Biostratigraphy, geochemistry and sedimentology of Middle to Late Jurassic strata in the Strážovce section (Strážovské vrchy Mts), Krížna Nappe of the Central Carpathians, Slovakia

2017 ◽  
pp. 0-0
Author(s):  
Jozef Michalík ◽  
Marta Bąk ◽  
Otília Lintnerová ◽  
Štefan Méres

Abstract. The Jurassic / Lower Cretaceous sequence of the Strážovce section has been deposited in the central, axial part of the Zliechov Basin. Its most characteristic part – the Ždiar Formation consists of bedded siliceous radiolarian limestones and radiolarites. The radiolarian assemblage typical of the North Tethyan Bioprovince lived during mid Oxfordian – Early Kimmeridgian in a warm upper part of the well stratified water column, partially near to the thermocline. Radiolarian abundance decreases upwards. Productivity decrease is quantified by the share of biogenic SiO2 as well as by high EFSi values during sedimentation of both the Ždiar and Jasenina formations. The geochemical data indicate relatively stable volume of the siliciclastic component of the rocks and a felsic character comparable to the Average Shale. The chemically homogeneous sedimentary signal indicates values of both CPA and EF ≤ 1 of Ti, Zr, Fe, Na, K, Rb, V and U. The values of EF > 1 signal enrichment of elements with affinity to carbonate minerals (Sr, Mn, P, Y, and Mg). Metal enrichment (Cu, Zn and Ni) indicates metal mobilization from other sources or due to carbonate diagenesis. In comparison to the Average Shale, decreased ΣREE´s and negative Cech and Euch anomalies could be regarded as a typical deep sea water signal. The differentiated REE record of higher calcareous beds of the Jasenina Fm suggests basinal dysoxic conditions. The “bell-shape” of curves (normalized to shale) indicate that REEs were slightly affected by carbonate diagenesis. The Oxfordian / Kimmeridgian siliceous sedimentation in the Zliechov Basin was influenced probably more by monsoon-controlled input of land derived weathered material than by hydrothermal fluids from the bottom rifts.

2020 ◽  
Vol 21 (2) ◽  
pp. 61
Author(s):  
Syarif Kurniawan ◽  
Hendarmawan Hendarmawan ◽  
Yoga A. Sendjaja ◽  
Euis Yuningsih

The Paleogene carbonate unit in the North West Java Basin has no cropped out and never been shown in the regional stratigraphy, whether as a formation or as a member of the existing formation. This paper provides new insight of the diagenetic process evidence by the stable isotope of 2H and 18O in formation fluids integrated with petrographic and geochemical data of rock and fluids samples analysis. The major minerals of this carbonate unit are: calcite, clay minerals, dolomite, quartz, plagioclase, and pyrite. From ICP-OES analyses result this carbonate rocks has the content of Fe, Mg and Al ranges 450-7800 ppm, 497-10892 ppm and 96-3900 ppm respectively, while Si and Sr are relatively low around 0.1 ppb to 0.7 ppm and 60 ppm to 570 ppm respectively. Formation water chemistry data shows the total charges for cation and anion were relatively balanced from 75.5 to 396.8 meq, the TDS from 4,904 mg/l to 22,351 mg/l, and SG from 1.005 to 1.016 and were dominated by elements of Na, Ca, Mg, Cl and HCO3. The δ2H and δ18O from water samples are between -26.2 to -37.2 (‰) and between -3.63 to 2.50 (‰) respectively. With all the correlation of geochemical and isotope data of both rock and water indicate that the Paleogene Carbonate system in the M-Field has been through at least once uplifting and one sea water rise/drowning event, with meteoric water affected diagenetic process. These geological processes shown by the calcite cementation, the presence of pyrite and quartz, recrystallization of the carbonate grains and mylonitic dolomite, high content of Mg, Fe and Al, and also the abruptly change of the δ13C and δ18O values.Keywords: Paleogene carbonate, geochemistry, water chemistry, stable isotope, diagenesis.


Author(s):  
Vera Rostovtseva ◽  
Vera Rostovtseva ◽  
Igor Goncharenko ◽  
Igor Goncharenko ◽  
Dmitrii Khlebnikov ◽  
...  

