was seen as more effective than P-CNTs. Adsorption data of Ni on P-CNTs followed Langmuir isotherm while the adsorption equilibrium model (Freundlich isotherm) of Ni, Fe, Cu and Pb on PEG-CNTs were fitted well. However, in both cases, the sorption kinetic study followed the pseudo-second-order model. The thermodynamics showed that the removal of toxic metals from battery wastewater was spontaneous and endothermic irrespective of the nano-adsorbents. The study found that surface modification of CNTs by polyethylene glycol adequately improved the nanotubes, thus leading to relatively adsorption capacities of heavy metals from industrial battery effluent.


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