Sea radiance coefficient, defined as the ratio of the sunlight reflected by the water bulk to the sunlight illuminating the water surface, is one of the most informative optical characteristics of the seawater that can be obtained by passive remote sensing. We got the sea radiance coefficient spectra by processing the data obtained in measurements from board a moving ship. Using sea radiance coefficient optical spectra it is possible to estimate water constituents concentration and their distribution over the aquatory of interest. However, thus obtained sea radiance coefficient spectra are strongly affected by weather and measurement conditions and needs some calibration. It was shown that practically all the spectra of sea radiance coefficient have some generic peculiarities regardless of the type of sea waters. These peculiarities can be explained by the spectrum of pure sea water absorption. Taking this into account a new calibration method was developed. The measurements were carried out with the portative spectroradiometers from board a ship in the five different seas: at the north-east coast of the Black Sea, in the Gdansk Bay of the Baltic Sea, in the west part of the Aral Sea, in the Kara Sea with the Ob’ Bay and in the Philippine Sea at the coast of Taiwan. The new method of calibration was applied to the obtained spectra of the sea radiance coefficient that enabled us to get the corresponding absorption spectra and estimate the water constituents concentration in every region. The obtained concentration estimates were compared to the values obtained in water samples taken during the same measurement cycle and available data from other investigations. The revealed peculiarities of the sea radiance coefficient spectra in the aquatories under exploration were compared to the corresponding water content and some characteristic features were discussed.


2012 ◽  
Vol 16 (7) ◽  
pp. 1845-1862 ◽  
Author(s):  
F. Jørgensen ◽  
W. Scheer ◽  
S. Thomsen ◽  
T. O. Sonnenborg ◽  
K. Hinsby ◽  
...  

Abstract. Geophysical techniques are increasingly being used as tools for characterising the subsurface, and they are generally required to develop subsurface models that properly delineate the distribution of aquifers and aquitards, salt/freshwater interfaces, and geological structures that affect groundwater flow. In a study area covering 730 km2 across the border between Germany and Denmark, a combination of an airborne electromagnetic survey (performed with the SkyTEM system), a high-resolution seismic survey and borehole logging has been used in an integrated mapping of important geological, physical and chemical features of the subsurface. The spacing between flight lines is 200–250 m which gives a total of about 3200 line km. About 38 km of seismic lines have been collected. Faults bordering a graben structure, buried tunnel valleys, glaciotectonic thrust complexes, marine clay units, and sand aquifers are all examples of geological structures mapped by the geophysical data that control groundwater flow and to some extent hydrochemistry. Additionally, the data provide an excellent picture of the salinity distribution in the area and thus provide important information on the salt/freshwater boundary and the chemical status of groundwater. Although the westernmost part of the study area along the North Sea coast is saturated with saline water and the TEM data therefore are strongly influenced by the increased electrical conductivity there, buried valleys and other geological elements are still revealed. The mapped salinity distribution indicates preferential flow paths through and along specific geological structures within the area. The effects of a future sea level rise on the groundwater system and groundwater chemistry are discussed with special emphasis on the importance of knowing the existence, distribution and geometry of the mapped geological elements, and their control on the groundwater salinity distribution is assessed.


Radiocarbon ◽  
1980 ◽  
Vol 22 (3) ◽  
pp. 684-692 ◽  
Author(s):  
Georgette Delibrias

14C measurements were carried out on sea water samples collected in 1973, in the Indian ocean. The results obtained for 9 vertical profiles between 27° S and 48°S are presented. In surface water, the bomb 14C content is maximum at middle latitudes. A time lag relative to the north hemisphere bomb 14C delivery is apparent. In the more southern latitudes, 14C content remains very low.


2021 ◽  
Author(s):  
Cemil Arkula ◽  
Nalan Lom ◽  
John Wakabayashi ◽  
Grant Rea-Downing ◽  
Mark Dekkers ◽  
...  

<p>The western edge of the North America plate contains geological records that formed during the long-lived convergence between plates of the Panthalassa Ocean and North America. The geology of different segments along western North America indicates different polarities (eastward and westward) for subducted slabs and thereby various tectonic histories and settings. The western United States (together with Mexico) plays a key role in this debate, many geologic interpretations assume continuous eastward subduction in contrast to observations within proximal geologic segments and tomographic images of the lower mantle below North America and the eastern Pacific Ocean which suggest a more complex subduction history. In this study, we aim to evaluate the plate tectonic setting in which the Jurassic ophiolites of California formed. Geochemical data from these ophiolites suggest that they formed above a nascent intra-oceanic or continental margin subduction zone. We first developed a kinematic reconstruction of the western US geology back to the Jurassic based on published structural geological data. Importantly, we update the reconstruction of the various branches of the San Andreas fault system to determine the relative position of the ophiolite fragments and adopt a previous restoration of Basin and Range extension which we expand northward towards Washington state. We then reconstruct North American margin deformation associated with Cretaceous to Paleogene shortening and strike-slip faulting. We find no clear candidates in the geological record that may have accommodated major subduction between the Jurassic ophiolite belt and the North American margin and consequently concur with the school of thought that considers that the ophiolite belt, as well as the underlying subduction-accretionary Franciscan Complex, likely formed in the North American fore-arc. We collected paleomagnetic data to reconstruct the spreading direction of the Jurassic Californian ophiolites, by providing new paleomagnetic data from sheeted dykes of the Josephine and Mt. Diablo Ophiolites. These suggest a NE-SW paleo-ridge orientation, oblique to the North American margin which may be explained by partitioning of a dextral component of subduction obliquity relative to North America. We used this spreading direction in combination with published ages of the ophiolites and our restoration of the relative position of these ophiolites prior to post-Jurassic deformation to construct a ridge-transform system at which the Jurassic ophiolites accreted. The results will be used to evaluate which parts of the subduction systems that existed in the eastern Panthalassa Ocean may reside in the western US, and which parts may be better sought in the northern Canadian Segment or/and in the southern Caribbean region.</p>


2021 ◽  
Vol 8 ◽  
Author(s):  
Vilnis Frishfelds ◽  
Juris Sennikovs ◽  
Uldis Bethers ◽  
Jens Murawski ◽  
Andrejs Timuhins

This study investigates a water transport features by extending Copernicus Marine Environment Service (CMEMS) to the Liepaja coast-port-channel-lake system with a two-way nested model. The Liepaja lake and Liepaja port are connected by Trade channel. The Liepaja port has three gates—the openings in wave breakers connecting the port aquatory with the Baltic sea. Each of gates has a corresponding dredged channel for securing the navigation. A hydrodynamic model is set up to study the flow and water level in this system. The area of the port gates, port and Trade channel are resolved by 33 m grid. The model results are verified against currents and sea level observations inside/outside port, Trade channel and Liepaja lake. Results and observations show that strong currents occur in the Trade channel in case of rapid sea level change in Baltic sea despite the Trade channel is rather shallow at the connection with Liepaja lake. The northern part of the Liepaja lake gets filled with brackish water during storm surge events. The channel has notable alternating current also during a relatively calm weather due to the port seiches. Long and narrow shape of the channel implies the Helmholtz type oscillations between the lake and the port with a period in approximately semidiurnal range. Hydrodynamic simulations describe well these oscillations but the phase of hourly scale oscillations in the port may differ in case of weak external forcing. Water exchange is significantly increased by the transit (gate to gate) sea currents. This transit flow usually occurs between South or Central gate and the North gate carrying sea water into the port. Northward flow of the surface layer is more characteristic in the port aquatory due the prevailing south-western winds. There are intense morphological processes at the coastline and underwater slope near the Liepaja port due to a sandy western coastline of Latvia, long fetch of the waves and strong currents at the port gates. Liepaja port is one of the Latvian ports in HywasPort operational service of hydrodynamics, waves and siltation.


1971 ◽  
Vol 178 (1051) ◽  
pp. 151-160 ◽  

The spermatozoa of the giant octopus of the North Pacific, freshly removed from spermatophores, showed very little motility, but on dilution with sea-water or 2.7 % NaCl, followed by dialysis against either of these two media, they became intensely motile and remained so for several days at 2 to 10 °C. At higher temperatures, particularly above 25 °C, octopus spermatozoa lost their motility rapidly. At 35 °C, complete and irreversible loss of motility occurred within less than 1 min. The motility of octopus spermatozoa at 2 to 10 °C persisted under both anaerobic and aerobic conditions and did not require the presence of exogenous glycolysable sugar. The addition of spermatophoric plasma to a motile sperm suspension inhibited motility. Other inhibitors were sodium azide, 2, 4-dinitrophenol and ethylenediaminetetra-acetate, at 0.001 M concentrations. ATP, ADP and arginine phosphate have been identified and quantitatively measured in octopus spermatozoa. On prolonged incubation of motile sperm suspensions a t 3 °C, ATP and ADP did not decline appreciably, whilst arginine phosphate decreased considerably. The decrease was even more pronounced in sperm suspensions which had first been inactivated by short exposure to 35 °C, prior to prolonged incubation at 3 °C. Glycogen, the main carbohydrate store of octopus spermatozoa, remained at a high concentration even in sperm suspensions kept for 5 days at 3 °C, and there was no appreciable difference in that respect between a sample containing motile spermatozoa and one in which, at the outset of incubation, the spermatozoa were immobilized by heating to 35 °C.


1968 ◽  
Vol 25 (6) ◽  
pp. 1269-1284 ◽  
Author(s):  
Adam S. Bursa

Starch observed in arctic waters of Canada, in the Baltic and Mediterranean seas, in the North Atlantic and Indian oceans, and in the waters about Bermuda, the Virgin Islands, and Jamaica is formed mostly in Gymnodinioideae, benthic algae, and higher aquatic plants and rarely in planktonic Chlorophyceae. In these phytoflagellates the fragile pellicle breaks when there are critical changes in salinity, temperature, or pressure and is subsequently decomposed by bacteria. The starch retains its shape after destruction of the protoplast, and accumulates in large quantities in aquatic habitats. Standing crops of free starch grains mark past blooms and mass mortalities of phytoplankton. The largest potato-like starch grains found in the oceans appear to be derived from the ocellar lenses of Warnoviaceae.Though Protozoa and various herbivores may ingest free planktonic starch, they were not observed to digest it. Large standing crops of starch and monosaccharides derived from amylolysis may affect nutrition in some animals, and influence the optical and chemical properties of sea water. Amylogenesis in some dinoflagellates starts from chondriosomes which are specialized in this process. In Prorocentrideae starch is formed within the ectoplasmic reticulum.


2002 ◽  
Vol 3 (1) ◽  
pp. 5 ◽  
Author(s):  
V. ZERVAKIS ◽  
D. GEORGOPOULOS

The combination of two research projects offered us the opportunity to perform a comprehensive study of the seasonal evolution of the hydrological structure and the circulation of the North Aegean Sea, at the northern extremes of the eastern Mediterranean. The combination of brackish water inflow from the Dardanelles and the sea-bottom relief dictate the significant differences between the North and South Aegean water columns. The relatively warm and highly saline South Aegean waters enter the North Aegean through the dominant cyclonic circulation of the basin. In the North Aegean, three layers of distinct water masses of very different properties are observed: The 20-50 m thick surface layer is occupied mainly by Black Sea Water, modified on its way through the Bosphorus, the Sea of Marmara and the Dardanelles. Below the surface layer there is warm and highly saline water originating in the South Aegean and the Levantine, extending down to 350-400 m depth. Below this layer, the deeper-than-400 m basins of the North Aegean contain locally formed, very dense water with different θ /S characteristics at each subbasin. The circulation is characterised by a series of permanent, semi-permanent and transient mesoscale features, overlaid on the general slow cyclonic circulation of the Aegean. The mesoscale activity, while not necessarily important in enhancing isopycnal mixing in the region, in combination with the very high stratification of the upper layers, however, increases the residence time of the water of the upper layers in the general area of the North Aegean. As a result, water having out-flowed from the Black Sea in the winter, forms a separate distinct layer in the region in spring (lying between “younger” BSW and the Levantine origin water), and is still traceable in the water column in late summer.


2018 ◽  
Author(s):  
Manon Tonnard ◽  
Hélène Planquette ◽  
Andrew R. Bowie ◽  
Pier van der Merwe ◽  
Morgane Gallinari ◽  
...  

Abstract. Dissolved Fe (DFe) samples from the GEOVIDE voyage (GEOTRACES GA01, May–June 2014) in the North Atlantic Ocean were analysed using a SeaFAST-picoTM coupled to an Element XR HR-ICP-MS and provided interesting insights on the Fe sources in this area. Overall, DFe concentrations ranged from 0.09 ± 0.01 nmol L−1 to 7.8 ± 0.5 nmol L−1. Elevated DFe concentrations were observed above the Iberian, Greenland and Newfoundland Margins likely due to riverine inputs from the Tagus River, meteoric water inputs and sedimentary inputs. Air-sea interactions were suspected to be responsible for the increase in DFe concentrations within subsurface waters of the Irminger Sea due to deep convection occurring the previous winter, that provided iron-to-nitrate ratios sufficient to sustain phytoplankton growth. Increasing DFe concentrations along the flow path of the Labrador Sea Water were attributed to sedimentary inputs from the Newfoundland Margin. Bottom waters from the Irminger Sea displayed high DFe concentrations likely due to the dissolution of Fe-rich particles from the Denmark Strait Overflow Water and the Polar Intermediate Water. Finally, the nepheloid layers were found to act as either a source or a sink of DFe depending on the nature of particles.


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